• New & Renewable Energy
• /
• v.2 no.4 s.8
• /
• pp.46-55
• /
• 2006

본 연구는 불소그룹을 함유한 술폰화된 아릴렌에테르계 블록 공중합체 고분자 전해질막의 제조 및 연료전지 특성에 관한 것이다. 이러한 불소그룹을 함유한 술폰화된 아랄렌에테르계 블록 공중합체를 제조하기 위하여 양말단에 불소계 비닐기를 가지면서, 고분자 전환시 상온에서 술폰화 가능한 biphenyl계 단량체와 술폰화가 불가능한 sulfonyl계 단량체를 각각 합성하였다. Biphenyl계 단량체로 부터 올리고머를 합성한 후 sulfonyl계 단량체와 열적 고리화 부가중합을 하여 다양한 몰조성을 갖는 일련의 perfluorocyclobutane(PFCB)기를 포함하는 블록 공중합체를 제조하였다. 제조된 블록 공중합체를 상온에서 술폰화제인 chlorosulfonic acid(CSA)를 이용하여 후술폰화시켜 강산 이온기인 sulfonic acid를 biphenyl계 올리고머 부분에 선택적으로 도입하였다. 이렇게 제조된 술폰화된 고분자를 제막한 후 연료전지 특성을 Nafion-115와 비교하였다. 술폰화가 되는 올리고머 블록의 비율 증가에 따라 이온교환능력 (IEC)이 증가하였고 , 그에 따른 팽윤도 역시 증가하는 것을 보였다. 술폰화된 고분자들은 건조 및 습윤 상태에서도 기계적 강도가 우수하였다. 최적화된 술폰화 블록 고분자(S-2) 를 대상으로 membrane electrolyte assembly(MEA) 를 제조하여 연료전지 초기성능을 측정한 결과 Nafion-112와 유사한 전기화학적 성능을 나타내었다.

• The Korean Journal of Quaternary Research
• /
• v.15 no.1
• /
• pp.47-52
• /
• 2001

April∼August precipitation (141 years : A.D. 1858∼1998) of Mt. Sorak region (East-central Korea) was reconstructed using a tree-ring chronology of Pinus densiflora sampled from Beakdam Shelter area. During the reconstructed Periods, dry periods were 1880∼1887, 1893∼1901 and 1922∼1938, and wet one 1906∼1918. In the long-term variation, the late 19th and early 20th century were drier than the late 20th century. Major wet/dry periodicities in April∼August precipitation series reconstructed were 3.16 and 4.14 years, indicating that short-term variation were more prominent than long-term one.

• Journal of the Korea Concrete Institute
• /
• v.19 no.5
• /
• pp.639-646
• /
• 2007

This study performed several tests for the durability of the concrete coated with nano synthesis ceramics which do not contain volatile organic compounds harmful to environment. The tests were adhesion test on dry and humid concrete, SEM test, MIP analysis, carbonation, chloride diffusion by electronic facilitation, freezing-thawing resistance, alkaline resistance, and brine resistance test. In the adhesion test on dry and humid concrete, nano synthesis ceramics coating produced the highest results among all the coatings tested. Nano synthesis ceramics adhered solidly on the concrete surface. The adhesive strength seemed to result from the hydrogen bond between nano synthesis ceramics which are inorganic and generated by hydrolysis and re-condensation reaction and the concrete's hydrates such as calcium silicate aluminate or calcium silicate hydrate. SEM test and MIP analysis results show surface structure with finest crevices pore in the nano synthesis ceramics coating applied concretes. In the carbonation, chloride diffusion, and freezing-thawing resistance tests, the concretes with nano synthesis ceramics coating indicated the best results. Based on these test results, further progress in application of nano synthesis ceramics coatings to various concrete structures including costal structures and sewerage arrangements can be expected.

• Geophysics and Geophysical Exploration
• /
• v.9 no.4
• /
• pp.304-315
• /
• 2006

We have examined the applicability of f-k analysis to the GPR direct wave measurement for water content to characterize vadose zone condition. When the vadose zone consists of a dry surface layer over wet substratum, we obtained f-k spectra where most of the energy is bounded by the air and dry soil velocities. In this case, dry soil velocity was successfully estimated by using high frequency data. On the other hands, when wet soil overlies dry substratum, the f-k spectra show a contrasting response where most of the energy travels with the velocity bounded by dry and wet soil velocities. In this case, the radar waves are trapped and guided within wet soil layer, exhibiting velocity dispersion. By adopting modal propagation theory, we could formulae a simple inversion code to find two layer's dielectric constants as well as layer thickness. By inverting the velocity dispersion curve obtained from f-k spectra of synthetic modeling data, we could obtain good estimates of dielectric constants of each layer as well as first layer thickness. Moreover, we could obtain more accurate results by including the higher mode data. We expect this method will be useful to get the quantitative property of real subsurface when the field condition is similar.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.9 no.4
• /
• pp.506-513
• /
• 2021

