• Title/Summary/Keyword: 전이온도

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Analysis of Stress Relaxation Behaviors of Geosynthetics (토목 합성재료의 응력완화 거동 해석)

  • Jeon, Han-Yong;Park, Young-Mok;Chung, Jin-Gyo
    • Journal of the Korean Geosynthetics Society
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    • v.3 no.4
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    • pp.21-27
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    • 2004
  • Stress relaxation behaviors of nonwoven geotextile and geomembrane which have protection, filtration and drainage, water barrier functions, respectively were analyzed. 'Theory of transition phenomena' was applied to interpretate the stress relaxation behaviors of two geosynthetics. The initial and later relaxation times for stress relaxation behaviors of geosynthetics were derived from the constitutive equations. The initial relaxation behaviors of these geosynthetics were dependent on the additional strains and were especially faster with temperature. Finally, both relaxation times of geosynthetics were shorter with additional strain and temperature.

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The Optical Property of nano-sized $Gd_2O_3:Eu^{3+}$ Phosphor using solution method (액상반응법으로 합성한 $Gd_2O_3:Eu^{3+}$ 나노형광체의 열처리 온도에 따른 광학적 특성)

  • Park, Chung-Sik;Kwak, Min-Ki;Yoon, Seung-Pil;Hong, Sung-Jei;Han, Jeong-In;Song, Yo-Seung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.05a
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    • pp.157-159
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    • 2005
  • 본 연구에서는 저온 액상반응법을 이용하여 활성제 Eu의 농도를 10wt%로 도핑하고 열처리를 각각 450, 700, $900^{\circ}C$로 1h 유지하여 $Gd_2O_3:Eu^{3+}$ 나노형광체를 합성하였다. 제조된 형광체의 결정화, 입자크기를 XRD, BET로 분석하였고, 이들이 발광 휘도에 미치는 영향을 확인하였다. 또한 합성된 형광체의 PL(photoluminescence) 특성을 알아보기 위해 여기파장 254nm 의한 발광스펙트럼, 611nm에 의한 여기스펙트럼을 조사하였다. 발광 특성은 611nm에서 주 peak을 갖는 $Eu^{3+}$ 이온에 의한 $^5D_0-^7F_{J(J=0,1,2)}$ 전이에 기인된 전형적인 Red 형광체의 특성을 나타냈고, 입자크기는 평균 20-60nm 정도이고, 발광강도는 열처리 온도가 증가함에 따라 향상되었다.

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A Study on Shrinkage Crack of Steel Composite Concrete Box Structure (Transfer Girder) (강합성 콘크리트 박스구조물(트랜스퍼 거더)의 건조수축 균열에 대한 연구)

  • Choi, Jung-Youl;Kim, Dae-Ill
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.6
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    • pp.685-691
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    • 2022
  • This study was based on the steel composite concrete box structure (Transfer girder) which was installed to support the skyscrapers directly above the subway line. In this study, it was analytically proved that the cause of cracks on the steel composite concrete box structure were the shrinkage cracks by comparing the results of crack investigation and numerical analysis. As the results, it was found that the internal temperature difference between concrete and steel members occurred according to the shape of the steel frame embedded in concrete, the location of vertical stiffener, and the closed section area. The narrower spacing of vertical stiffener was occurred the internal temperature concentration of the structure and the temperature difference increased. And the location of higher thermal strain and temperature were similar to the location of actual cracks by the visual inspection. Therefore, the internal temperature concentration parts were formed according to the presence and spacing of the vertical stiffeners and the inspection passage in the central part of the structure. The shrinkage cracks were occurred by the restrained of temperature expansion and contraction of the concrete. As the results of this study, it was important to separate and manage the non-structural cracks caused by shrinkage and the structural cracks in the maintenance of serviced steel-composite concrete structures.

Evaluation of Thermal Catalytic Decomposition of Chlorinated Hydrocarbons and Catalyst-Poison Effect by Sulfur Compound (염소계 탄화수소의 열촉매 분해와 황화합물에 의한 촉매독 영향 평가)

