• Title/Summary/Keyword: 전기화학 모델링

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Development of 3D DMFC Model for Flow Field Design (직접 메탄올 연료전지 유로 설계를 위한 3차원 모델 개발)

  • Kim, Hongseong;Danilov, Valeri A.;Lim, Jongkoo;Moon, Il
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.93-102
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    • 2007
  • The objective of this study is to develop a 3D DMFC model for modeling gas evolution and flow patterns to design optimal flow field for gas management. The gas management on the anode side is an important issue in DMFC design and it greatly influences the performance of the fuel cell. The flow field is tightly related to gas management and distribution. Since experiment for the optimal design of various flow fields is difficult and expensive due to high bipolar plate cost, computational fluid dynamics (CFD) is implemented to solve the problem. A two-fluid model was developed for CFD based flow field design. The CFD analysis is used to visualize and to analyze the flow pattern and to reduce the number of experiments. Case studies of typical flow field designs such as serpentine, zigzag, parallel and semi-serpentine type illustrate applications of the model. This study presents simulation results of velocity, pressure, methanol mole fraction and gas content distribution. The suggested model is verified to be useful for the optimal flow field design.

Thermo-Chemical Analysis of a Calcination Furnace to Produce Cathode Material for the Secondary Batteries (이차전지 양극활물질 제조용 소성로의 열화학적 해석)

  • Hwang, Min-Young;Kim, Yong-Gyun;Jeon, Chung-Hwan;Song, Ju-Hun;Kim, Yong-Tae;Chang, Youn-Han
    • Journal of the Korean Electrochemical Society
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    • v.12 no.2
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    • pp.155-161
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    • 2009
  • Lithium secondary batteries have been widely used in the portable electric devices as power source. Recently it is expected that the realm of its applications expands to the markets such as energy storage medium of hybrid electric vehicle(HEV), electric vehicle(EV). Cathode active material is crucial in terms of performance, durability, capacity of lithium secondary batteries. It is urgent to develope the technology for mass production of cathode material to cope with the markets' demands in the near future. In this study, a calcination furnace running in real production line is modelled in 3D, and the thermal flow and gas flow after chemical reaction in the furnace is analyzed through numerical computations. Based on the results, it is shown that large volume of $CO_2$ gas is generated from chemical reaction. High concentration of $CO_2$ gas and it's stagnation is clearly found from the reactant containers in which the reaction occur to the bottom area of the furnace. It is also studied that 15% or more $CO_2$ mol fraction could affect to proper formation of $LiCoO_2$ through TGA-DSC analysis. The solutions to evacuate carbon dioxide from the furnace are suggested through the change of furnace design and operating condition as well.

Assessment of Hydrogeochemical Characteristics and Contaminant Dispersion of Aquifer around Keumsan Municipal Landfill (금산 매립장 주변 대수층의 수리지화학적 특성 및 오염 확산 평가)

  • Oh, In-Suk;Ko, Kyung-Seok;Kong, In-Chul;Ku, Min-Ho
    • Economic and Environmental Geology
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    • v.41 no.6
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    • pp.657-672
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    • 2008
  • The purposes of this study are to investigate the hydrogeochemical characteristics of groundwaters around Keumsan municipal landfill, and to evaluate the contaminant dispersion from the landfill and its environmental impact. To achieve these goals, groundwater quality logging, hydrochemical analysis, multivariate statistical analysis, and contaminant transport modeling were performed. The water quality logging indicated a leaking from the landfill at the depth of 4-12m around a leachate sump. Electrical conductivity data indicated that groundwaters within 70-100m from landfill were affected by the landfill leakage. Principal components 1 and 2 obtained from principal components analysis (PCA) reflect the influence of leachate and the characteristics of aquifer media, respectively. The results of principal component analysis also indicated the natural attenuation processes such as cation exchange, sorption, and microbial biodegradation. The modeling results showed that groundwater flow westward along a valley from the landfill and contaminants transport accordingly.

