• Title/Summary/Keyword: 전도율

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Optical Constant Measurements of Highly Conductive Carbon Nanotube Films by Using Time-domain Terahertz Spectroscopy (시분해 테라파 분광학을 이용한 고전도성 탄소나노튜브 박막의 광학계수 측정)

  • Moon, J.Y.;Park, D.J.;Lim, J.H.;Rotermund, F.;Lee, S.;Ahn, Y.H.
    • Korean Journal of Optics and Photonics
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    • v.21 no.1
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    • pp.33-37
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    • 2010
  • We performed time-domain terahertz (THz) spectroscopy to determine optical constants of highly conductive carbon nanotube (CNT) films. The CNT films have been fabricated on a flexible plastic substrate by using spin-coating or vacuum filtration. We found that the transmission of THz waves can be controlled by manipulating the thickness of the films and by post-treatments. From amplitude and phase information of the transmitted THz waves, we obtain optical constants such as refractive indices and dielectric constants of the CNT films. The frequency dependent dielectric constants show good metallic behaviors, relevant to the Drude free electron models with high plasma frequencies. It is also found that the dielectric constants are higher for the acid-treated films. Finally, the frequency dependent dielectric constants which are free from substrate effects have been demonstrated by using CNT films deposited on cellulose membranes.

Self-Sensing of Single Carbon Fiber/Carbon Nanotube-Epoxy Composites Using Electro-Micromechanical Techniques and Acoustic Emission (전기적-미세역학시험법과 음향방출을 이용한 단일 탄소섬유/탄소나노튜브-에폭시 나노복합재료의 자체-감지능)

  • Park, Joung-Man;Jang, Jung-Hoon;Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Jong-Kyu;Lee, Woo-Il
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.5
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    • pp.411-422
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    • 2010
  • Self-sensing on micro-failure, dispersion degree and relating properties, of carbon nanotube(CNT)/epoxy composites, were investigated using wettability, electro-micromechanical technique with acoustic emission(AE). Specimens were prepared from neat epoxy as well as composites with untreated and acid-treated CNT. Degree of dispersion was evaluated comparatively by measuring volumetric electrical resistivity and its standard deviation. Apparent modulus containing the stress transfer was higher for acid-treated CNT composite than for the untreated case. Applied cyclic loading responded well for a single carbon fiber/CNT-epoxy composite by the change in contact resistivity. The interfacial shear strength between a single carbon fiber and CNT-epoxy, determined in a fiber pullout test, was lower than that between a single carbon fiber and neat epoxy. Regarding on micro-damage sensing using electrical resistivity measurement with AE, the stepwise increment in electrical resistivity was observed for a single carbon fiber/CNT -epoxy composite. On the other hand, electrical resistivity increased infinitely right after the first carbon fiber breaks for a single carbon fiber/neat epoxy composite. The occurrence of AE events of added CNT composites was much higher than the neat epoxy case, due to micro failure at the interfaces by added CNTs.

Characterization of Ni-YSZ cermet anode for SOFC prepared by glycine nitrate process (Glycine nitrate process에 의한 제조된 SOFC anode용 Ni-YSZ cermet의 물성)

  • Lee, Tae-Suk;Ko, Jung-Hoon;Lee, Kang-Sik;Kim, Bok-Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.1
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    • pp.21-26
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    • 2011
  • Ni-YSZ (Yttria Stabilized Zirconia) composite powders were fabricated by glycine nitrate process. The prepared powders were sintered at $1300{\sim}1400^{\circ}C$ for 4 h in air and reduced at $1000^{\circ}C$ for 2 h in a nitrogen and hydrogen atmosphere. The microstructure, electrical conductivity, thermal expansion and mechanical properties of the Ni-YSZ cermets have been investigated with respect to the volume contents of Ni. A porous microstructure consisting of homogeneously distributed Ni and YSZ phases together with well-connected grains was observed. It was found that the open porosity, electrical conductivity, thermal expansion and bending strength of the cermets are sensitive to the volume content of Ni. The Ni-YSZ cermet containing 40 vol% Ni was ascertained to be the optimum composition. This composition offers sufficient open porosity of more than 30 %, superior electrical conductivities of 917.4 S/cm at $1000^{\circ}C$ and a moderate average thermal expansion coefficient of $12.6{\times}10^{-6}^{\circ}C^{-1}$ between room temperature and $1000^{\circ}C$.

