• Title/Summary/Keyword: 중금속 제거

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Removal of Heavy Metal Ions Using Wood Charcoal and Bark Charcoal (목탄 및 수피탄의 중금속 이온 제거)

  • Jo, Tae-Su;Lee, Oh-Kyu;Choi, Joon-Weon
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.4
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    • pp.29-37
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    • 2007
  • To evaluate the effect of carbonization temperature of charcoal on the heavy metal adsorption property, Quercus mongolica wood and Larix kaempferi bark powder (100~60 mesh) were carbonized at between 400 and $900^{\circ}C$ at intervals of $100^{\circ}C$. In the properties of carbonized materials which affect the adsorption ability, pH increased with increasing the carbonization temperature, so that the pHs of wood and bark charcoal carbonized at $900^{\circ}C$ were 10.8 and 10.4, respectively. Also, in both materials, the carbon content ratio became larger as the carbonization temperature was raised. At the same carbonization temperature, carbon content ratio of the bark charcoal tended to be greater than that of the wood charcoal. In case of iodine adsorption which indicates the adsorption property in liquid phase, the wood charcoal showed higher adsorption value than the bark charcoal. From the investigation of adsorptive elimination properties of the charcoals against 15 ppm Cd, Zn, and Cu, the higher the carbonization temperature, the greater elimination ratio was. In comparison, the wood charcoal presented higher elimination ratio than that of the bark charcoal. In the wood charcoals carbonized at higher than $500^{\circ}C$, especially, 0.2 g of the charcoal was enough to eliminated almost 100% of the heavy metal ions. Heavy metal ion elimination ratio of the charcoals depended on the kinds of adsorbates. The effectiveness of adsorbates in adsorptive elimination by the charcoals were in order of Cu > Cd > Zn. This is because the physicochemical interaction between the adsorbate and adsorbent affects their adsorption properties, it is considered that subsequent researches are needed to improve the effectiveness of heavy metal adsorption by the charcoals.

Removal of Zinc by Vortex Flow Separator as BMPs in Residential Area (도시주거지역 와류형 비점오염 저감시설에서의 Zn제거특성)

  • Lee, Seung-Chul;Ha, Sung-Ryong
    • Journal of Environmental Impact Assessment
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    • v.19 no.4
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    • pp.443-452
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    • 2010
  • 본 연구에서는 도시지역의 하나인 주거지역에서 배출되는 강우유출수 내에 중금속이 장치형 비점 오염저감시설 중에 하나인 와류형시설에서 제거되는 특성을 파악하고자, 대상 중금속을 Zn으로 삼고 2007년 4월부터 2008년 11월까지 모니터링을 수행하였다. 유출수 모니터링은 와류형 시설의 유입부와 유출부에서 유량과 수질을 각각 시간변화에 따라 측정하였으며, 시설유입부와 유출부, 그리고 시설하부에 쌓인 침전물을 채취하여 침전물 모니터링도 수행하였다. 그 결과, 높은 강우강도에서 발생된 강우유출수는 와류형 시설내에 HRT를 감소시켜 Zn의 제거효율이 낮게 관측되었으며, 특히 HRT가 20분이내의 조건이 될 경우에는 처리효과가 없는 것으로 확인되었다. Zn는 입자성물질과 밀접한 관계를 맺으며 제거되는 특성을 보였으며, 입자성물질이 스크린에 의한 여과 및 침전작용이 일어날 때 입자성물질에 부착되어 거동하는 특성을 보였다. 그 중에 0.075mm 이하의 미세한 입자에 부착된 고농도의 Zn는 제거되지 못하였고, 와류형 시설 후단에 후처리시설로서 저류시설을 두어 충분한 HRT를 제공한 결과, 와류형 시설만을 운전하였을 때와 비교하여 높은 제거특성을 보이게 되었다.

Resistance of Some Metal Ions on Growth of Serratia marcescens Strain P (Serratia marcescens Strain P 성장에 미치는 중금속 내성)

  • 유관희;이호용
    • Microbiology and Biotechnology Letters
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    • v.20 no.6
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    • pp.693-698
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    • 1992
  • The resistant effect of several heavy metal ions to Serratia marcescens strain P was studied by the method of minimal inhibitory concentration(MIC), and testing for their metal biosorption. S. marcescens strain P showed a good survival in the presence of high concentrations of some metal ions, namely cadmium, lead, iron, magnesium, and manganese. Copper had the most inhibitory effect among tested. The MIC value was ranged from 0.79 to 1.58 mM. Cells of S. marcescens strain P exhibit an abnormally long lag phase when incubated in high concentrations of zinc and cadmium. Pigment production was reduced by zinc and cadmium, but enhanced by lead and iron. S. marcescens strain P was resistant to ampicillin, tetracycline, cefamandole and chloramphenicol with minimal inhibitory concentration of 128 $\mu$g/ml, 32 $\mu$g/ml, 256 $\mu$g/ml, and 8 $\mu$g/ml, respectively. The kinetics study of biosorptive uptake by S. marcescens strain P revealed that 16.59% of cadmium and 35.38% of lead were eliminated from the media.

