• 제목/요약/키워드: 전도성감응

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A stable solid state quantum dot sensitized solar cell with p-type CuSCN semiconductor and its dopping effect

  • Kim, Hui-Jin;Seol, Min-Su;Yong, Gi-Jung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.378-378
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    • 2011
  • 본 연구에서는 ZnO 나노선 기판을 제작하여 그 위에 밴드갭이 낮은 물질인 CdS, CdSe를 증착시킨 후 p-type 반도체 물질인 CuSCN을 증착시켜 안정성이 향상된 양자점 감응형 태양전지를 제작하였다. ZnO 나노선 기판은 투명한 FTO 기판 위에 ZnO를 진공증착시켜 seed layer를 제작하고 그 위에 $10{\mu}m$정도의 길이의 나노와이어를 성장시킨 후, 밴드갭이 낮은 CdS, CdSe 물질과의 다중접합을 이용하여 제작하고, 이러한 나노선 구조위에 chemical solution deposition을 이용하여 ${\beta}$-CuSCN을 형성시켰다. 양자점 감응형 태양전지는 ZnO 나노선을 photoanode로 이용하고 ZnO 나노선은 암모니아수와 아연염을 이용한, 비교적 저온의 수열합성법을 통해 합성하였고, sensitizer로 쓰인 CdS, CdSe 물질은 CBD방식을 통하여 합성된 나노선 위에 in-situ로 접합시켰다. 또한, 기존의 액체전해질을 이용한 양자점 감응형 태양전지의 안정성을 향상시키기 위해 p-type의 반도체 물질인 CuSCN물질을 propyl sulfide를 이용, ${\sim}80^{\circ}C$의 열을 가하여 in-situ 방식으로 다공성 구조에 효율적으로 접합이 가능하도록 deposition하였다. 일반적으로, CuSCN film은 홀 전도체로서의 장점을 지닌 반면, 전도성이 낮은 단점이 있기 때문에 이를 향상시키기 위해서 첨가제를 이용, 농도에 따라서 전도도가 향상되고 셀의 성능이 향상되는 것을 확인하였다. 이와 같이 합성된 구조는 주사전자현미경(SEM), X-선 회절(XRD), 솔라시뮬레이터 등의 분석장비를 이용하여 태양전지로서의 특성을 분석하였다. 또한 안정성 평가를 위하여 시간에 따른 셀의 특성변화도 비교하였다.

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Evaluation of KOMPSAT-2 System in the Conducted EMC Environment (전도성 전자파환경에서의 다목적실용위성 2호 시스템 설계 검증)

  • Kim, Tae-Youn;Lim, Seong-Bin;Choi, Seok-Weon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.8
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    • pp.138-144
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    • 2004
  • Satellite generates a complex electromagnetic noise by conducted and radiated coupling effect of the various electrical instruments. This noise may cause serious problems on the satellite system. To minimize the electromagnetic coupling effects and maintain the system safety margin, system noise reduction technique should be applied from the beginning of the system design. The KOMPSAT-2 system is evaluated by measuring the conducted noise on system electrical power leads and verifying a 6dB system safety margin under the complex noise environment with current injection. This paper describes the KOMPSAT-2 system evaluation result performed on ETB(Electrical Test Bed) and the analysed noise element, the analysed result will be reflected on FM(Flight Model) EMC test.

플라즈마 원자증착기술과 원자증착기술 제작된 $TiO_2-Al_2O_3$(core-shell)입자의 염료감응태양전지 광전극 특성 비교

  • Gang, Go-Ru;Cha, Deok-Jun;Kim, Jin-Tae;Yun, Ju-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.117-117
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    • 2013
  • 염료감응태양전지의 효율을 높이기 위해서, 광전극으로 쓰이는 다공성 $TiO_2$ 후막에 플라즈마원자증착기술(PEALD)과 원자증착기술(ALD)을 이용하여 알루미나($Al_2O_3$)막을 3차원적으로 균일하고 매우 얇게 형성하였다. 이를 통해서 태양빛에 의해 여기된 염료의 전자가 알루미나를 통과(tunneling)하여 $TiO_2$ 전도대로 도입되게 함과 동시에 $TiO_2$ 전도대로 도입된 전자들이 전해질과 염료로 재결합하는 현상을 방지하였다. 결국 이러한 작용에 의해서 염료감응태양전지의 개방전압을 높이는 효과를 관측하였다. 나아가 PEALD와 ALD 두가지 방식으로 형성된 $Al_2O_3$ 껍질층의 특성 차이를 비교 관찰하고 이에 따른 염료감응태양전지의 소자 특성에 미치는 영향을 고찰하였다.

