• Title/Summary/Keyword: 질량평균

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Determination of phenol using solid-phase extraction and HPLC/MSD/FLD in water (고체상추출법과 HPLC/MSD/FLD를 이용한 수질중의 페놀 분석)

  • Lee, Taejoon;Park, Keun-Young;Pyo, Dongjin
    • Analytical Science and Technology
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    • v.28 no.6
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    • pp.370-376
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    • 2015
  • An analytical method for determining phenol considered priority pollutants of the US EPA and precursor of toxic phenolic compounds by solid-phase extraction (SPE) and high performance liquid chromatographic systems (HPLC) equipped with fluorescence and mass selective detectors have been developed. The SPE process for sample preconcentration was performed on a commercially available Oasis HLB cartridge packed with polymeric sorbents. The effect of pH, elution solvent, and elution volume on the recoveries of the analytes were investigated with HPLC/FLD. Average recovery of >87.0% was achieved with 60 mg sorbents using 5 mL of methanol as an elution solvent at pH=3.

Control of Asymmetrical Tall Buildings under Wind Loading (비대칭 고층건물의 내풍 및 제진 해석)

  • 민경원;김진구;조한욱
    • Computational Structural Engineering
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    • v.10 no.2
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    • pp.203-211
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    • 1997
  • In the design of tall building system, the wind loading can be more dominant factor than earthquake loading, and thus, it is important to check the stability and human comfort against wind. Experimental wind tunnel test is usually performed to predict wind behavior of a tall building, however, the test is not cost-effective in the preliminary stage for various structural models of tall building systems. In this regard, the study is focused on the numerical wind analysis of the tall building with and without tuned mass dampers based on the three dimensional model of wind loads and building behavior. As a numerical result, an asymmetrical 102-story tall building is presented to show the results of root mean squares of build responses with and without tuned mass dampers.

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Nano-sized Silica를 이용한 Polymer bead의 대전 특성에 관한 연구

  • O, Yu-Mi;Kim, Seong-Un;Yun, Hae-Sang;Kim, Gyeong-Su;Park, Seon-U
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.202-202
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    • 2009
  • 대전제어제를 이용하여 전하량을 가지는 토너 입자를 제조하고, 입자의 유동성을 부여하기 위하여 입자의 표면처리를 하였다. 제조된 토너 입자의 크기는 약 $8{\mu}m$정도이며, 표면 처리를 위해 크기가 약 14nm 정도인 nano-silica를 사용하였다. 대전제어제가 첨가된 토너 입자의 평균 전하질량비는 30.9uC/g이고, 표면처리를 한 입자의 전하질랑비는 외첨 시간이 증가함에 따라 점차적으로 감소하는 것을 관찰 할 수 있었다. 또한 표면처리가 된 입자의 유동성은 표면처리를 하지 않은 입자 보다 우수하다는 것을 관찰 할 수 있었다.

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Topology Optimization in the Process of Conceptual Design (개념설계를 위한 토폴로지 최적화 기법)

  • 고병천
    • Journal of the KSME
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    • v.35 no.8
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    • pp.716-724
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    • 1995
  • 토폴로지 설계는 미리 형상이 결정되지 않은 새로운 개념의 제품을 설계하고자 할 때나 설계 경험이 풍부하지 못한 경우, 그 개념적 형상을 결정하는 데 매우 유용하다. 실제로 이러한 토폴 로지 설계의 결과를 최근 급속 시제품 제작기(rapid prototyping machine)와 함께 사용하게 되면 처음 개념설계에서 최초시제품의 형상을 예측하고 제작하는 데 많은 시간을 절약할 것으로 판 단된다. 그러나 토폴로지 최적화에 따른 구조물은 구조물의 한계 질량내에서 평균 강성이 가장 큰 구조물일 뿐, 국부적인 응력한계에 대한 최적화는 아니다. 따라서 최종적인 최적화 형상을 얻기 위해서는, 먼저 한계질량을 갖는 최적 토폴로지 구조물의 모델을 구하고, 이 모델에 대하여 설계변수에 따른 민감도 해석을 수행하여 최대응력의 한계값을 갖는 구조를 구하면 된다. 그림 10은 이러한 토폴로지 최적화와 민감도 해석을 통한 최적화를 수행하는 복합 최적설계 과정에 흐름도이다. 설계민감도 해석은 본 연구의 범위에 포함되지 않아서 여기서는 제외하였지만, 이에 관한 일반 상업화된 소프트웨어들이 많이 나와 있으므로 이를 참조하면 된다.