Evaluation of the Stability of Quay Wall under the Earthquake and Tsunami (지진 및 지진해일파 작용하의 해안안벽의 안정성평가)

  • Lee, Kwang-Ho;Ha, Sun-Wook;Lee, Kui-Seop;Kim, Do-Sam;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.27 no.3
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    • pp.41-54
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    • 2011
  • The present study analyzes the stability of waterfront quay wall under the combined action of earthquake and tsunami. Adopting the limit equilibrium method, the stability of waterfront quay wall is checked for both the sliding and overturning. Forces due to tsunami are compared with the proposed formula and the 3-D one-field Model for immiscible TWO-Phase flows (TWOPM-3D). Variations of the stability of wall are also proposed by the parametric study including tsunami water height, horizontal seismic acceleration coefficient, internal friction angle of soil, friction angle between the wall and the soil and the pore water pressure ratio. The present study about the stability of wall is also compared with the case when earthquake and tsunami are not considered. As a result, the result of numerical analysis about the tsunami force is similar to that of proposed formula. When earthquake and tsunami are simultaneously considered, the stability of wall in passive case significantly decreases and tsunami forces in active case are affected as a resistance force on the wall and so the stability of wall increases.

P Wave Detection Algorithm through Adaptive Threshold and QRS Peak Variability (적응형 문턱치와 QRS피크 변화에 따른 P파 검출 알고리즘)

  • Cho, Ik-sung;Kim, Joo-Man;Lee, Wan-Jik;Kwon, Hyeog-soong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.8
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    • pp.1587-1595
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    • 2016
  • P wave is cardiac parameters that represent the electrical and physiological characteristics, it is very important to diagnose atrial arrhythmia. However, It is very difficult to detect because of the small size compared to R wave and the various morphology. Several methods for detecting P wave has been proposed, such as frequency analysis and non-linear approach. However, in the case of conduction abnormality such as AV block or atrial arrhythmia, detection accuracy is at the lower level. We propose P wave detection algorithm through adaptive threshold and QRS peak variability. For this purpose, we detected Q, R, S wave from noise-free ECG signal through the preprocessing method. And then we classified three pattern of P wave by peak variability and detected adaptive window and threshold. The performance of P wave detection is evaluated by using 48 record of MIT-BIH arrhythmia database. The achieved scores indicate the average detection rate of 92.60%.

Sensitivity of Hydraulic Structures Design Parameter by Climate Change (기후변화에 의한 수공구조물 설계인자 민감도 연구)

