• Journal of the Mineralogical Society of Korea
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• v.15 no.1
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• pp.11-21
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• 2002

A mineralogical study was made in order to identify the relationship between uranium content in groundwater and rock chemistry using core rocks recovered from the drilling holes for wells in the Daebo Granite areas. Uraniferous minerals are of primary origin and occur as inclusions in accessory minerals such as zircon, monazite, and xenotime. Since the uraniferous minerals are very small to be 1 ~ 2 $\mu$m in size, it is difficult to distinguish their mineralogical species precisely. The frequent presence of dissolution cavities or dissolved textures in the accessory minerals suggests that uraniferous minerals dissolved partially and contributed to the groundwater chemistry. Because there is no clear relationship between host rocks and groundwater for uranium concentration, mineralogical characteristics of uraniferous minerals, together with aqueous geochemical conditions favorable for uranium dissolution, could play important roles in groundwaster chemistry.

• The Journal of Engineering Geology
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• v.32 no.2
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• pp.295-310
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• 2022

The Weolaksan and Sokrisan granites yield high SiO₂ and alkali (Na₂O+K₂O) contents and low CaO and P₂O₅ contents. The Al saturation index is ≥1.3, which indicates that the granites are peraluminous. The mean U and Th contents are 8.3 and 39.3 ppm, respectively, higher than typical Mesozoic granites in South Korea and about twice the global mean for granitic rocks. The causes of such high radioelement contents are related to high degrees of fractionation and the crustal origin of the granites. U- and Thbearing radioactive minerals occur in the granites include zircon, thorite, monazite, xenotime, fergusonite and uraninite. The fact that the mean Th/U ratio of the granites (5.4) is similar to the global average crustal value suggests that the radioelement contents of granite were controlled by the crustal source material. Given the correlation of Zr, Y, and heavy rare earth elements for U and Th, radioelements are more likely hosted by xenotime than zircon and monazite.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.289-302
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• 2007

Separation process of heavy minerals was performed with sand from Dunjang beach of Jaeundo, Shinangun, Chonnam, and the feasibility study separating heavy minerals was carried out, and their properties were studied. Samples were selected in three parts, which were upper part, middle part and lower part, with depth. Samples of heavy mineral groups separated with the spiral separator were chosen as starting materials, and they were separated with 3 times of table separation. Heavy minerals presenting in this area were ilmenite, zircon, rutile, anatase, monazite, and xenotime. In the results of 3 times of table separation, minor content of quartz, orthoclase, albite and muscovite were existed as gangue minerals. Accordingly, we concluded that additional specific gravity separation was needed. In the results of separation of heavy minerals by hand picking, it was confirmed that heavy minerals had various genesis because of their various roundness and color.

• Journal of the Mineralogical Society of Korea
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• v.15 no.2
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• pp.85-94
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• 2002

XRF, XRD, EPMA have been used to investigate microstructures and mineralogical changes caused by the faulting and fluids associated with faulting in the Quaternary fault gouge zones at the Sangchon, Ipsil and Wangsan faults located at the southeastern part of the Korean Peninsula. The chemical compositions of faulted rocks and protoliths analyzed by XRF show that the fault gouges are relatively enriched in TiO$_2$, P$_2$O$_{5}$, MgO, and Fe$_2$O$_3$) compared with protoliths, indicating that the fluids associated with faulting were highly activated. XRD results show that the fault gouges predominantly consist of quartz, feldspar, calcite and clay minerals. Clay minerals formed in the gouge zones are mainly composed of smectite characterized by a dioctahedral sheet. Based on EPMA analyses various kinds of sulfide, carbonate, phosphate minerals were identified in the gouge zones and protoliths. Xenotime of grey fault gouge of the Sangchon fault and sulfide minerals of contact andesitic rock of Ipsil fault and contact grey andesitic rock of Wangsan fault were probably formed by inflow of hydrothermal solution associated with faulting prior to the Quaternary. Carbonate minerals of contact andesitic rock and gouge zone of the Ipsil fault were formed by inflow of fluid associated with faulting prior to the Quaternary. They are heavily fractured and have reaction rim on their edge, indicating that faultings and inflow of fluids were highly activated after carbonate minerals were formed. Calcites of Wangsan fault seemed to be formed in syntectonic or posttectonic Quaternary faulting.g.

• Economic and Environmental Geology
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• v.45 no.6
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• pp.599-622
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• 2012

The phase I soil geochemical exploration was carried out targeting around Chau Binh area far from about 14 km with southeastern direction from Quy Chau within Nghe An province. The interval of sampling are horizontal 300 m with 14 line and longitudinal 500 m with 15 line, resulting in 194 soil samples. Based on the result of the phase I soil geochemical exploration, the phase II detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 56 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and Dai Loc gneissic granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite(about 300 g/t) and xenotime(about 10 g/t) to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the phase I soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.84 times). As a analysis result with ICP-MS on the soil samples from the phase II soil detailed pit survey, we identified outcrop considering as economic ore body at the grid point 4-7 pit with N40W attitude. As a synthetic consideration on the phase I soil geochemical exploration and phase II detailed pit survey, we tentatively designated areas considering as the extension of economic ore body with REE anomaly. In the near future, we have the plan to carry out the geophysical exploration and test drilling targeting the interval anticipated to the economic ore body.

