• Korean Journal of Mineralogy and Petrology
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• v.35 no.4
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• pp.457-467
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• 2022

Electron bombardment to silicate glass during electron probe microanalysis (EPMA) causes outward migration of Na from the excitation volume and subsequent decrease in the measured X-ray count rates of Na. To acquire precise Na₂O content of silicate glass, one should use proper analytical technique to avoid or minimize Na migration effect or should correct for decreases in the measured Na X-ray counts. In this study, we analyzed 8 silicate glass standard samples using automated Time Dependent Intensity (TDI) correction method of Probe for EPMA software that can calculate zero-time intercept by extrapolating X-ray count changes over analysis time. We evaluated an accuracy of TDI correction for Na measurements of silicate glasses with EPMA at 15 kV acceleration voltage and 20 nA probe current electron beam, which is commonly utilized analytical condition for geological samples. Results show that Na loss can be avoided with 20 ㎛-sized large beam (<0.1 nA/㎛²), thus silicate glasses can be analyzed without TDI correction. When the beam size is smaller than 10 ㎛, Na loss results in large relative errors up to -55% of Na₂O values without correction. By applying TDI corrections, we can acquire Na₂O values close to the reference values with relative errors of ~ ±10%. Use of weighted linear-fit can reduce relative errors down to ±6%. Thus, quantitative analysis of silicate glasses with EPMA is required for TDI correction for alkali elements such as Na and K.

• Journal of the Korean Geotechnical Society
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• v.23 no.11
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• pp.77-85
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• 2007

This paper investigates the mechanical characteristics of composite geo-material which was developed to reuse both dredged soils and bottom ash. The composite geo-material used in this experiment consists of dredged soil taken from the construction site of Busan New Port, cement, air foam and bottom ash. Bottom ash is a by-product generated at the Samcheonpo thermal power plant. Several series of laboratory tests were performed to investigate behavior characteristics of composite gee-material, in particular the reinforcing effect by mixing bottom ash. The experimental results of composite geo-material indicated that the stress-strain relationship and the unconfined compressive strength are strongly influenced by mixing conditions. Especially it was observed that the compressive strength of composite geo-material increased with an increase in bottom ash content due to reinforcing effect by the bottom ash. Compressive strength of composite geo-material increased with the increase in curing time. The 28-day strength of composite geo-material is $1.7{\sim}1.8$ times higher than the 7-day strength. The moist unit weight strongly depended on air-foam content as well as bottom ash content added to the composite goo-material. In composite geo-material, secant modulus ($E_{50}$) also increased as its compressive strength increased due to the inclusion of bottom ash.

• Journal of the Korean Geotechnical Society
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• v.24 no.5
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• pp.117-127
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• 2008

The volumetric pressure plate extractor (VPPE) was modified for the measurement of shear wave velocity ($V_s$) at various levels of matric suction as well as soil water characteristic curve (SWCC). A non-destructive technique with a pair of bender element (BE) was employed in order to measure the $V_s$ and the corresponding maximum shear modulus ($G_{max}$) of unsaturated soil specimens. Three types of soil were collected from different road construction sites in Korea. For all test soils, the variations in $G_{max}$ with the various levels of water content and matric suction were investigated using the developed apparatus. Compared with the preceding results from the suction-controlled torsional shear (TS) testing system and in-situ seismic tests, the feasibility fur evaluating modulus characteristics of unsaturated compacted soils with the developed VPPE-BE system was assessed. It was confirmed that the newly developed system would be potentially helpful in modeling seasonal variation of modulus.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.263-263
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• 2020

