• Title/Summary/Keyword: 중합체

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Separation of Colloidal Particles By Flow Field-Flow Fractionation Using Hollow Fibers For Ultrafiltration

  • 이향수;신세종;이원주;민병렬
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.04b
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    • pp.59-61
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    • 1997
  • 최근 신소재에 관한 연구는 첨단기술 발전에 주요한 역할을 하고 있음은 주지의 사실이며, 특히 다목적, 다기능 고분자는 여러 분야에 활용되므로 이에 관한 집중적인 연구가 활발히 진행되고 있다. 고분자는 보통 화합물과는 달리 여러 분자량의 중합체가 분포되어 있으므로 물리-화학적 특성을 알아내기가 힘들뿐만 아니라, 이러한 고분자 물질의 분자량, 분자량 분포 등의 정보가 폭 넓게 파악되어야만 그 물질의 정확한 활용과 소재 개발이 가능하다. 특히 protein 등과 같은 생체 고분자들은 유전, 특정 반응에 작용하는 효소, 호르몬 등 수많은 연구가 진행 중에 있으나 그 분리.정제 과정은 상당히 어려우며, 경우에 따라서는 분리. 정제 과정에서 활성을 잃은 경우도 있다. 따라서 이러한 고분자들의 물성을 확인하는 과정이 최우선적으로 필요하다.

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Liquid Crystal Alignment Effects on the New Homopolymerized N-(phenyl)male iron ids Photopolymer Surface (새로운 광중합법을 이용한 N-(phenyl)maleimide 단독 중합체 광폴리머 표면을 인용한 액정 배향 효과)

  • 황정연;서대식;김준영;김태호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.117-120
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    • 2001
  • A new photoalignment material PFCPMI, poly [4-(fluorocinnamate) phenylmaleimide], was synthesized and the nematic liquid crystal (NLC) aligning capabilities on the photopolymer surface. The NLC pretilt angle generated by non-UV filter method on the PFCPMI surface was higher than that of the UV filter method. A good LC alignment by non-UV filter method was observed at 150\`c of annealing temperature. However, the alignment defect of the NLC by UV filter method was measured above 150$^{\circ}C$ of annealing temperature. Consequently, the high pretilt angle and the good LC alignment in NLC using non-UV filter method can be achieved.

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Liquid Crystal Alignment Effects on the Homopolymerized N-(phenyl) maleimide Photopolymer (N-(phenyl)maleimide 단독 중합체 광폴리머를 이용한 액정 배향 효과)

  • 황정연;김준영;이윤건;서대식;김태호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.423-428
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    • 2002
  • The photoalignment material PFCPMI, poly[4-(fluorocinnamate)phenylmaleimide], was synthesized and the nematic liquid crystal(NLC) aligning capabilities on the photopolymer surface. The NLC pretilt angle geneated by non-UV filter method on the PFCPMI surface was higher than that of the UV filter method. A good LC alignment by non-UV filter method was observed at $150^{\circ}C$ of annealing temperature. However, the alignment defect of the NLC by UV filter method was measured above $150^{\circ}C$ of annealing temperatue. Consequently, the high pretilt angle and the good LC alignment in NLC using non-UV filter method can be acheived.

A Research Trend on Space Charge Analysis in Polymer Irradiated by Electron Beam (전자빔 조사에 의한 중합체 내의 공간 전하 분석 연구 동향)

  • Kim, Byung-Woo;Lee, Hyung-Chul;Ahn, Jong-Hyun;Hwang, Jong-Sun;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1990-1991
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    • 2007
  • Spacecrafts such as most of commercial satellites that are operating in the geostationary orbit can be subjected to intense irradiation by charged particles. The surface made of dielectric materials can therefore become probable sites for damaging electrostatic discharges. Thanks to a specially equipped chamber, the spatial environment can be reproduced experimentally in the laboratory. In this paper, the behavior of high energy electrons injected in polymers such as PolyMethylMetaAcrylate (PMMA) and Kapton is studied. Results obtained by surface potential technique, pulse-electro acoustic device and a cell based on the split Faraday cup system are analyzed and discussed.

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Fabrication of a Micro fluidic Lens having variable focal length (가변 초점거리 마이크로 유체렌즈 제작)

  • Lee J.S.;Park J.G.;Kim G.M.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.10a
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    • pp.572-575
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    • 2005
  • A microlens connected to microfluidic channel is fabricated. The microlens is sealed with an elastomeric membrane which deforms by pressure of fluid driven by a syringe pump resulting in the shape change of the microlens. The optical properties of the microlens could be controlled by changing the microlens shape. The microlens system were made of an elastomer, PDMS, using molding from a photoplastic master patterned by UV photolithography. The test results show the optical property of the lens could be made into convex and concave type by applying the fluidic pressure positive and negative.

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Fatigue Behavior of Glassy Polymers by Ultrasonic NDE (초음파탐상법에 의한 유리질 중합체의 피로거동 해석)

  • Lee, O.S.;Rho, E.H.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.10 no.1
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    • pp.56-64
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    • 1990
  • It is well-known that the defects (existing in structures) and the material degradation(caused by the fatigue load) generally initiate the failure of structures. The NDE such as ultrasonic technique which can be used to detect the size and the orientation of defects has been utilized to estimate the life and stability of structures. However, only few experimental reports made by using the ultrasonic technique have been published for the case of fatigue estimation of materials and structures. The purpose of this study is, thus, to derive the relationship between ultrasonic attenuation and fatigue behavior of Polycarbonate and PMMA through ultrasonic characterization. It is also attempted to offer NDE experimental procedure which may be useful to predict fatigue life.

