• Title/Summary/Keyword: 전해생성

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Properties of the $(La_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$ Based Electrolyte for Solid Oxide Fuel Cell (고체산화물 연료전지 $(La_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$계 전해질의 제조 및 특성평가)

  • 박상선;이미재;윤기현;최병현
    • 한국전기화학회:학술대회논문집
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    • 2002.07a
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    • pp.271-276
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    • 2002
  • 고체산화물 연료전지의 구성요소인 전해질의 $(La_{1-x}Sr_x)(Ga_{1-y}Mg_y)O_{3-\delta}$계의 결정상 및 미세구조특성을 연구하였다. Mg의 첨가량이 증가할수록 Sr의 고용량도 증가하였으며 Sr의 함량이 많으면 2차상인 $LaSrGa_3O_7$상이 생성되었으며 Mg의 첨가량이 증가함에 따라서는 $LaSrGaO_4$상이 생성되었다. $LaSrGaO_4$상이 생성된 경우에는 낮은 전도도를 나타내었으며 $LaSrGa_3O_7$상의 경우에는 전기전도도에 큰 영향을 미치지 않았다. 또한 Sr과 Mg 첨가량의 증가는 grain 성장을 억제하였으며 $(La_{0.8}Sr_{0.2})(Ga_{0.8}Mg_{0.2})O_{3-\delta}$$1000^{\circ}C$에서 0.1S/cm 정도의 전기전도도를 나타내었다.

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A current profiling method for IPM in single-phase source inverter without Electrolytic Capacitor (전해 캐패시터가 없는 단상 입력 인버터를 위한 매입형 동기전동기의 구동 전류 파형 생성 방법)

  • Son, YoungRack;Lee, Wook-Jin;Ha, Jung-Ik
    • Proceedings of the KIPE Conference
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    • 2012.07a
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    • pp.401-402
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    • 2012
  • 본 논문에서는 전해 캐패시터가 없는 단상 입력 인버터 시스템의 출력 전류 파형 생성 알고리즘을 제안한다. 제안된 알고리즘은 모터 제정수에 의한 전압 변화를 고려하여 계통 전류 형태를 정현파에 가깝게 만드는 출력 전류 지령을 구할 수 있다. 운전 조건에 맞는 최적 출력 전류를 수치 해석을 통해 구하고, 이를 참조표로 만들어 사용한다. 제안된 구동 전류 파형 생성 알고리즘에 대해 설명하고, 모의 실험을 통해 제안된 알고리즘의 타당성을 검증했다.

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The Characteristics of Flashing Evaporation by Pressure Drop and Electrolysis Current (감압온도 및 전해전류변화에 따른 감압증발특성 연구)

  • 이기우;장기창;전운표;박기호;이계중;라호상;박일환
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1999.05a
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    • pp.177-182
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    • 1999
  • 감압증발의 효율을 향상시키기 위한 방법으로 액주내의 기포생성에 의한 자기 미립화를 수반하는 과열액분류의 증발을 분사 감압증발이라고 하며, 특히 적절한 방법으로 액체내에 기포핵을 공급하는 경우에는 매우 좋은 증발성능이 얻어 진다는 것이 보고되어 있다. 따라서 본 연구에서는 온배수를 감압증발시켜 저온저압의 증기를 제조하여 MVR로부터 승온승압에 의해 고온의 증기를 얻기위한 것이 연구의 목적이므로, 증발효율향상을 위해 기포핵 공급용 전해전류장치를 설치하고, 감압증발용의 노즐을 원통형 튜브로 대체하기위해 튜브형 노즐로 부터 과열액을 급격히 감압시켜 자기미립화에 의한 증발을 유도하여 전해전류가 증발효율에 미치는 영향을 실험적으로 연구하고자 작동액체로써 물을 사용하고, 액체온도, 액체유량, 과열도 및 기포핵 공급용의 전해전류량을 변화시켜 실험을 수행하였다.(중략)

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Preparation of Chlorine Dioxide Aqueous Solution by Un-divided Electrochemical Cell using RuO2 anode (RuO2를 양전극으로 사용한 무격막 전해셀에서의 이산화염소수 제조)

  • Kwon, Tae Ok;Park, Bo Bae;Roh, Hyun Cheul;Moon, Il Shik
    • Applied Chemistry for Engineering
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    • v.20 no.3
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    • pp.296-300
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    • 2009
  • Generation of chlorine dioxide ($ClO_2$) was studied by the un-divided electrochemical cell system using $RuO_2$ anode material. Sodium chlorite ($NaClO_2$) was used as a precursor compound of chlorine dioxide. Effect of various operating parameters such as feed solution flow rate, initial solution pH, $NaClO_2$ and NaCl conc., and applied current density on the produced chlorine dioxide concentration and solution pH were investigated in un-divided electrochemical cell system. Produced chlorine dioxide concentration and solution pH were strongly depends on the initial solution pH and feed solution flow rate. Sodium chloride (NaCl) was not only good electrolyte, it was also used as a raw material of chlorine dioxide with $NaClO_2$. Observed optimum conditions were flow rate of feed solution (90 mL/min), initial pH (2.3), $NaClO_2$ concentration (4.7 mM), NaCl concentration (100 mM), and current density ($5A/dm^2$). Produced chlorine dioxide concentration was around 350 mg/L and solution pH was around 3.

