• Title/Summary/Keyword: 진동흡수기

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A study on the identification of turquoise by FT-IR (FT-IR을 이용한 터키석의 감별에 관한 연구)

  • Kim Young-Chool
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.6
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    • pp.272-276
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    • 2004
  • Inorganic materials, including gemstones, also have characteristic vibrational energies in the infrared that can be used for identification. For infrared spectroscopy, absorptions associated with the vibrations of the crystal structure (lattice vibrations) are characteristic of the given combination of atoms constituting the gemstone. Natural turquoise $CuAl_6(PO_4)_4\cdot(OH)_8\cdot 5H_2O$ can be distinguished easily from its common substitutes in the infrared range 2000~450$\textrm{cm}^{-1}$ by features in the mid-infrared. Gilson turquoise, which is a synthetic, exhibits a significantly smoother pattern when compared with natural turquoise, because of a different state of aggregation. Also, because the natural turquoise and gibbsite are so different chemically, their patterns are very different. The technique, which is infrared spectroscopy, is nondestructive and, with Fourier transform instrumentation, extremely rapid.

Preconcentration and Determination of Trace Cobalt and Nickel by the Adsorption of Metal-PDC Complexes on the Anion-Exchange Resin Suspension (금속-PDC 착물의 음이온교환 수지 상 흡착에 의한 흔적량 코발트와 니켈의 동시 예비농축 및 정량)

  • Han, Chul-Woo;In, Gyo;Choi, Jong-Moon;Kim, Sun Tae;Kim, Young-Sang
    • Analytical Science and Technology
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    • v.13 no.5
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    • pp.608-615
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    • 2000
  • A determination method of trace nickel and cobalt in water samples was studied and developed by adsorbing their complexes on ion exchange resin suspension. The analytical ions were formed as complexes with a ligand of APDC (ammonium pyrrolidinedithiocarbamate) and adsorbed on anion exchange resin of Dowex 2-X8. After the suspension was filtered out with membrane filter, the complexes were dissolved in HCl solution by an ultrasonic vibrator for ET-AAS determination. Several conditions were optimized as followings. pH of sample solution: 5.0, amount of ligand APDC: more than 430 times in mole ratio, the type and concentration of acid: 0.1 M HCl, and vibration time: 7 minutes. The addition of palladium in the HCl solution could improve the reproducibility and sensitivity by a matrix modification in the absorbance measurement. This procedure was applied for the analysis of three kinds of real water samples. The detection limits equivalent to 3 times standard deviation of blank were Co 0.36 ng/mL and Ni 0.27 ng/mL and recoveries in spiked samples were 99-102% for cobalt and 100-105% for nickel.

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Isobaric Vapor-Liquid Equilibrium of 1-propanol and Bromochloromethane System at Subatmospheric Pressures (감압하에서 1-propanol과 Bromochloromethane의 정압 기-액 평형)

  • Jang, Hoi-Gu;Kang, Choon-Hyoung
    • Applied Chemistry for Engineering
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    • v.21 no.3
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    • pp.295-300
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    • 2010
  • A binary system of 1-propanol and bromochloromethane which exhibits an azeotropic point and a considerable nonideal phase behavior probably due to the large boiling point difference is not amenable in the actual chemical processes such as the distillation tower and absorber. Therefore, experimental data of phase behavior data of this mixture are indispensable in understanding the inherent thermodynamic characteristics for an efficient application of the system in the industrial processes. In this work, the isobaric vapor-liquid equilibrium of a binary mixture consisting of 1-propanol and bromochloromethane was measured by using a recirculating equilibrium cell at various pressures ranging from 30 to 70 kPa. The measured VLE data were correlated in a satisfactory manner by using the UNIQUAC and NRTL models along with the thermodynamic consistency test based on Gibbs/Duhem equation. In addition, the excess molar volume of the mixture was also measured by using a vibrating densitometer and correlated with a Redlich-Kister polynomial.

Characteristic comparison analysis of the green tourmalines from Myanmar and other deposits (미얀마와 타산지 녹색 투어말린의 특성비교 분석)

  • Kim, Kyung-Jin;Chung, Chae-Min;Ahn, Yong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.1
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    • pp.39-46
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    • 2014
  • The green tourmalines from Kayah state, Myanmar were investigated by WD X-ray fluorescence, UV-vis, and mid-infrared spectroscopy for comparison to tourmalines of other deposits. The group of tourmaline was calculated and classified by chemical analysis. The samples belonged to the Calcic group and Uvite. The green tourmalines showed a strong absorption band at 415 and 611 nm. The presence of $V^{3+}$ ions is responsible for these absorption bands. Combination of the stretching and bending mode by the vibration between cationic and hydroxyl units (metal-OH) are observed in the 4600 ~ 4200 $cm^{-1}$.

