• Title/Summary/Keyword: 접촉처리

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Enhancement of adhesion between Cu thin film and Polyimide modified by ion assisted reaction (이온보조 반응법에 의하여 표면처리된 Polyimide (PI) 표면과 구리박막의 접착력 향상)

  • 석진우
    • Journal of the Microelectronics and Packaging Society
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    • v.4 no.1
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    • pp.19-30
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    • 1997
  • 고분자 Polyimide (PI) film 표면을 반응성 가스 분위기에서 1KeV의 에너지를 가지 는 여러 종류의 이온빔으로 조사하여 표면을 개질하였다. PI표면의 친수성과 표면에너지를 측정하기 위해 접촉각 측정기를 사용하였으며 개질 된 표면의 화학적 변화를 측정하기 위해 X-ray photoelectron spectroscopy (XPS)를 사용하였다. 표면 개질을 위한 이온조사량은 5 $\times$1014 -1$\times$1017 ions/cm2이며 반응가스는 0-8scm까지 변화시켰다. 아르곤 이온빔으로 표면 개질시에는 67。에서 40。까지 감소하였고 표면에너지는 46 dyne/cm에서 64dyne/cm까지 증가하였다. 산소를 6sccm 주입하면서 산소 이온빔으로 표면 개질시 물과의 접촉각은 67。 에서 최대 12。까지 감소하였으며 표면에너지는 46dyne/cm에서 72dyne/cm까지 증가하였고 이때의 이온조사량은 5$\times$1014 -1$\times$1017 ions/cm2 이였다. 여러 종류의 반응성 가스와 이온을 사용하여 개질하여 본 결과 산소분위기에서 산소 이온을 이용하여 개질 하였을 때 접촉각이 8。인 표면을 얻을수 있었다, 산소분위기에서 아르곤 이온빔으로 1$\times$1017 ions/cm2 의 이온 조사량으로 개질 된 Pi 시료를 대기 중에 보관하였을 때에는 110시간 후 65。로 증가하였고 물속에서 보관하였을 때에는 46。로 증가하였다. 그러나 산소 이온빔에 산소분위기에서 개 질 된 시료의 경우 물속에 보관할 경우 접촉강의 증가없이 일정한 값을 나타내었다. 이온조 사로 개질된 시료의 화학적 변화를 확인하기 위하여 XPS 사용하였다. 표면 개질 전의 PI 시료와 산소 분위기에서 1$\times$1017 ions/cm2의 아르곤 이온빔으로 개질한 XPS peak 결과로 보아 Cls의 spectra를 보면 C-C, C-N 그리고 C=O의 결합들은 intensity가 감소하였고 C-O 의 intensity는 증가하였다. Nls peak로 보아 imide N 성분은 이온빔의 조사로 인하여 감소 하였고 C-O의 intensity는 증가하였다. Nls peakk로 보아 imide N성분은 이온빔의조사로 감소하였고 Ols peak로 보아 C-O는 증가하였고 C=O는 약간의 감소가 나타났다. 또한 이온 보조 반응법을 이용하여 처리한 시료의 경우 접착력이 증가하는데 이는 주로 C-O 결합의 산소와 Cu와의 상호작요에 의한 것임을 알수 있었다.

Interfacial Adhesion Properties of Surface Treated Polyarylate Fiber with Polyethylene Naphthalate (폴리아릴레이트 섬유의 표면처리에 의한 폴리에틸렌 나프탈레이트 수지와의 계면접착특성)

  • Yong, Da Kyung;Choi, Han Na;Yang, Ji Woo;Lee, Seung Goo
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.24-30
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    • 2012
  • Morphological changes of polyarylate (PAR) fiber treated with formic acid and ultraviolet (UV) were observed by using a scanning electron microscope (SEM) and an atomic force microscope (AFM). The results were analysed by using root mean square (RMS) roughness. In addition, the chemical changes of surface was investigated using contact angle and the interfacial adhesive strength between PAR fiber and PEN (Polyethylene naphthalate) matrix was calculated using the Pull-out test results. As the acid treatment concentration and UV irradiation time increased, cracks and pores were produced on the PAR fiber surface. Due to the roughness increased, the contact angle was decreased. For this reason, RMS roughness of PAR fiber was increased and the interfacial adhesive strength between the PAR fiber and PEN matrix was improved. The increase of interfacial adhesive strength was responsible for the increase of surface area which have cracks and pores.

