• Title/Summary/Keyword: 전위 계수

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Evaluation of Steel Corrosion of Slag Concrete by Half-cell Potential Method (반전지-전위 측정방법을 활용한 슬래그 콘크리트의 철근 부식 저항성능 평가)

  • Lee, Bo-Kyeong;Kim, Gyu-Yong;Kim, Rae-Hwan;Yoon, Min-Ho;Lee, Young-Wook;Choe, Gyeong-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.3-4
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    • 2014
  • There is high probability of steel corrosion on the reinforced concrete exposed to marine environment by penetration of chloride ion. When making concrete structure with slag as admixture in marine environment, salt damage can be prevented. Therefore, this paper presents experimental results of steel corrosion resistance of slag concrete considering marine environment through half-cell potential method which is one of the nondestructive test. As a result of half-cell potential experiment, it was assumed that every specimen exposed to marine environment was not corroded, and as a result of destroying specimens, it was confirmed that there was no corrosion in specimens.

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Propagation Analysis of Surface Crack Due to Hertzian Contact (헤르쯔접촉에 의한 표면균열의 전파해석)

  • Kim, Seock-Sam
    • Tribology and Lubricants
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    • v.8 no.2
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    • pp.35-43
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    • 1992
  • 취성재료의 마멸천이기구를 규명하기 위해 반무한탄성체상에 표면균열이 존재할 때 그 위를 헤르쯔 접촉하중이 이동할 경우를 해석모델로 하여 선형파괴역할을 도입하여 해석하였다. 해석방법으로는 표면균열을 인상전위의 연속분포로 치환하여 Erdogan-Gupta의 방법으로 균열끝면의 응력확대계수를 구하여, 취성재료의 균열전파조건인 Erdogan-Sih Criterion을 사용하여 그 전파특성을 해석하였다. 본 논문에서는 마멸율이 적은 마멸에서 마멸율이 큰 마멸로 전이할 때 급격한 표면손상과 마찰계수의 급격한 증가를 동반하므로 이에 대한 해석에 중점을 두었다. 해석결과는 접촉하중과 마찰계수의 증가는 표면균열의 전파를 야기시켜 대규모 마멸입자를 생성시키게 됨을 보여주었다.

The Economies of Scale and Scope in the Medical Service Industry of Korea and Its Policy Implications (한국 의료서비스산업의 규모 및 범위의 경제와 그 정책적 시사점)

  • Kim, Seon Jae;Lee, Younghwa
    • The Journal of the Korea Contents Association
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    • v.13 no.11
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    • pp.176-186
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    • 2013
  • The purpose of this study is to investigate the economies of scale and scope in the medical service industry of Korea using the multiple output translog cost function. The results show that the single-product scale economy (SSE) estimated is highly significant and less than one, implying that Korean medical service institutes are on average enjoying the product-specific scale economy in providing their services. In addition, the ray scale economies (RSE) reflects the overall economy of the scale in individual firm, showing less than one. Thus, the medical service industry in Korea is generally operating in the region of increasing returns to scale. The findings provide evidence of the economy of scope, in particular, with the joint production of inpatient and outpatient services as well as inpatient and administrative services.

Modeling of Size-Dependent Strengthening in Particle-Reinforced Aluminum Composites with Strain Gradient Plasticity (변형률 구배 소성을 고려한 입자 강화 알루미늄 복합재의 크기 종속 강화 모델링)

  • Suh, Yeong-Sung;Park, Moon-Shik;Song, Seung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.7
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    • pp.745-751
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    • 2011
  • This study proposes finite element modeling of dislocation punching at cooling after consolidation in order to calculate the strength of particle-reinforced aluminum composites. The Taylor dislocation model combined with strain gradient plasticity around the reinforced particle is adopted to take into account the size-dependency of different volume fractions of the particle. The strain gradients were obtained from the equivalent plastic strain calculated during the cooling of the spherical unit cell, when the dislocation punching due to CTE (Coefficient of Thermal Expansion) mismatch is activated. The enhanced yield stress was observed by including the strain gradients, in an average sense, over the punched zone. The tensile strength of the SiCp/Al 356-T6 composite was predicted through the finite element analysis of an axisymmetric unit cell for various sizes and volume fractions of the particle. The predicted strengths were found to be in good agreement with the experimental data. Further, the particle-size dependency was clearly established.