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EMC Compatability Analysis on Geostationary Satellite (정지궤도 인공위성의 전자파 호환성 해석)

  • Chae, Tae-Byeong;Oh, Seung-Hyeub
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.36 no.12
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    • pp.1207-1215
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    • 2008
  • Satellite generates a complex electromagnetic noise by conducted and radiated coupling effect of the various electrical instruments. This noise may cause serious problems on the satellite system. To minimize the electromagnetic coupling effects and maintain the system safety margin, system noise reduction technique should be applied from the beginning of the system design. The COMS system is evaluated by measuring the conducted noise on system electrical power leads at PSR(Power Supply Regulator) and verifying a 6 dB system safety margin under the complex noise environment with current injection. The radiated noise due to the complex transmit antenna configuration is evaluated by integrating all unit-level RE measurement results, and the RF compatibility between spacecraft and launch vehicle is analyzed with the above estimations. This paper describes the COMS EMC compatibility analysis with respect to each unit level EMC test results, and RF compatibility analysis between spacecraft and launch vehicle. The analyzed results will be reflected on FM(Flight Model) EMC test.

EMC Design and Evaluation in Conduction Environment (전도성 EMC 설계 및 검증기술)

  • Kim, Tae-Yun;Im, Seong-Bin;Choe, Seok-Won
    • Aerospace Engineering and Technology
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    • v.5 no.2
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    • pp.67-76
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    • 2006
  • This paper describes the analysis method to define the system specification for conducted EMI environment and verification method to evaluate the conducted EMI performance. Conducted EMI environment is characterized by the electrical power subsystem which is mainly issued by the switching circuit noise, common ground impedance coupling. To define and control these EMI problems, EMI assesment through system analysis are preceded at the early design phase and then EMI reduction methods are applied during the unit/system development phase. System EMC should be carefully controlled and designed in the consideration of EMC safety margin and its performance is fully evaluated at the whole development period.

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Studies on the Sensing Mechanism of Conducting Polymer for Volatile Organic Compound Sensing (휘발성 유기화합물 측정을 위한 전도성고분자 센서의 감응기구에 관한 연구)

  • Hwang, Ha-Ryong;Baek, Ji-Heum;Heo, Jeung-Su;Lee, Deok-Dong;Im, Jeong-Ok;Lee, Jun-Yeong
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.599-602
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    • 2001
  • In this study, we fabricated chemically polymerized PPy and PANi films with different selectivity by controlling dedoping time. And the sensing properties and mechanism of VOCs adsorption to conducting polymers were investigated. Thin sensor had higher sensitivity compared to thick one, and dedoped sensor for 1-minute highest sensitivity. Upon gas absorption, polypyrrole exhibited positive sensitivity while polyaniline had negative sensitivity. PPy film show hydrophilic property and PANi film show hydrophobic property. After the gas absorption, the sensitivity increased as a function of polarity of absorbed molecules. These behaviors are due to the polar molecules absorbed with the movable polaron or free carrier, and then it interrupt or generate the movement of polaron and carrier, and then it changes the conductivity of polymer. We found that conducting polymer sensors are very sensitive to the difference in polarity of gas molecules.

