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Investigation of plasma effect for defect-free nitrogen doping of graphene

  • Lee, Byeong-Ju;Jeong, Gu-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.211.2-211.2
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    • 2016
  • 그래핀은 본연의 우수한 물성으로 인하여 전자소자, 에너지 저장매체, 유연성 전도막 등 다양한 분야로의 응용가능성이 제기되었으나, 실제적인 응용을 위해서는 구조적인 결함을 최소화하며, 특성을 자유로이 제어하거나 향상시키는 공정의 개발이 요구된다. 특히 그래핀을 전자소자로 응용하기 위해서는 전기적 특성을 제어하는 것이 요구된다. 일반적으로 화학적 도핑은 그래핀의 전기적 특성을 제어하는 효율적인 방법으로 알려져 있다. 화학적 도핑은 그래핀을 구성하는 탄소원자를 이종원자로 치환하거나 표면에 흡착시켜 기능화 된 그래핀을 얻는 방법으로, 특정 가스 분위기에서 고온 열처리하거나 활성종들이 존재하는 플라즈마에 노출시키는 방법이 제시되었다. 특히 플라즈마를 이용한 도핑방법은 저온에서 단시간의 처리로 도핑이 가능하고, 플라즈마 변수를 변경하여 도핑정도를 수월하게 제어할 수 있다는 장점을 가지고 있다. 그러나 플라즈마내의 극성을 띄는 다양한 활성종들의 충돌효과로 인하여 구조적인 손상이 발생하여 오히려 특성이 저하될 수 있어 이를 고려한 플라즈마 공정조건의 설정이 필수적이다. 따라서 본 연구에서는 플라즈마에 노출된 그래핀의 Raman 특성을 고찰함으로써 화학적 도핑과 구조적인 결함의 경계를 확립하고 구조결함의 형성을 최소화한 효율적인 도핑조건을 도출하였다. 그래핀은 물리적 박리법을 이용하여 300 nm 두께의 실리콘 산화막이 존재하는 실리콘 웨이퍼 위에 제작하였으며, 평행 평판형 직류 플라즈마 장치를 이용하여 전극의 위치, 인가전력, 처리시간을 변수로 암모니아($NH_3$) 플라즈마를 방전하여 그래핀의 Raman 특성변화를 관찰하였다. 그래핀의 구조적 결함 및 도핑 효과는 라만 스펙트럼의 D, D', 2D밴드의 강도와 G밴드의 위치와 반치폭(Full width at half maximum; FWHM)의 변화를 통해 확인하였다. 그 결과, 인가전력과 처리시간에 따라 결함형성과 질소도핑 영역이 구분 가능함을 확인하였으며, 이를 바탕으로 결함형성을 최소화한 효율적인 도핑조건이 접지전위, 0.45 W의 인가전력, 처리시간 10초이며, 최적조건에서 계산된 도핑레벨은 $1.8{\times}10^{12}cm^{-2}$임을 확인하였다.

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Fault-Tolerant Driving Control of Independent Steer-by-Wire System for 6WD/6WS Vehicles Using High Slip (고슬립을 이용한 6 륜구동/6 륜조향 차량 고장 안전 주행 제어)

  • Nah, Jae Won;Kim, Won Gun;Yi, Kyongsu;Lee, Jongseok;Lee, Daeok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.6
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    • pp.731-738
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    • 2013
  • This paper describes a fault-tolerant driving control strategy for an independent steer-by-wire system in sixwheel-drive/six-wheel-steering vehicles. An algorithm has been designed to realize vehicle maneuverability that is as close as possible to that of non-faulty vehicles by inducing high slip ratio of the wheel through a faulty steer-by-wire system in order to reduce the lateral tire force, which is resistant to the yaw motion. Considering the transition of the longitudinal tire force of a wheel with a faulty steer-by-wire component, the longitudinal tire forces are optimally distributed to the other wheels. Fault-tolerant driving performance has been investigated via computer simulations. Simulation studies show that the proposed algorithm can significantly improve the maneuverability of a vehicle with a faulty steer-by-wire system as compared to the optimal traction distribution method.

