• Title/Summary/Keyword: 적하법

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The Effect of Temperature on the Critical Micelle Concentration of Cationic Surfactant for Chemical Dispersants (유처리제용 양이온 계면찰성제의 임계미셀농토에서 온도의 효과)

  • kim, Yeoung-Chan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.14 no.2
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    • pp.145-148
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    • 2008
  • Cationic surfactant can be used as cosmetics and chemical dispersants. The variation of critical micelle concentration (CMC) with temperature over the range $40^{\circ}C$ to $60^{\circ}C$ for N-octadecyl pyridinium bromide was measured by drop methods. Thermodynamic quantities such as free energy, enthalpy, entropy and heat capacity for micellization of N-octadecyl pyridinium bromide in water were calculated by fourth-degree polynominal equation In the result, free energy change was decreased generally by the increment of temperature.

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장치장에서 베이 내 컨테이너의 효율적인 재정돈 방안

  • 강재호;류광렬;김갑환
    • Proceedings of the Korea Inteligent Information System Society Conference
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    • 2004.11a
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    • pp.287-295
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    • 2004
  • 컨테이너 터미널의 적하 작업은 사전에 계획된 순서대로 컨테이너를 장치장(yard)에서 하나씩 반출하여 선박에 선적하는 작업이다. 만일 현재 반출하고자 하는 컨테이너의 상단에 다른 컨테이너들이 장치되어 있다면, 부득이하게 위에 놓여 있는 컨테이너들을 다른 곳으로 옮겨야 하는 재취급(rehandling)이 발생하고 이로 인하여 반출 작업은 지연된다. 본 논문에서는 적하 계획이 수립되어 장치장의 한 베이(bay)내 컨테이너들의 반출 순서가 결정되었을 때, 반출 시작 시점까지 남는 유휴 시간을 활용하여 재취급이 발생하지 않도록 컨테이너들을 재정돈(이적, 리마샬링)하는 방안을 제안한다. 본 제안 방안은 분지 한계법(branch and bound)을 적용하여 컨테이너 이동 계획을 탐색하며, 생성된 해는 최소의 컨테이너 이동 횟수가 보장된다. 4 단 6 열과 5 단 9 열의 장치장 구조를 대상으로 실험한 결과 99% 이상의 상황에서 허용할 수 있는 시간 내에 계획을 수립할 수 있음을 확인하였다.

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컨테이너 터미널에서 수출컨테이너의 작업순서 및 장치위치 결정

  • Bae, Jong-Uk;Park, Yeong-Man
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2009.10a
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    • pp.177-178
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    • 2009
  • 본 연구는 반입 작업에서 수출 컨테이너의 작업순서 및 장치위치를 결정하는 문제를 다루었다. 수직 배치형 컨테이너 터미널에서 적하작업시간의 단축을 위해서는 가능한 해측에 컨테이너를 장치하는 것이 유리하지만 반입 외부 트럭의 빠른 회전시간의 측면에서는 육측이 선호된다. 이때 수출 컨테이너의 장치위치는 본선작업 우선순위에 따라 가중치가 다르고 이에 소요되는 장치소요시간에 따라 외부트럭들의 대기시간도 달라진다. 따라서 본 연구는 외부 트럭들의 예정 도착시간과 최대대기시간 그리고 적하작업의 선호 장치위치를 동시에 고려한 혼합정수모델을 개발하고 이를 활용한 적용 예를 제시하였다.

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Assignment and Operation Sequencing for Remarshalling of a Vertical Yard Block in Automated Container Terminals (자동화 컨테이너 터미널에서 수직형 블록의 이적작업을 위한 할당 및 작업순서)

  • Bae Jong-Wook;Park Young-Man;Kim Kap-Hwan
    • Journal of Navigation and Port Research
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    • v.30 no.6 s.112
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    • pp.457-464
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    • 2006
  • Remarshalling operation is one of the operations considered important in an automated container terminal to perform quickly loading operations and delivery operations. It arranges the containers scattered at a verticla yard block in order to reduce the transfer time and the rehandling time of ATC(Automated Transfer Crane)s. This paper deals with the remarshalling planning problem minimizing the weighted operation time. This problem can be decomposed into 2 subproblems, storage space assignment problem and operation sequencing problem Storage space assignment problem decides to where containers are transported in terms of transportation time cost.. With results of a previous subproblem, operation sequence problem determines the ATC operation sequence, which minimizes the dead-heading of ATC This study formulates each subproblem with mixed integer program and dynamic program. To illustrate the proposed model, we propose an instance to explain the process of remarshalling planning.