The durability and safety of reinforced concrete structures significantly depend on the reinforcement conditions, concrete cover thickness, cracks, and concrete strength. There are two ways to accurately determine the information on reinforcing bars embedded in concrete - the local destructive method and the non-destructive rebar detection test. In general, the non-destructive rebar detection tests, such as the electromagnetic wave radar method, electromagnetic induction method, and radiation method, are adopted to avoid damage to the structural elements. The moisture content and temperature of concrete affect the dielectric constant, which is the electrical property of concrete, and cause interference in the non-destructive rebar detection test results. Therefore, in this study, the effects of the electromagnetic wave radar method and electromagnetic induction method have been analyzed according to the temperature and surface moisture content of concrete. Due to the technological advancement and development of equipment, the average error rate was less than 5% in the specimens at 24℃, irrespective of their operating principles. Among the tested methods, the electromagnetic induction method showed very high accuracy. The electromagnetic wave radar method indicated a relatively small error rate in the dry state than in the wet state, and exhibited a relatively high error rate at high temperatures. It was confirmed that the error could be reduced by applying the electromagnetic wave radar method when the temperature of the probe was low and in a dry state, and by using the electromagnetic induction method when the probe was in a wet state or at a high temperature.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.22 no.4
• /
• pp.26-34
• /
• 2008

This study focus on segmentation process that classifies road surfaces into 5 different categories, dry, wet water, icy, and snowy surfaces by analyzing asphalt-paved road images taken in daylight. By using the polarization coefficients, the proportions of horizontally polarized components to vertically polarized components, regions with over 1.3 polarization coefficients are classified as wet surfaces. Except for wet surfaces, the decision process a lies time-frequency analysis to other parts by using the third order wavelet packet transform. In addition, by using the average frequency characteristics of dry and icy surfaces from image templates, decide which is closer to a test image, and finally identify dry and icy surfaces. It is confirmed that the reposed estimation and segmentation of recognition on various images. This can be interpreted as an indication that image-only mad surface condition supervision is probable.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2006.06a
• /
• pp.25-30
• /
• 2006

When wet soil overlies dry soil, which can be found in the infiltration test, the radar wave is not attenuated and guided within wet soil layer. This phenomenon is known to be the dispersive guided wave and happens when the thickness of upper wet layer is less than or comparable to the wavelength of radar wave. In this study, we have conducted the FDTD modeling and obtained the velocity dispersion curve to identify the dispersive guided wave through F-K analysis. This guided wave can be explained by modal propagation theory and a simple inversion code was developed to obtain the two layer's dielectric constants as well as layer thickness. By inverting the dispersion curve from synthetic modeling data, we could obtain the accurate dielectric constants and layer thickness. Moreover, we could enhance the accuracy by including the higher mode data. We expect this method will be very useful to get the quantitative property of subsurface when the condition is similar.

• Magazine of the Korea Concrete Institute
• /
• v.9 no.1
• /
• pp.143-151
• /
• 1997

Chemical resistance of the cement mortar containing the Thermally Activated Diaomite(TAD) and H.M.(Heavy Metals) has been studied. The H.M.. extracted from EAF(Electrica1 Arc Furnace) Dust. were saturated with diatomite. The diatomite was then thermally activated at $750{\circ}C$ for 30minutes and powdeled. The powder was mixed with a portland cement on a weight basis from 0%. 2.5%. 5.0%. 10%. 20%. The optimum mixture. after those mixtures were subjected to compressive strength(7 and 28days) and leaching bchaviour of H.M.. was tested for its experiment on Wet/Dry cycles and chemical resistance(e.q. imrncrsion in 5%(Conc.) of H2S04, CaC12 and hlgSO4. It was shown that the cement, mortar containing 10% of' P.D. gave a rise to the remarkable increase in compressive strength. The compressive strength was generally decrease beyond the addition of 10% of P.D. The maximum $496kgf/cm^2$ of 28days compressive strength was acheiveti when 10% of P.D. was added to the cement mortar.

• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 2001.11a
• /
• pp.59-59
• /
• 2001

전보에서 발표한 바와 같이, 대상 라이너지 제조공장의 습부 운전조건이 지극히 악화되어 있으며 초지 시스템이 지종교체 등의 충격에 전혀 완충작용을 못하는 이유로 는 용수를 포함한 지료의 전하특성을 조절해주지 못하기 때문인 것으로 판단되었다. 특 히 양이온성 고분자로서 유일하게 사용하고 있는 보류향상제가 적절히 작용하지 못하 기 때문에 보류도가 저하되고, 제품내에 보류되지 못한 다량의 미세분이 백수 중에 존 재함으로서 결과적으로 지료의 전기적 특성을 더욱 악화시키는 악순환이 되풀이 되는 것으로 판단되었다. 이와 같이 강하게 음으로 하전된 지료의 전기적 특성을 조절하기 위해서는 양이온성 고분자의 사용량을 증가시키거나 고분자의 전하밀도 또는 분자량을 변화시켜 보는 것이 일반적인 습부첨가제 사용방법이라고 할 수 있다. 따라서 대상 습부공정의 조업조건을 호전시키기 위해서는 적절한 보류향상시스 템의 적용이 가장 시급한 현안이라고 판단되어 선규 보류제의 현장적용시험을 수행한 결과, 백수의 COD와 미세분이 격감하고 탈수성이 향상되어 습부공정의 운전조건이 호 전됨을 관측할 수 있었다. 그러나 2달 이상에 걸친 보류제 현장적용시험 기간 중에 생 산된 라이너지의 제반 물성들은 별다른 변화를 관측할 수 없었다. 이는 적용된 보류제 의 상당 부분이 계내의 미세분과 작용하여 소모되기 때문으로 판단되었다. 본 연구에서는 보류제의 투입 이전에 보류제와는 상대적으로 저분자량과 고 전 하밀도를 가진 고분자 전해질 4종을 사용하여 라이너지 지료의 전하를 중화시키고자 하였으며, 이러한 공정으로 생산된 라이너지의 물성변화를 관측하였다. 물성으로는 파 열강도, 압축강도, 습윤인장강도 및 염료 고착능력 등을 살펴보았다.시아노에틸화한 PYA가 안정된 분자구조를 유지하고 있음을 확인할 수 있었다. 시아노에틸화한 PYA용액의 점탄성 평가를 위하여 storage modulus와 loss modulus 를 분석하였다. 일반적 유변특성 평가 결과 PYA용액은 shear-thinning, pseudoplastic 한 특성을 나타내어 표면사이즈 공정에서의 적용 가능성을 확인할 수 있었다. 사용하는 통계기법 중의 하나인 주성분회귀분석을 실시하였다. 주성분 분석은 여러 개의 반응변수에 대하여 얻어진 다변량 자료의 다차원적인 변 수들을 축소, 요약하는 차원의 단순화와 더불어 서로 상관되어있는 반응변수들 상호간 의 복잡한 구조를 분석하는 기법이다. 본 발표에서는 공정 자료를 활용하여 인공신경망 과 주성분분석을 통해 공정 트러블의 발생에 영향 하는 인자들을 보다 현실적으로 추 정하고, 그 대책을 모색함으로써 이를 최소화할 수 있는 방안을 소개하고자 한다.금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다. within minimum time from beginning of the shutdown.및 12.36%, $101{\sim}200$일의 경우 12.78% 및 12.44%, 201일 이상의 경우 13.17% 및 11.30%로 201일 이상의 유기의 경우에만 대조구와 삭

• Geophysics and Geophysical Exploration
• /
• v.18 no.3
• /
• pp.125-132
• /
• 2015

The water saturation ($S_w$), which is very important to estimate hydrocarbon reserves in the reservoir, has been determined from resistivity index (RI) by using the Archie's formula. However, in many cases, it has been reported that n is not constant for a given formation and it could be varied with water saturation. In addition, it frequently happens that the line obtained by linear regression analysis on log-log scale does not pass through the origin. In order to overcome these drawbacks, we suggested a modified Archie's formula, which can handle almost all the RI vs. $S_w$ cross-plots whether the trend is straight or curved and whether it passes through the origin or not. We also demonstrated that how to determine conductivity exponent ${\mu}$, critical water saturation $S_c$, and saturation distribution factor b in the laboratory to use the modified Archie's formula. Since the modified Archie's formula takes into account pore structure, pore water distribution, and wettability of reservoir such as clean sandstone and carbonate rocks, it might improve field applicability.