  • Jo, Wan-Kuen;Shin, Seung-Ho;Yang, Chang-Hee;Kim, Mo-Geun
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.577-583
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    • 2007
  • To overcome certain disadvantages of past typical control techniques for toxic contaminants emitted from various industrial processes, the current study was conducted to establish a thermal catalytic system using mesh-type transition-metal platinum(Pt)/stainless steel(SS) catalyst and to evaluate catalytic thermal destruction of five chlorinated hydrocarbons[chlorobenzene(CHB), chloroform(CHF), perchloroethylene (PCE), 1,1,1-trichloroethane(TCEthane), trichloroethylene(TCE)]. In addition, this study evaluated the catalyst poison effect on the catalytic thermal destruction. Three operating parameters tested for the thermal catalyst system included the inlet concentrations, the incineration temperature, and the residence time in the catalyst system. The thermal decomposition efficiency decreased from the highest value of 100% to the lowest value of almost 0%(CHB) as the input concentration increased, depending upon the type of chlorinated compounds. The destruction efficiencies of the four target compounds, except for TCEthane, increased upto almost 100% as the reaction temperature increased, whereas the destruction efficiency for TCEthane did not significantly vary. For the target compounds except for TCEthane, the catalytic destruction efficiencies increased up to 30% to 97% as the residence time increased from 10 sec to 60 sec, but the increase of destruction efficiency for TCEthane stopped at the residence time of 30 sec, suggesting that long residence times are not always proper for thermal destruction of VOCs, when considering the destruction efficiency and operation costs of thermal catalytic system together. Conclusively, the current findings suggest that when applying the transition-metal catalyst for the better destruction of chlorinated hydrocarbons, VOC type should be considered, along with their inlet concentrations, and reaction temperature and residence time in catalytic system. Meanwhile, the addition of high methyl sulfide(1.8 ppm) caused a drop of 0 to 50% in the removal efficiencies of the target compounds, whereas the addition of low methyl sulfide (0.1 ppm), which is lower than the concentrations of sulfur compounds measured in typical industrial emissions, did not cause.

Morphological Structure of Poly(trimethylene terephthalate) Fibers Annealed by Passing on the Plate Heater (연속 평판열처리에 의한 폴리(트리메틸렌 테레프탈레이트) 섬유의 미세구조 변화)

  • Hong, Seong-Hag;Kim, Ryong;Choi, Chang-Nam;Choi, Hee;Lee, Woong-Eui;Cho, Sung-Yong
    • Polymer(Korea)
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    • v.27 no.2
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    • pp.106-112
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    • 2003
  • Poly(trimethylene terephthalate)(PTT) fibers were treated by passing on the plate heater to study the annealing effect on the change of morphological structure and physical properties. In the X-ray diffraction curves of PTT annealed, a sharp peak at 2$\theta$=15.6$^{\circ}$ appeared and the peak intensity became stronger with the increase of annealing temperature and time. This peak was based on the (010) plane of PTT crystals. The crystallinity determined by density measurement was also increased by annealing. With the increases of temperature and time, the dynamic viscoelastic behaviors were shown to be a large reduction in T(tan $\delta$$_{max}$). The birefringence and $T_g$ were also reduced, but the melting temperature was the same. These results mean that the molecular chains in armorphous region are transfered into the crystalline legion, making the remained chains relaxed during annealing at tensionless state.

Comparison of Gene Expression in Larval Fat Body of Helicoverpa assulta in Different Temperature Conditions (온도변화에 따른 담배나방 유충 지방체의 유전자 발현 비교 분석)

  • Cha, Wook Hyun;Kim, Kwang Ho;Lee, Dae-Weon
    • Korean journal of applied entomology
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    • v.57 no.3
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    • pp.165-175
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    • 2018
  • Insects are known to live at wide range of temperature, but can not survive when they are exposed to over $40^{\circ}C$ or below supercooling point. The larvae of Helicoverpa assulta have been reared at high ($35^{\circ}C$), low (3 to $10^{\circ}C$), and room temperature ($25^{\circ}C$; control). To identify stress-related genes, the transcriptomes of fat body have been analyzed. Genes such as cuticular proteins, fatty acyl ${\Delta}9$ desaturase and glycerol 3 phosphate dehydrogenase were up-regulated whereas chitin synthase, catalase, and UDP-glycosyltransferase were down-regulated at low temperature. Superoxide dismutase, metallothionein 2, phosphoenolpyruvate carboxykinase and trehalose transporter have been up-regulated at high temperature. In addition, expressions of heat shock protein and glutathione peroxidase were increased at high temperature, but decreased at low temperature. These temperature-specific expressed genes can be available as markers for climate change of insect pests.

