• Journal of the Korean Electrochemical Society
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• v.18 no.1
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• pp.17-23
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• 2015

$Li_4Ti_5O_{12}$ (LTO) have attracted much attention of researchers in the field of energy storage, because of their excellent stability for electric vehicle application. A main drawback of LTO is however their insulating nature due to the wide bandgap, which should be addressed to enhance the battery performance. In this study, we investigated the effect of water solubility of dopant precursor on the electrochemical characteristics of conducting LTO prepared by doping with $Cr^{3+}$ ions with the well-known wet-mixing method. The solubility of dopant precursor directly affected the morphology and the phase of doped LTO, and therefore their battery performance. In the case of employing the most soluble dopant precursor, $Cr(NO_3)_2$, the doped LTO demonstrated a markedly enhanced discharge capacity at high C-rate (130mAh/g @ 10C), which is about 2 times higher value than that of bare LTO.

• Applied Chemistry for Engineering
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• v.10 no.7
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• pp.1014-1019
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• 1999

Copolyamic acid PMDA/6FDA-PDA(PAA) and homopolyamic acids PMDA-PDA(PAA) and 6FDA-PDA(PAA) were synthesized from 1,2,4,5-benzenetetracarboxylic dianhydride(PMDA) and 2,2'-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride(6FDA) as the dianhydride and 1,4-phenylenediamine (PDA) as the diamine. Residual stresses were detected in-situ during thermal imidization of the co- and homopolyimide precursors as a function of processing temperature over the range of $25{\sim}400^{\circ}C$ using thin film stress analyzer(TFSA), and morphological structures were investigated by WAXD. In comparison, the resultant residual stress of polyimide films composed of different compositions decreased with the increasing content of PMDA unit in the chain and was about 5 Mpa in compression mode for PMDA-PDA. In this study, the synthesis of random PMDA/6FDA-PDA copolyimide could be completed and compensate for the difficulty of process due to high $T_g$ of PMDA-PDA and relatively higher stress of 6FDA-PDA. It showed that we can make a low level stress copolyimied having excellent mechanical properties by incorporating appropriate rod-like rigid structure PMDA-PDA unit into 6FDA-PDA polyimide backbone which generally shows higher stress due to rotational hinges such as bulky di(trifluoromethyl). Specially, PMDA/6FDA-PDA(0.9:0.1:1.0) satisfied excellent mechanical property and low level stress as an inter layer showing low dielectric constant.

• Fire Science and Engineering
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• v.16 no.1
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• pp.18-23
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• 2002

Efficiency estimation of toxicity free resistance cable experiments were conducts to understand toxicity free fire ersistance polyolefin insulation material and smoke density characteristic and combustion gas corrosion analysis. A main cause of fire-growth and generating toxic gas when it burns, should be dealt with great care in life safety design. Similar patterned fire incidents such as, Inchon Live-Hof Pub Restaurant as, Sea-land Children Resort have proven that serious loss of lives were caused by hazardous gas generated fire resistance cable materials. In this paper, Referenced documents were ASTM E662 standard test method for specific Ds genalated by solid materials. The furnace control system shall maintain the required irradiance level under steady-state condition with the chamber door closed of 2.5$\pm40.04〔w/$\textrm{cm}^2$〕for 20 min. According to the results of the smoke density analysis of NFR-8 and FR-PVC the highest decomposition flaming smoke density range of NFR-8 and FR-PVC were 25.2 to 37.5 and 51.1 respectively. Nonflaming smoke density range of NFR-8 and FR-PVC were 100.4 to 112.2 and 126.5 to 398.8. Also, the fire gases was occurred carbon monoxide and decomposition than in polyolefin due to incomplete combustion of PVC which has high content of carbon in chemical compound.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.21 no.5
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• pp.10-24
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• 2007

In the dissertation, a power conversion system for fuel cell is composed of a PWM inverter with LC filter in order to convert fuel cell voltage to a single phase 220[V]. In addition, new insulated DC-DC converters are proposed in order that fuel cell voltage is boosted to 380[V]. In this paper, it requires smaller components than existing converters, which makes easy control. The proposed DC-DC converter controls output power by the adjustment of phase-shift width using switch $S_5\;and\;S_6$ in the secondary switch which provides 93-97[%] efficiency in the wide range of output voltage. Fuel cell simulator is implemented to show similar output characteristics to actual fuel cell. Appropriate dead time td enables soft switching to the range where the peak value of excitation current in a high frequency transformer is in accordance with current in the primary circuit. Moreover, appropriate setting to serial inductance La reduces communication loss arisen at light-load generator and serge voltage arisen at a secondary switch and serial diode. Finally, TMS320C31 board and EPLD using PWM switching technique to act a single phase full-bridge inverter which is planed to make alternating current suitable for household

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.662-668
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• 2018

Most electric rooms are located in the underground spaces of buildings. When a fire occurs in electrical equipment, the fire expands to cable insulation material, resulting in toxic smoke and combustion products. If the smoke and combustion products quickly move vertically and horizontally, the evacuation of occupants and firefighting activities will be hindered. Therefore, it is necessary to design optimal equipment for smoke control in cases of fires in electric rooms. This study analyzes the characteristics of smoke and combustion products in fires in a cubicle-type switchboard in an electric room using PyroSim, which is based on the program Fire Dynamics Simulator (FDS). The fire modeling consists of four scenarios according to the operation mode of the mechanical ventilation equipment, the amount of air supply and exhaust, and the location of the air supply slot. The analysis shows that the mechanical ventilation equipment improves the smoke density, visibility, carbon monoxide concentration, and temperature characteristics. The visibility and temperature characteristics were improved when the air flow rate and the location of the air supply slot from fire defense regulations were applied.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.5
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• pp.689-696
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• 2018

