• Membrane Journal
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• v.27 no.2
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• pp.109-120
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• 2017

The reverse electrodialysis (RED) is an energy generation system to convert chemical potential of saline water directly into electric energy via the combination of current derived from a redox couple electrolyte and ionic potential obtained when cation ($Na^+$) and anion ($Cl^-$) pass through cation exchange membrane (CEM) and anion exchange membrane (AEM) into fresh water, respectively. Ion exchange membrane, a key element of RED system, should satisfy requirements such as 1) low swelling behavior, 2) a certain level of ion exchange capacity, 3) high ion conductivity, and 4) high perm-selectivity to achieve high power density. In this paper, research trends and prospects of ionomer materials and ion exchange membranes are dealt with.

• Analytical Science and Technology
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• v.11 no.3
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• pp.151-155
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• 1998

Electrochemical behaviours on 1.0 mM methylviologen ($MV^{2+}$) in 100 mM NaCl+27 mM $MgCl_2$ solution, without and with sodium dodecyl sulfate (SDS), were studied. The intersection of two lines on ${\Delta}E_p$ (the difference between the anodic, $E_{pa}$, and the cathodic, $E_{pc}$, peak potentials) of the first and second redox waves vs. -log[SDS] plot was determined as a critical micelle concentration (CMC). When $Mg^{2+}$ was added, the effective access of $MV{\cdot}^+$ to the glassy carbon electrode surface became possible and the formation of micelles was retarded.

• Analytical Science and Technology
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• v.6 no.1
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• pp.47-55
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• 1993

The quantitative determination of trace cyanide ion in the presence of sulfide ion has been studied by addition of cupric ion using differential pulse Cathodic Stripping Voltammetry. The detection limit of cyanide ion in the presence of $5.0*10^{-5}M$ sulfide ion and $1.0*10^{-3}M$ cupric ion was $2.0*10^{-7}M$ in KCI-Phosphate buffer(pH=7.0) at accumulation potential -0.30V and accumulation time 3.0 min.

• Journal of the Korean Chemical Society
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• v.32 no.2
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• pp.130-134
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• 1988

Direct differential-pulse cathodic stripping voltammetry on mercury electrode (HMDE) provides a sensitive technique for low level cyanide measurement in distilled and sulfide free solution. Cyclic voltammetry revealed the forming and redissolution reactions were reversible at pH 7 in 0.1M KCl-0.01M phosphate supporting electrolyte. The analytical conditions have been optimized. With deposition time of 3 min at deposition potential 0.00V(vs. Ag/AgCl) in this medium of pH7, quite reproducible and linear calibration curve was obtained down to $3{\times}10^{-7}M$ (8ppb) $CN^-$ which was the detection limit.

• Journal of the Korean Chemical Society
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• v.39 no.1
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• pp.23-28
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• 1995

Differential-pulse cathodic stripping voltammetry was applied to the Sn(II)-cupferron complex in 0.1 M acetate buffer solution (pH 4.20). Effects of solution pH, ligand concentration, accumulation potential, and accumulation time on the reduction peak current for the adsorptive complex of Sn(II)-cupferron were investigated. Interferences by other metal cations that affected on reduction peak current were also discussed. The detection limit was 3.1${\times}$10-9 M (0.37 ppb) of Sn(II) with 60 seconds accumulation time. The relative standard deviation (n=8) for 5${\times}$10-8 M Sn(II) was 3.0%.

• The Korean Journal of Food And Nutrition
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• v.13 no.4
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• pp.360-364
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• 2000

We studied the degree of rancidity of linoleic acid for the electrochemical redox reaction in time course and the kinetic parameters. The current of the linoleic acid was increased and the potential was shifted to the positive potential when scan rates were faster. The redox reaction of the linoleic acid was proceeding to totally irreversible and diffusion controlled reaction. From these results, diffusion coefficient(D$\_$o/) of linoleic acid was observed to 2.61$\times$10$\^$-6/ ㎠/s in the 0.1 M TEAP/DMF electrolyte solution. Also, exchange rate constant(K$\^$o/) was observed to 9.79$\times$10$\^$-11/ cm/s. The leaving time in air condition was found to affect the rancidity. We predicted that the product was carbonyl compounds.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2008.10a
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• pp.337-340
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• 2008

When high surge voltage invaded into the ground rod contacted with ground water, the ionization phenomena are happened in the water. Although some researchers have surveyed the ionization phenomena in soil, they have just analyzed the variation of the ground resistance. The most important role of the ground rod is to elect human beings from potential rise and to dissipate energy to the earth safely. In this wort we presented the method evaluating the potential reduction and energy dispersion. Also we analyzed theses factors as a function of charging voltages at the water resistivity of $50\;{\Omega}{\cdot}m$ using the Matlab Program. As a result the ground rod potential was reduced to 38 kV by ionization just below breakdown voltage. The energy more than half of the total injected energy was dispersed through the grounding electrode caused due to ionization.

• Geophysics and Geophysical Exploration
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• v.5 no.2
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• pp.78-83
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• 2002

The finite element method combined with the sensitivity method is adopted for 2-dimensionl Fourier transform inversion. To improve the efficiency of inversion calculation, multi-resolution wavelet method is proposed., Theoretical data which is obtained from above method is shown to examine the proposed method. Theoretical model assumes that underground cavity is located in limestone area. In theoretical model, 16 current and potential electrodes are located to get theoretical data. It is shown that the about inversion method is very exact and useful calculation method, in case the larger model is very small such as under ground cavity.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.12 no.4
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• pp.55-61
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• 1998

Generally, in the calculation of ground resistance in the grounding system, the method measuring ground potential rise which is caused by low frequency source injection is used. But both lightning and surge impulse re very harmful to electric equipment. In this connection, this paper presents the results of an experimental investigation of transient behavior of ground impedances when lightening current is injected to the electric rod the experimental results are agreement with the theoretical analysis. In addition, the states on the behavior of ground electrodes under impulse currents due to lighting strokes are presented. And the impulse impedance reductions caused by discharge in the soils are presented.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.25 no.5
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• pp.85-91
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• 2011

A grounding system is generally composed of several vertical, horizontal electrodes or grids. Excessive ground potential rises due to adjacent grounding electrodes can cause failures or misoperation of electronic devices and control systems. It is therefore necessary for computer-related and information-oriented equipment to be placed at a sufficient distance from the areas influenced by grounding electrodes. In this paper, in order to propose a method for evaluating the ground potential rise and interference in the vicinity of vertical grounding electrodes, the experimental and theoretical results on the potential interference between vertical grounding electrodes and its frequency dependence were described. The ground potential rise is sharply decreased with increasing the distance between grounding electrodes. In case that the separation of vertical grounding electrodes is less than 1.5[m], the potential interference coefficient was greater than 0.1 and linearly increased with the frequency of the test current within the frequency of 1[MHz].