• Title/Summary/Keyword: 접촉처리

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Effect of Surface Treated SiC on Thermal Stability and Mechanical Interfacial Properties of Carbon Fiber/Epoxy Resin Composites (탄소섬유 강화 에폭시 수지 복합재료의 열안정성 및 기계적 계면특성에 미치는 SiC 표면처리 영향)

  • 박수진;오진석;이재락;이경엽
    • Composites Research
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    • v.16 no.3
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    • pp.25-31
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    • 2003
  • In this work the effect of surface treated SiC on thermal stability and mechanical interfacial properties of carbon fiber/epoxy resin composites. The surface properties of the SiC were determined by acid/base values and contact angles. The thermal stabilities of carbon fiber/epoxy resin composites were investigated by TGA. The mechanical interfacial properties of the composites were studied in ILSS, critical stress intensity factor ($\textrm{K}_{IC}$), and critical strain energy release rate($\textrm{G}_{IC}$) measurements. As a result, the acidically treated SiC(A-SiC) had higher acid value than untreated SiC(V-SiC) or basically treated SiC(B-SiC). According to the contact angle measurements, it was observed that chemical treatments led to an increase of surface free energy of the SiC surfaces, mainly due to the increase of the specific(polar) component. The mechanical interfacial properties of the composites including ILSS, $\textrm{K}_{IC}$, and $\textrm{G}_{IC}$ had been improved in the specimens treated by chemical solutions. These results were explained that good wetting played an important role in improving the degree of adhesion at interfaces between SiC and epoxy resin matrix.

Sorption of ο-Cresol by Granular Activated Carbon (GAC) and Abiotic Transformation on GAC Surface (입상활성탄에 의한 오르토크레졸(ο-cresol)의 흡착과 비생물학적 변형)

  • 한인섭;김용환
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.87-94
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    • 2004
  • The effects of pretreatment of GAC and dissolved oxygen (DO) on the sorption capacity for ο-cresol were investigated using pretreated GAC under oxic and anoxic conditions. Virgin GAC was used with pretreated GACs by $O_2$, acid and base as sorbents. Sorption capacity of GAC was dependent on the oxygen conditions according to the pretreatment methods. Virgin GAC showed increased sorption capacity when DO was present in the solution, while $O_2$-pretreated GAC did not show any considerable capacity change. Acid- and base-pretreated GACs were relatively more influenced by presence of DO as compared with virgin GAC. Both acid and base-pretreated GACs showed a rapid sorption rate at the initial stage, but as contact time became longer the sorption was slower. Sorbed ο-cresol was extracted with micro-Soxhlet extraction apparatus using the GAC separated from the rate experiments. Within 1 hour both acid and base-pretreated GACs showed the decrease in extraction efficiencies under both oxic and anoxic conditions. After 1 hour such a trend (the increase as contact time was longer) was not observed and showed relatively constant efficiencies of 35∼50%. According to the results of this study $O_2$contacted with GAC before sorption as well as DO present in the solution during sorption could influence the GAC sorption capacity.

충적층 지하수의 철, 망간 기작 및 효율적 처리 방안 연구 -강변여과수 개발 현장을 중심으로-

  • 김형수;김충환;김병군;백건하;최현숙
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.125-128
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    • 2002
  • 강변 여과 취수 방식을 활용한 국내 충적층 지하수의 이용을 위해서는 망간에 대한 수처리가 주요 사항인 것으로 나타났다. 강변 여과 방식 취수 원수의 망간 함량은 먹는 물 수질 기준을 부분적으로 상회하지만, 이러한 망간에 대한 저감 처리는 기존의 지표수를 취수하여 처리하는 수처리 공정에 비해서는 상대적으로 효율적인 것으로 판단된다. 실제로, 국내 최초의 강변 여과 방식 취수를 활용하는 창원시 대산 지구 원수는 공기 포기, 급속 여과, 활성탄 여과를 통해, 먹는 물 수질 기준을 상회하는 망간을 효과적으로 처리하고 있는 것으로 평가되었다. 특히, 활성탄 여과가 망간제거 효과를 보이는 점은 특이한 현상으로, 활성탄 내에서도 철 관련 박테리아에 의한 망간 처리 가능성을 시사하고 있다. 또한 망간과 함께 나타나는 철 성분은 망간의 침전 처리에 긍정적인 면으로 작용하는 것으로 판단된다. 한편, 고령군 다산면에서의 실증 플랜트 실험은 전염소처리와 망간접촉여과를 통해 먹는 물 기준 이하의 망간 함량을 확보하는 데는 성공하였으나, 이러한 처리 기작이 안정화되는데 까지는 약 3개월 내외의 시간이 요구되는 것으로 나타났다.