Frequency stabilization of laser and absolute wavelength measurement of 13C2H2 for DWDM system (13C2H2 분자를 이용한 반도체 레이저 주파수 안정화 및 그 파장 측정)

  • 문한섭;서호성;이인원
    • Korean Journal of Optics and Photonics
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    • v.13 no.2
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    • pp.123-127
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    • 2002
  • We have measured the wavelengths of the absorption lines of the $^{13}$ C$_2$H$_2$molecule by using a wavelength meter calibrated against the national optical frequency standard (iodine Stabilized He-Ne Laser, KRISS-R701) in the visible wavelength region. To measure the absolute wavelengths of the absorption lines, the frequency of the laser has been stabilized in the peaks and the sides of the absorption lines of $^{13}$ C$_2$H$_2$. Also, we have proposed the development of a frequency standard source of ITU-T grid using stabilization in the sides of the absorption lines of $^{13}$ C$_2$H$_2$.

DATA and FT-IR absorption spectra of PbO-Bi2O3-B2O3-SiO2 glasses (PbO-Bi2O3-B2O3-SiO2 유리계 열시차분석과 FT-IR 흡수 스펙트럼)

  • Lee, Chan-Ku;Lee, Su-Dae
    • Journal of Korean Ophthalmic Optics Society
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    • v.8 no.1
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    • pp.17-22
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    • 2003
  • The experimental FT-IR spectra and DTA curves of the $PbO-Bi_2O_3-B_2O_3-SiO_2$ glasses have been investigated. The composition ratio dependence of glass transition temperature showed that the structure of this glass system changes at 60 mol% $Bi_2O_3$. We have observed that the FT-IR spectra of the investigated samples with high bismuth content are dominated by bands associated to the structural units of the heaviest cation, $Bi^{3+}$ and the boron atoms in the treated samples are three and four coordinated even for very high $Bi_2O_3$ content. The low intensity of these non-bridging oxygen bands, for high PbO content glasses, can be attributed to the strong network-forming roles of PbO. The glasses absorption bands exhibited a greater change in intensities on crystallization.

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Infrared Spectroscopic Studies on Dickite and Pyrophyllite: Far-IR and Mid-IR Regions (딕카이트와 엽납석에 대한 적외선 분광학적 연구: 원적외선 및 중간적외선 영역)

  • 추창오;김수진
    • Journal of the Mineralogical Society of Korea
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    • v.14 no.2
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    • pp.119-127
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    • 2001
  • FTIR spectroscopic study was undertaken on dickite and pyrophyllite with Si and Al cations in the far-infrared(Far-IR) and mid-infrared (Mid-IR) regions, respectively. Attempts were made to present bonding information and make assignments on the absorption bands of dickite in the Far-IR region. Dickites contain a small proportions or kaolinite or nacrite layers. FTIR can be used as a potential tool for characterizing the presence of mixed-layer with different polytypes of the kaolin minerals. There is no clear relationship between Hinckley index and crystallinity of dickite. Although pyrophyllite shows a strong OH stretching band at 3673-3676 $cm^{-1}$ / corresponding to an inner hydroxyl group, the weak band at $3645-3648 cm^{-1}$ seems to be due to the symmetric vibration if the symmetry of the structure is not ideal, probably due to the presence of trace Fe or mixture phases of 1Tc and 2M polytypes.

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On the Calibration of Impact Hammer Sensitivity (충격 해머의 감도보정)