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경북 고령군 다산면 충적층 강변여과 취수 현장에 대한 수리 모델링

  • 원이정;김형수;구민호;백건하
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.401-404
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    • 2003
  • 경북 고령군 다산면의 충적층 강변여과 취수에 따른 수위변화 모델링을 시도하였다. 단순화된 2가지 모델을 기본으로 하여 1일 평균 1만 5천톤의 상수도 공급 시, 일정수두 유지를 위한 연간 취수 계획 및 적정 취수량을 검토하였다. 한편, 질량 균형(mass balance)을 통하여 모델 검증 및 시기별 하천수와 지하수의 유입 비율을 예비적으로 산정하였으며, 투수계수와 함양량 변화에 따른 지하수위의 민감도를 검토하였다. 하천수 유입 비율은 시기별로 65∼85% 범위를 갖는 것으로 나타났으며, 지하수위는 함양량 변화에는 둔감한 반면, 투수계수에 대해서는 상대적으로 민감한 것으로 평가되었다.

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General Derivation of Two-Fluid Model (2상 유동 모델의 일반적인 유도)

  • Hee Cheon No
    • Nuclear Engineering and Technology
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    • v.16 no.1
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    • pp.1-10
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    • 1984
  • General time-volume averaged conservation equations and jump conditions for two-phase flows are derived here. The time-averaged equations for a single phase region in two-phase flow are obtained from local instant balance equations by a technique often used for single phase turbulent flow equations. The results obtained by integrating the time averaged equations over a flow volume are spatially averaged twice; first, they are averaged over a single phase region of the k-th phase and then averaged over the total volume of the k-th phase, in a flow volume. The mass, momentum, and energy conservation equations are obtained from the general time-volume averaged equations. The advantages of the present model are explained by comparing it with Ishii's model (1) and Banerjee's model (2). Finally, the assumptions and approximate terms of the equations of the THERMIT-6S are clarified.

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Combustion Characteristics of Orifice Size of Torch in a CVCC (토치 점화 장치의 오리피스 직경에 따른 연소특성 파악)

  • Kwon, Soon-Tae;Kim, Hyeong-Sig;Choi, Chang-Hyeon;Park, Chan-Jun;Ohm, In-Young
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2010.04a
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    • pp.59-63
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    • 2010
  • Seven different size of orifice were applied in a constant volume combustion chamber for evaluating the effects of torch-ignition on combustion. The initial flame development and flame propagation were analyzed by the mass fraction burn and combustion enhancement rate. The combustion pressures were measured to calculate the mass fraction burn and the combustion enhancement rates. In addition, the flame propagations were visualized by the shadowgraph method for the qualitative comparison. The result showed that the combustion pressure and mass burned fraction were increased when using the torch-ignition device. The combustion enhancement rates of torch-ignition cases were improved in comparison with conventional spark ignition. Finally, the visualization results showed that the torch-ignition induced faster burn than conventional spark ignition due to the earlier transition to turbulent flame and larger flame surface, during the initial stage.

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Mass Loss and Air Entrainment Rate of Whirl Fire by Height of Fire Source (화점높이 변화에 따른 Whirl Fire의 질량감소 및 공기유입속도)

  • Park, Hyung-Ju
    • Fire Science and Engineering
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    • v.25 no.2
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    • pp.126-131
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    • 2011
  • This study is intended to understand mass loss rate and air entrainment rate of the whirl fire by height of fire source. Liquid fuels were methanol and n-Heptane which are used in many studies of whirl fire. Size of vessel was 100 mm ${\times}$ 100 mm ${\times}$ 50 mm and the vessel was made by stainless steel. When height of fire source changed from 0 cm to 30 cm, air entrainment rate showed the fastest in case of 0 cm. And in the same height of fire source, average and maximum air entrainment rate showed the fastest in 30 cm of anemometer. From the results of whirl fire for methanol and n-Heptane, mass loss rate and air entrainment rate of n-Heptane was found to faster 1.33 to 1.58 times and 4.38 to 5.44 times compared with methanol, respectively. Consequently, mass loss rate and air entrainment rate in whirl fire was able to identified decrease as height of fire source increases and the higher the heating value, increases the that's value.