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Effect on Co-Situs Application of Coated Urea Complex Fertilizer in Dry Seeded Rice (벼 건답직파재배시 완효성 복합비료의 접촉시비효과)

  • Park, Ki-Do;Kwen, Hye-Young;Park, Chang-Young;Jeon, Weon-Tae;Kim, Choon-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.2
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    • pp.112-117
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    • 2002
  • This study was conducted to investigate effects on the co-situs application of coated urea complex fertilizer in dry seeded rice in Dukpyong series soil. Number of spikelet established in 15 days after seeding, conventional plot was $120ea\;per\;m^2$. and whole layer placement(WLP), co-situs application 70%(CSA70%) plot and co-situs application 50%(CSA50%) plot were 146, 126 and $120ea\;per\;m^2$, respectively. There was not concentration obstacle in co-situs application plot in spite of closing application between seed and coated urea complex fertilizer. The amount of $NH_4-N$ into soil solution in different growth stage was highest in WLP 70% plot compare to other treatment. N uptaken amount was highest in CSA 70% plot as $94kg\;ha^{-1}$ compare to $90kg\;ha^{-1}$ of WLP 79% plot and $82kg\;ha^{-1}$ of CSA 50% plot. However, N use efficiency of CSA 50% plot was highest among treatments as 48%. Rice yield was highest in CSA 70% plot as 102% compared to conventional plot.

Butanol Separation/Concentration by Plasma Treated Pervaporation Membrane (저온 플라즈마 처리된 투과증발막의 부탄올 분리/농축 연구)

  • 김현영;임군택;김성수
    • Membrane Journal
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    • v.10 no.4
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    • pp.198-204
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    • 2000
  • Pervaporation membranes were fabricated by low temperature plasma treatment the concentrate butanol solution from fermentation process. Effects of power, reaction time, and monomer flow rate were examined to optimize the (W!FM)t value as 4.0389 x 109 J . min/kg. Various organic compounds were tested in plasma treatment. Contact angle and relative sorption ratio were examined in terms of membrane performance. With the increase of contact angle and relative sorption ratio separation factor was enhanced from 0.186 to 3.525. and butanol flux increased from 0.042 to 0.567 kglm2. hr. Hydrophobicity of the membrane increased the affinity with butanoL Heat of mixing for monomer with butanol was examined, but failed to find the trend, because plasma polymerization of monomer produced the new compounds much different from monomers.

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Enhanced Hydrophilicity of Polyethersulfone Membrane by Various Surface Modification Methods (다양한 표면개질을 이용한 폴리에테르설폰 막의 친수성 향상)

  • Park, So Jung;Hwang, Jun Seok;Choi, Won-Kil;Lee, Hyung Keun;Huh, Kang Moo
    • Polymer(Korea)
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    • v.38 no.2
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    • pp.205-212
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    • 2014
  • Polyethersulfone (PES) membranes were modified by various physico-chemical modification methods to enhance the surface hydrophilicity for application as a separation membrane to separate and collect water vapor from the flue gas. Homogeneous PES flat-sheet membranes were prepared and modified by acid treatment, blending and plasma treatment for hydrophilic surface modification. The surface characteristics of the modified PES membranes were evaluated by ATR-FTIR, XPS, SEM and contact angle measurements. No significant change in hydrophilicity was observed for the PES membranes modified by acid treatment with sulfuric acid or blending with various compositions of poloxamer as an amphiphilic PEO-PPO-PEO tri-block copolymer. On the other hand, Ar plasma treatment led to a significant increase in the hydrophilicity of the surface, depending on the plasma treatment time. As a result, the PES membrane could be the most efficiently surface-treated by applying the plasma treatment for enhancing their surface hydrophilicity.

A Study on the Changes in Surface Properties According to Post-treatment of SLA 3D Printing Materials (SLA 3D 프린팅 소재의 후처리에 따른 표면특성 변화 연구)

  • Bae, Seo Jun;Im, Do Jin
    • Korean Chemical Engineering Research
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    • v.60 no.1
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    • pp.132-138
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    • 2022
  • In this study, a basic study was performed to systematically compare the changes in surface properties according to the post-processing method of the stereolithography (SLA) printing method, which is a photocuring 3D printing method, and to provide information on the post-processing method suitable for the application. Although it was possible to improve some of the transparency of the SLA-type output by regularly changing the irregular microstructure of the surface through polishing, it was difficult to secure sufficient transparency like glass. The change in contact angle characteristics due to grinding showed a tendency to slightly increase as the grinding time increased and the particle size of the sandpaper used was small, but the variation between samples was large and the average contact angle was 77~90°, showing no statistically significant difference. Surface treatment methods other than polishing were tried, and it was confirmed that it was possible to easily and simply improve the transparency by applying a commercially available vehicle scratch remover or silicone oil. In addition, a method for securing high transparency such as glass by using a scratch remover after sequential grinding while reducing the particle size of the sandpaper was proposed. Finally, even after surface treatment through polishing and various methods, it was difficult to secure a contact angle of 90° or more.

