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Effects of Adding Mg to AlSi Coating for Hot Stamping Steel (자동차용 핫스탬핑 AlSi 도금중 Mg 첨가효과)

  • Yang, Wonseog;Lee, Jeamin;Kim, Changkyu;Ahn, Seungho;Castaneda, Homero
    • Corrosion Science and Technology
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    • v.20 no.4
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    • pp.196-203
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    • 2021
  • To improve corrosion resistance and reduce the hydrogen uptake of 22MnB5, up to 5% Mg was added to the AlSi coating of 22MnB5. After hot-stamping and electrocoating were done on the metallic-coated specimen, the surface characteristics of the steel, hydrogen uptake content, and corrosion resistance were examined by transmittance electron microscopy, thermal desorption spectrometry, cyclic corrosion testing, and electrochemical impedance spectroscopy. Mg was investigated as MgO on the surface layer after hot-stamping while it existed as Mg2Si before hot-stamping. The total hydrogen content of 22MnB5 was decreased along with the Mg content. However, there was no difference at 0.2 wt% or more. When a small amount of Mg was added, the coating corrosion resistance was decreased, but when it was added at around 1.0 wt%, the greatest corrosion resistance increase was seen. However, when 3 wt% or more was added excessively, the corrosion resistance was decreased. MgO on the surface was considered to suppress H uptake by the AlSi melting solution and increase the barrier effect of the coating.

Effect of Carbon Equivalent and Cooling Rate on Microstructure in A516 Steels for Pressure Vessel (압력용기용 A516 강의 미세조직에 미치는 탄소 당량과 냉각 속도의 영향)

  • Lee, Hyun Wook;Kang, Ui Gu;Kim, Min Soo;Shin, Sang Yong
    • Korean Journal of Materials Research
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    • v.29 no.8
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    • pp.511-518
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    • 2019
  • In this study, the effect of carbon equivalent and cooling rate on microstructure and hardness of A516 steels for pressure vessel is investigated. Six kinds of specimens are fabricated by varying carbon equivalent and cooling rate, and their microstructures and hardness levels are analyzed. Specimens with low carbon equivalent consist of ferrite and pearlite. As the cooling rate increases, the size of pearlite decreases slightly. The specimens with high carbon equivalent and rapid cooling rates of 10 and $20^{\circ}C/s$ consist of not only ferrite and pearlite but also bainite structure, such as granular bainite, acicular ferrite, and bainite ferrite. As the cooling rate increases, the volume fractions of bainite structure increase and the effective grain size decreases. The effective grain sizes of granular bainite, acicular ferrite, and bainitic ferrite are ~20, ~5, and ${\sim}10{{\mu}m$, respectively. In the specimens with bainite structure, the volume fractions of acicular ferrite and bainitic ferrite, with small effective grains, increase as cooling rate increases, and so the hardness increases significantly.

The Study on Material Characteristics of Slags Excavated from Iron Making Site (제철 유적 출토 철재(鐵滓)의 재료학적 특성 연구)

  • Kang, Yoon-Hee;Cho, Nam-Chul;Song, Hyeon-Jeong;Go, Hyeong-Sun
    • Journal of Conservation Science
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    • v.26 no.2
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    • pp.171-182
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    • 2010
  • The slag excavated from Gyesil-ri in Gongju, Yeonje-ri in Cheongwon and Beopcheonsaji (temple) site in Wonju are analyzed by X-ray Fluorescence Analyzer, metallurgical microscope, SEM-EDS etc., for chemical composition and microstructure to figure out the raw material and the iron manufacturing technique. First of all, as a result of principal component analysis, the total Fe-content of slag from Gyesil-ri is 39 to 44% and the modified rate is 15 to 21%, which is common in ancient iron slag. Yeonje-ri site is found the ancient iron-smelting furnace. The total Fe-content of slag from Yeonje-ri is 41 to 43% and modified rate is 18~30%, which is also the general value in the ancient slag. However only slag is excavated in the residential area at Beopcheonsaji site and there is no iron making relic. In addition, the result of principal component analysis contains that the total Fe-content of Beopcheonsaji site is 52 to 57%, and modified rate is 8 to 14%. It shows that the total Fe-content of Beopcheonsaji site is higher than relic from Gyesil-ri and Yeonje-ri and the modified rate is lower than other sites. This results mean that recollecting rate of Fe in Beopcheonsaji site is lower than other sites. Also, as a result of minor elements analysis, the slag from Gyesil-ri has the higher level of Ti, V and Zr than other sites and the microstructure are observed as magnetite and ulvospinel, so that the raw material of slag is iron sand. But the slag from Yeonje-ri and Beopcheonsaji site are identified to use iron ore. As a result of microstructure observation, fayalite, gray-columnar crystal, is found in the slag from Yeonje-ri and big wustite as main phase is observed in the slag from Beopcheonsaji site. This study show that the slag from Yeonje-ri is made of smelt ash produced during smelting works and the slag from Beopcheonsaji site is made of forging ash produced during forging work concerning the excavated location and the microstructure.