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Dye-sensitized solar cells by structure control of $TiO_2$ thin-film layer (박막형 $TiO_2$ 전극구조 제어를 이용한 염료감응형 태양전지)

  • Kim, Hyun-su;Lee, Jin-kyu;Oh, Jae-kyung;Park, Kyung-won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.118-120
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    • 2009
  • 태양전지는 무한한 차세대 청정에너지로 주목을 받으며 그 개발의 필요성이 높아지고 있다. 이중 염료 감응형 태양전지(Dye-Sensitized Solar Cells, DSSC)는 낮은 제조 단가와 높은 효율로 기존의 Si 태양전지를 대체할 새로운 방법으로 연구되고 있다. 염료감응태양전지에 사용되는 $TiO_2$는 광촉매 성질 및 전자 전도성이 좋으며, 무독성에 가격이 저렴하여 다양한 분야에서 현재 많이 연구되고 있는 재료이다. 많이 사용되어지는 TiO2의 표면적은 염료의 흡착에 관여하므로 표면적의 제어는 매우 중요한 요소이다. $TiO_2$를 기판에 증착하는 방법으로는 Electrophoretic deposition, Chemical bath deposition, RF Margnetron sputtering, Electron-beam evaporation 등이 있으며 본 실험에서는 RF Magnetron sputtering을 사용하여 기판에 증착시키는 방법으로 구조를 제어하고자 한다. 이렇게 제조된 $TiO_2$ 박막을 SEM(Scanning Electron Microscopy)과 Solar simulator를 이용하여 표면형상과 Photocurrent-voltage curve를 분석하였다. 이것을 토대로 제조된 $TiO_2$박막의 구조가 염료감응태양전지에 미치는 영향을 연구해보고자 한다.

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Radiated Emission / Susceptibility Tests for the KSLV-I 2nd Stage Engineering Model (KSLV-I 2단부 엔지니어링 모델 복사성 방사/감응 시험)

  • Ji, Ki-Man;Lee, Soo-Jin;Chung, Eui-Seung
    • Aerospace Engineering and Technology
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    • v.6 no.1
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    • pp.173-181
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    • 2007
  • Radiated emission / susceptibility performance of the KSLV-I 2nd stage which are controlled from the unit level to the system level should be examined and managed all over the frequency ranges in order to ensure the normal operation of the SC, the 1st stage of the KSLV-I, ground support equipments which are installed at the space center, and other wireless communication networks. Not only unintentional electric field emissions from the KSLV-I system and its subsystems should be restricted to the levels less than the limits specified in the EMC requirements, but also proper test and evaluation method should be established, respectively. In this paper, radiated emission/susceptibility test limits, method, and test results of the KSLV-I 2nd stage engineering model are presented.

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EMC Compatibility Analysis of CEU EMC test results in the Optical Satellite System (광학위성 카메라전자부 EMC 시험결과의 시스템 양립성 검토)

  • Jang, Jae-Woong;Kim, Tae-Yoon;Lim, Seong-Bin;Moon, Guee-Won
    • Aerospace Engineering and Technology
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    • v.9 no.2
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    • pp.161-167
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    • 2010
  • CEU(Camera Electronic Unit) loaded in optical satellite for a high resolution image acquisition is composited with CC(Camera Controlloer), FPA(Focal Plane Assembly) and CEUP(CEU Power supply). EMC test and analysis results are explained in this paper. CE, CS, RE and RS test is performed in the 1st EMC test, RE, RS test which is not complied and influence considerably after shielding structure is performed in the 2nd EMC test. An effect due to the noise of CEU in the GPS/S-band receiving band is analyzed based on 2nd EMC test results. Margin more than 6dB is guaranteed when CEU is shielded.

A study on the Oxide Semiconductors electrodes for DSSC (염료감응형 태양전지를 위한 산화물반도체 전극에 관한 연구)

  • Hwang, Hyun Suk;Kim, Hyung Jin
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.7
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    • pp.4925-4929
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    • 2015
  • Dye-sensitized solar cell(DSSC) has aroused intense interest owing to its competitive price and stabilized properties than Si based solar cells. Recently, many studies have been reported on the DSSC, especially development of a transparent conductive oxide-less dye-sensitized solar cell(TCO-less DSSC). In this paper, a thick and porous Ti electrode for low cost DSSC developed its properties. To estimate the Ti electrode, the films are tested FESEM and J-V evaluation method. An increase in Ti thickness from 50 nm to 200 nm mainly affects the fill factor without noticeably changing the photocurrent density. It was confirmed that optimal DSSC efficiency was obtained at Ti 150 nm.