• Journal of Conservation Science
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• v.33 no.2
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• pp.131-147
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• 2017

The purpose of this study is to analyze the characteristics of Punchong and Whiteware pottery excavated from the kiln site in Dongkok-Town, Gimge. Scientific analysis is carried out to evaluate the physical and chemical properties of the body and glaze. The physical properties indicate the gradual development of the production technology with respect to the kiln operating conditions and period. In chemical properties, the ceramic body is found to be made of raw materials from the same source, but the mixing method depends on the type of Punchong and Whiteware pottery, the production kiln, and period. Whiteware pottery is manufactured with less over 1.3% of the colorant content and more about 1.2% of the $K_2O$ flux content than Punchong pottery. This compositions allow easier vitrification at the same temperature. These characteristics which is low colorant content and high flux content become more prominent as lately. The ceramic glaze is likely to have changed the type of raw materials used after 16~17C, as the contents of MgO, $TiO_2$, MnO, $P_2O_5$ are less three to ten times than 15C.

• Journal of the Korean Chemical Society
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• v.35 no.6
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• pp.645-652
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• 1991

The stability constants$(K_f)$ of the complexes of some transition and post-transition metal ions (Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), Zn(Ⅱ), Cd(Ⅱ), Pb(Ⅱ), Hg(Ⅱ)) with $N_2O_3$-donor macrocyclic ligand, 1,15-diaza-3,4 : 12,13-dibenzo-5,8,11-trioxacyclooctadecane ($NtnOdienH_4$), have been determined by potentiometry in aqueous solution at $25^{\circ}C$. Log $K_f$ values of the complexes were : Co(Ⅱ): 3.83, Ni(Ⅱ) : 4.56, Cu(Ⅱ) : 7.74, Zn(Ⅱ) : 4.98, Cd(Ⅱ) : 3.91, Pb(Ⅱ) : 6.65, and Hg(Ⅱ) : 14.87. The order of stabilities of transition metal complexes was the same as the natural order of stability proposed by Williams-Irving. In post-transition metal complexes, the order of stabilities was Cd(Ⅱ) < Pb(Ⅱ) < Hg(Ⅱ), and the covalent character in metal ion-donor atoms bonds appeared a dominant factor in the stability. In methanol solution, each metal ion forms 1 : 1 complex, while Ni(Ⅱ) ion forms both 1 : 1 and 1 : 2 complexes. It was confirmed by $^1H-$ and $^{13}C-$NMR spectral study that the nitrogen atoms in the ligand were major contributors for the complexation of post-transition metal ions with the ligand. It was shown, by elementry analysis, electrical conductivity and magnetic susceptibility measurements, and spectral analysis, that solid Cu(Ⅱ)-and Zn(Ⅱ)-complexes have a distorted octahedral and a tetrahedral structure, respectively.

• Journal of Conservation Science
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• v.27 no.3
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• pp.291-300
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• 2011

Archaeomagnetic dating method is used to assign a date to the archaeological remains in which burnt soil is found by measuring the changes in terrestrial magnetism with the thermal remanent magnetization retained in burnt soil. This method, in particular, is quite useful to determine an age of the archaeological remains in which no properties are found, which makes it difficult to assigning a date. Hemp kiln and lime kiln fall under remains of these features, and 21 and 5 archaeomagnetic data from both kilns respectively were obtained by measuring the- remanent magnetization in burnt soil samples that are extracted in hemp kilns and lime kilns in the country. The results of archaeomagnetic dating with these data show the age range of the hemp kilns is between the late 10th century A.D. and the middle of the 19th century, and that of the lime kilns is between the early 16th century A.D. and the middle of the 18th century. The factor that the number of data collected from the hemp kilns was comparatively more than those from the lime kilns might affect the result, however corresponding to the fact that hemp had been used for a long period of time, the period of hemp kiln are widely spread over the chronological table. And the archaeomagnetic dating of lime kiln, in view of archaeological periods, is not only in accord with the late Joseon period when the tombs with lime-soil mixture barrier in trend; this is also telling that its width of archaeological period is comparatively narrow.

• Journal of Conservation Science
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• v.32 no.1
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• pp.1-10
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• 2016

At the archaeological site, there are a variety of fired soil remains with which archaeomagnetic dating is measured, and there are also different kinds of kilns equipped with favorable plasticity conditions, so quality data can be gained. Among them, roof tile kilns indicate fairly great results of archaeomagnetic measuring. This should be associated with the properties of soil consisting of the kilns. With a lot of experimental results, it has been found that the fired soil samples of roof tile kilns have formed very stable residual magnetization. This author conducted archaeomagnetic research to present archaeomagnetic results of measuring about roof tile kilns from Goryeo in Gyeonggi. With the archaeomagnetic data of measuring 21 samples, this researcher tried to estimate the archaeomagnetic dating of roof tile kilns from Goryeo in Gyeonggi and divided them into three groups, group A (A.D.900~1150), group B (A.D.1150~1250), and group C (A.D.1300~1400) to figure out their relative order and arrange them in order. Through this kind of archaeomagnetic research, it will be possible to identify the dating of 21 roof tile kilns from Goryeo in Gyeonggi and also contribute considerably to chronological research on roof tile kilns from Goryeo. In the body, the remains and kilns belonging to each group are presented in detail.

