• Title/Summary/Keyword: 진동반응

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Vibration-to-Vibration Energy Transfer Between HF and DF in the Mixture (HF와 DF 혼합계내에서의 상호간 진동-진동 에너지 이동)

  • Chang Soon Lee;Yoo Hang Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.1
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    • pp.26-33
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    • 1984
  • The rate constants for the following vibration-to-vibration energy exchange reactions have been calculated theoretically for the temperature range from 300 to 800K and for n = 2 to 5. HF(v=n) + DF(v=0) ${\to}$ HF(v=n-l) + DF(v=l) + ${\Delta}E$(a) DF(v=n) + HF(v=0) ${\to}$ DF(v=n-l) + HF(v=l) + ${\Delta}E$(b) In calculation the loosely-held, non-rigid dimer collision model and semiclassical method have been employed. The results show that the rate constants for the processes (a) are much greater than those for the processes (b). Also, it is found that the rate constants for the processes (a) increase with decreasing temperature and with increasing quantum number, while those for the processes (b) show the opposite tendencies. These findings are explained in terms of the sign and magnitude of the energy mismatch, ${\Delta}E$.

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The Implementation of Interrupt-based method to transmit in USN (Interrupt 기반의 반응 속도가 향상된 센서 데이터 전송 방법 구현)

  • Lee, Min-Goo;Kang, Jeong-Hoon;Lim, Ho-Jung;Yoon, Myung-Hyun
    • Proceedings of the KIEE Conference
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    • 2008.10b
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    • pp.546-547
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    • 2008
  • 본 논문은 무선 센서 네트워크 플랫폼을 이용한 어플리케이션 개발 과정에서 비규칙적인 센싱 데이터의 획득 후 빠른 시간 내에 이를 전송하기 위한 효율적인 방법에 대한 고찰에서 시작되었다. 개발과정에서 진동 센서를 채택하여 이원화된 메시지 전송 프로세스를 구현하였다. 즉, 진동센서의 불규칙 센싱 완료 인터럽트 발생에 따른 메시지 전송 프로세스와 타이머에 의한 주기적인 진동 센싱 및 메시지 전송 프로세스로 동작할 수 있는 방법을 구현하였다. 따라서 본 논문에서는 인터럽트 기반의 센싱 데이터 전송방법과 주기적인 센싱 데이터 전송방법에 대한 비교 분석을 통해 반응속도 측면에서 인터럽트 기반의 센싱 데이터 전송 방법이 더욱 효율적인 데이터 전송 프로세스임을 보여주고자 한다.

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Characteristics of Transformed Vibration Level According to Vibration Characteristics (진동특성에 따른 수직보정 진동레벨의 변환 특성 연구)

  • 양형식;박경준
    • Explosives and Blasting
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    • v.21 no.1
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    • pp.77-84
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    • 2003
  • 발파진동은 보통 지반진동속도로 계측되며, 발파설계나 구조물의 피해 산정에 사용된다 그러나 인체의 반응-이나 가축의 피해 산정 문제에서는 현행 소음진동규제법과 관련하여 인체의 감각적 감응척도에 따른 진동레벨을 주로 사용하므로 변환이 필요하다. 본 연구에서는 디지털 필터에 의한 진동레벨 변환 프로그램을 이용하여 진동의 특성이 따른 진동레벨 변환의 특성을 고찰하고 문제점을 제시하였다.

A Vibration Response Analysis of Steel Building Frame with K Shape Brace Vibrationally Controlled by Turbulent Flow Dampers sealed by Visco-elastic Material (점탄성물질 난류댐퍼를 이용한 K형 철골 브레이스 골조의 진동응답해석)

  • Lee, Ho
    • Journal of Korean Association for Spatial Structures
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    • v.6 no.2 s.20
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    • pp.61-68
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    • 2006
  • In this thesis, a full-scale K shape damper test model was constructed in which a passive vibration control system. This passive vibration control system was incorporated with the use of a newly developed turbulent flow damper sealed by viscoelastic material. A series of tests and earthquake observation has been conducted in this test model. The purpose of the present thesis is to investigate the vibration response characteristics of the building and to verify the effectiveness of the vibration control system. By the static loading test, it was recognized that incorporation of the dampers had little influence on static horizontal stiffness of the building. Free vibration tests revealed that the dampers incorporated increased the damping ratio of the building up to 3 times compared with the undamped case. The effectiveness of the developed vibration control system was confirmed based on the excitation tests and earthquake response observation.