화학적 식각법을 이용한 사파이어 기판의 결함 구조 연구

  • Lee, Yu-Min;Kim, Yeong-Heon;Ryu, Hyeon;Kim, Chang-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.327-327
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    • 2012
  • 사파이어는 우수한 광학적, 물리적, 화학적 특성을 가지고 있는 물질 중의 하나이며, 청색 발광특성을 나타내는 GaN와 격자상수, 열팽창 계수가 가장 유사할 뿐만 아니라 가격도 상대적으로 저렴하기 때문에 GaN 성장을 위한 기판으로 사용될 수 있다. 실제로 사파이어는 프로젝터와 전자파 장치, 군사용 장비 등 다양한 분야에 응용되고 있으며, 발광 다이오드(LED)를 위한 기판으로 활용됨으로써 그 수요가 급격히 증가하고 있다. 그러나 사파이어 결정의 성장 중에 생길 수 있는 전위(dislocation)와 적층결함(stacking fault) 등의 결정 결함들은 결정 내에 존재하여 역학적, 전기적 성질에 큰 영향을 미칠 수 있다. 특히 사파이어가 청색 발광소자의 기판으로 사용되는 경우, 사파이어 기판 내부의 결정 결함은 증착되는 박막 특성에 영향을 미치게 된다. 따라서 사파이어의 보다 나은 응용을 위해서는 결정 결함에 대한 평가기술과 결함의 형성 메커니즘 등에 대한 이해가 필요하다. 특히, 결함의 정량적 평가 기술의 개발은 사파이어의 상용화에 중요한 핵심요소 중 하나이다. 결정을 산이나 염기 등을 이용하여 화학적 식각을 하게 되면 분자나 원자 간의 결합이 약한 부분이나 높은 에너지 상태에 있는 부분부터 반응을 하게 되는데, 이러한 반응을 통해 결정의 표면에 형성되는 것을 에치 피트(etch pit)라고 한다. 일반적으로 결정 내에 존재하는 전위는 높은 에너지 상태이므로, 이러한 에치 피트는 전위와 관련되어 있다. 따라서 사파이어 결정과 같은 결정질 물질은 표면의 식각을 통하여 관찰되는 에치 피트 등의 형상이나 반응성 등을 평가하여 결정 특성을 연구할 수 있다. 본 연구는 화학적 식각법으로 사파이어 결정의 특성을 평가하기 위하여 진행하였다. 사파이어 결정의 식각을 위하여 다양한 산-염기 용액들이 사용되었다. 식각 용액의 종류에 따른 사파이어 결정의 식각거동을 연구하고, 표면에 나타나는 형상을 연구하여 사파이어 결정의 구조적 특성을 파악하였다. 특히, 에치 피트 형성거동의 시간 및 온도 의존성에 관한 연구를 진행하였다.

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Portable titrator equipped spectroscopic detectors; Spectrator (분광학적 검출기가 내장된 휴대용 적정기: 스펙트레이터)

  • Shin, Jiwon;Chae, Gyoyoon;Kim, Yeajin;Kim, Sangho;Chae, Yoonsu;Chae, Won-Seok
    • Analytical Science and Technology
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    • v.34 no.3
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    • pp.128-133
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    • 2021
  • During titration, several chemical reactions result in changes not only in the potential of chemicals, but also in the colors of the indicator. In a potentiometric titration, a titration curve is obtained by measuring the abrupt change in the potential at the endpoint. Generally, acid-base titration is performed by observing the color change caused by an indicator to determine the endpoint. The method of determining the endpoint by measuring the potential difference has been well established and commercialized; however, the devices that can obtain the endpoint by observing the color change are limited. Consequently, in this study, a simple and precise spectral endpoint detector was manufactured using a drop-counter comprising an infrared emitter and a phototransistor, a white light LED as the light source and photodetector, and an analog-to-digital converter (Arduino). Spectrator, a new named, showed excellent results in terms of the reproducibility of acid-base titration using thymol blue as an indicator. Herein, we present the results of the Spectrator-manufacturing process as well as the experimental results.

