• Title/Summary/Keyword: 점도변화

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Development of antibacterial PLA fiber to relieve atopy irritation (아토피완화용 PLA 항균사 개발)

  • Yong, Kwang-Joong;Nam, Seung-Min;Ham, Jin-Soo;Yang, Kwang-Wung;Rho, Yong-Hwan
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.52-52
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    • 2011
  • PLA 섬유는 폴리머의 주성분이 옥수수에서 추출한 모노머를 중합한 화학섬유가 아닌 인체친화적인 식물성 소재이며 생분해성이 좋은 친환경 소재로 최근 주목받고 있는 섬유소재이다. 본 연구에서는 아토피완화용 여러 섬유 구조체 개발에서 사용되는 섬유소재중 PLA 원사에 항균성 물질을 혼입하여 PLA 항균사 제조를 위한 연구를 수행하였다. PLA Grade의 점도가 낮아질수록 Grade별 용융 지수값은 차이를 나타내지만 방사온도 $230^{\circ}C$를 변곡점으로 하여 용융점도가 급격히 변하였으며, 특히 방사온도 $240^{\circ}C$의 경우 용융지수가 100을 넘어가고 폴리머의 색깔이 황갈색을 띄어 폴리머의 열분해가 많이 일어났을 것으로 판단되었다. PLA의 적정 방사온도 구간은 $210{\sim}225^{\circ}C$ 구간이 최적이며 그 이상에서는 Color 변화 및 물성 저하가 나타나는 것으로 판단되었다. 항균성 PLA 섬유를 제조하기 위하여 피톤치드계 유기항균제를 이용하였으며, 피톤치드에 기능성 엘라스토머를 사용하여 Capsulation을 진행하였다. 이러한 유기항균제 Powder의 경우 비중이 낮아 표면적로 인하여 마스터배치 칩을 만드는 공정에서 잘 혼합되지 않는 문제점이 발생하였으나, 피톤치드의 함량을 조절하여 PLA와의 마스터배치 칩 제조를 시험하였다. 압출온도와 토출량, Screw 조건(Mixing, Zone)을 시험하여 적정 조건을 설정하였다. 항균사 PLA 섬유는 Sheath/Core 복합방사 형태와 단독사 형태의 2가지 Type을 제조하였다. Sheath/Core 복합방사 폴리머 구성은 Sheath부에 PLA항균사, Core부에 PLA 또는 저융점 PET를 사용하였다. Core부의 폴리머는 제사성에 큰 영향을 미치지 않았으나, 항균 마스터배치의 함량이 증가할수록 Pack압 상승이 급격히 일어나는 단점이 나타났다. 항균제 5% 정도가 혼입되어 있는 경우에 2.1 이상의 정균활성치와 99.8% 정도의 정균감소율 성능을 나타내었다. PLA 단독사의 경우, 항균제 최적 함량은 3% 이상으로 정균활성치 5.5 이상, 정균감소율 99.9%의 우수한 항균특성을 나타내었다.

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Effect of Hydrocolloids on Rheological Properties of Bread Dough (Hydrocolloid가 빵 반죽의 레올로지 특성에 미치는 영향)

  • Cho, Hyun;Lee, Myung-Koo;Lee, Jeong-Hoon;Lee, Si-Kyung
    • Applied Biological Chemistry
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    • v.51 no.1
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    • pp.6-10
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    • 2008
  • This study was carried out to investigate rheological properties of bread dough by adding hydrocolloids such as arabic gum, pectin and carboxyl methyl cellulose (CMC). 0.2% and 0.5% of each hydrocolloid were added to the dough. Farinograph, pH of dough, extensograph, fermometer and amylograph were analyzed. In farinograph, water absorption rate of dough was increased by adding hydrocolloids and the highest water absorption resulting in 70.8% was shown by adding 0.5% of CMC. Dough development time increased but stability decreased. pH of dough was lowered by adding hydrocolloids and pH of dough with 0.5% of pectin was the lowest. In extensograph, resistance of dough decreased but extensibility increased and R/E value lowered. In fermometer, $CO_2$ gas production increased and dough with 0.2% of CMC showed the largest gas production. In amylograph, initial gelatinization temperature increased by $0.5-1.5^{\circ}C$, but temperature for maximum viscosity was lowered by $1-1.5^{\circ}C$ and maximum viscosity was increased.

