• Title/Summary/Keyword: 조시차

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Assessment of Practical Use of Recycling Oil from the Pyrolysis of Mixed Waste Plastics (혼합폐플라스틱의 열분해를 통한 회수오일의 이용가능성 평가)

  • Phae Chae-Gun;Kim Young-shin;Jo Chang-Ho
    • Journal of Energy Engineering
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    • v.14 no.2 s.42
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    • pp.159-166
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    • 2005
  • In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

Determination of Estrone by Adsorptive Stripping Voltammetry (흡착 벗김 전압전류법에 의한 에스트론의 정량)

  • Hong, Taekee;Kyong, Jin Burm;Lee, Hyun Jung;Czae, Myung-Zoon
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.34-39
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    • 1999
  • Estrone such as estriol and estradiol can not be determined by votammetric methods, because these are electrochemically inactive in the potential windows for mercury drop electrode. Nitro-derivatives of estrone are electro active and nitration of estrone is accomplished by heating the solution involving estrone and sodium nitrite in a water-bath at $100^{\circ}C$ for 30 min. Such nitro-derivatives are determined directly by voltammetry. The electrochemical behavior for nitrated estrone was investigated by cyclic voltammetry. The trace estrone was determinated by differential pulse adsorptive cathodic stripping voltammetry. Nitrated estrone gives a well defined voltammetric wave at ca. - 0.61 V (vs. Ag/AgCl electrode). The electrochemical reaction was irreversible process in sodium borate buffer at pH 11 and nitrated estrone was strongly adsorbed on the surface of mercury electrode. The optimal experimental conditions for the determination of nitrated esterone were found to be 0.05 M sodium nitrate, 0.01 M sodium borate, pH 11.0, and an accumlation potential of 0.10 V (vs. Ag/AgCl). The detection limit was as low as $1{\times}10^{-9}M$ for estrone with 2 min accumulation time.

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Manufacture of Ordinary Portland Cement Clinker Using Cement Paste of the Waste Concrete (폐콘크리트로부터 회수된 시멘트 페이스트 미분말의 시멘트 원료화 연구)

  • Ahn, Ji-Whan;Kim, Hyung-Seok;Cho, Jin-,Sang;Han, Gi-Chun;Han, Ki-Suk;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.40 no.8
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    • pp.804-810
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    • 2003
  • The fine powder produced by heating and grinding of the waste concrete in the waste construction was investigated whether utilize as substitution raw material of SiO$_2$, CaO, and Al$_2$O$_3$ source for OPC clinker manufacture is possible or not. In order to synthesize OPC clinker, limestone, shale, converter slag and fly ash were used as main raw materials, and modulus was fixed LSF 91.0, SM 2.60, IM 1.60. The synthesized clinkers were characterized. The Main products of synthesized clinker were C$_3$S, ${\beta}$-C$_2$S, C$_3$A, C$_4$AF as OPC clinker at 1,43$^{\circ}C$. As a result of TG-DTA and burnability index(B.U) analysis of each raw mixtures, the formation temperature of clinker phases was similar and B.I was showed easy burning as 48.6∼51.4.

SEASONAL VARIATIONS OF CHLORIDE, CALCIUM AND MAGNESIUM ION CONCENTRATIONS IN NAGDONG RIVER WATER AT MUL GEUM INTAKE STATION OF BUSAN CITY WATER FROM MARCH 1974 TO MARCH 1975 (낙동강 물금구취수장 상수도원수의 염화이온 칼슘 마그네슘 농도의 연간변동에 대하여(1974년-1975년))

  • WON Jong Hun;YANG Han Serb
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.11 no.2
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    • pp.103-109
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    • 1978
  • The contents of chloride ion, calcium and magnesium in Nagdong River water were determined at Mul Geum where the intake station for Busan city water is located. Samples were taken in spring and neap tides of every month from March 1914 to March 1975. The range and mean values of the chloride ion and total hardness were 5.12-39.4ppm, 11.9ppm; 27.8-70.8ppm, 49.5ppm respectively from March 1974 to January 1975. The highest values were found in the period of the widest tidal range of a year, from February 9 to March 9 in 1975, such as tile ranges and means of chloride ion and total hardness were 10.8-876 ppm, 89.8ppm : 48.0-407ppm, 89.9ppm. On several days of this period those concentrations were over the criteria of drinking water, 150 ppm in chloride and 300ppm in total hardness. Chloride ion concentration was increased with increasing of water level of the Nagdong River at Mul Geum. The patterns of the variations of tide level were similar to that of water level with delay of 2.5 hours in spring tides and 3 hours in neap tides.