The Study of PM10, PM2.5 Mass Extinction Efficiency Characteristics Using LIDAR Data (라이다 데이터를 이용한 PM10, PM2.5 질량소산효율 특성 연구)

  • Kim, TaeGyeong;Joo, Sohee;Kim, Gahyeong;Noh, Youngmin
    • Korean Journal of Remote Sensing
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    • v.37 no.6_2
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    • pp.1793-1801
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    • 2021
  • From 2015 to June 2020, the backscattering coefficients of 532 and 1064 nm measured using LIDAR and the depolarization ratio at 532 nm were used to separate the backscattering coefficient at 532 nm as three types as PM10, PM2.5-10, PM2.5 according to particle size. The mass extinction efficiency (MEE) of three types was calculated using the mass concentration measured on the ground. The overall mean values of the calculated MEE were 5.1 ± 2.5, 1.7 ± 3.7, and 9.3 ± 6.3 m2/g in PM10, PM2.5-10, and PM2.5, respectively. When the mass concentration of PM10 and PM2.5 was low, higher than average MEE was calculated, and it was confirmed that the MEE decreased as the mass concentration increased. When the MEE was calculated for each type according to the mixing degree of Asian dust, PM2.5-10 was twice at pollution aerosol as high as 2.1 ± 2.8 m2/g, compare to pollution-dominated mixture, dust-dominated mixture, and pure dust of 1.1 ± 1.8, 1.4 ± 3.3, 1.1 ± 1.5 m2/g, respectively. However, PM2.5 MEE showed similar values irrespective of type: 9.4 ± 6.5, 9.0 ± 5.8, 10.3 ± 7.5, and 9.1 ± 9.0 m2/g. The MEE of PM10 was 5.6 ± 2.9, 4.4 ± 2.0, 3.6 ± 2.9, and 2.8 ± 2.4 m2/g in pollution aerosol (PA), pollution-dominated mixture (PDM), dust-dominated mixture (DDM), and pure dust (PD), respectively, and increased as the dust ratio value decreased. Even if the same type according to the same mass concentration or Asian dust mixture was shown, as the PM2.5/PM10 ratio decreased, the MEE of PM2.5-10 decreased and the MEE of PM2.5 showed a tendency to increase.

Characteristics of Atmospheric Dry Deposition of Nitrogen-containing Compounds (대기 중 질소산화물의 건식침적 특성)

  • Yi, Seung-Muk;Han, Young-Ji;Cheong, Jang-Pyo
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.775-784
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    • 2000
  • Nitrate dry deposition fluxes were directly measured using knife-leading-edge surrogate surface (KSS) covered with greased strips and a water surface sampler (WSS). The average gaseous flux ($8.3mg/m^2/day$) was much higher than the average particulate one ($3.0mg/m^2/day$). The best fit gas phase mass transfer coefficient (MTC) of $HNO_3$ was obtained by linear regression analysis between measured gaseous flux containing nitrogen compounds and measured ambient $HNO_3$ concentration. The result showed that the MTCs of $HNO_3$ were approximately two times higher than those of $SO_2$. Especially, during the ozone action day, measured gaseous fluxes containing nitrogen compounds were much higher than those ones calculated as the product of measured ambient $HNO_3$ concentration and gas phase MTC of $HNO_3$, which is calculated from MTC of $SO_2$ using Graham's diffusion law. This result indicated that other nitrogen compounds except $HNO_3$ contributed to gaseous flux containing nitrogen compounds into the water surface sampler. The theoretical calculations suggest the contributions of nitrous acid ($HNO_2$) and PAN to the gaseous dry deposition flux of nitrogen containing compounds to the WSS.

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