• Economic and Environmental Geology
• /
• v.55 no.4
• /
• pp.377-388
• /
• 2022

Laboratory-scale experiments were performed to identify the As removal mechanism of the residual slag generated after the mineral carbonation process. The residual slags were manufactured from the steelmaking slag (blast oxygen furnace slag: BOF) through direct and indirect carbonation process. RDBOF (residual BOF after the direct carbonation) and RIBOF (residual BOF after the indirect carbonation) showed different physicochemical-structural characteristics compared with raw BOF such as chemical-mineralogical properties, the pH level of leachate and forming micropores on the surface of the slag. In batch experiment, 0.1 g of residual slag was added to 10 mL of As-solution (initial concentration: 203.6 mg/L) titrated at various pH levels. The RDBOF showed 99.3% of As removal efficiency at initial pH 1, while it sharply decreased with the increase of initial pH. As the initial pH of solution decreased, the dissolution of carbonate minerals covering the surface was accelerated, increasing the exposed area of Fe-oxide and promoting the adsorption of As-oxyanions on the RDBOF surface. Whereas, the As removal efficiency of RIBOF increased with the increase of initial pH levels, and it reached up to 70% at initial pH 10. Considering the PZC (point of zero charge) of the RIBOF (pH 4.5), it was hardly expected that the electrical adsorption of As-oxyanion on surface of the RIBOF at initial pH of 4-10. Nevertheless it was observed that As-oxyanion was linked to the Fe-oxide on the RIBOF surface by the cation bridge effect of divalent cations such as Ca²⁺, Mn²⁺, and Fe²⁺. The surface of RIBOF became stronger negatively charged, the cation bridge effect was more strictly enforced, and more As can be fixed on the RIBOF surface. However, the Ca-products start to precipitate on the surface at pH 10-11 or higher and they even prevent the surface adsorption of As-oxyanion by Fe-oxide. The TCLP test was performed to evaluate the stability of As fixed on the surface of the residual slag after the batch experiment. Results supported that RDBOF and RIBOF firmly fixed As over the wide pH levels, by considering their As desorption rate of less than 2%. From the results of this study, it was proved that both residual slags can be used as an eco-friendly and low-cost As remover with high As removal efficiency and high stability and they also overcome the pH increase in solution, which is the disadvantage of existing steelmaking slag as an As remover.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.11 no.1
• /
• pp.48-54
• /
• 2023

In this research, The basic physical properties and EMP shielding performance by thickness were evaluated for optimum composition of EMP shield concrete that can be applied on-site by mixing carbon-based materials with high conductivity into concrete that uses electric furnace oxidized slag (EOS). As a result of the evaluation, it was confirmed that the slump decreased as the amount of mixed carbon fib er (CF) increased, and increased when milled carb on (MCF) was mixed. As for the compressive strength, it was confirmed that EOS enhanced the strength compared to NA, and it was confirmed that the strength decreased when CF and MCF were mixed. As the thickness of the EMP shielding measurement increases, the shielding rate increases, and it was confirmed that the type of conductive material and the thickness of the test specimen have a greater influence on the shielding rate than the Amount of conductive material added. As a result of a comparative evaluation, EOS CF 0.2 is considered suitable for EMP shield concrete formulation.

• Resources Recycling
• /
• v.7 no.1
• /
• pp.34-40
• /
• 1998

This shdy was invcsligated on reduction rate of EAF dust wth solid carbon cantents. The rate equation for reduction ofEAF dust was obtaincd in the tempcrahlrc range cot 910-108O"C, and the ratio of zinc removal and metallization raho of ironoxides to thc reaction time was also analysed. From the XRD analysis for slag residues '||'&'||'er reaction, the cxistcncc DI themixture of Akemmite[Ca2MgSi2O.] and SiO, was identified.ed.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.3 no.1
• /
• pp.15-21
• /
• 2015

Recently, attempts of replacing some of natural aggregate with mix of low quality aggregate are carried out for stable supply of aggregate. However, low quality aggregate such as recycled aggregate produced during the disposal process of construction wastes and by-product aggregate produced by industrial activities has problem of failing to comply to KS Standards. Therefore, we have compared fundamental properties of concrete by using granite crushed aggregate, recycled aggregate, blast furnace and electric arc furnace slag aggregate for effective utilization of lacking aggregate resources. As the result, slump in case of mixed use of aggregate was increased 0~10% compared to single use. Therefore, it is judged to be economically advantageous as it can expect effects in unit quantity or reduction of SP agent. Compressive strength in case of mixed use of aggregate was increased 0~10% compared to single use as it filled internal crevice of concrete with continuous particle size distribution. Accordingly, if we utilize by satisfying standard particle scope through mix of aggregate with different cause of formation in proper ratio, it was possible to confirm utility of mixed aggregate with demonstration of effects of increases of fluidity and compressive strength of concrete.

• Resources Recycling
• /
• v.18 no.4
• /
• pp.14-23
• /
• 2009

In terms of resources recycling and resolving waste disposal problems, it is very important to recover precious metals like Au, Ag and Pd and valuable metals like Cu, Sn and Ni from the scraps of waste electrical and electronic equipment(WEEE) that consists of detective electrical and electronic parts discarded during manufacturing electrical and electronic equipments and waste electrical and electronic parts generated during disassembling them. In general, the scraps of WEEE are composed of various metals and alloys as well as refractory oxides and plastic components. Precious and valuable metals from the scraps of WEEE can be recovered by gas-phase-volatilization, hydrometallurgical, or pyrometallurgical processes. However, the gas-phase-volatilization and hydrometallurgical processes have been suggested but not yet commercialized. At the present time, most of the commercial plants for recovering precious and valuable metals from the scraps of WEEE adopt pyrometallurgical processes. Therefore, in this paper, the technical and environmental aspects on the important pyrometallurgical processes through literature survey are reviewed, and the scale-up result of a new pyrometallurgical process for recovering the precious and valuable metals contained in the scraps of WEEE using waste copper slag is presented.