A Study on the Growth of ZnO Thin Films Deposited on the Sapphire Sustrates (사파이어기판 상의 ZnO 박막 성장에 관한 연구)

  • Lee, Yong-Ui;Kim, Hyeong-Jun;Yang, Hyeong-Guk;Park, Jong-Cheol;Kim, Yu-Taek;Kim, Yeong-Jin
    • Korean Journal of Materials Research
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    • v.6 no.3
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    • pp.341-346
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    • 1996
  • R-sapphire 기판위에 rf magnetron 스퍼터 방법으로 ZnO 박막을 증착하여 박막의 증착변수에 따른 결정성장방향과 SAW 특성을 분석하였다. 증착온도, 압력, rf 전력에 의해 박막 성장면이 (002)에서 (110)으로의 전이가 관찰되었다. 5mTorr, 40$0^{\circ}C$, 250W의 rf 전력에서 가장 우수한 (110)방향의 에피 ZnO 압전 박막의 SAW 특성을 분석하기 위하여 제작된 마스크를 사용하여 IDT를 구성한 후 SAW 특성을 분석한 결과 h/λ=0.08의 조건에서 전단속도가 약 5232m/s로서 고주파용 SAW 필터의 제조에 적합한 특성을 보이고 있다.

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Cure Mechanism of DGEBA/MDA/HQ-PGE System (DGEBA/MDA/HQ-PGE 계의 경화반응 메카니즘)

  • Song, Yeong-Uk;Choe, Hyeong-Gi;Sim, Mi-Ja;Kim, Sang-Uk
    • Korean Journal of Materials Research
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    • v.6 no.3
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    • pp.291-296
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    • 1996
  • Diglycidy1 ether of bisphenol A (DGEBA)/4, 4' -methylene dianiline(MDA)에 hydroquinonepheny1 glycidy1 ether(HQ-PGE)를 첨가한 계의 경화반응 메카니즘 FT-IR을 이용하여 연구하였다. 15$0^{\circ}C$에서 경화반응이 일어날 경우 반응기간이 증가할 때 에폭시기와 히드록시기는 감소하였고, 에테르기는 증가하였다. 그리고, HQ-PGE의 함량이 증가함에 따라 에폭시기의 소모량이 증가하였고, 유리 전이 온도가 감소하였다. 이로부터 HQ-PGE는 반응에 참여할 때 사슬 확장제와 반응 가속제로 작용함을 할 수 있었다.

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비 Cd계 양자점 합성 및 LED 응용

  • Kim, Yeong-Guk
    • Ceramist
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    • v.16 no.2
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    • pp.42-49
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    • 2013
  • 기존의 Cd계 양자점에 비해 독성 문제가 적은 비 Cd계 양자점은 합성 공정과 발광 특성 제어의 난이도로 인해 아직 Cd계 양자점에 비해 응용성이 떨어지는 상태이다. 또한 기존의 형광체와 같이 쓰이거나 이를 대체하기 위해서는 온도에 따른 발광안정성 확보가 필요하지만, 아직은 전이금속 도핑된 II-VI족 양자점을 제외하면 쉽지 않은 실정이다. 그러나 핵-껍질 구조 형성, 표면처리 등 많은 연구를 통해 Cd계 양자점과 거의 동등한 발광효율을 얻을 수 있게 되었으며, 발광의 색순도를 표시하는 발광선폭 역시 Cd계 양자점에 상당히 근접하였다. 특히 BLU 응용을 위해서는 좁은 발광선폭이 필수적이며 조명용 백색 LED 응용을 위해서도 색순도가 높으며 발광효율이 우수한 적색 형광입자의 필요성이 크다. 대표적인 비 Cd계 양자점인 InP의 경우 공유결합성이 커서 합성 과정에 어려움이 있으며, 표면 제어가 쉽지 않으나 부단한 연구개발을 통해 40~50 nm까지 발광선폭을 줄였으며, 발광효율도 거의 100%에 육박하는 값을 얻은 바 있다. 향후 좀더 많은 연구개발을 통해 발광 안정성이 우수하고 색순도가 높은 고특성 비 Cd계 양자점의 개발이 이루어 지면 조명용 LED나 디스플레이의 고성능화를 실현시키는 중요한 소재가 될 것으로 기대한다.

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Transesterification for FAME production of Rapeseed Oil

  • Jeong, Gwi-Taek;Yun, Dae-Hyeon;Gang, Chun-Hyeong;Choe, Byeong-Cheol;Lee, Un-Taek;Park, Don-Hui
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.164-168
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    • 2003
  • Fatty acid methyl esters (FAMEs) show large potential applications as diesel substitutes, and they are known as biodiesel fuel. Biodiesel fuel as a renewable energy is an alternative that can reduce energy dependence on petroleum and air pollution. Several processes for the production of biodiesel fuel have been developed. Transesterification process under alkali-catalysis and short-chain alcohol gives high level yield of methyl esters in short reaction times. In this research, transesterification of rapeseed oil was investigated to produce the FAMEs. Experimental reaction conditions included molar ratio of oil to alcohol, concentration of catalyst, types of catalysts, reaction time, and reaction temperature. The conversion ratio of rapeseed oil enhanced with the alcohol-oil mixing ratio and with the reaction temperature.

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