• Title/Summary/Keyword: 중금속 오염 토양

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A Study on Optimal Conditions for Washing the Heavy Metal Polluted Soil in Ka-hak Mine (가학광산 중금속 오염토양의 세척 최적조건 연구)

  • Kim, Teayoup;Park, Jayhyun;Park, Juhyun
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.517-526
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    • 2018
  • In order to remove pollutants from the soil in the Ka-hak mine site, this study investigates optimization of the acid washing conditions for the soil. The soil at the site is presumed to be contaminated by diffused heavy-metal-contaminated tailings. The major heavy metal pollutants in the soil are copper, lead, and zinc. Gravels larger than 5mm in size constitute approximately 38% of the soil, and these are the least polluted by heavy metals. On the other hand, it is difficult to reduce the concentration of heavy metals in fine soils, particularly those whose sizes are less than 0.075 mm. The results of the continuous process using a hydro-cyclone show that fine soil particles consisting of at least 20% of the raw soil must be separated before the chemical soil washing process in order to achieve reliable cleaning.

Soil Neutralizer Selection for Phytostabilzation Using Miscanthus sinensis Anderss. in Heavy Metal Contaminated Soil of Abandoned Metal Mine (폐금속광산 중금속오염토양에서 억새를 이용한 식물안정화공법을 위한 토양개량제 선정)

  • Jung, Mun Ho;Ji, Won Hyun;Lee, Jin Soo;Yang, In Jae
    • Economic and Environmental Geology
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    • v.53 no.5
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    • pp.517-528
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    • 2020
  • The objectives of this study were to select optimal soil amendments through analysis of heavy metal availability in soil and uptake to Miscanthus sinensis Anderss. for phytostablization in heavy metal contaminated soil of abandoned metal mine. M. sinensis was cultivated for 6 months at contaminated soil with several soil treatments (bottom ash 1 and 2%, fly ash 1 and 2%, waste lime+oyster 1 and 2%, acid mine drainage sludge (AMDS) 10 and 20%, compost 3.4%, and control). The analysis results of heavy metal concentrations in the soil by Mehlich-3 mehthod, growth and heavy metal concentrations of M. sinensis showed that AMDS 20% was more effective than other amendments for phytostablization, and AMDS 10% showed second effectiveness. Waste lime+oyster, bottom ash and fly ash were also improved compared to control. Mobility of some heavy metal was increased by treatments. Therefore, it is necessary of preparatory investigation of soil condition to select soil amendment to apply on-site phytostablization.

Effects of Heavy Metal Contents in Soil on the Growth of and their Uptake by Red pepper (토양중 중금속함량이 고추의 생육 및 중금속 흡수에 미치는 영향)

  • Park, No-Kwuan;Lee, Jong-Pal;Park, Seon-Do;Choi, Boo-Sull;Kim, Bok-Jin
    • Korean Journal of Environmental Agriculture
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    • v.18 no.1
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    • pp.24-27
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    • 1999
  • When red pepper was cultivated in the polluted soil with heavy metals, the content of these heavy metals affected. The contents of heavy metals at a site near Zinc mine dump in the Youngyang area were very high compared with those in a normal area and it was highest in 2.0km site. followed 2.5km > 3.0km apart from Zinc mine dump. The growth of red pepper was remarkably poor and the contents of heavy metals in polluted soil were higher than in unpolluted soil. The relationship between the content of Zn, Cu, Pb, Cd, As and the growth of red pepper was negatively correlated, respectively. A higher correlation seemed to exist among the content of Zn.Cu, Cd, As in soil, of Zn, Cd, and As in red pepper. The result indicated that heavy metals were absorbed and accumulated by plants grown in the polluted area.

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Concentration of Zn, Cu, and Pb in Soils and Accumulation of Its in Plants around Abandoned Mine Vicinity (폐광산 주변 토양의 Zn, Cu, Pb의 함량 및 식물체내 축적)

  • Seo Sang-Woo;Moon Sung-Gi;Choi Chul-Mann;Park Yeon-Kyu
    • Journal of Life Science
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    • v.15 no.5 s.72
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    • pp.826-833
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    • 2005
  • This study was conducted to inform basic data for management of abandoned mine that was based on soil heavy metal concentration of the non-rearing and the rearing sites in Guundong Mine which had been completed of improve contamination soils, and examined into standard plant which had tolerances about pollution that analyzed into its accumulated heavy metals contents in the wild plant of naked soil. Consider form the result of contents by depth of soils heavy metals in the non-rearing sites, S1 point judged by contaminated to heavy metals of tailing leach after weathering caused by rainfall and permeate in S1 point soils when restored rest of tailing in 1996 restoration project. Lead of S2 point was not contaminated seriously by restoration and S3 point considered that heavy metals which leach by rainfall in the contaminated soils in mine vicinity accumulated in the abandoned paddy through river When heavy metals of rearing sites soils were examined from the view point of upside of mine point (SP1, SP2, and SP3) of same above the sea level, zinc (537.5 mg/kg) content of SP1 point was highest, and copper (535 mg/kg) and lead (141.5 mg/kg) in the SP3 point were high. To considered as orderly plenty of heavy metals in the plant were respectively in order, Perilla frutescens var. cauta KUDO (SP1 and SP4) >Artemisia princeps PAMPAN (SP2) > Miscanthus sinensis ANDERSSON(SP5) > Vicia angustifolia var. segetilis (THUILL.) K. KOCH. (SP2). Especially, there were plenty of heavy metals in P. frutescens var. acuta, so it judged as a standard plant which have tolerances about heavy metals pollution sites. Therefore, we need more study about the heavy metals accumulate ability of P frutescens var. acuta in future.

