• Title/Summary/Keyword: 중금속함량조사

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A Study on the Separation of Mercury from Spent Mercury Batteries (단추형 폐수은 전지로부터 수은 분리에 관한 연구)

  • 손정수;박경호
    • Resources Recycling
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    • v.3 no.1
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    • pp.32-37
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    • 1994
  • Mercury in spent button type batteries can be separated and recovered with vacuum distillation method. It was found that mercury in the battery began to distill at $150^{\circ}C$ and organic substanced like a packing material was decomposed at$ 300^{\circ}C$. More than 99.9% of mercury contained in the battery was distiled and separated at about $250^{\circ}C$ and 20 torr with 8 hours' reaction time. The dissolution tests of the residue after distillation showed that mercury concentration in the solution were lower than 5 ppb and this values satisfied the environ-mental condition. Also as the furnace heating rate was above $15^{\circ}C$/min, it was found that the spent battery was destroyed because of increased pressure in the battery inside.

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Preparation of Chlorella Drinks and Its Quality Characteristics (클로렐라 음료의 제조와 그 품질 특성)

  • Kim Jung-Soo
    • The Korean Journal of Food And Nutrition
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    • v.17 no.4
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    • pp.382-387
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    • 2004
  • This study was performed to evaluate the quality characteristics of the drink with chlorella and Prunus mume. The chlorella drinks were prepared in four different ratios such as chlorella extract 5%, 10% and Prunus mume extract 0.2%, 0.4% added in chlorella extract 5%. In the color of the chlorella drinks, chlorella extract 10% had lower Hunter's color values(L, a, b) than chlorella extract 5%. The hunter's L(lightness) and a(redness) values were lower for Prunus mume extract 0.4% compared to Prunus mume extract 0.2%, however, there was no difference in the b(yellowness) values. A safety test showed that the drinks are clear from heavy metals and total bacteria and colifom bacteria. In the sensory test of the drinks, the sensory scores(color, taste, flavor, overall acceptability) show the best result on chlorella extract 5%(with Prunus mume extract 0.4% added), followed by chlorella 5%(with Prunus mume extract 0.2% added). The score for chlorella extract 10% was the lowest.

Characterization of Illegally Dumped Wastes in Riversides of Nakdong River (낙동강 중류 고수부지내 매립폐기물 특성 연구)

  • Kim, Youngsug;Choi, Boram;Lee, Wontae;Kang, Sungwon;Ahn, Kwangho;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.9
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    • pp.21-25
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    • 2011
  • This study was performed to evaluate characteristics of illegally dumped wastes in the riversides of Nakdong river found during dredging of Nakdong river. Precise classification of the wastes found in the riversides is essential to proper treatment of the wastes. We tried to determine whether these wastes contained toxic compounds and stabilized. Wastes were found at 27 sampling points out of 159 segments investigated and these wastes were not classified as toxic wastes. In addition, clay soils were found at 60 sampling points, and these soils were not classified as wastes. Thus, these soils are thought to be recycled as construction materials. Some samples were not stabilized, which means biodegradation was still progressed in these areas.

A Study on Heavy Metal Contents in Processed Foods and Their Safety Evaluations (가공식품 중 중금속 함량 및 안전성 평가)

  • Lee, Hyo-Jung;Shim, Jee-Youn;Oh, Hyun-Suk;Jang, Mi-Ran;Lee, Yoon-Ae;Lee, Ryun-Kyung;Kim, Min-A;Lee, Sang-Min;Cho, Tae-Yong;Kang, Ho-Il
    • Korean Journal of Food Science and Technology
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    • v.44 no.1
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    • pp.21-27
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    • 2012
  • This research was carried out as a survey on the contents of lead, cadmium, and arsenic in processed foods (milk, vegetable oil, and margarine) in Korea. The limits of quantification (LOQs) were Pb 0.3 ${\mu}g/kg$, Cd 0.15 ${\mu}g/kg$, and As 0.45 ${\mu}g/kg$ for milk and Pb 0.61 ${\mu}g/kg$, Cd 0.31 ${\mu}g/kg$, and As 0.91 ${\mu}g/kg$ for vegetable oil and margarine. The recoveries were 92.6-98.0% for Pb, 91.2-98.9% for Cd, and 97.9-104.7% for As. The average levels of Pb were 2.395 ${\mu}g/kg$ for milk, and 7.656 ${\mu}g/kg$ for vegetable oil. The average levels of Cd were 0.483 ${\mu}g/kg$ for milk, and 0.380 ${\mu}g/kg$ for vegetable oil, and levels of As were 0.781 ${\mu}g/kg$ for milk, and 1.241 ${\mu}g/kg$ for vegetable oil. The results of this study showed that Pb, Cd, and As contents in the whole samples were less than the maximum residual levels in the processed foods that were specified by the Codex standard.