댐 유역 수문자료는 댐의 효율적인 운영, 중장기 댐 운영 계획, 수자원 관리, 댐 저수량 예보 등에 사용된다. 댐의 주요 수문자료로는 일반적으로 유입량인 강수량과 유량으로 구성되어있으며 유출량인 방류량, 증발량, 토양수분량으로 구분한다. 현재 강수량, 유량, 방류량은 지속적으로 계측하고 있으나 증발산량과 토양의 저류량 등은 실제적으로 측정의 어려움을 가지고 있다. 본 연구에서는 실측자료를 물수지 방정식에 대입해 발생한 잔차를 통해 산출한 증발산량과 비교적 정확성이 높다고 알려져 있는 GLDAS NOAH 지형 모형자료에서 산정된 증발산량간의 비교를 수행하였다. 또한 이렇게 각각 산정한 증발산량으로 월별로 물수지 분석을 정량화하여 분석하였다. 유량자료는 후영교 수위관측소의 자료, 강수량은 괴산군(청천면사무소) 강수량관측소 외 15개소 자료, 댐 방류량자료 등의 실측자료를 사용하였으며, 증발량은 GLDAS NOAH 지표면 model을 이용하여 산정하였다. 저수지 토양수분량은 자료가 없어 고려하지 않았다. 2019년 괴산댐 유역의 총 유입량은 218.54 백만㎥이며, 증발량을 고려한 총 유출량은 200.50 백만㎥으로 나타나 댐의 저류량은 18.05 백만㎥으로 나타났다. 그러나 실제 저수지의 수위-저수용량 곡선식을 이용하여 계산된 총 저류량은 0.06 백만㎥으로 상당한 차이를 보이고 있다. 이 원인으로 1. 증발량 추정자료 사용, 2. 토양저류량 미 고려, 3. 자료가 없는 취수량 미 고려 4. 유량, 방류량, 강수량 자료 오차 등이 있는 것으로 판단된다. 한편, GLDAS NOAH 지표면 model을 이용한 연 저수지증발량과 물 수지 방적식을 이용한 연 저수지증발량은 각각 0.79 백만㎥, 18.84 백만㎥으로 나타나, 역시 차이를 보인다. 이는 물 수지 방정식을 이용한 연 저수지증발량은 토양수분증발량 미 고려에 따른 것과 GLDAS NOAH 지표면 model자료는 직접적인 실측 자료가 아닌 추정 자료로 다소 오차가 있을 것으로 생각된다. 댐 유역 물의 이동을 추적하고 이를 정량적으로 나타내는 것은 결과적으로 효율적인 댐 운영을 가능하게 한다. 그러나 최근 실시되는 유량측정과는 달리 물 수지 분석의 주요 인자인 증발량과 토양수분량 등은 측정이 전무하여 여러 가지 방법으로 추정하는 현실이다. 추후 이러한 수문자료를 실측하여 제공한다면 댐 관리 및 중장기 댐 운영 계획 수립 등 효율적인 댐 운영에 대단히 유용할 것으로 기대된다.

• Analytical Science and Technology
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• v.22 no.3
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• pp.210-218
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• 2009

A gas chromatography-tandem mass spectrometry (GC-MS/MS) method was developed and validated for simultaneous determination of amphetamine derivatives and norketamine in human hair. Preparation of hair involves external decontamination, mechanical pulverization, incubation and extraction prior to instrumental analysis. The samples were derivatized using heptafluorobutyric anhydride, and analyzed by GC-MS/MS. The linear ranges were 0.05-20.0 ng/mg for the analytes except for 3,4-methylenedioxyamphetamine, with good coefficients of determination ($r^2$ >0.998). The intra-day and inter-day precisions were within 10.7% and 8.5%, respectively. The intra-day and inter-day accuracies were between -1.6 and 17.0% and -2.6 and 10.5%, respectively. The limits of detections for each analyte were lower than 0.007 ng/mg, while recoveries were 75.9-100.9%. When the method was applied to hair samples obtained from suspected drug abusers, the concentrations in hair samples were 0.97-19.30 ng/mg for methamphetamine and 0.14-2.56 ng/mg for amphetamine.