The Remediation Characteristic of Soil Contaminated with Heavy Metal and Total Petroleum Hydrocarbon (TPH) by Enhanced Electrokinetic with Fenton Oxidation and Soil Flushing Method (펜톤 산화와 토양 세정이 보강된 동전기에 의한 중금속 및 총 석유 탄화수소(TPH)로 오염된 토양의 정화 특성)

  • Seo, Seok-Ju;Na, So-Jeong;Kim, Jung-Hwan;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.34 no.3
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    • pp.885-893
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    • 2014
  • This research reports the enhanced Electrokinetic (EK) with $H_2O_2$ and sodium dodecyl surfate (SDS), which are commonly used in Fenton oxidation and soil flushing method, in order to remediate soil contaminated with heavy metals and Total Petroleum Hydrocarbons (TPH) simultaneously. In addition, influences of property of soil and concentration of chemical solution were investigated through experiments of different types of soils and varying concentration of chemical reagents. The results indicated, in the experiments using artificially contaminated soil, the highest removal efficiency of heavy metals using 10% $H_2O_2$ and 20mM SDS as electrolytes. However, in the experiments using Yong-San soils (study area), remediation efficiency of heavy metals was decreased because high acid buffering capacity. Through experiment of 20% $H_2O_2$ and 40mM SDS, increased electric current influences the remediation of heavy metals due to decrease in the soil pH. In the experiments of Yong-San soils, the remediation efficiency of TPH was decreased compared with artificially spiked soils because high acid buffering capacity and organic carbon contents. Furthermore, the scavenger effect of SDS influenced TPH oxidation efficiency under the conditions of injected 40mM SDS in the soils. Therefore, the property of soil and concentration of chemical reagents cause the electroosmotic flow, soil pH, remediation efficiency of heavy metals and TPH.

Lime (CaO) and Limestone ($CaCO_3$) Treatment as the Stabilization Process for Contaminated Farmland Soil around Abandoned Mine, Korea (폐광산 주변 중금속 오염 농경지 토양 복원을 위한 석회(CaO)와 석회암($CaCO_3$)의 안정화 효율 규명)

  • Lee, Min-Hee;Lee, Ye-Sun;Yang, Min-Jun;Kim, Jong-Seung;Wang, Soo-Kyn
    • Economic and Environmental Geology
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    • v.41 no.2
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    • pp.201-210
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    • 2008
  • The mixing treatment process using lime (CaO) and limestone ($CaCO_3$) as the immobilization amendments was applied for heavy metal contaminated filmland soils around Goro abandoned Zn-mine, Korea in the batch and pilot scale continuous column experiments. For the batch experiments, with the addition of 0.5 wt.% commercialized lime or limestone, leaching concentrations of As, Cd, Pb, and Zn from the contaminated filmland soil decreased by 70, 77, 94, and 95 %, respectively, compared to those without amendments. For the continuous pilot scale column experiments, the acryl column (30 cm in length and 20 cm in diameter) was designed and granulated lime and limestone were used. From the results of column experiments, with only 2 wt.% of granulated lime, As, Cd, and Zn leaching concentrations decreased by 63%, 97%, and 98%, respectively. With 2 wt.% of granulated limestone, As leaching concentration reduced from 135.6 to 30.2 ${\mu}g/L$ within 5 months and maintained mostly below 10 ${\mu}g/L$, representing that more than 46% diminution of leaching concentration compared to that without the amendment mixing. For Cd and Zn, their leaching concentrations with only 2 wt.% of limestone mixing decreased by 97%, respectively compared to that without amendment mixing, suggesting that the capability of limestone to immobilize heavy metals in the filmland soil was outstanding and similar to that of lime. From the column experiments, it was investigated that if the efficiency of limestone to immobilize heavy metals from the soil was similar to that of lime, the limestone could be more available to immobilize heavy metals from the soil than lime because of low pH increase and thus less harmful side effect.

부산 일부지역 토양과 농작물의 중금속 함량에 관한 연구

  • Jeong, Gap-Seop;Lee, Nam-Geol
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.11a
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    • pp.475-478
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    • 2006
  • 부산 일부지역 토양의 중금속 오염과 농작물로의 전이에 의한 중금속 오염을 측정하고자 산분해에 의한 함량분석을 실험하였다. 대상지역 토양의 pH는 $5.62{\sim}6.71$의 범위였으며, 평균 중금속 함량은 $0.05{\sim}19.39ppm$의 범위에서 Mn(13.82ppm)>Zn(8.33ppm)>Pb(2.89ppm)>Cu(0.99ppm)>Cd (0.07ppm)의 분포로 나타났고, 조사대상 중금속의 토양중의 함량은 모두 Clarke수보다 작은 값으로 측정되어 오염도가 낮은 상태였다. 농작물에는 Cd(0.04ppm)$Pb\;6.6%{\sim}Zn\;87.6%$의 범위였다.

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