A Study on the Site Acceptance Test(SAT) Evaluation Algorithm of Energy Storage System using Li-ion Battery (리튬이온전지를 이용한 전기저장장치의 SAT용 성능평가 알고리즘에 관한 연구)

  • Park, Jea-Bum;Kim, Byung-Ki;Kim, Mi-Sung;Rho, Dae-Seok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.6
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    • pp.26-37
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    • 2019
  • Recently, standardization of installation progress and technology of site acceptance test(SAT) for energy storage system(ESS) are being required due to performance of ESS depending on working condition and environment even though the quality and safety of each component of ESS is guaranteed. And also, it has been required to perform not only performance testing by H/W equipments but also performance verification by S/W tool, in order to more accurately and reliably validate the performance of the ESS in advanced countries. Therefore, this paper proposes evaluation algorithm for SAT to evaluate performance of ESS and presents modeling of SAT test equipment for ESS by using PSCAD/EMTDC. Furthermore, 30[kW] scaled portable test equipments is implemented based on the proposed algorithm and modeling. From the various simulation and test results, it is confirmed that performance of ESS related to characteristics of capacity and Round-trip efficiency, Duty-cycle efficiency, low voltage ride through(LVRT) and Anti-islanding can be accurately evaluated and that the simulation results of PSCAD/EMTDC are identical to test results of 30[kW] test equipment.

Vibration Control of CD-ROM Feeding System Using ER Fluids (ER 유체를 이용한 CD-ROM 피딩 시스템의 진동 제어)

  • 김형규;임수철;최승복;박영필
    • The Korean Journal of Rheology
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    • v.11 no.2
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    • pp.97-104
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    • 1999
  • This paper presents vibration control of a drive feeding system consisting of a new type of CD-ROM(compact discread only memory) mount using electro-rheologocal(ER) fluid. Chemically treated starch particles and silicon oil are used for ER fluid. and its field-dependent yield stresses are experimentally distilled under both the shear and the flow modes. On the basis of the yield stress, an appropriate size of ER CD-ROM mount adapted to conventional feeding system is designed and manufactured. Vibration isolation performance of the proposed mount is evaluated in the frequency domain and compared with that of conventional rubber mount. The ER CD-ROM mount is then installed to the drive feeding system and the system equation of motion is derived. Following the formulating the sky-hook controller, computer simulation is undertaken in order to evaluate vibration suppression of the feeding system subjected to various disturbances(excitations).

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A Modeling for Li-Ion Battery Performance Analysis of GEO Satellite (정지궤도 인공위성 리튬-이온 배터리 성능 해석을 위한 모델링)

  • Koo, Ja-Chun;Ra, Sung-Woong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.2
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    • pp.150-157
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    • 2014
  • Li-Ion battery is used in the most satellites now due to advantages such as weight, thermal dissipation and self discharge compared to the previous generations of electrochemical batteries. The performance analysis model of the Li-Ion battery is needed to aid the design of new satellite electrical power subsystem. This paper develops the performance analysis model of the Li-Ion battery to apply to the electrical power subsystem design and energy balance analysis on geostationary orbit. The analysis model receives the satellite bus power, solar array power and battery temperature and gives the battery voltage, charge and discharge currents, taper index, state of charge and power dissipation. The results from the performance analysis are compared and analyzed with the flight data to verify the model. The compared results show satisfactory without significant difference with the flight data.

Modeling of the Conditioning Process in Chemical Mechanical Polishing (컨디셔닝 공정의 수학적 모델링)

  • Chang, One-Moon;Park, Ki-Hyun;Lee, Hyun-Seop;Jung, Won-Duck;Park, Sung-Min;Park, Boum-Young;Seo, Heon-Deok;Kim, Hyoung-Jea;Jeong, Hae-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.569-570
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    • 2006
  • The conditioning process is very important process for the CMP (Chemical Mechaning Polishing). This process regenerates the roughness of the polishing pad during the CMP process, increases the MRR (Material Removal Rate) and gives us longer pad life so conditioning process is essential for the CMP, and conditioning process influences the polishing pad shape gradually. Conditining process is related to the Non-Uniformity. In This paper, Kinematic of the conditioning process and mathematic modeling of the pad wear is studied and result shows how the various parameters influence the pad shape and WIWNU[1]. Consequently through these parameter, optimal design of the conditioning process equipment is predicted.