• Analytical Science and Technology
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• v.21 no.4
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• pp.272-278
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• 2008

Methods to separate 14 rare earth elements (REEs) and yttrium by the $AG^{(R)}$ 50W-X8 cation exchange resin, and to determine REEs by inductively coupled plasma atomic emission spectrophotometry (ICP-AES) were described. Ion exchange capacities of REEs on the resin were so high that the REEs were quantitatively ion exchanged under the flow rate of 0.3~1.0 mL/min at pH 1~6. The breakthrough capacity curve of the REEs showed that ion exchange capacities of light REEs (Cerium group) were greater than that of the heavy REEs (Yttrium group). When $200{\mu}g$ of each REEs was ion exchanged on 100 mg of resin, most of the heavy REEs were quantitatively desorbed with 10 mL of 2.0 M of $HNO_3$, while most of the light REEs with 30 mL. The method was applied to the monazite sample. The REEs could be separated from matrix, since ion exchange capacities of matrix ions of Ca, Ti, Mg, Mn were much lower than that of the REEs. However the relative standard deviations of the analytical results by the present method were not improved, as high as 1~5%.

• The Journal of the Convergence on Culture Technology
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• v.9 no.3
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• pp.633-640
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• 2023

In this study, numerical analysis was performed based on field investigation to derive an appropriate reinforcement method by analyzing the displacement behavior characteristics of concrete blocks generated in the direct fixation track on the bridges of the serviced light rail transit. The track of this study was a direct fixation track on a sharp curved track, and the problem of movement of the concrete blocks installed on the bridge deck in the longitudinal and lateral directions occurred. In this study, based on the finite element model using 3D solid elements, the behavior of the direct fixation track that could be occurred under operating load conditions was analyzed. In addition, the reinforcement effect of various reinforcement methods was analyzed. As a result of analyzing the lateral displacement before and after reinforcement, it was analyzed that the maximum lateral displacement after reinforcement under the extreme lateral wheel loads significantly decreased to about 3% (about 0.1mm) compared to before reinforcement. In addition, as a result of examining the generated stress of the filling mortar, bridge decks, and reinforcing bar, it was analyzed that all of them secured a sufficient safety factor of 2.6 or higher, and the optimal conditions for the reinforcement method were derived. Therefore, it is judged that the number of anchoring reinforcements and symmetrical anchor placement reviewed in this study will be effective in controlling the occurrence of lateral displacement of concrete blocks and securing the structural integrity of bridges and concrete blocks.

• Analytical Science and Technology
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• v.22 no.4
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• pp.326-335
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• 2009

A specific analytical method able to identify and quantify traces of six glucocorticoids residues in eggs were developed. The extraction and clean-up parameters for simultaneous analysis were evaluated and HPLC and spectrometric conditions were also established. For determination of glucocorticoids, 5 g of egg was transferred into a test tube, adjusted pH 5.2 with acetate buffer and was $\beta$-glucuronidase/arylsulfatase from Helix pomatia added. The mixture was centrifuged and supernatant was extracted twice with 20 mL n-hexane. The extraction was performed with HLB cartridge using methanol, followed by clean-up with silica cartridge using methanol/ethyl acetate (4/6, v/v). The analytes were determined by HPLC/ESI-MS/MS operating in the negative ion mode. Validation studies with fortified egg samples for established method were performed. The result of method validation gave good efficiency, linearity, accuracy and precision. The correlation coefficients ($r^2$) of the calibration curves appeared to be higher than 0.99 in egg, indicating excellent linearity. LOD was ranged 0.09 to $0.17{\mu}g/kg$, and recoveries for most compounds were in the range of 55.7-69.8%. This method can be used to determine ${\mu}g/kg$ levels of glucocorticoids in eggs.