A Study on Iron Manufacturing and Technology through Analysis Reports of Iron artifacts in the Baekje Area (유물분석 자료를 통한 백제지역의 제철과 철기 제작기술 연구)

  • Kim, Soo-Ki
    • Journal of Conservation Science
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    • v.30 no.4
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    • pp.335-343
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    • 2014
  • This study classified the result of non-metallic inclusion analysis and result of microstructure investigation on the ironware excavated in the Baekje region into Han River, Geum River, and Yeongsan River to estimate the iron making temperature and study the characteristics of regional and temporal characteristics of the heat treatment technology and steel making technology. Regardless of era, bloom iron and sponge iron are judged to be the major method for making as a directreduction process in all three regions. The result of the reinterpretation of the non-metallic inclusion by the oxide ternary constitutional diagram suggest that the temperature inside of the furnace is estimated to be between $1,100{\sim}1,300^{\circ}C$ while making the steel. The magnetic iron ores are the major raw material of steel ore and irons with high $TiO_2$ are estimated to use iron sands. Ironware with $CaO/SiO_2$ rate higher than 0.4% are considered to have artificially added the flux of calcareous materials. It was found that the iron making method is the solid caburizing-steel which caburizes low-carbon steels by the CO gas and $CO_2$ gas created when heating the forging furnace with charcoal. Also, the ironware manufacturers in the Baekje during 3rd century recognized the heat treatment technology as they performed carburizing process and quenching to intentionally increase the strength of necessary parts.

Scientific Analysis of Slags and Furnace Wall collected from Iron Production Site at Suryong-ri Wonmorongi in Chungju (충주 수룡리 원모롱이 야철지 수습 철재 및 노벽의 과학적 분석)

  • Cho, Hyun-Kyung;Cho, Nam-Chul;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.29 no.2
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    • pp.139-147
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    • 2013
  • This study focused on iron making related information through analyzing slags and furnace wall collected from iron production site of Suryong-ri Wonmorongi, Chungju. Total Fe content of slags were from 36.98% to 44.47% and this range was general recovery rate of iron in ancient. Compounds of calcium included slags was supposed to add intentionally during smelting process as deoxidation agent in order that these helped to separate iron from impurities. Furnace wall didn't make of high alumina clay because of low $Al_2O_3$. Microstructure and main components of slags show that No. 1 to 3 slags with fayalite and wustite were products of iron ore smelting. However, No.4 slag is more likely to smelt by iron sand because of ulvospinel with $TiO_2$ in No. 4 slag. Therefore, iron ore were not only used but iron sand in smelting and furnace wall made of general clay with low $Al_2O_3$ content in this area.

광양만 제품부두 1, 2, 3, 4 선석 및 고철부두의 계류안정성 검토

  • Kim, Yeong-Bok;Kim, Se-Won;Jeong, Tae-Gwon
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2010.10a
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    • pp.94-99
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    • 2010
  • 광양제철소의 광양만 제품부두에 접안하여 양하역 할 대상선박에 대해 여러 가지 해상조건에 대해 계류해석을 수행하였으며, 이를 통해 광양만 부두에서의 계류 적정선박을 선정하기 위한 기준 설정의 기초자료를 만들기 위해 노력하였다.