플라즈마 처리에 의한 원뿔형 다중벽 탄소나노튜브 다발의 형성기전

  • Im, Seon-Taek;Kim, Gon-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.129-129
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    • 2010
  • 플라즈마 처리를 통하여 수직 합성된 다중벽 탄소나노튜브가 원뿔형 다발이 될 수 있으며 원뿔형 탄소나노튜브 다발은 기존의 구조적, 기계적 성질의 향상과 더불어 향상된 전계방출 능력을 가질 것으로 기대되어 이를 X-선원, 전계방출디스플레이(FED), 유기발광다이오드(OLED) 백라이트 등의 전자빔 원으로 적용하기 위한 연구가 진행되고 있다. 원뿔형 탄소나노튜브 다발의 형상 제어를 통하여 전계방출특성을 향상시킬 수 있으며 이를 위해 원뿔형 탄소나노튜브 다발이 생성되는 메커니즘과 조사되는 플라즈마의 역할에 대해서 이해하는 것이 중요하다. 본 연구에서는 플라즈마 생성부와 조사부를 분리한 유도결합형 플라즈마 원을 사용하여 입사되는 이온의 에너지, 조사량, 입자 종을 독립적으로 제어하였고 이를 통하여 원뿔형 탄소나노튜브 다발이 형성되는 메커니즘과 플라즈마의 역할을 밝혀내었다. 알곤 및 수소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되지 않았으나 질소 및 산소 플라즈마 처리에서는 원뿔형 탄소나노튜브 다발이 형성되었다. 특히 산소 플라즈마 처리가 원뿔형 탄소나노튜브 다발 형성에 효과적이었다. 원뿔형 탄소나노튜브 다발의 형성 메커니즘은 탄소나노튜브의 분극과 쉬스 전기장의 상호작용을 이용한 모델을 사용하여 설명하였다. 질소 및 산소 플라즈마 처리에서는 탄소나노튜브 끝단에 생성되는 C-N, C-O 결합에 의해 향상된 유도 쌍극자와 쉬스 전기장에 의해 탄소나노튜브 끝단이 모여 원뿔형 탄소나노튜브 다발이 생성됨을 밝혀내었다. 산소 플라즈마 처리에서 입사되는 이온의 에너지 조절에 의한 쉬스 전기장 조절과 조사량 조절을 독립적으로 수행하여 원뿔형 탄소나노튜브 다발의 직경 및 높이가 쉬스 전기장 및 조사량에 따라 조절 가능함을 보였다. 이로부터 입사되는 이온의 입자 종, 쉬스 전기장 및 조사량 조절 등의 플라즈마 인자 조절을 통하여 원뿔형 탄소나노튜브 다발의 형상 제어가 가능함을 보였다. 탄소나노튜브의 형상 제어와 더불어 세슘 입자 삽입을 통한 탄소나노튜브의 일함수 감소를 통하여 향상된 전계 방출 특성을 갖는 탄소나노튜브 팁의 제조 가능성을 확인하였다.

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Isolation, Characterization, and Control of Pseudomonas kribbensis and Pantoea vagans that cause Soft-rot Disease Isolated from Chinese Cabbages

  • Lee, Kang Wook;Kim, Geun Su;Kim, Jeong A;Kwon, Do Young;Lee, Jin Ju;Kim, Il Chul;Kim, Sang Gu;Kim, Tae Seok;Lee, Sang Yun
    • Journal of Food Hygiene and Safety
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    • v.37 no.2
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    • pp.55-62
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    • 2022
  • The bacterial soft-rot disease is one of the most critical diseases in vegetables such as Chinese cabbage. The researchers isolated two bacteria (Pseudomonas kribbensis and Pantoea vagans) from diseased tissue samples of Chinese cabbages and confirmed them as being the strains that cause soft-rot disease. Lactic-acid bacteria (LAB), were screened and used to control soft-rot disease bacteria. The researchers tested the treatments with hypochlorous acid water (HAW) and LAB supernatant to control soft-rot disease bacteria. The tests confirmed that treatments with the HAW (over 120 ppm) or LAB (Lactobacillus plantarum PL203) culture supernatants (0.5 mL) completely controlled both P. kribbensis and P. vagans.

Relative importance of climatic and habitat factors on plant richness along elevation gradients on the Mt. Baekhwa, South Korea (백화산 고도별 식물 종풍부도에 대한 기후 및 서식지 인자의 상대적 중요성)

  • Lee, Chang-Bae;Chun, Jung-Hwa
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.20 no.3
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    • pp.233-242
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    • 2018
  • This study explored the richness patterns of vascular plant species and evaluated the effects of the climatic and habitat variables on the observed patterns along elevational gradients on the Mt. Baekhwa, South Korea. Plant data were recorded from 70 plots and a total of 187 plant species with 78 woody and 109 herbaceous species were recorded along two study transects, the Banyasa and Bohyunsa transects, on the Mt. Baekhwa. A total of 154 plant species with 66 woody and 88 herbaceous species and 131 plant species with 58 woody and 73 herbaceous species were recorded along the Banyasa and Bohyunsa transects, respectively. We used simple ordinary least squares regression model, multi-model inference and variation partitioning to analyze the relative contribution of climatic and habitat variables on the elevational richness patterns. Species richness pattern for vascular plants along the Banyasa transect monotonically decreased with elevation, whereas plant species richness showed reversed hump-shaped pattern along the Bohyunsa transect. Although the elevational patterns of species richness for vascular plants were different between the both transects, habitat variables are more important predictors than climatic variables for the elevational patterns of plant species richness along our study transects on the Mt. Baekhwa. These results indicate that elevational diversity patterns of vascular plants may be different even between nearby elevational transects in a mountain ecosystem but the diversity patterns may be controlled by same drivers.