• Journal of Food Hygiene and Safety
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• v.26 no.1
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• pp.16-24
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• 2011

A method was established for the simultaneous determination of sugar alcohols, erythritol, xylitol, sorbitol, inositol, mannitol, maltitiol, lactitol and isomalt by High Performance Liquid Chromatography (HPLC). The sugar alcohols were converted into strong ultraviolet (UV)-absorbing derivatives with p-nitrobenzoyl chloride (PNBC). HPLC was performed on Imtakt Unison US-$C_18$ column, using acetonitrile: water (77:23) as a mobile phase and UV detection (260 nm). The calibration curves for all sugar alcohols tested were linear in the 10~200 mg/L range. The average recoveries of the sugar alcohols from three confectioneries spiked at 100 ppm of eight sugar alcohol standards ranged from 81.2 to 123.1% with relative standard deviations ranging fromo 0.2 to 4.9%. The limits of detection (LODs) were $0.5{\sim}8\;{\mu}g/L$ and the limits of quantification (LOQs) were $2{\sim}17\;{\mu}g/L$. Reproducibility of 8 sugar alcohols was 0.28~1.97 %RSD. The results of the analysis of confectioneries showed that 89 samples of 130 were detected and the sugar alcohols content of samples investigated varied between 0.4 and 693.7 g/kg. A method for the simultaneous determination of eight sugar alcohols will be used as basic data for control of sugar alcohols in confectioneries, and quality control in food manufacturing.

• Investigative Magnetic Resonance Imaging
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• v.1 no.1
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• pp.119-124
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• 1997

Purpose: To assess the utility of magnetic resonance(MR) cerebral blood volume (CBV) map in the evaluation of brain tumors. Materials and Methods: We performed perfusion MR imaing preoperatively in the consecutive IS patients with intracranial masses(3 meningiomas, 2 glioblastoma multiformes, 3 low grade gliomas, 1 lymphoma, 1 germinoma, 1 neurocytoma, 1 metastasis, 2 abscesses, 1 radionecrosis). The average age of the patients was 42 years (22yr -68yr), composed of 10 males and S females. All MR images were obtained at l.ST imager(Signa, CE Medical Systems, Milwaukee, Wisconsin). The regional CBV map was obtained on the theoretical basis of susceptibility difference induced by first pass circulation of contrast media. (contrast media: IScc of gadopentate dimeglumine, about 2ml/sec by hand, starting at 10 second after first baseline scan). For each patient, a total of 480 images (6 slices, 80 images/slice in 160 sec) were obtained by using gradient echo(CE) single shot echo-planar image(EPI) sequence (TR 2000ms, TE SOms, flip angle $90^{\circ}$, FOV $240{\times}240mm,{\;}matrix{\;}128{\times}128$, slice-thick/gap S/2.S). After data collection, the raw data were transferred to CE workstation and rCBV maps were generated from the numerical integration of ${\Delta}R2^{*} on a voxel by voxel basis, with home made software (${\Delta}R2^{*}=-ln (S/SO)/TE). For easy visual interpretation, relative RCB color coding with reference to the normal white matter was applied and color rCBV maps were obtained. The findings of perfusion MR image were retrospectively correlated with Cd-enhanced images with focus on the degree and extent of perfusion and contrast enhancement. Results: Two cases of glioblastoma multiforme with rim enhancement on Cd-enhanced Tl weighted image showed increased perfusion in the peripheral rim and decreased perfusion in the central necrosis portion. The low grade gliomas appeared as a low perfusion area with poorly defined margin. In 2 cases of brain abscess, the degree of perfusion was similar to that of the normal white matter in the peripheral enhancing rim and was low in the central portion. All meningiomas showed diffuse homogeneous increased perfusion of moderate or high degree. One each of lymphoma and germinoma showed homogenously decreased perfusion with well defined margin. The central neurocytoma showed multifocal increased perfusion areas of moderate or high degree. A few nodules of the multiple metastasis showed increased perfusion of moderate degree. One radionecrosis revealed multiple foci of increased perfusion within the area of decreased perfusion. Conclusion: The rCBV map appears to correlate well with the perfusion state of brain tumor, and may be helpful in discrimination between low grade and high grade gliomas. The further study is needed to clarify the role of perfusion MR image in the evaluation of brain tumor.