  • 한상보
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1991.04a
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    • pp.71-74
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    • 1991
  • 구조물의 진동특성을 파악하기 위한 실험적 모우드 해석법에서 기진력을 제 공하는 한 방법으로 힘 측정기가 부착된 해머를 이용한 충격시험기법이 널 리 사용되고 있다. 충격해머 시험의 유용성은 기진력의 에너지가 정현파 기 진력의 경우처럼 특정 주파수대에 산재해 있는 것이 아니라 가용 주파수 영 역내에 연속적으로 분포해 있다는 점이며 이러한 충격력은 가용 주파수 범 위내에 있는 모든 고유진동형을 여가시킬 수 있다는 장점이 있다. 충격헤머 가 가지고 있는 동적특성은 구조물을 가진시키는 선형충격량의 크기를 결정 하며, 이는 다시 충격력의 크기와 가용 주파수 범위를 결정하게 된다. 일반 적으로 가진주파수 범위는 해머의 질량에 반비례하고 충격해드의 경도에 비 례하는 것으로 알려져 있다. 해머의 질량 자체가 충격력의 크기를 좌우하기 도 하므로, 가진력의 크기를 고려하여 해머의 질량이 선택되며 충격헤드는 충격시간을 조절하기 위하여 적절히 선택된다. 충격해머에 장착된 힘측정기 의 감도는 해머질량과 충격헤드의 질량 변화에 영향을 받게 되는데, 충격 시 험시 측정되는 값은 해머에 부착되어 있는 힘측정기에 가해지는 힘인 반면 구조물에 가해지는 기진력은 충격해드와 구조물사이에 발생되는 힘이다. 이 두 힘의 비는 해머 및 충격해드의 질량효과에 따라 좌우된다. 주어진 충격시 험에서 충격해머의 질량효과를 정확히 조건에 따라 감도보정을 해 주어야 한다. 충격해머의 감도보정에 대해서는 문헌[2]에 잘 나타나 있다. 본 논문에 서는 전압감도에 미치는 영향을 파악하고자 질량 효과를 고려한 수학적 모 형을 제시하고 그 모형의 타당성을 실험을 통해 검정하고자 한다.방법 을 제시하였다. 이와 아울러 제어계의 환경변화에 따른 파라메타의 변화에 적응적으로 응답이 가능해야 하는 적응 소음제어 시스템에서, 음향궤환과 함 께 필히 고려해야 하는 부가적인 전달함수의 영향을 고려한 능동 소음제어 에 대해 연구하였다. 경량화 추세에 따라 지반이나 케이싱이 경량이거나 유연하여 회전축과 동적으로 연성된 경우 회전축-베어링-지반으로 이루어진 2중구조의 회전축 계 동특성을 해석할 수 있는 프로그램을 개발하므로서 회전 기계류의 진동 전반에 걸친 문제점에 대한 그 원인과 현상을 명확히 분석하여 국내의 전기 계류의 보다 신뢰성있는 설계 및 제작자료를 확보하는데 기여할 수 있게 하 였다.존의 small molecular Gd-chelate에 비해 매우 큼을 알 수 있었다. MnPC는 간세포에 흡수된 후 담도계로 배출되는 간특이성 조영제임을 확인하였다. 장비 내에서 반복 시행한 평균값의 차이는 대체적으로 유의한 차이가 없었으나, 다른 장비에서 반복 시행한 장비간의 사이에는 유의한 차이가 있는 경우가 더 많았다. 따라서 , MRS 검사를 소뇌나 뇌교의 어떤 절환에 적용하기 전에 각 장비 마다 정상 기준치를 반드시 얻은 후에 이상여부를 판 정하는 것이 필수적이라고 생각된다.EX> 이상이 적절한 진단기준으로 생각되었다. $0.4{\;}\textrm{cm}^3$ 이상의 좌우 부피차를 보이는 모든 증례에서 육안적으로도 해마위축이 뚜렷이 나타났다. 결론 : MR영상을 이용한 해마의 부피측정은 해마경화증 환자의 진단에 있어 육안적인 MR 진단이 어려운 제한된 경우에만 실제적 도움을 줄 수 있는 보조적인 방법으로 생각된다

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Vibration Characteristics and Topology Optimization of a Double Damper Lock-Up Clutch in a Torque Converter System (토크컨버터 장착 이중댐퍼 체결클러치의 진동특성해석 및 위상최적화)

  • Kim, Kwang-Joong;Kim, Cheol
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.8
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    • pp.1129-1136
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    • 2010
  • Damper springs in a drive-line absorb the impulsive torque generated when a lock-up clutch is connected directly, instead of via a fluid coupling. Design optimization and finite element analysis were performed to improve the shock- and vibration-absorption capacity of the lock-up clutch. For this purpose, a multi-body dynamics model was developed by including the main parts of a vehicle, such as an engine with a clutch, a transmission, drive shafts and wheels, and a whole mass of a vehicle. The spring constants were selected so that resonance of a system could be avoided. Damper springs were optimized on the basis of the spring constants, impulsive torques, compressed angles, spring counts, fatigue constraints, etc. Topology optimization was performed for three plates with the damper springs. The compliance was set up as an objective function, and volume fraction was fixed below 0.3. A new shape for the plates was proposed on the basis of the topology result.

A Study on the Floating OWC Chamber Motion in Waves (부유기 OWC 챔버의 파중 운동해석)

  • 홍도천
    • Journal of Ocean Engineering and Technology
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    • v.16 no.3
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    • pp.19-27
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    • 2002
  • The motion of a floating OWC chamber in waves is studied taking account of fluctuating air pressure in the air chamber. An atmospheric pressure drop occurs across the upper opening of the chamber which causes not only hydrodynamic but also pneumatic added mass and damping forces to the floating chamber. A velocity potential in the water due to the free surface oscillating pressure patch is added to the conventional radiation-diffraction potential problem. the potential problem inside the chamber is formulated by making use of the Green integral equation associated with the Rankine Green function wile the outer problem with the Kelvin Green function. The two integral equations are solved simultaneously by making use of a matching boundary condition at the lower opening of the chamber to the outer water region. The chamber motion in the frequency domain is calculated for various values of parameters related to the atmospheric pressure drop. The present methods can also be sued for the analysis of air-cushion vehicle motion as well as for the design of a floating OWC wave energy absorber.