  • Kong, Jung-Sik;Kim, UlAnYi
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.419-419
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    • 2011
  • 이상호우, 사막화, 빙하융해, 생태계 먹이사슬 변화, 이상기온 등 기후변화의 행태는 지구 곳곳에서 다양하게 발발되고 있으며 그로인해 발생되는 인적 물적 피해가 심각하다. 1996년 집중호우에 의한 연천댐체 파괴, 2002년 8월의 낙동강 유역 장기홍수, 2002년 태풍 루사 및 2003년 태풍 매미 등 국내에서는 기후변화 중에서도 주로 이상호우로 인해 발생하는 피해가 많았으며 이들은 주기성이나 특성을 갖지 않아 예측이 어려운 관계로 망양보뢰 식의 후처리에 급급한 실정이었다. 최근 기후변화에 따른 지역별 홍수량, 가뭄량 등에 관한 연구가 가속화되고 있으며, 이와 더불어 해당 기후모델 발현 시 기존 구조물에 미치는 영향에 대한 연구도 필수적이다. 나아가 기존 구조물 뿐 아니라 새로 시공되는 구조물의 설계에서 기후변화에 대한 안정성을 위해 추가적으로 포함해야 할 요소가 있는지에 대한 연구도 필요하다. 본 연구에서는 가상 기후모델에 대해 그 모델이 예측하는 홍수량이 실제 발현되었을 경우를 가정하여, 기존 수공구조물의 안정성에 미치는 영향을 살펴보고 영향인자의 민감도를 분석하고자 한다. 대상 수공구조물은 붕괴 시 영향력이 큰 정도를 기준으로 필댐, 콘크리트차수벽형석괴댐(CFRD), 콘크리트중력식댐, 제방으로 그 범주를 제한 하였으며 대상유역은 한강으로 가정하였다. 구조물의 안정성 검토방법은 각 구조물의 종류에 따라 상이하다. 흙이 주 재료인 제방과 필댐의 경우, 침투(Piping)와 비탈면(Sliding)에 대한 안정성 평가가 이루어지며 CFRD는 댐체와 벽체로 나누어 안정성평가를 하며 댐체 안정성 평가방법은 필댐과 유사하다. 본 연구에서는 하천설계기준(2009)과 댐설계기준(2005)에 따라 각 구조물의 기준안전율을 책정하였으며 점착력, 내부마찰각, 단위중량 등의 물성치는 해당 지역의 토질특성에 따라 여러 문헌을 참고하여 설정하였고 이를 SEEP/W, SLOPE/W 프로그램을 이용하여 구조해석을 실시하였다. 콘크리트중력식댐은 활동, 전도, 지지력에 대해 각각 안정성을 평가하며 MIDAS와 ABAQUS 프로그램을 병행하여 해석하였다. 민감도(Sensitivity)란 안정성에 영향을 미치는 설계인자들의 변화에 따라 안정성이 어떻게 변화하는 지를 말한다. 기후변화에 의한 수공구조물 설계인자 민감도 연구를 통해 기존 설계과정 또는 안정성 검토 시 해당인자의 기여도를 높이거나 새로운 설계인자를 추가하여 미래 상황에 대한 구조물의 위험 정도를 과거대비 상세히 예측할 수 있으며 나아가 적절한 대응 방안 제시에 기여하여 기후변화에 따른 피해를 감소할 수 있을 것이라고 생각된다.

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Preparation and Characterization of the Impregnation to Porous Membranes with PVA/PSSA-MA/THS-PSA for Fuel Cell Applications (연료전지 응용을 위한 다공성막에 가교된 PVA/PSSA-MA/THS-PSA의 함침을 통한 고내구성 이온교환막의 제조 및 특성 연구)

  • Kim, Il-Hyoung;Kim, Sung-Pyo;Lee, Hak-Min;Park, Chan-Jong;Rhim, Ji-Won;Cheong, Seong-Ihl
    • Membrane Journal
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    • v.21 no.3
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    • pp.299-305
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    • 2011
  • This study deals with the preparation of polymeric electrolyte membranes having high durability for the application of fuel cells. The membranes under investigation were prepared the impregnation to porous polyethylene membranes with poly(vinyl alcohol)(PVA), poly(styrene sulfonic acid-co-maleic acid), and (PSSA-MA)3-(trihydroxysilyl)-1-propanesulfonic acid (THS-PSA). To characterize the resulting membranes, the water contents, the contact angles, FT-IR, the proton conductivity and the the modulus were measured. The proton conductivity of 30% content of THS-PSA at $55^{\circ}C$ gave excellent $1.27{\times}10^{-1}S/cm$ and the mechanical strength was improved 7 times higher up to the THS-PSA content 15%, as a result, the durability was elevated extensively.

Surface Resistance of Antistatic Agent Using Lithium-Fluoro Compound and Quaternary Ammonium Salt and Characteristics Evaluation of Antistatic Film (리튬 불소계 화합물과 4차 암모늄염을 사용한 대전방지제의 표면저항 및 대전방지필름의 특성 평가)