A Study on the Characteristic of Capillary Pore and Chloride Diffusivity by Electrical Difference of High-Strength Concrete Using Metakaolin (메타카올린을 사용한 고강도콘크리트의 모세관공극 특성과 전위차 염소이온 확산계수에 관한 연구)

  • Kim, Nam-Wook;Yeo, Dong-Goo;Song, Jun-Ho;Bae, Ju-Seong
    • Journal of the Korea Concrete Institute
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    • v.19 no.4
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    • pp.499-506
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    • 2007
  • According to the high demand of concrete structures with high performance, various studies have examined on the high performance concrete, especially high strength concrete. Various admixtures are required to produce high strength concrete and silica fume has been the most popular admixture. Recently, however, metakaolin, which is similar to silica fume in properties but cheaper, has been introduced to high strength concrete. In this study, high-strength concrete using metakaolin were studied of capillary pore structure by mercury intrusion porosimetry technique and the accelerated chloride diffusivity by electrical difference. In result, it was found that the pore structure improved and compressive strength increased and chloride diffusivity reduced as more metakaolin content was added. In addition, a regression analysis of $5{\sim}2,000nm$ pore volume and both compression strength and chloride diffusivity revealed that each these had a high correlation of about 0.76 and 0.68.

자연전위의 효율적 측정을 위한 전극의 잡음요소 분석

  • Song, Seong-Ho;Gwon, Byeong-Du
    • Journal of the Korean Geophysical Society
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    • v.5 no.1
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    • pp.9-18
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    • 2002
  • We performed a long-term monitoring of self-potential(SP) using the Cu-CuSO₄non-polarizable electrode and copper-clad electrodes(CCE) in a test site in order to analyze the effects of surrounding environmental noises such as temperature, rainfall and soil moisture content on the electrodes. Analysis of the temperature dependence of the non-polarizable electrodes showed that is temperature coefficient was about +0.5 mV/°Fwhen its end was exposed to atmosphere while it was less than +0.5 mV/℃ when submerged into the subsurface, which reflects that there exists an 8 to 11 hour lag between temperatures at the depth of 15 cm and atmosphere. CCE was independent of atmospheric temperature in subsurface but showed temperature coefficient of 1.0 mV/℃ when exposed to atmosphere. Drifts of 1 to 2 mV recorded with the non-polarizable electrode directly related to the soil moisture content when it was buried in subsurface. Drift with CCE also showed similar trend to the soil moisture content, and 5 mV drift was recorded according to 5% of daily variation. The soil moisture content had strong effects on the measurement with CCE in rainfall since the flow potential is generated on the surface of the electrode.

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Experimental Study on the Time-dependent Property of Chloride Diffusivity of Concrete (콘크리트의 염소이온 확산계수의 시간의존성에 대한 실험적 고찰)

  • Choi, Doo Sun;Choi, Jae Jin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.4A
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    • pp.365-371
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    • 2009
  • It is time-consuming to estimate chloride diffusivity of concrete by concentration difference test. For the reason chloride diffusivity of concrete is mainly tested by electrically accelerated method, which is accelerating the movement of chloride ion by potential difference. In this study, portland cement concrete and concrete containing with ground granulated blast-furnace slag (40 and 60% of cement by weight) with water-cementitious material ratio 40, 45, 50 and 60% were manufactured. To compare with chloride diffusivity calculated from the electrically accelerated test and immersed test in artifical seawater, chloride diffusivity tests were conducted. From the results of regression analysis, regression equation between accelerated chloride diffusivity and immersed chloride diffusivity was linear function. And the determinant coefficient was 0.96 for linear equation.

Hierarchical Finite-Element Modeling of SiCp/Al2124-T4 Composites with Dislocation Plasticity and Size-Dependent Failure (전위 소성과 크기 종속 파손을 고려한 SiCp/Al2124-T4 복합재의 계층적 유한요소 모델링)

  • Suh, Yeong-Sung;Kim, Yong-Bae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.2
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    • pp.187-194
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    • 2012
  • The strength of particle-reinforced metal matrix composites is, in general, known to be increased by the geometrically necessary dislocations punched around a particle that form during cooling after consolidation because of coefficient of thermal expansion (CTE) mismatch between the particle and the matrix. An additional strength increase may also be observed, since another type of geometrically necessary dislocation can be formed during extensive deformation as a result of the strain gradient plasticity due to the elastic-plastic mismatch between the particle and the matrix. In this paper, the magnitudes of these two types of dislocations are calculated based on the dislocation plasticity. The dislocations are then converted to the respective strengths and allocated hierarchically to the matrix around the particle in the axisymmetric finite-element unit cell model. The proposed method is shown to be very effective by performing finite-element strength analysis of $SiC_p$/Al2124-T4 composites that included ductile failure in the matrix and particlematrix decohesion. The predicted results for different particle sizes and volume fractions show that the length scale effect of the particle size obviously affects the strength and failure behavior of the particle-reinforced metal matrix composites.