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Effect of Green Tea Beverage on the Removal of Cadmium and Lead by Membrane Filtration (막투과법에 의한 녹차음료의 카드뮴 및 납 제거효과)

  • Choi, Sung-Inn;Lee, Jung-Hi;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.26 no.6
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    • pp.740-744
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    • 1994
  • This study was undertaken to prove the suppressing effect of green tea on the intestinal absorption of heavy metals using in vitro membrane filtration system. From drinking water contaminated with 10 and 100 times level of water quality standard for heavy metals, the removal ratio of lead (Pb) was $50{\sim}70%$ by green and black teas, and $30{\sim}40%$ by roasted barley tea. The removal ratio of cadmium (Cd) was $30{\sim}40%$ by green tea and black teas, and $10{\sim}20%$ by roasted barley tea. The removal effect from drinking water contaminated with both lead and cadmium was lower than that from water contaminated singly with lead or cadmium. It appears that tea components and filter membrane compete toward the adsorption of two heavy metals. Among the extraction conditions of raw tea materials at $70^{\circ}C$, 2 minutes and $95^{\circ}C$ , 10 minutes, the removal ratios of heavy metals were similar.

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Organobentonite as a dual sorbent for Chlombenzene and Lead (클로로벤젠과 납의 동시 제거를 위한 흡착제로서의 유기 벤토나이트에 관한 연구)

  • 이정주;박재우;김일규
    • Journal of Soil and Groundwater Environment
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    • v.6 no.4
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    • pp.41-50
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    • 2001
  • The use of clay has been the favored method of reducing or eliminating hazardous contaminants in the leachate from landfills. But, neither natural clays nor organoclays modified with surfactants are able to effectively sorb both heavy metals and organic contaminants. Therefore, the objective of this study is to determine the optimal amount of surfactant added on the clay mineral to effectively remove both of them. For this purpose, Na-Bentonite as the natural clay, and hexadecyltrimethylammonium (HDTMA) as the cationic surfactant were used, Chlorobenzene and lead ($Pb^{2-}$) were selected as representative contaminants. Experimental result showed that chlorobenzene sorption increased with increasing HDTMA to bentonite, ratios. On the contrary, the removal rate of lead decreased as the amount of HDTMA increased. The removal of chlorobenzene was influenced by the amount of HDTMA added to the bentonites rather than initial concentration of chlorobenzene, but the removal of lead was much more influenced by the initial concentration of lead. The adsorption of lead was not affected by chlorobenzene, and vice versa. The competitive sorption between the heavy metal and the organic contaminant was not present.

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Study on As Removal from Mine Tailing using MGS Gravity Separator (다중비중선별기를 이용한 광물찌꺼기로부터 비소제거 연구)

  • Kim, Jun-Hee;Kim, Min-Gyu;Kim, Woo-Ram;Han, Oh-Hyung
    • Resources Recycling
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    • v.23 no.5
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    • pp.36-43
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    • 2014
  • It comtained various kinds of heavy metal in beneficiatian tailing and in order to eliminate the heavy metals, various technologies have been researched, But there are a limits because many problems and restrictions are accompanied. Therefore, in this study, in order to solve this problem, It was performed gravity separation using melti-gravity seperator (MGS) to remove As contained in tailing, which can sort out even the fine particle. It was attempted a study to remove As, which is a kind of heavy metals, by MGS gravity separation and verified the impact by slope, wash water, pulp density, rotational speed and feed rate. In the results of performing gravity concentration under the condition with the MGS slope of $3^{\circ}$, wash water of 5 l/mm, pulp density of 30%, rotational speed of 208 rpm, and the feed rate of 265.24 g/mm, the As removal rate of 88.21% and yield of 92.25% were obtained.

Removal of Heavy Metal Ions by Surfactant Enhanced Ultrafiltration (계면활성제 증진 한외여과에 의한 중금속 이온의 제거)

  • 안순철;김종수;이광래
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.114-115
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    • 1997
  • 1.서론 : 중금속 및 유독한 금속물질을 함유한 기존의 폐수처리법으로는 다양한 방법이 있으나, 계면활성제를 첨가한 분리기술은 환경적인 측면과 경제적인 측면에서 타 공정에 비해 우수함이 입증된바 계속적인 연구개발이 진행되어 왔다. (생략)

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축류식 가이드 베인 구조 -반건식 세정기

  • 한국환경기술인연합회
    • Environmental engineer
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    • s.121
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    • pp.46-49
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    • 1996
  • 반건식 세정기는 기존습식처리 설비의 단점인 폐수 및 백연의 발생, 설비의 내구성 저하 등을 보완한 유해가스 처리설비로 탁월한 가스 및 중금속 제거효율, 백연 및 폐수의 발생이 전무하며, 반응생성물의 분리제거로 후단집진설비의 부하를 최대한 줄 일 수 있는 21세기 첨단 유해가스 제거기술의 결정체이다.

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소리없는 환경폭탄! 중금속

  • 이명헌
    • Journal of the korean veterinary medical association
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    • v.39 no.7
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    • pp.616-623
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    • 2003
  • 산업발전으로 인한 유해 독성물질의 대량방출은 이미 자연계에 중대한 위협요소가 되고 있다. 특히 중금속은 산업폐기물의 형태로 양산되며 자연 생태계의 자정능력으로도 쉽게 제거되지 않을뿐 아니라 생체내 축적성이 강하여 사람과 동물의 건강에 심각한 영향을 미칠 수 있다. 또한 현대 사회 발전을 주도하는 산업형태가 대부분 공해배출형이며, 문명의 고도화에 따른 에너지 다소비형의 생활형태는 자연환경을 황폐화시키고 있어 삶의 질 향상과 공중보건을 위해서 인위적인 해결방안이 마련되어야 할 중대한 시점에 와 있다. 가축의 생산기반의 축산환경은 축산물의 안전성과 직결되므로 축산현장에서 중금속 등 유해물질의 안전관리를 위하여 고도의 전문성을 갖춘 수의사의 적극적인 계도와 홍보가 절실히 요구된다.

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