System grounding is applied to the neutral point of a power source to secure the from any abnormal voltage and/or grounding fault. System grounding, which is applied mainly in ships is an ungrounded and resistance grounded system. Vessels using the MV power system with 3.3kV, 6.6kV, and 11kV mainly adopt a high resistance grounding system among the resistance grounding systems. The ground fault accounts for 95% of all faults occurring in the electrical system and when a fault occurs, the line-to-ground voltage of the power system is increased excessively, which adversely affects the onboard insulation system. This study analyzed the variation characteristics of the line-to-ground voltage neutral point according to the degree of ground fault in a resistance ground system applied in vessels. For this purpose, the characteristics of the grounding system were first explained, and the modeling of the neutral point potential of the line-to-ground voltage of the resistance grounding system in the vessels was derived. Finally, this study examined how the line-to-ground voltage, line voltage, and neutral point change according to various variable environments through MATLAB simulations.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.2
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• pp.683-688
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• 2018

In this study, we analyzed the heat generation state of a flat heating element by using image processing technology in conjunction with carbon fiber. The flat heating element is manufactured by chopping the carbon fiber to a small size and bonding it again using a dispersing agent. The solution of carbon fiber, bound together using the dispersant, is then filtered onto the nonwoven fabric. The last step is to obtain flat carbon fibers in the form of nonwoven fabrics for the purpose of drying the filtered carbon fibers. In the flat heating element, electricity may be applied to the carbon fiber on the surface produced in this manner. In this study, the flat heating element was analyzed by four methods. The analysis of the heat generation characteristics and heating rate of the flat heating element confirmed that the fabricated sheet heating element corresponds to a normal army. The analysis of the insulation coating and flat heating element module, which can be used for actual product manufacturing, involves two dimensional image analysis using image processing technology. The thermal image analysis of the flat heating element is a programming technique that not only analyzes the heat generation state in both two and three dimensions, but also displays the upper and lower 15 to 20% ranges of temperature corresponding to the heat generation in the image. In the final analysis, it is possible to easily find the erroneous part in the manufacturing process by directly showing the state of the fabricated flat heating element on the screen. By combining this image analysis method of the flat heating element with the existing method, we were able to more accurately analyze the heat generation state.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.6
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• pp.2484-2490
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• 2012

This study reports on the development and performance verification of cell simulation boards of simulator and the embedded program for board control of the battery management system (BMS) of electric vehicle (EV) cars, which manages the next-generation automotive lithium-ion battery pack. Here, we have improved the speed of the simulator by using operational (OP) amplifier and transistors that were connected in series. In addition, using a digital analog converter (DAC) in each channel, we have improved the performance by channel-to-channel isolation (isolation) as compared to the traditional methods. Furthermore, by constructing a current-limiting protection circuit, one can be protected from disturbance and, by utilizing a precision shunt resistor for the current sensor, we have increased the precision of the current control. In order to verify the performance of the developed simulator, we have performed the experiment 10 times, with values ranging from 0.5 V to 5 V, and a voltage drop step of 0.5 V. Significance analysis of experimental data, and repeatability tests were performed, showing an average standard deviation of 0.001~0.004 V, indicating high repeatability and high statistical significance of the current method and system.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.20 no.3
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• pp.129-134
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• 2020

Moisture infiltration inside the solar cell module, filling of EVA sheet, melting of the frame seal, and deterioration of power generation performance in the module one year after installation are occurring. Whitening phenomenon, electrode corrosion phenomenon, and dielectric breakdown phenomenon are appearing in solar cell module installed in Korea before 5-7 years, leading to deterioration of power generation performance, and big problems for long-term reliability and long life technology are emerging. Therefore, in order to solve these problems, the development of a micro inverter (MiCrco Inverter Converter, MiC) including the function of securing the durability of the solar cell module and monitoring the aging progress and the solar cell based on the monitoring data from the MiC smart monitoring programs have been proposed to determine the aging of modules. In addition, in order to become a highly efficient solar smart monitoring system through systematic operation management through IT convergence with MiC that has enhanced monitoring function of solar cell module, SoC(System On Chip) in micro inverter is the environment for solar cell module. There is a demand for functions that can detect information in a complex manner and perform communication and control when necessary. Based on these requirements, this paper aims to develop SoC-based low-cost MiC smart photovoltaic system technology.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.19 no.6
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• pp.57-63
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• 2019

S-parameters were used to analyze the effect of the circuit according to the height of the EMI shield layers. Among the S-parameters, S11, S21, S22, and S31 were used as factors for determining the effect on the circuit function. Simulations were performed using shields made of Graphite and Ferrite, and the frequencies were run from 100 MHz to 1 GHz. As the height of the shield was increased, the value of S21 was getting closer to 0 dB. In addition, the SE value was confirmed to improve the shielding performance according to the thickness of the insulating layer only in a specific frequency band. Based on 800um with thickest silicon dioxide thickness, the FG structure averaged -1 dB in narrow frequency bands between 100 MHz and 300 MHz, showing better efficiency than GF with an average of -2 dB. Although GF structures do not show high efficiency, they exhibit average performance of -3 dB in frequency bands between 100 MHz and 1 GHz rather than FG structures that sway over a wide range. In other words, FG and GF structures have trade-off structures. Therefore, it should be noted that the appropriate structure is selected for use.