STUDIES ON THE CONTENTS OF MERCURY, CADMIUM, LEAD, AND COPPER IN EDIBLE SEAWEEDS IN KOREA (한국산 주요 식용 해조중의 수은 카드뮴 납 및 구리의 함량)

  • KIM Chang Yang
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.5 no.3
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    • pp.88-96
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    • 1972
  • 1. The present paper deals with the contents of heavy metals such as mercury, cadmium, lead and copper in 17 species of edible seaweeds collected from Jumunjin, Pohang, Pusan, Chungmu, Yeosu and Wando areas. 2. The concentration of mercury in the air-dried seaweeds ranged from 0.02 to 0.52 ppm, as shown by the following species: 0.36ppm (0.09-0.50) in Enteromorpha spp., 0.25 ppm (0.14-0.31) in Undaria sp., 0.19 ppm (0.02-0.52) in Porphyra spp., and 0.10ppm (0.02-0.24) in Laminaria spp. in that order. If these concentrations are converted to the wet bases, they will be about 1/4 to 1/5 of the present levels. In general, the samples collected from the east coast showed relatively lower levels than those from the south coast. The mercury concentrations found in the Korean seaweeds are lower than the permissible levels reported. 3. The concentration of cadmium in the air-dried seaweeds ranged from 0.02 to 1.48 ppm, and the levels in the different species showed in the following order: 0.97 ppm (0.41-1.18) in Hizikia sp., 0.33 ppm (0.03-0.63) Undaria sp., and 0.32 ppm (0.04-0.67) in Porphyra spp. The concentration of cadmium in the samples on the wet bases become 1/4 to 1/5 of the present level. The laver Porphyra spp. collected from the east coast showed relatively lower levels than those of the cultured species along the south coast. All of the concentrations are still below than the permissible levels. 4. In general, lead concentration is 0.20-1.31 ppm which is lower than the permissible level. The concentration becomes about 0.05-0.3 ppm on the wet base. 5. Copper concentration ranged from 0.90-17.0 ppn on the dry base which is about 0.2-4.0 ppm on the wet base. It is interesting to note that the samples collected from Busan region showed relatively higher levels than those sampled from other regions.

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A Study on Hygiene and Safety of Sanitary Wet Towel (물수건의 위생실태 및 안전성 연구)

  • Kim, Young-Sug;Kim, Yang-Hee;Kim, Young-Su;Kim, Dae-Hwan;Ryu, Kyong-Shin;Yoon, Mi-Hye
    • Journal of Food Hygiene and Safety
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    • v.31 no.4
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    • pp.258-263
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    • 2016
  • The risks of sanitary indicative bacteria, heavy metals and chlorinated derivatives in 94 cases of sanitary wet towels used in food services (39 from sanitary wet towel treatment business, 55 from food services) were assessed in the present study. Lead was detected in the range of N.D.~0.41 mg/kg (75 cases were not detected), N.D.~0.25 mg/kg of arsenic (93 cases were not detected), N.D.~0.01 mg/kg of cadmium (7 cases were lower than limit of quantitation; 87 cases were not detected), 0.003 mg/kg ~ 0.09 mg/kg of mercury. And chromium (VI) was not detected from all samples. The level of lead was the highest among the tested heavy metals, and the highest concentration of lead was 0.41 mg/kg. However, it was only 2.1% of legal limit (less than 20 mg/kg). The average moisture content of the samples was 61.9% (50.0% ~ 77.0%) and it showed no relevance to the detection of bacterial counts. Escherichia coli was not detected. Bacterial counts were detected 43 cases and among them, 24 cases were exceeded the legal limit. It was verified that the packaging conditions of sanitary wet towel (whether it is packed by a piece or not and sealed or not) are critical factors to cause the germ contamination and cross contamination in the wet towels. The chlorinated derivatives (chlorites and chlorates) were detected in 17 (19.3%) out of 88 cases. The results would be used as preliminary information to establish the programs of "Safety education for manufacturers and public policy of safety".