Characterization of Acryl Polymer Concretes for Ultra Thin Overlays (초박층 덧씌우기용 아크릴 폴리머 콘크리트의 특성 연구)

  • Kim, Dae-Young;Kim, Tae-Woo;Lee, Hyun-Jong;Kim, Hyung-Bae
    • International Journal of Highway Engineering
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    • v.12 no.3
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    • pp.1-8
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    • 2010
  • This study is performed to evaluate the physical and mechanical characteristics of an acryl polymer concrete that is developed as an overlay material for cement concrete slabs and pavements. Various laboratory tests including viscosity, flow, compressive strength, flexural strength, tensile strength, linear shrinkage, thermal expansion and thermal compatibility tests are performed. It is observed from the laboratory tests that the acryl polymer concrete developed in this study satisfies all the requirements suggested by ACI guideline. In addition to the laboratory tests, an accelerated performance testing (APT) is conducted to validate the performance of the acryl polymer concrete. During the APT, no significant distresses are observed until 15,903,939 cycles of equivalent single axle loading is applied. Finally, a 10mm thick overlay with the acryl polymer concrete is applied on top of an old deteriorated concrete pavement to evaluate field performance. Right after the field construction, skid resistance, noise and roughness are measured. The skid resistance and noise level have been significantly improved while the roughness is increased. Periodic investigation for the field study section will be conducted to evaluate the long-term performance.

A Study on Rheological Behavior of Korean Straight Asphalts (국내 스트레이트 아스팔트의 거동 특성 연구)

  • Kim, Nam-Ho;Hwang, Sung-Do;Park, Young-Cheol
    • International Journal of Highway Engineering
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    • v.1 no.2
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    • pp.121-133
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    • 1999
  • This study was based on the evaluation of 9 asphalts that were produced in five major Korean refineries. The study was concentrated to identify the problems of the current asphalt specification (KS M 2201) and to determine the ranges of visco-elastic asphalt behavior. As a conventional asphalt property. asphalt penetration, ring and ball(R&B) softening point, asphalt viscosity, and flash point of asphalt were measured. Also Dynamic Shear Rheometer (DSR) were used to evaluate visco-elastic properties of asphalts in the $-20^{\circ}C$ through $30^{\circ}C$ temperature range. These properties before and after the short-term (RTFO) and long-term (PAV) aging were compared and analyzed to achieve the research objectives. The conclusion from this study can be summarized by the followings. The low temperature rheological behavior of all the straight asphalt from five major Korean refineries is similar regardless of asphalt grade. In the mean while, the rheological behavior at high and intermediate temperature of Korean straight asphalt varies depending on asphalt grade.

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Design of Reduced Shear Stress with High-Viscosity Flow Using Characteristics of Thin Film Flow on Solid Surfaces (완전접촉 경계면 위의 박막유동 특성을 이용한 고점도 전단유동에 따른 표면응력 감소 설계)

  • Park, Boo Seong;Kim, Bo Hung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.12
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    • pp.1027-1034
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    • 2014
  • The shear stress on a surface due to the thin film fluid flow is an important issue. In case of a rotating disk, the fluid is delivered to the edge of the disk by centrifugal force, which acts as a body force on the fluid. Wear of a surface is affected by the shear stress acting on the surface and curvature. In this study, we utilize computational fluid dynamics software to model the ratio of curvature and local shear stress on solid surfaces. The key goal of the study is to determine an optimized curvature for the thin film fluid flow on a solid surface in order to minimize the local shear stress affecting the wear of this surface. Our results on the effects of curvature will be utilized for the design of devices that utilize thin film fluid flow on a solid surface, such as rotating-disk spray systems and thin film coating.