Design of PI-type Fuzzy Logic Controller for a Turbojet Engine of Unmanned Aircraft (무인 항공기용 터보 제트 엔진의 PI-구조 퍼지 추론 제어기 설계)

  • Jie, Min-Seok;Mo, Eun-Jong;Lee, Kang-Woong
    • Journal of Advanced Navigation Technology
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    • v.9 no.1
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    • pp.34-40
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    • 2005
  • In this paper we propose a turbojet engine controller of unmanned aircraft based on the Fuzzy-PI algorithm. To prevent any surge or a flame out event during the engine acceleration or deceleration, the PI-type fuzzy controller effectively controls the fuel flow input of the control system. The fuzzy inference rule made by the logarithm function of acceleration error improves the tracking error. Computer simulations applied to the linear model of a turbojet engine show that the proposed method has good tracking performance for the reference acceleration and deceleration commands.

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An Integrated Management Model of Administrative Role-Based Access Control and Delegation Policy (ARBAC과 위임 정책의 통합 관리 모델)

  • Oh, Se-Jong;Kim, Woo-Sung
    • The KIPS Transactions:PartC
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    • v.11C no.2
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    • pp.177-182
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    • 2004
  • Delegation is one of important security policies in the access control area. We propose a management model of delegation integrated with ARBAC model for environment of distributed access control. We Integrate PBDM delegation model with ARBAC97 model, and suggest integrity rules of delegation for preventing security threats in new model. Our model supports both free delegation for users without intervention of administrators, and controlling delegation for security administrators.

Permission-Based Separation of Duty Model on Role-Based Access Control (역할기반 접근제어 환경에서 접근권한 기반의 임무분리 모델)

  • Oh Se-Jong
    • The KIPS Transactions:PartC
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    • v.11C no.6 s.95
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    • pp.725-730
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    • 2004
  • Separation of Duty(SOD), with delegation, is one of important security principles in access control area. The role-based access control model adopts SOD principle, but it has some problems; SOD concept is inconsistent with role hierarchy, permissions that have no relation with SOD may be restricted, and delegation may violate SOD. We propose permission-based SOD model on role-based access control. We establishes SOD as a set of permissions instead of role level SOD. Furthermore we propose a principle of role activation. It solves SOD problems of RBAC and supports easy implementation of SOD policy.

Design of Control Algorithm for Mass Driving Anti-Rolling System Considering Control Input Constraint (제어 입력포화를 고려한 횡동요 저감장치용 제어알고리듬 설계)

  • Moon, Seok-Jun;Lim, Chae-Wook;Lee, Hae-Jong
    • Journal of the Society of Naval Architects of Korea
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    • v.42 no.6 s.144
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    • pp.566-574
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    • 2005
  • Reduction of a ship's rolling is the most important performance requirement for improving the safety of the crew on board and preventing damage to cargos as well as improving the comfort of the ride. A mass driving anti-rolling system (MO-ARS) might be one candidate of several systems against the ship's rolling. As the movable range of the mass on the ship is finite, the control system must include restriction on the mass position to protect the device and the ship. This restriction usually causes windup phenomenon and control performance is deteriorated seriously. Two control algorithms, anti-windup control and saturated sliding mode control, are studied in this paper. Control performance and robustness problem are checked out by numerical simulations.

Dynamic Response and Control of Airship with Gust (외란이 작용하는 비행선의 동적 반응 및 제어)

  • Woo, G.A.;Park, I.H.;Oh, S.J.;Cho, K.R.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.6
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    • pp.69-77
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    • 2002
  • To acquire the dynamic response and design the controller of the airship, the longitudinal motion of the airship with respect to the vertical gust, which is the nonlinear system, was studied. The effects of the apparent mass and moment of the airship delay the dynamic response and the settling time, which are slower than those of conventional airplanes. The current object of the airship is designed to cruise at 500~1000m altitude. At that height, the atmospheric conditions are generally unstable by wind gust. In this paper, it has been studied for the case of vertical gust, since the apparent mass effects are dominant in has been studied for the case of vertical gust, since the apparent mass effects are dominant in that plane. In addition to the study of the dynamic responses of the airship, the controller was designed using the PID-controller. When the gust was applied, airship responses were recovered of equilibrium states. However, it takes too ling time for recovery and the speed of airship is reduced. So, the aim in this paper was to fasten the recovery speed and to get back the cruising velocity. The control parameters were determined from the stability mode analysis, and the control inputs were the thrust and the elevator deflection angle.