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A CFD Modeling of Heat Generation and Charge-Discharge Behavior of a Li-ion Secondary Battery (Li-ion 이차전지의 충방전 시 발열 및 충방전 특성의 CFD 모델링)

  • Kang, Hyeji;Park, Hongbeom;Han, Kyoungho;Yoon, Do Young
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.114-121
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    • 2016
  • This study investigates a CFD modeling of the charge-discharge behavior due to heat generation during charge-discharge cycles of a Li-ion secondary battery(LIB). Present LIB system adopted a current-density equation, heat and mass transfer governing equations upon the 1-dimensional system to the thickness direction for the rectangular pouch configuration. According to the 3-kinds of the charge-discharge current densities of 1C($17.5A/m^2$), 3C($52.5A/m^2$) and 5C($87.5A/m^2$) subject to a 3 V of cut-off voltage, a constant-temperature system at 298 K and three different heat generating systems were analyzed with comparison. Battery capacity decreases with increment of charge-discharge densities not only at the constant-temperature system but also at the heat-generating system. The time for charge-discharge cycles increases at the heat-generating system compare to the constant-temperature system. These trends are considered that the increase of temperature due to heat generation causes the decrement of equilibrium potential of electrodes and the increment of diffusivity of Li ions. Furthermore, cooling effects were discussed in order to control the influence of heat generation due to charge-discharge behavior of a Li-ion secondary battery.

A Numerical Modeling of the Temperature Dependence on Electrochemical Properties for Solid Oxide Electrolysis Cell(SOEC) (고체 산화물 수전해 시스템(SOEC)에서 전기화학적 특성의 온도 의존성에 대한 수치 모델링)

  • Han, Kyoung Ho;Jung, Jung Yul;Yoon, Do Young
    • Journal of Energy Engineering
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    • v.29 no.2
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    • pp.1-9
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    • 2020
  • In recent days, fuel cell has received attention from the world as an alternative power source to hydrocarbon used in automobile engines. With the industrial advances of fuel cell, There have been a lot of researches actively conducted to find a way of generating hydrogen. Among many hydrogen production methods, Solid Oxide Electrolysis Cell(SOEC) is not only a basic way but also environment-friendly method to produce hydrogen gas. Solid Oxide Electrolysis Cell has lower electrical energy demands and high thermal efficiency since it is possible to operate under high temperature and high pressure conditions. For these reasons, experimental researches as well as studies on numerical modeling for Solid Oxide Electrolysis Cell have been under way. However, studies on numerical modeling are relatively less enough than experimental accomplishments and have limited performance prediction, which mostly is considered as a result from inadequate effects of electrochemical properties by temperature and pressure. In this study, various experimental studies of commercial Membrane Electrode Assembly (MEA) composed of Ni-YSZ (40wt%, Ni-60 wt% YSZ)/8-YSZ (TOSOH, TZ8Y)/LSM (La0.9Sr0.1MnO3) was utilized for improving effectiveness of SOEC model. After numerically analyzing effects of electrochemical properties according to operating temperature, causing the largest deviation between experiments and simulation are that Charge Transfer Coefficient (CTC), exchange current density, diffusion coefficient, electrical conductivity in SOEC. Analyzing temperature effect on parameter used in overpotential model is conducted for modeling of SOEC. cross-validation method is adopted for application of various MEA and evaluating feasibility of model. As a result, the study confirm that the numerical model of SOEC based on structured process of effectiveness evaluation makes performance prediction better.

Parametric Study of SOFC System Efficiency Under Operation Conditions of Butane Reformer (부탄 개질기 운전조건에 따른 SOFC 시스템 효율에 대한 연구)

  • Kim, Sun-Young;Baek, Seung-Whan;Bae, Gyu-Jong;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.4
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    • pp.341-347
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    • 2010
  • In this study, the efficiency of a solid-oxide fuel cell (SOFC) system with a steam reformer or prereformer was analyzed under various conditions. The main components of the system are the reformer, SOFC, and water boiling heat recovery system. Endothermic and exothermic reactions occur in the reformer and SOFC, respectively. Hence, the thermal management of the SOFC system greatly influences the SOFC system efficiency. First, the efficiencies of SOFC systems with a steam reformer and a prereformer are compared. The system with the prereformer was more efficient than the one with steam reformer due to less heat loss. Second, the system efficiencies under various prereformer operating conditions were analyzed. The system efficiency was a function of the heat requirement of the system. The efficiency increased with an increase in the operating temperature of the prereformer, and the maximum system efficiency was observed at $450^{\circ}C$ for a S/C of 2.0.