Optimal Duration of Determining the Insecticidal Effect of Carbofuran on Nilaparvata lugens Using Different Application Methods (카보퓨란 처리 방법 별 벼멸구에 대한 살충 효과 판별 최적 시기)

  • Lee, Siwoo;Jung, Jin Kyo;Seo, Bo Yoon;Park, Chang-Gyu
    • Korean journal of applied entomology
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    • v.56 no.4
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    • pp.351-356
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    • 2017
  • For determining the insecticidal effect of Carbofuran on the Brown planthopper, Nilaparvata lugens, sucking toxicity by drenching application, sucking and contact toxicity by leaf dipping application, and contact toxicity by topical application were examined. Drenching caused two types of mortality patterns. One was logarithmic curve at a relatively high concentration (8~30 ppm) with over 40% mortality in 24 h, and the other was an S-shaped curve at low concentrations (1~4 ppm) with over 60% mortality on the fifth day after Carbofuran treatment. Leaf dipping application caused a rapid increase in mortality in a day, and this effect decreased steadily with time. Topical application showed steep increase in mortality in a day, and hardly increased thereafter. The best mortality evaluation time for the drenching application was the second day (42 h), and that for the leaf dipping and topical applications was the first or second day after Carbofuran application. When the insecticide has systemic effects, drench application provides the best efficacy and its insecticidal effects persist for a longer time than any other application method.

Development of the Inductive Proximity Sensor Module for Detection of Non-contact Vibration (비접촉 진동 검출을 위한 유도성 근접센서모듈 개발)

  • Nam, Si-Byung;Yun, Gun-Jin;Lim, Su-Il
    • Journal of the Korea Society of Computer and Information
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    • v.16 no.5
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    • pp.61-71
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    • 2011
  • To measure the fatigue of metallic objects at high speed vibration while non-contact precision displacement measurement on how to have a lot of research conducted. Noncontact high-speed vibration detection sensor of the eddy current sensors and laser sensors are used, but it is very expensive. Recently, High-speed vibrations detection using an inexpensive inductive sensor to have been studied, but is still a beginner. In this paper, a new design of an inexpensive inductive proximity sensor has been suggested in order to measure high frequency dynamic displacements of metallic specimens in a noncontact manner. Detection of the existing inductive sensors, detection, integral, and amplified through a process to detect the displacement noise due to weak nature of analog circuits and integral factor in the process of displacement detection is slow. The proposed method could be less affected by noise, the analog receive and high-speed signal processing is a new way, because AD converter (Analog to Digital converter) without using the vibration frequency signals directly into digital signals are converted. In order to evaluate the sensing performance, The proposed sensor module using non-contact vibration signals were detected while shaker vibration frequencies from 30Hz to 1,100 Hz at intervals of vibrating metallic specimens. Experimental results, Vibration frequency detection range of the metallic specimins within close proximity to contactless 5mm could be measured from DC to 1,100Hz and vibration amplitude of the resolution was $20{\mu}m$. Therefore, the proposed non-contact inductive sensor module for precision vibration detection sensor is estimated to have sufficient performance.

The Effect of Plasma on Hydrophilic Surface Modification of LDPE (저밀도 폴리에틸렌의 친수성 표면개질에 미치는 플라즈마의 영향)

  • Hwang, Seung-No;Jeon, Bup-Ju;Jung, Il-Hyun
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.383-387
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    • 1998
  • The effect of hydrophilic surface modification of low density polyethylene(LDPE) byt the plasma gas($O_2$, $N_2$, and $O_2/N_2$) was investigated from the point of view of the functionalities of the generated LDPE surfaces and the contact angle. By virtue of x-ray photoelectron spectra(XPS) and attenuated total reflectance(FT-IR ATR) analysis, the LDPE surfaces treated with plasma were generated with oxygen functionalities of carbonyl, carboxyl, and the like, nitrogen functionalities by nitrogen plasma and mixing of nitrogen and oxygen plasma treatment were identified with. It was found that nitrogen plasma treatment showed with minimum value at contact angle for rf-power and treatment time, we had obtained optimum condition for hydrophilic surface modification at composite parameter, [(W/FM)t] 520~550GJs/kg.

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