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Gel Properties of Mook Manufactured from Acorns Harvested in Various Countries according to Storage Period (수입 원산지별 도토리묵의 저장기간에 따른 겔화 특성)

  • Yang, Kee-Heun;Lee, Kun-Jong;Kim, Mee-Ree
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.8
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    • pp.1168-1175
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    • 2012
  • Gel properties of Mook manufactured from acorn harvested in various countries [domestic (KAS), Chinese (CAS), and North Korea (NAS)] were analyzed according to storage period. Gel properties included water binding, syneresis of gel, DSC (differential scanning calorimetry), X-ray diffraction, SEM (scanning electron microscopy), texture, Hunter's color value, and sensory value. Water binding of NAS, CAS, and KAS were 233.8%, 217.3%, and 215.0%, respectively. Syneresis of gel from KAS, CAS, and NAS were 2.06%, 1.85%, and 1.45%, respectively, after 1 day of storage. There were significant differences upon storage for 1~3 days (p<0.05), whereas were no significant differences upon storage for 4~10 days. Peak temperature of gelatinization property by DSC was $55.28^{\circ}C$ for KAS, $54.45^{\circ}C$ for CAS, and $54.12^{\circ}C$ for NAS after 1 day of storage. Hardness of texture in NAS, KAS, and CAS were 374.9, 357.4, and 348.9, respectively, after 1 day of storage. Hunter's color L value, and a value were highest in NAS, whereas b value was the lowest in CAS. There were no significant differences in any particular sensory values.

A Method to Use the Land-Use Zoning Information to Extract the DIF Zones (기반시설부담구역 추출을 위한 용도지역지구 공간정보 적용방안 연구)

  • Lee, Yong Jik;Choei, Nae Young
    • Journal of Korean Society for Geospatial Information Science
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    • v.22 no.1
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    • pp.89-99
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    • 2014
  • The current Development Impact Fee (DIF) Zoning Law allows Korean localities to designate the DIF Zone for the areas where there have been up-zoning in land-uses due to any minute additions and/or amendments in the existing clauses or provisions in the National Territory Planning Law as well as all other laws related to urban and regional planning. In reality, however, it is almost impossible to trace the sporadic and infinitesimal changes that might occur in every corner of the statutory clauses of a great number of planning related laws. This study, in an effort to overcome such practical difficulties, tries to chase the time-series zoning alterations in especially the consecutive land-use information layers of the Korea Land Information System (KLIS) as comparable analogues of the outcomes of the amendments in various planning laws. A study locality is chosen among the entire localities in the Capital Region based on the selection criteria dictated by the DIF Zoning Law such as the population- and building permit increase rate. It has been verified that the methodology suggested herein is practically applicable and successfully capable of extracting a number of DIF zones with considerable areal sizes, which could not have otherwise been possible. The consequences of this study, in this context, are expected to contribute to prevent the uncontrolled developments as the DIF Zoning Law itself was originally intended to achieve.

SEASONAL VARIATIONS OF THE CONTENTS OF INORGANIC CONSERVATIVE CONSTITUENTS OF NAGDONG RIVER WATER AT MULGEUM INTAKE STATION OF BUSAN CITY WATER FROM JANUARY 1979 TO APRIL 1980 (낙동강 물금취수장 상수도 원수의 무기보존성분량의 연간변동에 대하여(1979년 1월-1980년 4월))

  • LEE Bae Jung;WON Jung Hun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.13 no.3
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    • pp.103-108
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    • 1980
  • The contents of inorganic conservative constituents in Nagdong River water were determined at Mulgeum where the intake station for Busan city water is located. Samples were taken at intervals of one hour from 7 a.m. to 7 p.m. at spring and neap tides of every month from January 1979 to April 1980. Annual ranges and means of the chemical constituents were as follows: electrical conductivity $99-912\mu\mho/cm,\;200\mu\mho/cm;$ chlorides 6.0-256 ppm, 17.2 ppm; sulfates 4.1-37.9 ppm, 23.5 ppm; calcium 4.2-28 ppm, 13 ppm; magnesium 2.2-23 ppm, 5.6 ppm; sodium 5,0-126 ppm, 14 ppm; and potassium 1.2-10.8 ppm, 2.6 ppm respectively. At several times in this period, the concentrations of chloride ion exceeded 150 ppm that is the criteria for drinking water. The chloride ion concentration was higher at spring tides than that at neap tides and the contents of inorganic conservative constituents were higher in winter than those in summer. The chloride ion concentration showed the highest value at Mulgeum about 4 hors after the high water in Busan harbour.