  • Soh, Soon-Young;Chun, Yong-Jin;Lee, Jae-Kyeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.4
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    • pp.575-581
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    • 2020
  • A colorless antistatic agent was prepared for use in antistatic films for liquid crystal displays (LCDs) requiring low surface resistance and high transmittance. Among various lithium-fluoro compounds and quaternary ammonium salts, antistatic materials were selected based on their electrical conductivity, and antistatic agents were prepared to measure the surface resistance. As a result, the material with high conductivity showed a relatively low surface resistance, i.e., relatively good antistatic performance. Based on the antistatic materials selected, the formulation ratio for producing the best antistatic agent was established through the experimental design method and the effects of each factor were analyzed. The higher the use of lithium- fluoro compounds as antistatic materials, the higher the ratio of oligomer use with multi-functional groups, and the smaller the surface resistance. The quaternary ammonium salts increased the antistatic performance of the lithium-fluoro compounds, but the effects of the amount used were not relatively large. After manufacturing the antistatic PET film, the properties of the antistatic film showed low surface resistance values (<109 Ω/sq.), high permeability (>92%), low haze (<0.5%), and high whiteness (L>95). In addition, the antistatic film reliability was found to be excellent by showing a stable surface-resistance change rate of less than 10%, even under high temperature and high humidity conditions.

Characterization and Performance of MEA for Direct Methanol Fuel Cell Prepared with PFA Grafted Polystyrene Membranes via Radiation-Grafting Method (방사선 그라프트 PFA-폴리스티렌 멤브레인으로 제조한 직접 메탄올 연료전지용 MEA의 성능과 특성)

  • Kang, Se-Goo;Peck, Dong-Hyun;Kim, Sang-Kyung;Lim, Seong-Yop;Jung, Doo-Hwan;Park, Young-Chul;Shin, Jun-Hwa;Kang, Phil-Hyun;Nho, Young-Chang;Shul, Yong-Gun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.173-180
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    • 2009
  • In order to develop a novel polymer electrolyte membrane for direct methanol fuel cell (DMFC), styrene monomer was graft-polymerized into poly(tetrafluoroethylene perfluoropropyl vinyl ether) (PFA) film followed by a sulfonation reaction. The graft polymerization was prepared by the $\Upsilon$-ray radiation-grafting method. Subsequently, sulfonation of the radiation-grafted film was carried out in a chlorosulfonic acid/1,2-dichloroethane (2 v/v%) solution. The chemical, physical, electrochemical and morphological properties of the radiation-grafted membranes (PFA-g-PSSA) were characterized by fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). The water uptake, ionic conductivity, and methanol permeability of the PFA-g-PSSA membrane were also measured. The cell performances of MEA prepared with the PFA-g-PSSA membranes were evaluated and the cell resistances were measured by an impedance analyzer. The MEA using PFA-g-PSSA membranes showed superior performance for DMFCs in comparison with the commercial Nafion 112 membrane.

Effects of the Utilization of Sawdust During Composting of Poultry Manure on Physico-Chemical Characteristics and Earthworm (계분의 퇴비화 과정중 이화학적 성상 변화가 지렁이 생존에 미치는 영향)

  • HwangBo, Soon;Jo, Ik-Hwan
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2004.12a
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    • pp.1-16
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    • 2004
  • This study was conducted to investigate effects of different ratios of sawdust to poultry manure as an earthworm feed on the change of physico-chemical characteristics and earthworm viability during composting, and further to provide the basic information for an efficient vermicomposting using the manure of livestock. Experimental earthworm used in this study was Eisenia foetida and the ratio of sawdust and poultry was determined to 100:0(A), 80:20(B), 70:30(C), 60:40(D) and 50:50(E) on the basis of volume. The results are summarized as follows. Earthworm appeared after 6 wk of aging period, and it was possible for the earthworm to survive in treatments of C. D and E including 30 $^{\sim}$ 50% of sawdust. C/N ratio was significantly higher (P<0.05) in treatments of sawdust mixture (B, C, D, and E) than poultry manure alone (A treatment).Appropriate C/N ratio for earthworm survival was the range of 16.9 to20.7. During period of aging, pH value and electrolyticconductivity (EC) were the highest in the treatment of poultry manure alone. However, as the inclusion of sawdust was increased, pH showed decreasing tendency. Appropriate pH and EC for earthworm survival were 7.69 to 7.79, and 2.77 to 2.87mS/cm, respectively. The results from this study indicated that the mixing of poultry manure with sawdust more improved physico-chemical environment for earthworm growth in comparison with poultry manure alone, and sawdust showed the sufficient possibilityas a bulking agent for an efficient vermicomposting of poultry manure.

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