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A Study on Chemical Cyclodehydration of Aromatic Poly(ether-amide-amic acid)s (방향족 폴리(에테르-아미드-아미드산) 중합체의 화학적 탈수 고리화 반응)

  • Ahn, Young Moo
    • Textile Coloration and Finishing
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    • v.7 no.4
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    • pp.39-44
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    • 1995
  • A study has been made about some correlations in the chemical cyclization of precursors, poly(ether-amide-amic acid)s by treating in solution a mixture of acetic anhydride and pyridine in the presence of 4,4-dimethyl formamide, with the poly(ether-amic acid)s being respectively reacted between trimellitic anhydride chloride and 3 kinds of diamines, i.e., 4,4'-bis(m-aminophenoxy) benzophenone, 2,2'-bis[4-(m-aminophenoxy) phenyl] propane and 4,4'-bis(m-aminophenoxy) diphenyl sulfone. The cyclization of imide ring in the poly(ether-amide-amic acid)s may be regarded as an intramolecular acylation of amide group by o-carboxyl group. As a result of this reseach, the effects on the conversion to poly(ether-amide-imide)s have been found by changing the ratio of cosolvents in the cyclization mixture.

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Optimum micro dimple configuration on the elastomer seal surface (탄성중합체 시일 표면의 미세 딤플에 대한 최적설계)

  • Yoo, Dae-Won
    • Design & Manufacturing
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    • v.14 no.4
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    • pp.1-10
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    • 2020
  • The seal plays a role in preventing oil leakage when the lip and the rotating shaft come into contact with the fluid and air pressure. Recently, micro dimples or micro pockets are processed and used on the lubrication surfaces of thrust bearings, mechanical bearings, and piston rings. Compared to a smooth surface, micro dimples reduce friction and increase the life of parts. This paper analyzed various kinds of micro dimple shapes on the sealing surface, i.e. circle, rectangle, triangle, and trapezoid. For this purpose, Introduced the design of experiments to work out a micro dimple configuration, unlikely to be damaged from cracks and low in contact stress. As a result, the triangular dimple showed the best results. Optimal factors were dimple size 0.15 mm, dimple depth 0.0383 mm, dimple density 40%, and the maximum equivalent stress was 9.1455 MPa, and the maximum contact pressure was 9.6612 MPa. This paper analyzed the optimal shape of dimples by finite element analysis. As a research project, experiments and comparative analysis of micro dimple shapes are needed.

천연(天然)고무와 합성(合成) Cis-Polyisoprene 간(間)의 성질(性質) 비교(比較)

  • ;Bristow, G.M.;Campbell, J.M.;Farlie, E.D.
    • Elastomers and Composites
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    • v.3 no.1
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    • pp.62-74
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    • 1968
  • 천연(天然)고무 및 합성(合成) 고(高) cis 1 : 4 polyisoprene, 대표적(代表的)으로 'Natsyn 400'의 가공(加工), 배합(配合) 또는 가황체(加黃體)의 성질(性質)들의 차이점(差異點)들에 대(對)하여 설명(說明)하였다. 합성중합체(合成重合體)는 미리 소연(素鍊)함이 없이 충전제(充塡劑)를 첨가(添加)함으로서 가공(加工)이 용역(容易)하였으며 CV형(形) 천연(天然)고무에 있어서도 이점(利點)이 나타났다. 천연(天然)고무 배합물(配合物)은 점착성(粘着性)이 좋으며, 특(特)히 미가황물(未加黃物)의 강도(强度)가 현저(顯著)하게 우수(優秀)하다. 가황과정(加黃過程) 및 몇몇가황체(加黃體)의 성질(性質)에 있어서의 차이(差異)는 비(非)고무질(質)을 함유(含有)하지 않는 Natsyn으로 나타난다. 기타(其他)의 가황체성질(加黃體性質)의 차이(差異)는 천연(天然)고무에 있어서 그 가황체(加黃體)가 인장시(引張時)에 결정(結晶)하는 경향(傾向)을 크게 나타내고 있고 특(特)히 고온(高溫)에서 이들 차이(差異)가 현저(顯著)하다.

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Development of the Bubble-Damage Polymer Detector for Neutron Dosimetry (중성자 선량측정을 위한 Bubble-Damage Polymer Detector의 개발)

  • Kang, Y.H.;Hong, U.;Kim, D.S.
    • Journal of Radiation Protection and Research
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    • v.13 no.1
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    • pp.1-7
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    • 1988
  • A bubble-damage polymer detector, which operation principles are based on vaporization of superheated liquid drops by interaction with radiations, is developed for neutron dosimetry. The detectors are fabricated by dispersing the superheated liquid drops of Freon12 into transparent and elastic polymer made of acylamide and glycerine. The bubbles formed by neutron irradiation are immediately visible. The neutron sensitivity of the detectors is 4-7 bubbles/10$\mu$ Sv for Am-Be neutrons.

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