Evaluation of Insecticidal Activity of Pesticides Against Hemipteran Pests on Apple Orchard (사과과수원의 노린재류에 대한 농약의 생물활성 평가)

  • Lee, Sun-Young;Yoon, Changmann;Do, Yun-Su;Lee, Dong-Hyuk;Lee, Jung-Sup;Choi, Kyung-Hee
    • The Korean Journal of Pesticide Science
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    • v.19 no.3
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    • pp.264-271
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    • 2015
  • Stink bugs do damage on various crops including upland crops and tree fruits. Especially, yellow-brown stink bug (Halyomorpha halys ($St{\aa}l$)) and brown-winged green (Plautia stali) are severely damaged on apple orchard. Using seven insecticides - dinotefuran WP, etofenprox WP, chlorpyrifos WP, cabaryl WP, chlothianidin SC, flonicamid WG, and bifenthrin WG - registered on apple, contact and residual toxicities were tested on both male and female of P. stali and H. halys that preferred apple fruit. Contact toxicity of dinotefuran WP was excellent on male P. stali 48 hours after treatment (HAT) with 96.7% and significant on male Halyomorpha halys 48 HAT with 74.5% but the others had low effect. Contact toxicity on these stink bugs were higher in male than female. All insecticides except flonicamid, residual effects were all effective on both male and female of P. stali, while chlorpyrifos and bifenthrin were showed higher residual toxicity on both male and female of H. halys in laboratory condition. Two insecticides, chlorpyrifos and bifenthrin, were selected for the field test. Bifenthrin have a high residual effect on P. stali until 5 days after treatment, but have a low residual toxicity on H. halys in the field test. Chlorpyrifos showed higher residual toxicity in the laboratory, however, showed low residual efficacy on two species stink bug onto the field.

Efficient Finite Element Analyses of Contact Problems by Domain/Boundary Decomposition Method (영역/경계 분할법을 이용한 저복 문제의 효율적인 유한요소 해석)

  • Ryu, Han-Yeol;Shin, Eui-Sup
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.5
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    • pp.404-411
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    • 2007
  • new domain/boundary decomposition method is suggested to perform efficient finite element analyses of contact problems. A penalty method is used for connecting an interface or contact interfaces with neighboring subdomains that satisfy continuity conditions. As a result, the derived effective stiffness matrices are always positive definite, and computational efficiency can be improved to a considerable degree. Moreover, any complex-shaped domain can be divided into independently modeled subdomains without considering the conformity of meshes along the interface. Using a computer code based on the present method, these advantageous features are confirmed through a set of numerical examples.

Contactor Coupled Sequencing Batch Reactor for Nitrogen Removal (접촉조 결합형 연속회분식반응조를 이용한 질소제거)

  • Nam, Se-Yong;Lee, Sang-Min;Kim, Dong-Wook;Seo, Yong-Chan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.11
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    • pp.1141-1145
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    • 2005
  • A contactor coupled sequencing batch reactor composed of pre-anoxic contact zone and intermittently aerated zone was proposed and operated for nitrogen removal. Emphasis was placed on the fact that the contactor can be operated in a rapid reaction mode that results In biological uptake but incomplete metabolism of organic matter. Consequently, 61.2% of the sewage SCOD was adsorbed to activated sludge by 30-minute contact reaction. The specific uptake of organic matter was 22.3 mg SCOD/g MLVSS that enhanced the denitrification efficiency in the following denitrification stage. The removal efficiencies of the organic matter(SCOD) and the total nitrogen(T-N) were 86% and about 60% at the TCOD/TKN ratio as low as 6.0, respectively.

Dynamic Shear Behaviors on the Normally Consolidation Clay-Geosynthetic Interface (토목섬유-정규압밀점토의 접촉면 동적 전단거동 평가)

  • Bae, Hyogon;Jang, Dongin;Kwak, Changwon;Park, Innjoon
    • Journal of the Korean GEO-environmental Society
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    • v.19 no.12
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    • pp.33-39
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    • 2018
  • In this study, important characteristics were identified for the Geosynthetic-soil interface using overburden pressure and saltwater and fresh water to evaluate silt shear behavior of the Geosynthetic-soil interface. In addition, waste landfill can secure spaces for waste disposal in the sea and this spaces can be used for additional facilities which will be necessary in the future. Analysis of behavior characteristics on interface of Geosynthetic-soil shows that, if analyzed using standard consolidometers, the consolidation stress of fresh water increased significantly more than saltwater. When analyzed using cyclic shear apparatus, saltwater and freshwater in both conditions, the displacement value increases as the wire gauges become closer to the lower module, and the shear fracture tends to occur radically under saltwater conditions than fresh water. Therefore, seawater, fresh water that act on the interface of geosynthetic-soil, and installation of facility using geosynthetic should be considered as important parameters that are essential for the dynamic design factor of the water controlling facility.