Analysis of Coherence in Middle School Students' Representation of Particulate Concepts (중학생들의 전해질과 이온에 관련된 입자 개념 표현의 일관성 분석)

  • Yoon, Heojeong;Lee, Yoonha
    • Journal of the Korean Chemical Society
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    • v.58 no.6
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    • pp.580-589
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    • 2014
  • The concepts used to explain specific phenomenon can be influenced by context or coherent regardless of context. The purpose of this study is to understand middle school students' concept of particles in particular context and to investigate the effects of context on concept of particles. A conceptual questionnaire was developed to find out how students represented particles in two contexts: solid and solution states of electrolytes, and ion precipitation reaction. The questionnaire was administered to $9^{th}$ grade students after classes of 'electrolyte and ions' unit. The responses of students were analyzed using framework developed for categorization of students' concepts. The results are as follows: First, it was found that students used various concepts on particles when they explained solid and solution state of electrolytes, respectively. Second, we identified students' concepts of particles used to explain ion precipitation reaction. In addition, we recognized that majority of students failed to write correct chemical symbols. Third, approximately 79% of students showed coherent responses for explanation of particles in solution state of both electrolytes and ion precipitation reaction. About 57% of students had scientific concepts. Some suggestions were made based on results for acquisition of scientific concepts on particles in different contexts.

Carbon Dioxide Reduction to Alcoholson Perovskite-Type $La_{0.9}$$Sr_{0.1}$$CuO_3$ Electrodes (페로브스카이트 ($La_{0.9}$$Sr_{0.1}$$CuO_3$) 전극에서 이산화탄소의 전해환원에 의한 알콜류 생성)

  • 김태근;임준혁
    • Journal of Environmental Science International
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    • v.5 no.5
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    • pp.677-682
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    • 1996
  • The electrochemical carbon dioxide reduction to produce acetaldehyde, methanol and ethanol is investigated by using perovskite type electrode ($La_{0.9}$$Sr_{0.1}$$CuO_3$). The experiments were Performed under 100 mA/cm2 and -2 to -2.5 V vs. Ag/AgCl. The highest faradaic efficiencies for methanol, ethanol, acetaldehyde were 11.6, 15.3, and 6.2%, respectively. The experimental data demonstrated that the capability of the perovskite type oxide for the electrode of electrochemical carbon dioxide reduction to produce alcohols was superior to other metal electrode. Key words : Perovskite, Electrode, Alcohol Formation, Electrochemical Reduction, Carbon Dioxide Fixation.

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Hydrogen Production through High Temperature Steam Electrolysis System (고온 수증기 전해 수소제조)

  • Choi, Ho-Sang
    • Membrane Journal
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    • v.19 no.1
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    • pp.1-6
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    • 2009
  • Hydrogen energy id the 2nd clean energy able to be produced from the abundant resources, and the products of combustion or reaction do not spread an environmental pollution. Also, the hydrogen is the chemical media easily to transport and storage as energy source. The hydrogen production technology using by water splitting through electrolysis could be usable as a permanent renewable energy system without the environmental impact. The key technology of high temperature steam electrolysis is the development of an electrolyte rapidly to conduct an oxygen or proton ion decomposed from water. Subsequently, the important technology is to keep the joining technology of an electrolyte membrane and electrode materials to affect into the current efficiency.

A Study on the NOx Reduction of Flue Gas Using Seawater Electrolysis (해수 전기분해를 적용한 배연 탈질 기술에 관한 연구)

  • Kim, Tae-Woo;Kim, Jong-Hwa;Song, Ju-Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.4
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    • pp.570-576
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    • 2012
  • In this study, we investigated the characteristics of NO oxidation using un-divided electrolyzed seawater as oxidant. The concentration of available chlorine and the temperature of electrolyzed seawater are increased with electrolysis time in the closed-loop constant current electrolysis system. While NO gas flow through bubbling reactor which is filled with electrolyzed seawater, the oxidation rate of NO to $NO_2$ is increased with the concentration of available chlorine and the temperature. $NO_2$, generated by oxidation reaction, is dissolved in electrolyzed seawater and existed as $HNO_3{^-}$ ion.

New Control Technique of Harmful Algal Blooms by Electrolytic Sea Water Mixed with Yellow Loess (황토의 적조구제효과 및 전해수 혼합에 의한 새로운 적조구제 기술)

  • 배헌민;김창숙;김숙양;조용철;윤성종
    • Proceedings of the Korean Society of Fisheries Technology Conference
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    • 2000.10a
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    • pp.143-144
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    • 2000
  • 자연황토를 해수와 혼합 분쇄, 적조발생 해역에 정확히 살포하여 보다 경제적으로 황토를 살포하는 황토살포기 및 황토가 pH값의 변화에 따라 활성도가 달라지는 연구결과에 착안하여 해수를 전기분해하여 생성되는 전해수(산성수 및 알칼리수)에 황토를 혼합하여 황토를 활성화시켜 적조구제효율을 높이는 방법에 대하여 연구를 실시, 보다 효율적이며 친환경적인 적조구제 기술을 개발하였다. (중략)

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