Analysis of Traditional Process for Yukwa Making, a Korean Puffed Rice Snack (I): Steeping and Punching Processes (전통 유과가공공정의 분석(I): 수침 및 꽈리치기 공정)

  • Kang, Sun-Hee;Ryu, Gi-Hyung
    • Korean Journal of Food Science and Technology
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    • v.34 no.4
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    • pp.597-603
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    • 2002
  • The analysis of traditional process for a Korean puffed rice snack (Yukwa) is needed to develop an advanced process for Yukwa-making. Steeping and punching (Koarichigi) processes, consume time and labor in Yukwa-making, were analyzed on this study. Steeping of waxy rice at $15^{\circ}C$ for 3 days was required to equilibrate moisture absorption in waxy rice kernel. However, steeping for more than 6 days was required soft texture and small air cell distribution of Yukwa. Protein content at pericarp on endosperm of waxy rice kernel was decreased and starch granule was damaged during steeping. RVA paste viscosity was the highest at 6 day steeping after than decreased. Expansion ratio of Yukwa was increased with the increase in steeping time. Air bubbles in dough after punching were uniformly distributed and kneading energy input was decreased with the increase in steeping time. Soft texture, unique texture of Yukwa could be controlled by controlling steeping time and kneading energy input during punching process.

Relationship between RVA Properties and Film Physical Properties of Native Corn Starch and Hydroxypropylated Corn Starch (천연옥수수전분과 hydroxypropyl화 옥수수전분의 RVA특성과 필름 물성의 관계)

  • Han, Youn-Jeong;Kim, Suk-Shin
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.1023-1029
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    • 2002
  • Relationship between RVA properties and physical properties of film made from native corn starch and hydroxypropylated corn starch at various levels of plasticizers was examinel. Tensile strength of the film decreased, but its elongation and water vapor permeability increased with increasing plasticizer concentration. The film with glycerol showed greater changes in physical properties than that with sorbitol. Hydroxypropylated starch film showed lower tensile strength, higher elongation, and higher water vapor permeability than the native starch film. Sorbitol resulted in films with relatively high tensile strength, whereas glycerol produced films with increased elongation. The most reliable parameters for the relationship between RVA properties and film properties were RVA peak viscosity, tensile strength, and water vapor permeability. Water vapor permeability and tensile strength had linear relationship with RVA properties. The tensile strength and water vapor permeability of film could be predicted using the RVA peak viscosity.

A Phytosociological Study of Natural Forest Communities at Mt. Jokye Area (조계산지역(曹溪山地域) 삼림군집(森林群集)의 식물사회학적(植物社會學的) 연구(硏究))

  • Kim, Tae Uk
    • Journal of Korean Society of Forest Science
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    • v.76 no.4
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    • pp.418-424
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    • 1987
  • Considering the seral stage of succession, phytosocialogical analysis was carried out to investigate the structure and property of community of Pinus densiflora, Pinus densiflora-Quercus spp.-Carpinus laxiflora, and Quercus spp.-Carpinus laxiflora. The study area included a section of 200m high at the sea level in Mt. Jokye, Seungju-gun, Chunlanam-do. The results show that density of forest trees tended to be decreased, Shannon species diversity index increased, and dominance decreased as seral stage progressed. Patterns of DBH class distribution showed nearly S types. In the study area succession of forest community might progressed toward climax, leading from Pinus densiflora community to Quercus spp.-Carpinus laxiflora community with intermediary Pinus densiflora-Quercus spp.-Carpinus laxiflora community. The fact that there was no pure community of Quercus spp. might be due to the rapid development of forest community investigated.