Synthesis of Hydrous $TiO_2$ Powder by Dropping Precipitant Method and Photocatalytic Properties (침전제 적하법을 이용한 $TiO_2$ 분말 제조 및 광촉매 특성)

  • 이병민;신대용;한상목
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.308-313
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    • 2000
  • Hydrous titanium oxide particles with anatase phase were prepared from 0.05 mol TiCl4 solution using NH4HCO3 as precipitant by the droopping precipitant method. The sequential change of pH is completed by a sudden and steep increase in a pH value of the range of 6~7 to which the concentration of adsorbed OH- and H+ ions on TiO2 surface is equal. Rutile phase started precipitating with anatase phase as an increase of reaction temperature above 6$0^{\circ}C$ in aqueous 0.05mol TiCl4 solution and its specific surface area was found to decrease from 452 $m^2$/g($25^{\circ}C$) to 164$m^2$/g(8$0^{\circ}C$). Specific surface area decreased rapidly when anatase powders precipitated at 4$0^{\circ}C$ were heat-treated at temperature higher 40$0^{\circ}C$. FT-IR result confirmed that it was due to the decrease of OH species within hydrous titanium oxides. The loss of ethanol after illumination of the powder heated at $600^{\circ}C$ and $700^{\circ}C$ for 4 h was 66 and 68.8%, respectively.

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Investigation of Tieback wall Behavior based on Generated Mass Movement (Mass Movement가 타이백 앵커 벽체의 거동에 미치는 영향평가)

  • 임유진
    • Journal of the Korean Geotechnical Society
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    • v.16 no.5
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    • pp.83-92
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    • 2000
  • 벽체의 수평변위 중 토체의 침하 및 앵커체 자체의 움직임 등으로 인해 발생하는 mass movement가 타이백 앵커토류벽의 거동에 미치는 영향을 조사하였다. 시공사례에 대한 유한요소 해석을 실시하여 벽체의 변위, 겉보기토압, mass movement 및 앵커 자유장 내에서의 하중 변화를 투적하였다. 유한요소해석법을 이용해 mass movement를 계산, 예측할 수 있었으며, 시공 순서에 따흔 앵커 자유장 내의 하중변화를 예측할수 있었다. 현장계측결과와 유한요소해석결과로부터 벽체변위, 겉보기토압 및 앵커의 하중 변화에 미치는 mass movement의 영향이 매우 큼을 확인 할 수 있었다.

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Antioxidant and antimicrobial activities of Jeok Hasuo (Polygonum multiflorum Thunb.) and Baek Hasuo (Cynanchi wilfordii Radix) root extracts (적하수오 및 백하수오 추출물의 항산화 및 항균 활성)

  • Choi, Hyunkyung;Jang, Yuyi;Oh, Jun-Hyun
    • Food Science and Preservation
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    • v.23 no.3
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    • pp.432-437
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    • 2016
  • The objective of this research was to investigate the antioxidant and antimicrobial activities of Jeok Hasuo (Polygonum multiflorum Thunb., PM) and Baek Hasuo (Cynanchi wilfordii Radix, CW) root extracts. Total phenolic contents of PM and CW root extracts were determined and the antioxidant activities of the root extracts were determined by scavenging activity of diphenylpicrylhydrazyl (DPPH) radicals. The antimicrobial activities against Staphylococcus aureus and Propionibacterium acnes were determined and expressed as the minimum inhibitory concentration (MIC). The disc diffusion method was also used to determine the zone of inhibition. The butanol extracts of PM and CW roots exhibited greater total phenolic contents (1,212.6 and 1,454.5 mg/g GAE, respectively) than those of ethanol and water extracts. The ethanol (89.0%) and butanol extracts (88.9%) of PM exhibited significantly greater DPPH radical scavenging activities than that of water extracts (73.1%) (p<0.05). Only ethanol extract exhibited an MIC of 0.8 mg/mL against both bacteria. Zones of inhibition started to form when the concentration of extract was greater than 5 mg/disc. The diameters of the zone of inhibition of PM and CW were measured to be 8.9 and 9.2 mm against S. aureus and P. acnes, respectively, exhibiting the greatest antimicrobial activities among the extracts. This research demonstrated that the PM and CW root extracts possessed not only antioxidant activity but also strong antimicrobial activity against skin-related bacteria.