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열간 압연 공정에서의 플라잉 터치 기법 연구

  • Kim, Seong-Jin;Kim, Hyeon-Hui;Yun, Seong-Min;Choe, Yong-Jun;Lee, Min-Cheol
    • ICROS
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    • v.21 no.3
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    • pp.20-24
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    • 2015
  • 산업이 발달함에 따라 품질이 좋으면서 가격이 저렴한 철판에 대한 수요가 늘어나고 있다. 이러한 수요를 만족시키기 위해 제철소에서는 압연 시 발생하는 불량을 줄이기 위한 연구를 하고 있다. Flying Touch 기법은 열간 압연 시 발생하는 스크래치 불량을 줄이기 위한 방법이다. 본 논문에서는 Flying Touch 기법의 특징에 대하여 소개하고 Flying Touch 기법을 적용하여 실험할 수 있는 시뮬레이터의 설계와 제작에 대하여 간략하게 소개하였다. Flying Touch 기법은 아직 연구개발 단계의 방법이지만 제어 이론의 변화와 연구를 통해 더욱 개선될 수 있다.

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Sintering Behavior of Zirconium Diboride with addition of Sintering Agents (소결조제 첨가에 따른 반응소결 탄화규소계 세라믹스의 특상 향상)

  • 우상국;한인섭;홍기석;서두원;장병국
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 2002.05a
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    • pp.149-154
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    • 2002
  • 산업 부문 중 고온을 이용하는 에너지 다소비 부문인 제철ㆍ제강업, 요업, 화학공업, 및 금속공업 등에 있어서 고온 예열의 낭비 및 잦은 부품의 교체로 인해 가격의 상승, 국제 경쟁력의 약화 및 에너지 낭비가 초래되고 있다. 특히 알루미늄, 동 등의 금속 용해로에 사용되는 로재의 경우 금속재를 사용할 경우 고온에서의 사용이 제한적이며 부식 등에 의한 잦은 교체로 정확한 품질제어가 불가능하다.(중략)

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공기공급 시스템에 적용되는 Vortex Tube의 에너지 분리특성에 관한 연구(II) -표면의 단열효과에 따른 영향-

  • 추홍록;상희선;이병화
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 1998.05a
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    • pp.19-24
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    • 1998
  • vortex tube의 에너지 분리현상이 Ranque에 의해 처음으로 발견된 이래 vortex tube는 산업현장에서의 그 이용률이 점차 증대되고 있다. 특히, 최근에는 작업자의 쾌적한 작업환경을 조성하여 작업능률을 향상시킬 목적으로 제철소 등의 고온, 고습 작업장이나 분진, 석면, 유해먼지나 가스, 증기 등이 많이 발생하는 작업장에서 냉각복(air cool jacket) 또는 공기공급식 호흡보호구의 공기공급시스템에 많이 활용되고 있다. 이러한 vortex tube를 이용한 냉각복 및 호흡보호구는 작업자의 능률향상뿐만 아니라 직업병의 예방 및 안전측면에서 매우 효율성이 높아 그 적용범위가 점차 확대될 전망이다. (중략)

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Development of a radiation thermometer for the adaptive steel plant (제철소 적응형 복사온도계 개발)

  • Park, Sang-Gug
    • Journal of the Korean Society of Industry Convergence
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    • v.5 no.3
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    • pp.173-178
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    • 2002
  • In this research, we have worked about the radiation thermometer which can be applied to the hazard circumstance such as steel plant. In the results, we have developed radiation thermometer of a measuring range $500-1500^{\circ}C$, accuracy ${\pm}0.1%$, repeatability ${\pm}0.1%$, resolution $0.2^{\circ}C$. We performed extensive field test for 6 months at the hot strip mill in steel plant. Through the test, we have confirmed the reliability of the developed pyrometer.

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