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The Behavior Variation of the Ion Viscosity and the Compressive Strength of the Seawater and Freshwater Flooded Chlorosulfonated Polyethylene After Accelerated Thermally Ageing (가속 열화 후 해수 담수 침지된 Chlorosulfonated Polyethylene의 이온 점도와 압축 강도의 특성 변화)

  • Hong, So Young;Kim, Min Ju;Jeong, Eun Mi;Kim, Jin Pyo;Shin, Yong Deok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.6
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    • pp.490-495
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    • 2019
  • This study performs the thermal aging of chlorosulfonated polyethylene (CSPE) for 807.36 and 1,614.48 hours at $110^{\circ}C$, which is equivalent to 40 and 80 years of aging at $50^{\circ}C$ in nuclear power plants, respectively. Flat-type CSPEs were soaked in seawater for five days and then dried for five days at room temperature. Furthermore, the soaked CSPEs were cleaned for 5 days with fresh water and dried for 1,100 days at room temperature. Through this process, the log IV of the CSPEs decreases, whereas the dissipation factor of the CSPEs increases as thermally accelerated aged years increase at the measured frequency. Although the phase degree of the response voltage versus excitation voltage of the CSPEs increases, that of the response current versus excitation voltage decreases with the thermally accelerated aging. The thermal conductivity of the CSPEs increases slightly, but the thermal diffusivity does not vary with the thermally accelerated aged year increase. The displacement of the compressive strength of the CSPEs decreases gradually as the thermally accelerated aged years increase.

Habitat characteristics of exotic fish in Korean reservoirs (농업용 저수지 내 외래어종의 분포특성)

  • Son, Minwoo;Byun, Jisun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.512-512
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    • 2016
  • 우리나라의 다양한 수계에서는 배스로 대표되는 외래어종의 유입에 따른 심각한 생태계 교란이 발생하고 있다. 외래어종은 활발한 먹이활동 및 영역다툼을 통해 우리나라 고유종의 섭취 및 경쟁 우위에 위치하고 있다는 것이 많은 보도를 통해 발표되었다. 본 연구에서는 외래어종 중 배스(Large mouth bass)에 초점을 두고 동계 및 춘계의 서식처 특성을 살펴본다. 다양한 수계 중 갇혀있는 시스템으로 간주할 수 있는 농업용 저수지에 초점을 맞추고 현장조사를 실시한다. 하지만 현장조사 중 일부는 강과 같이 열린 서식처 공간도 포함하고 있다. 본 연구는 배스가 동면을 하지 않는 대신 수온에 큰 영향을 받으며 저수온기의 서식활동을 지속한다는 가정 하에 수온과 배스가 활동하는 영역의 상관성을 이해하고자 하였다. 조사는 국내 4개 지점 이상에서 이루어졌으며 수심 20 m 정도의 깊은 저수지에서부터 하수종말처리장에서 처리수가 유입되는 도시형 하천까지 포함한다. 이 중 수심 20 m 정도의 농업용 저수지에서는 7회 이상의 정밀 조사를 수행하여 수심별, 수온별 배스의 서식특성을 이해할 수 있도록 집중조사를 실시하였다. 현장조사 결과 배스는 $1-2^{\circ}C$의 수온차에도 민감하게 반응하며 서식처를 형성한다는 사실을 알 수 있다. 수온의 평면적 분포는 서식처의 형성에 많은 영향을 주는 것으로 판단되며 수온 안정기인 동계의 경우는 수온 종분포에 따라 군락을 형성하며 서식층을 결정한다는 점도 유추된다. 4월 중순 이후의 춘계는 배스의 산란기로 종확산에 큰 영향을 미치는 가장 중요한 시기이다. 이 시기 이후 하계에는 다시 부화한 개체가 독립적으로 서식처를 이동하는 또다른 종확산의 시기이다. 따라서 계절별에 따른 보다 면밀하고 지속적인 조사를 통해 4계절 순환에 따른 배스의 서식 특성 변화를 조사하는 과정이 필수적으로 이루어져야 한다.

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