A New Analytical Method for the $Dy^{3+}$ Ion Using the Luminescence Enhancement by the Treatment of o-Phenanthroline on the TLC Plate (TLC Plate에서의 발광증폭 및 o-Phenanthroline에 의한 Energy Transfer를 이용한 $Dy^{3+}$ 이온의 미량 분석법)

  • Jeong, Hyuk
    • Analytical Science and Technology
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    • v.11 no.5
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    • pp.386-393
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    • 1998
  • A new analytical luminescence method for the $Dy^{3+}$ ion was studied using the luminescence enhancement by the treatment of the o-phenanthroline on the TLC plate. Compared to the specific emission intensities of the ion in water solution, if the ion solution is spotted on the TLC plate, the luminescence intensities were extremely enhanced. There was additional enhancement effect of the luminescence intensities of the ions on the TLC plate, if the ion on the TLC plate is treated with o-phenanthroline. Based on the luminescence enhancement, the detection limit was improved by more than 4 order of magnitude compared to that of solution sample. The dynamic ranges and correlation coefficients of the calibration curves near the detection limit were 102 order and ~0.99, respectively. The energy-transfer mechanism was explained for the theoretical back ground of the luminescence enhancement.

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Optimal hot water extraction conditions of fermented Polygonum multiflorum root by Lentinula edodes pegler mycelials using response surface methodology (반응표면 분석법에 의한 표고균사체발효 적하수오 열수 추출조건의 최적화)

  • Oh, Junseok;Hong, Jae-Heoi;Park, Tae-Young;Shin, Ji-eun;Kim, Kyung-Je;Jin, Seong-Woo;Ban, Seung-Eon;Koh, Young-Woo;Im, Seung-Bin;Seo, Kyoung-Sun
    • Journal of Mushroom
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    • v.16 no.1
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    • pp.22-30
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    • 2018
  • This study was performed to determine optimal extraction conditions of fermented Polygonum multiflorum root by Lentinula edodes (JMI10079) Pegler mycelials using response surface methodology. The independent factors were extraction temperature (X1: $40-100^{\circ}C$), extraction time (X2: 2-10 hrs.), and the ratio of water to sample (X3: 33-100 mg/mL). Their effects were assessed on dependent variables of the extract properties, which included soluble solid contents (Y1), $^{\circ}Brix$ of sample extract (Y2), total polyphenol content (Y3), total flavonoid content (Y4), 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) radical cation scavenging activity (Y5) and 2,2-diphenyl-1-picrylhydrazyl radical scavenging activity (Y6). The experimental data obtained were fit to a second-order polynomial equation. The optimal extraction conditions for fermented P. multiflorum root were: X1: $91.22^{\circ}C$, X2: 7.72 hrs, and X3: 39.71 mg/mL.

The Synthesis and Characterization of Beta Alumina Powder by Microwave Extraction and Calcination Method (마이크로파 추출 및 하소법에 의한 베타 알루미나 분말 합성 및 특성)

  • 박희찬;박성수;정기석;김병우;이상은
    • Journal of the Korean Ceramic Society
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    • v.38 no.8
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    • pp.749-754
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    • 2001
  • 마이크로파 추출 및 하소 공정을 통하여 카올린으로부터 베타 알루미나 전구체 및 베타 알루미나 분말을 합성하였다. 황산 알루미늄 및 가성소다의 혼합 용액을 교반되는 에탄올 용액 중에 적하시켜서 $Al_2$(SO$_4$)$_3$.17$H_2O$$Na_2$SO$_4$.10$H_2O$의 균일한 침전물을 얻었다. $\beta$- 및 $\beta$\"-Al$_2$O$_3$상으로 구성된 베타 알루미나를 얻기 위하여 재래식 및 마이크로파 하소법으로 주어진 온도에서 약 2h 동안 침전물 시료를 하소하였다. 재래식 하소된 시료에 비하여 마이크로파 하소된 시료는 $\beta$\"-Al$_2$O$_3$상이 상대적으로 많이 존재하였다. 또한, 재래식 하소된 시료와 마이크로파 하소된 시료의 미세구조는 매우 상이하였다. 매우 상이하였다.

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