• Journal of Soil and Groundwater Environment
• /
• v.13 no.4
• /
• pp.54-61
• /
• 2008

Permeable reactive barriers (PRBs) technology has been focused in contaminated groundwater remediation. It is necessary to select adequate reactive material according to characteristics of contaminant in groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through column test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Column test was performed in the condition of 1) single and multi contaminated solution and 2) different initial concentration of cadmium. Retardation factor of cadmium is 3.94 in multi contamination. But that of copper is 40.3 in single and 25 in multi. The difference of retardation between cadmium and copper is due to affinity, resulted from the difference of electronegativity. In multi-contamination, copper effluent concentration was above initial copper concentration and at the same time lead effluent concentration was decreased. This phenomenon was considered that lead extract copper sorbed in slag and then lead was sorbed to the vacant sorption site instead. And as the initial concentration was increased, the retardation factor of cadmium became decreased.

• Resources Recycling
• /
• v.11 no.6
• /
• pp.3-11
• /
• 2002

Recently, waste printed circuit board (PCB) has significantly increased in its amount due to the rapid development of electronic industries. Since several kinds of noxious materials and also valuable metals are contained in it, the waste PCB is in an urgent need of recycling for the dual purposes for the prevention of environmental pollution and recovery of valuable resources. Also, the catalyst which equipped in the exhaust pipes of automobiles to reduce emission of air pollutants contains precious met-als so that their recovery from the waste auto-catalysts is required. In this study, the recovery of valuable metals from waste PCB and auto-catalyst by arc furnace melting process has been investigated, which is known to be very stable and suitable f3r less production of pollutants due to its high operating temperature. The effect of the kind of flux on the recovery of precious metals was examined by using quicklime, converter slag, and copper slag as the flux. In addition, the influence of direct and alternating current and the applying direction of direct current has been investigated. It was observed that using converter or copper slag as a flux was more desirable for a higher efficiency in the precious metal recovery compared with quicklime. For the effect of current, application of direct current taking the bottom as a negative pole generally showed a better efficiency for the extraction of valuable metals from waste PCB, which was also observed for the case of waste auto-catalyst. The average recovery of precious metals from both wastes by arc furnace melting process was very high, which was up to in the range of 95～97%.

• Journal of the Korea Concrete Institute
• /
• v.18 no.2 s.92
• /
• pp.267-274
• /
• 2006

Greenhouse gas reduction will be highlighted as the most pending question in the cement industry in future because the production of Portland cement not only consumes limestone, clay, coal, and electricity, but also release waste gases such as $CO_2,\;SO_3$, and NOX, which can contribute to the greenhouse effect and acid rain. To meet the increase of cement demand and simultaneously comply with the Kyoto Protocol, cement that gives less $CO_2$ discharge should be urgently developed. This study aims to manufacture non-sintering cement(NSC) by adding phosphogypsum(PG) and waste lime(WL) to granulated blast furnace slag(GBFS) as sulfate and alkali activators. This study also Investigates the hydration reaction of NSC through analysis of scanning electron microscopy(SEM), X-ray diffraction(XRD), differential thermal analysis(DTA), and pH. Results obtained from analysis of the hydrate have shown that the glassy films of GBFS are destroyed by the activation of alkali and sulfate, ions eluted from the inside of GBFS react with PG and produce ettringite, and consequently the remaining component in GBFS slowly produced C-5-H(I) gel. Here, PG is considered not only to play the role of simple activator, but also to work as a binder reacting with GBFS.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.17 no.1
• /
• pp.76-84
• /
• 2013

In this study, some engineering properties of OPC and GGBFS shotcrete mortars with alkali-free or aluminate accelerator were experimentally examined. As a result, GGBFS mortars with alkali-free accelerator were significantly similar to OPC mortars with same accelerator with respect to both setting time and compressive strength. Comparatively, GGBFS mortars with aluminate accelerator showed a good performance with an increased replacement of GGBFS. Furthermore, when replaced with GGBFS over 50%, the mortars exhibited superior performances of electrical resistivity and chloride ions penetration resistance. Accordingly, it is suggested that GGBFS has a beneficial effect as shotcreting materials in the condition of proper replacement levels.

• Journal of the Korean Ceramic Society
• /
• v.39 no.6
• /
• pp.540-549
• /
• 2002

In this work, the hydration behaviour of portland cement pastes containing fly ash, blast-furnace slag and silica fume is investigated by Impedance Spectroscopy(IS). As fly ash or blast-furnace slag was added to portland cement, the values of R$_{t(s+1)}$ and R$_{t(s+1)}$ were decreased in the early hydration period. It showed that hydration of cement containing blending components was slower than it of the reference cement paste with the same W/C ratio. However, the cement paste containing silica fume had a large value of R$_{t(s+1)}$ and R$_{t(int)}$due to very rapid pozzolanic reactivity of silica fume in the hydration time. In OPC-fly ash system, a characteristic plateau region appeared between straight-line and semicircle. The plateau region continued to grow in range with the content of fly ash and the hydration time.