• Journal of the Mineralogical Society of Korea
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• v.31 no.3
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• pp.193-213
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• 2018

Soil geochemical exploration to check anomalies related to mineralization was carried out targeting around Quy Hop area within Nghe An province, Northern Vietnam. The interval of sampling are horizontal 250 m with 13 line and longitudinal 300 m with 25 line, resulting in 325 soil samples. Based on the result of soil geochemical exploration, the pitting survey was carried out targeting the grid point with high TREO content, resulting in 73 soil samples within 8 pits. The geology of the survey area are consisted of Ban Chieng biotite granite complex intruding Bu Khang formation comprising of schist, gneiss and limestone. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. By ICP-MS result of soil samples, total REE oxide content of background amount is about 1.4 times of crustal abundance, depleting the light rare earth (about 0.2 times) and enriching the heavy rare earth (about 1.5 times). By ICP-MS result of pit soil samples, we identified TREO more than 1,000 ppm in 6 pits. It may be considered that REE ore bodies may develop in NE-SW direction, compared with the geochemical results of Quy Chau area.

• Economic and Environmental Geology
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• v.46 no.2
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• pp.179-198
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• 2013

The Boziguoer A-type granitoids in Baicheng County, Xinjiang, belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks. The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite, an aegirine or arfvedsonite alkali feldspar granite, and a biotite alkali feldspar syenite. The major rock-forming minerals are albite, K-feldspar, quartz, arfvedsonite, aegirine, and siderophyllite. The accessory minerals are mainly zircon, pyrochlore, thorite, fluorite, monazite, bastnaesite, xenotime, and astrophyllite. The chemical composition of the alkaline granitoids show that $SiO_2$ varies from 64.55% to 72.29% with a mean value of 67.32%, $Na_2O+K_2O$ is high (9.85~11.87%) with a mean of 11.14%, $K_2O$ is 2.39%~5.47% (mean = 4.73%), the $K_2O/Na_2O$ ratios are 0.31~0.96, $Al_2O_3$ ranges from 12.58% to 15.44%, and total $FeO^T$ is between 2.35% and 5.65%. CaO, MgO, MnO, and $TiO_2$ are low. The REE content is high and the total ${\sum}REE$ is $(263{\sim}1219){\times}10^{-6}$ (mean = $776{\times}10^{-6}$), showing LREE enrichment HREE depletion with strong negative Eu anomalies. In addition, the chondrite-normalized REE patterns of the alkaline granitoids belong to the "seagull" pattern of the right-type. The Zr content is $(113{\sim}1246){\times}10^{-6}$ (mean = $594{\times}10^{-6}$), Zr+Nb+Ce+Y is between $(478{\sim}2203){\times}10^{-6}$ with a mean of $1362{\times}10^{-6}$. Furthermore, the alkaline granitoids have high HFSE (Ga, Nb, Ta, Zr, and Hf) content and low LILE (Ba, K, and Sr) content. The Nb/Ta ratio varies from 7.23 to 32.59 (mean = 16.59) and the Zr/Hf ratio is 16.69~58.04 (mean = 36.80). The zircons are depleted in LREE and enriched in HREE. The chondrite-normalized REE patterns of the zircons are of the "seagull" pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly. The Boziguoer A-type granitoids share similar features with A1-type granites. The average temperature of the granitic magma was estimated at $832{\sim}839^{\circ}C$. The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature, anhydrous, and low oxygen fugacity conditions.

• Economic and Environmental Geology
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• v.47 no.2
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• pp.147-168
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• 2014

The soil geochemical exploration was carried out targeting around Tri Le area far from about 30 km with northwestern direction from Que Phong within Nghe An province. The interval of sampling are horizontal 200 m interval with 23 line and longitudinal 300 m with 10 line, resulting in 228 soil samples. Based on the result of the soil geochemical exploration, the detailed pitting survey was carried out targeting the grid point with high TREO content, resulting in 75 soil samples within 7 pits. The geology of survey area are consisted of Ban Chieng biotite granite complex and granitic gneiss intruding Ban Khang formation comprising of quartz schist and marble. Main mineralization in the study area have the characteristics of occurrence with tin, ruby and REE-bearing monazite and xenotime to be thought as occurring at the alteration zone of granite complex. In order to elucidate the source rock of monazite and xenotime confirmed from heavy sand, soil geochemical exploration was carried out. As a analysis result with ICP-MS on the soil samples from the soil geochemical exploration, total REE oxide content of background amount to about 2 times of crustal abundance, enriching the heavy rare earth(about 2 times) and light rare earth(about 1.5 times). As a analysis result with ICP-MS on the soil samples from the soil detailed pit survey, we only identified outcrop considering as economic weathered granite body at the grid point 1-10 pit among 7 pits. As a synthetic consideration on the soil geochemical exploration and detailed pit survey, we tentatively designated Tri Le area as no promising target for REE. In 2014, we have the plan to carry out the soil geochemical exploration targeting the extended economic REE ore body in Quy Chau as project area from 2011 to 2012.