Relationship between Extraction Methods of Copper in Soil and the Bioaccumulated Copper in Earthworm (Microcosm soil test를 이용한 지렁이 체내 축적 구리 농도와 구리 침출법 간의 상관관계 비교)

  • Choi, Youn-Seok;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.4
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    • pp.298-310
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    • 2007
  • This study compared the correlation between the accumulated copper content in earthworms and the copper concentration rate of soil measured using several methods to extract heavy metals from soil. For the experiment, a microcosm soil test was carried out using copper contaminated soil from the vicinity of copper-roofed buildings and earthworms (Eisenia fetida). Soils from the study area were used to produce 6 treatments; control, 1C (contamination level with the lowest treated copper concentration rate), 2C, 4C, 8C, and 16C (contamination level with the highest treated copper concentration rate). Microcosm soil test using the 6 treatments proved that as the copper content in soil and the experiment time increased, the growth rate of and the accumulated copper concentration rate in earthworms increased as well. The degree of the increase corresponded to the order of the treated copper concentration levels in microcosm soils. Standard method of the ministry of environment and EPA method 3051 were used to obtain the copper concentration in soil and the total copper content in soil, respectively. The correlation coefficient (r) of 0.9875~0.9993 between the copper content extracted by the standard method and the total copper content shows high positive correlation. The correlation coefficient of the copper content in soil extracted by the standard method and the accumulated copper content in earthworms, and the correlation coefficient of the total copper content in soil and the accumulated copper content in earthworms were ranged from 0.9193 to 0.9728 and from 0.9282 to 0.9844, respectively, showing highly significant positive correlation. Due to the high correlation between the copper concentration in soil and the accumulated copper content in earthworms, it is concluded that earthworms are suitable to be used as biological indicator species or for bio-monitoring against copper contamination of soil.

Bacterial Productivity and Degradability of Organic Compounds in the Coastal Area of East Sea (동해 연안역의 박테리아 생산력과 유기물질의 분해능)

  • 이기성;고동규;김근호;이영근;최청일;최영길
    • Korean Journal of Environmental Biology
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    • v.17 no.1
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    • pp.59-69
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    • 1999
  • Bacterial population, signal compounds of pollution, bacterial productivity, heterotrophic activity and the activities of extracellular enzymes were analyzed four times from July 1994 to April 1995 at Daejin, Galnam, Pohang, and Ulsan in the coastal area of Bast Sea in order to investigate the state of eutrophication. The population of heavy metal resistant bacteria in Pohang was the highest among all stations. The bacterial populations which could utilize C -P compounds (phosphonate) showed the highest at Pohang that was expected for the industrial and agricultural effluents to inpour. It could be useful as an index of expectation about the influx of industrial sewages and agricultural effluents. The activities of extracellular enzymes for the degradation of organic matter were the highest in the Ulsan Chuyongam, but low in Daejin. These results showed positive relationship with the population of heterotrophic bacteria and bacterial productivity The ratio of poly-P and DNA in Pohang was the highest, and that in Ulsan, Galnam, and Daejin consecutively, corresponding with the distribution of heterotrophic bacteria. In case of the heterotrophic activities, each of the stations gives difference of seasonal variation in heterotrophic activities. Bacterial productivity seemed to be dependent on seasons; the highest in summer and the lowest in fall and winter. These seasonal variations of bacterial productivity seems to be similar with those of heterotrophic bacteria. It is suggested that the state of eutrophication could be evaluated by the criteria of the population sizes and the productivities of microorganisms, the amount of poly-P, heterotrophic activity, the activities of extracellular enzymes, etc.