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pH Solubility Properties and Improved Dissolution of Pranlukast as an Poorly Water-soluble Model Drug Prepared by Spray-drying with Plasdone S-630 (플라스돈 S-630과 함께 분무건조된 모델 난용성 약물로서 프란루카스트의 pH 용해도 특성 및 용출률 개선)

  • Cho, Won-Hyung;Lee, Young-Hyun;Song, Byung-Joo;Yoo, Seok-Cheol;Lim, Dong-Kyun;Khang, Gil-Son
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.277-283
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    • 2011
  • Solid dispersion is mainly used for improved dissolution of poorly water-soluble drugs. Solid dispersion of pranlukast was prepared by spray-drying with plasdone S-630. When pH of water was high, pranlukast was highly soluble in the solubility experiment of solid dispersions with varying pH. The particle size of pranlukast particles in solid dispersions was measured to be in nanometers scale based on particle size analysis. Zeta-potential analysis confirmed the negative charge of solid dispersion. SEM was used to observe the surface of solid dispersion, which confirmed spherical morphology, DSC and XRD confirmed the amorphous nature of solid dispersions. The in vitro test was carried out to find improved dissolution rate of pranlukast solid dispersion in simulated juice gastric and a controlled experiment was carried out to compare pranlukast solid dispersions with a conventional drug (Onon$^{(R)}$), These results showed the dissolution properties of pranlukast solid dispersions prepared by spray drying proper for the oral pharmaceutical formulation.

Physicochemical properties of powdered, soft and hard type rice flour by different milling methods (제분방법에 따른 분질, 연질 및 경질미 가루의 이화학적 특성)

  • Choi, Ok Ja;Jung, Hee Nam;Shim, Ki Hoon
    • Food Science and Preservation
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    • v.22 no.2
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    • pp.174-181
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    • 2015
  • This study investigated the physicochemical properties of three different types of rice flour prepared via dry and wet milling. The powder, soft, and hard-types of rice flour were Suwon No. 542, Suwon No. 541, and Unbong No. 30, respectively. The analysis of the proximate compositions of the different types of rice flour showed that their moisture content was 7.03~7.99%, their crude protein was 7.94~8.35%, their crude lipid was 0.71~1.49% and their crude ash was 0.25~0.82%. For the Hunter's color values, the L value was highest in the wet-milled rice flour, the a value was highest in the dry-milled rice flour, and the b value was highest in the dry-milled rice flour. All the samples showed distinctive rice starch particles in the particle analysis using scanning electron microscope. The dry-milled rice flour showed the greatest amount of irregular particles and the coarsest texture. The water absorption and water solubility indices were higher in the wet-milled soft- and hard-type rice flour. The crystallinities of the samples by X-ray diffractography were all A-type, but the crystallinity of the dry-milled hard-type rice flour was higher in diffraction degree. For the amylogram properties, the wet-milled soft-type rice flour showed the highest maximum viscosity, breakdown and setback. In the meanwhile, the dry-milled soft-type rice flour showed the highest initial pasting temperature, onset, peak, and end temperatures despite of the reverse enthalpy.

Comparisons of Characteristics of Amaranth Starches Isolated from five Cultivars Grown in Korea (국내산 아마란스로부터 분리한 전분의 특성 비교)

  • Choi, Cha-Ran;Choi, Hun-Jae;Kim, Sung-Ran;Lee, Jae-Hak;Shin, Mal-Shick
    • Korean Journal of Food Science and Technology
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    • v.32 no.2
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    • pp.252-257
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    • 2000
  • The physicochemical and pasting properties of amaranth starches isolated from five cultivars, Andy, Suvarna, Nu World, K266-1, K432, grown in Korea, were investigated. The shapes of starch granules were all polygonal and size was in the range $1.14{\sim}1.48\;{\mu}m$ for all five cultivars. X-ray diffractograms were shown typical A type diffraction patterns for all amaranth starches. The protein and crude lipid contents of starches were $0.13{\sim}0.23%$ and $0.01{\sim}0.05%$, respectively. The apparent amylose contents ranged from $2.79{\sim}4.35%$ and the water binding capacities were $128.05{\sim}135.80%$. The transmittances of 0.1% amaranth starch suspensions except K266-1 increased rapidly above $65^{\circ}C$, thereafter increased slowely. The initial pasting and peak temperature ranges of five cultivars by RVA were $71.3{\sim}73.7^{\circ}C$ and $81.5{\sim}84.0^{\circ}C$, respectively. The peak and cooling viscosities followed the order : Nu World>Andy>Suvarna>K432>>K266-1. Nu World was shown the highest peak (166), final (103) and cooling viscosities (30 RVU). K266-I exhibited the lowest setback (-38) of all five cultivars. Gelatinization (To) and peak temperature (Tp) of amaranth starches in DSC thermograms were $65.7{\sim}68.0^{\circ}C$ and $70.6{\sim}75.8^{\circ}C$, respectively. Enthalpies followed the order: K266-1

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