• Journal of Conservation Science
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• v.34 no.5
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• pp.345-358
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• 2018

The purpose of this study is to analyze the characteristics of low-grade 12th-century celadons, which were excavated from a kiln site in Noksan-dong, Busan. The physical and chemical properties of the body and the glaze are evaluated through scientific analyses. All the selected celadon shards have a similar body color, regardless of the kiln from which they originated. The celadon shards from 2 3 kilns are brighter than those from 4 5 kilns, and there are two saturations, namely gray and brown. The brightness of the glaze shows a high contribution of red and yellow. The porosity of the selected shards is 8.8% in the gray saturation and 16.1% in the brown saturation. The major chemical compositions of the body and glaze are in the typical chemical composition of the celadon, but the $TiO_2$ flux contents are different. The visible characteristic difference between the 2 3 kilns and the 4 5 kilns can be attributed to the mixing and the firing process rather than the raw materials used. The difference in the $Fe_2O_3$ and $K_2O$ flux between the 2 3 and 4 5 kilns can be attributed to changes in the ingredient combination during the process. In conclusion, Noksan-dong celadon could not be easier vitrification due to the manufacturing process that primary burning process, It is highly likely that there were process differences in kilns to produce high quality celadon.

• Conservation Science in Museum
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• v.19
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• pp.19-40
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• 2018

Most stone monuments in Korea are made from the granitoids found extensively throughout the nation. To identify the provenance of the stone materials, this study carried out comprehensive analyses of the occurrence, physical properties, mineralogy, and chemical composition of Stupa for National Preceptor Wongong at Geodonsa Temple and Five-story Pagoda at Cheonsusa Temple, both located in the Gangwon region. Their features were compared with those of granite from Wonju City near the sites of the two monuments. Stupa for National Preceptor Wongong is composed purely of two-mica granite, whereas Five-story Pagoda was made from both two-mica and biotite granites. The occurrence and magnetic susceptibility of the two granite monuments generally coincide with those of granite from Wonju. When selecting materials for the restoration of stone monuments, it is deemed necessary to carry out a field survey on granite in areas adjacent to the locations of the stone monuments subject to restoration.

• Journal of Conservation Science
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• v.32 no.4
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• pp.549-560
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• 2016

The purpose of this study is to identify the material characteristics of blackwares excavated from the Bonggok kiln site in Jinan-gun, Jeollabuk-do Province, South Korea, by scientific analyses and a reproduction experiment. Scientific analyses were conducted to determine the physical properties, chemical composition and for microscopic observation of blackwares. A reproduction experiment was also conducted by producing ceramic samples with black glaze, red ocher and limestone, and then cross sections of the samples were observed. The analysis results showed that all the excavated blackwares have similar properties such as chromaticity, specific gravity, absorption factor and porosity, but there is a difference depending on the crystallization of the ceramics. Thermal analysis showed that the exothermic peak was observed at about $1200^{\circ}C$, and crystal structure analysis indicated the presence of mullite. Hence, it can be concluded that the firing temperature of the excavated blackwares was around $1100-1200^{\circ}C$. Moreover, the glaze present on these blackwares has about 22% higher $Fe_2O_3$ content than those excavated from other places; however, the former has lower CaO content. For the reproduction experiment, samples were made using limestone as a flux and red ocher as a glaze. The results show that the cross section of the glaze layer of the reproduced sample have iron crystals with dendritic structures, similar to those present in the excavated black-wares. It is assumed that such iron crystals were formed during the process of melting and solidification of the iron oxide present in the blackwares.

• Polymer(Korea)
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• v.38 no.6
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• pp.827-831
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• 2014

An organic radical polymer (ORP) was prepared by radical polymerization and following oxidation into nitroxyl radical. Two different oxidation methods were employed and their radical concentrations were measured using electroparamagnetic resonance spectroscopy (EPR) and UV-visible absorption (UV-vis) spectroscopy. From these measurements, $H_2O_2-Na_2WO_4$ oxidation method exhibited a complete oxidation, which resulted in 97.6% spin concentration. Also, it was revealed that convenient and cheap UV-vis measurement was useful for preliminary radical concentration comparison. After applied as a cathode material in lithium ion batteries, ORP electrode showed a high initial capacity ($110mAh\;g^{-1}$), a good initial efficiency (96%), a very high rate performance (70% charging during 1.2 min) and stable cycle performance.

• Journal of the Korean Magnetics Society
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• v.18 no.4
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• pp.136-141
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• 2008

In this study, the magnetic(static and high-frequency) and microwave absorbing properties have been investigated in Ru-Co substituted M-hexaferrites($BaFe_{12-2x}Ru_xCo_xO_{19}$). The powders and sintered specimens were prepared by conventional ceramic processing technique. With the calcined powders, the composite specimens were prepared using the silicone rubber as a matrix material. The substitution ratio of Ru-Co to obtain in-plane magnetic anisotropy, thus having the minimum coercivity, is much smaller (about x=0.3) than the previously reported Ti-Co substituted specimen. Owing to this low substitution, the specimen has a large value of saturation magnetization($M_s$=65 emu/g). Ferromagnetic resonance behavior and microwave absorbing frequency band is strongly influnced by the coercvity which can be controlled by Ru-Co substitution ratio. It is found that the M-hexaferrites with planar magnetic anisotropy by doping Ru-Co in both sintered and composite form have superior microwave absorbing properties in GHz frequency range.