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Chemical Compositions of Sewage Sludges and Nitrogen Mineralization in Sewage Sludge Applied Soil (하수오니의 화학적 조성과 토양중 질소 무기화)

  • Park, Mi-Hyun;Lee, Seung-Heon;Yoo, Sun-Ho;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.2
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    • pp.189-196
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    • 1998
  • Swage sludge cakes produced from domestic wastewater treatment plants were collected from 21 different sites throughout Korea, and chemical properties of the sludge samples were determined. Inorganic nutrient contents did not indicate great differences among swage sludges from each sites, whereas the toxic heavy metal contents differed greatly. T-N, $NH_4{^+}-N$ and $NO_3{^-}-N$ contents from 21 sites sludges ranged 2.3-6.0, 291-4284, $1.4-58.8mg\;kg^{-1}$, respectively. Heavy metal (Cd, Cu, Pb and Zn) contents ranged 2.86-58.22, 144.0-5417.3, N.D.-943.5, and $N.D.-8,083mg\;kg^{-1}$, respectively. One of the sludges was treated to soils at rates of 12.5, 25, 50. and 100, $Mg\;ha^{-1}$ and incubated for 12 weeks to determine nitrogen materialization rate. Ammoniun nitrogen content decreased sharply at higher rates of sludge treatment up to 8 weeks after treatment and did not change much, while $NO_3{^-}$ increased at all treatment levels. The net amount of mineralized N of sludge treatment rates (12.5, 25, 50, and $100Mg\;ha^{-1}$) during 12weeks incubation were 189.0, 277.2, 303.8 and $376.6mg\;kg^{-1}$.

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Effects of Liquid Pig Manure Application on Rice Growth and Environment of Paddy Soil (돈분뇨 액비 시용이 벼의 생육 및 논 토양 환경에 미치는 영향)

  • Jeon, Weon-Tai;Park, Hyang-Mi;Park, Chang-Yeong;Park, Ki-Do;Cho, Young-Son;Yun, Eul-Soo;Kang, Ui-Gum
    • Korean Journal of Soil Science and Fertilizer
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    • v.36 no.5
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    • pp.333-343
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    • 2003
  • This experiment was carried out to improve the utilization of liquid pig manure (LPM) for rice at the two textures of valley soil in 2000 and 2001. The soil textures were coarse loamy and fine loamy in Sachon and Jisan series, respectively. Treatments consisted of no fertilized plot, chemical fertilized plot, LPM 150%, LPM 100%, LPM 100%+NK (top dressing) 30%, LPM 70%+NK 30%, LPM 50%+NK 50% plot. LPM was applied as basal fertilizer compare to nitrogen of chemical fertilized plot. Total N contents in the LPM were 6.0 and $4.5g\;kg^{-1}$ in 2000 and 2001, respectively. After the experiment, P and K contents of soils were not difference between chemical and LPM application plots. But heavy metal contents in soils were slightly higher in LPM application plots than in chemical fertilized plot. Immediately after LPM application, ammonia gas content was $18mg\;kg^{-1}$ in LPM 150% plot, but it was $3mg\;kg^{-1}$ in LPM 50% plot. Two days after LPM application, ammonia gas content was 3 times higher in coarse loamy than in fine loamy soil. After rotary tillage, ammonia gas was not detected at all LPM treatments. This result suggests that rotary tillage can reduce the nasty smell of LPM quickly. Inorganic nitrogen, $NO_3$ and $NH_4$, contents in water of paddy was higher at coarse loamy soil from rice transplanting to tillering stage. After that season, inorganic nitrogen contents of water were not different according to soil texture and treatments. Content of $NH_4-N$ in soil solution was higher at LPM plots than chemical fertilizer plot. Total nitrogen contents in rice plant after harvesting were higher at chemical fertilization plot than LPM application plot, but K contents showed an opposite tendency. Rice yield was decreased only in LPM plots at two soil textures. But yield was not significantly difference between chemical fertilizer and LPM+top dressing plots at coarse loamy soil and increased 5% at LPM 50%+NK 50% plot at fine loamy soil in 2001.