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A Study on the Reduction of Nitric Oxide Molecule (NO) to Nitroxyl Anion (NO-) by Vibrational Energy (진동에너지에 의한 산화질소 분자(NO)의 음이온(NO-)으로의 환원반응에 관한 연구)

  • Cho, Seon-Woog
    • Journal of the Korean Chemical Society
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    • v.46 no.1
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    • pp.14-18
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    • 2002
  • It is shown that one-electron reduction of nitric oxide (NO) to nitroxyl anion $(NO^-)$ can be accelerated by vibrational energy. Potential energy surfaces of NO and $NO^-$ reveal that the vertical transition between them has favorable energetics for vibrationally excited molecule. Also, Franck-Condon factors between NO and $NO^-$ vibrational wave functions are calculated. It shows that the number of open channels increases with increased vibrational energy. These results mean that we can control the rate of reduction of NO to $NO^-$ by radiating an appropriate light.

차량산업에서의 인체진동

  • 장한기
    • Journal of KSNVE
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    • v.12 no.2
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    • pp.113-119
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    • 2002
  • ‘인체진동(human vibration)’은 진동에 대한 인체의 반응(human response to vibration)의 줄임말로써, 환경으로서의 진동 및 충격이 인체에 미치는 물리적, 심리적 영향을 측정, 평가하는 것을 주요 연구대상으로 한다. 인체진동 분야의 주요 연구개발은 객관적인 물리량의 산출뿐만 아니라 주관적인 느낌을 수치화하는 작업을 포함하기 때문에 기계진동, 생체역학(biodynamics)과 기본적인 역학과 심리측정학(psychometrics), 심리물리학(psychophysics), 인간공학(ergonomics) 등과 같이 다양한 종류의 학문이 요구된다.(중략)

Introduction to Electrochemical Quartz Crystal Microbalance Technique for Leaching Study of Metals (금속 침출연구를 위한 전기화학적 미소수정진동자저울 기술 소개)

  • Kim, Min-seuk;Chung, Kyeong Woo;Lee, Jae-chun
    • Resources Recycling
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    • v.29 no.1
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    • pp.25-34
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    • 2020
  • Electrochemical Quartz Crystal microbalance is a tool that is capable of measuring nanogram-scale mass change on electrode surface. When applying alternating voltage to the quartz crystal with metal electrode formed on both sides, a resonant frequency by inverse piezoelectric effect depends on its thickness. The resonant frequency changes sensitively by mass change on its electrode surface; frequency increase with metal dissolution and decrease with metal deposition on the electrode surface. The relationship between resonant frequency and mass change is shown by Sauerbrey equation so that the mass change during metal dissolution can be measured in real time. Especially, it is effective in the case of reaction mechanism and rate studies accompanied by precipitation, volatilization, compound formation, etc. resulting in difficulties on ex-situ AA or ICP analysis. However, it should be carefully considered during EQCM experiments that temperature, viscosity, and hydraulic pressure of solution, and stress and surface roughness can affect on the resonant frequency. Application of EQCM was shown as a case study on leaching of platinum using aqueous chlorine for obtaining activation energy. A platinum electrode of quartz crystal oscillator with 1000 Å thickness exposed to solution was used as leaching sample. Electrogenerated chlorine as oxidant was purged and its concentration was controlled in hydrochloric acid solution. From the experimental results, platinum dissolution by chlorine is chemical reaction control with activation energy of 83.5 kJ/mol.

Dependency of Dynamic Behavior of Circular Foundation on Ground and Foundation Characteristics (지반 및 원형기초의 특성이 기초의 동적거동에 미치는 영향)

  • Ahn, Jae-Hun
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.2
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    • pp.111-117
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    • 2008
  • The effect of characteristics of ground and circular foundation on the dynamic behavior of the foundation in vertical motion are considered using an approximated analytical solution and a finite element analysis with absorbing (consistent transmitting) boundary. The shear wave velocity of homogeneous ground affects the resonant frequency of the foundation much but has nothing to do with the maximum response amplitude at resonant frequency. The density in this case affects both the resonant frequency and the maximum response. The size and the mass of the circular foundation are related both to the resonant frequency and the maximum response. However, Poisson's ratio has very little effect on dynamic behavior of the foundation. When the ground is not homogeneous but has the layers, different formations of shear wave velocities would also change the maximum response at resonant frequency.