• Title/Summary/Keyword: 재료선정

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CIGS 태양전지 용액전구체 paste공정 연구

  • Park, Myeong-Guk;An, Se-Jin;Yun, Jae-Ho;Kim, Dong-Hwan;Yun, Gyeong-Hun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.27.1-27.1
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    • 2009
  • Chalcopyrite구조의CIS 화합물은 직접천이형 반도체로서 높은 광흡수 계수 ($1\times10^5\;cm^{-1}$)와 밴드갭 조절의 용이성 및 열적 안정성 등으로 인해 고효율 박막 태양전지용 광흡수층 재료로 많은 관심을 끌고 있다. CIS 계 물질에 속하는 $Cu(InGa)Se_2$ (CIGS) 태양전지의 경우 박막 태양전지 중 세계 최고 효율인 20%를 달성한 바 있으며, 이는 기존 다결정 웨이퍼형 실리콘 태양전지의 효율에 근접하는 수치이다. 그러나 이러한 우수한 효율에도 불구하고 박막 증착시 동시증발장치 혹은 스퍼터링장치와 같은 고가 진공장비를 사용하게 되면 공정단가가 높을 뿐만 아니라 사용되는 재료의 20-50%의 손실을 감수해야만 한다. 또한 대면적 Cell제작에 어려움이 있기 때문에 기술개발 이후의 상용화 단계를 고려할 때 광흡수층 박막 제조 공정단가를 획기적으로 낮출 수 있고 대면적화가 용이한 신 공정 개발이 필수적이다. 이러한 관점에서 비진공 코팅방법에 의한 CIS 광흡수층 제조 기술은 CIS 태양전지의 저가화 및 대면적화를 가능케 하는 차세대 기술로 인식되고 있고 최근 급속한 발전을 이루고 있는 미세 입자 합성, 제어 및 응용 기술에 부합하여 많은 세계 연구기관 및 기업체에서 활발히 연구를 진행하고 있다. 비진공 방식에 의한 CIS 광흡수층 제조 기술은 전구체 물질의 형태에 따라 크게 입자형 전구체를 사용하는 방법과 용액 전구체를 사용하는 방법으로 나눌 수 있다. 본 연구에서는 용액 전구체를 paste 공정으로 실험하였다. 이는 용액전구체 물질 제조가 입자형 전구체 제조에 비해 매우 간단하고, 전구체 물질 내 구성원소의 원자비를 쉽게 조절할 수 있다는 장점 및 사용효율이 높아 소량의 source로도 박막 제작이 가능해 공정 단가 절감에 큰 효과가 기대되기 때문이다. 실험에 사용 된 용액전구체는 $Cu(NO_3)$$InCl_3$, $Ga(NO_3)$를 Cu, In, Ga 출발 물질로 선정하여 이를 메탄올에 완전히 용해시켜 binder인 셀룰로오즈와 메탄올을 섞은 용액과 혼합하여 전구체 슬러리를 형성하였다. 이 슬러리를 paste공정으로 precursor막을 입히고 저온 건조 후 Se 분위기에서 열처리하여 CIGS박막을 얻을 수 있었다. 박막의 특성을 XRD, SEM, AES, TGA등으로 분석하였다.

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Experimental Study for the Development of Vibration-Controlled Concrete (I) (진동제어 콘크리트 개발에 관한 실험적 연구(I))

  • 정영수;이대형;최우성
    • Magazine of the Korea Concrete Institute
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    • v.8 no.5
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    • pp.123-133
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    • 1996
  • Recently, the construction of infrastructures has been booming and accelerating to keep up with rapid economic growth. Construction activities and operation of transportation facilities cause unfavorable effects such as civil petitions associated with vibration-induced damages or nuisances. Accordingly, the objective of this study is to develop vibration-controlled concrete using various vibration-controlled mixtures, and also to recycle obsolete materials in part. As the first step to achieve this research, preliminary mix designs have been carried out to obtain an appropriate mix proportion above 200kg/$\textrm{cm}^2$ in uniaxial compressive strength. Test specimen based on the mix proportion selected have been actuated by the impact hammer to investigate their dynamic characteristics. Vibration-controlled mixtures are foam, latex, rubber powder and plastic resin, which have been determined to reduce a vibration by and large. KS F2437 and travel time method have been used to figure out 1st natural frequency and dynamic elastic moduli. Damping ratios have been computed by adopting the polynomial curvefitting method and the geometric analysis method on the frequency response spectrum curve. of which results have been compared and analyzed hereon.

A Study of the Characteristics of Painting Materials Used in Welcome Feast for the Pyeongan Governor: Focusing on Banquet at Yeongwangjeong Pavilion (평안감사향연도(平安監司饗宴圖)의 채색 재료 특성 연구 -연광정연회도(練光亭宴會圖)를 중심으로-)

  • Park, Jin Ho;Chang, Yeon Hee;Ko, Soo Rin
    • Conservation Science in Museum
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    • v.28
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    • pp.109-136
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    • 2022
  • This study analyzes the , one of the three panels of 《Welcoming Banquets for the Governor of Pyeong-an》, a documentary painting of the late Joseon Dynasty, with the aim to identify the coloring materials used in the painting. The painting was first imaged at each wavelength in order to minimize the potential problems in the process of analyzing specific parts. This study applied X-rays to identify ink, gold, and organic and inorganic pigments and used infrared rays to find ink and copper-based pigments. It also applied hyperspectral imaging to distinguish organic pigments from black, blue, and green materials. It also analyzed spots selected for each color to identify the following materials: white lead (white), ink/indigo (black), a combination of red lead and cinnabar (red), pink dye, purple dye, iron oxides (brown), orpiment/dye (yellow), malachite/malachite and yellow dye/indigo (green), azurite/white lead and indigo/indigo (blue), indigo and cochineal (violet), and gold leaf (gold). It is expected that more efficient analysis will be made possible by securing a sufficient library for each wavelength.

Model Tests on a Plastic Pipe Pile for the Analysis of Noise, Energy Transfer Effect and Bearing Capacity due to Hammer Cushion Materials (해머 쿠션 재질에 따른 모형말뚝의 소음, 에너지 전달효율 및 지지력 분석)

  • Lim, Yu-Jin;Hwang, Kwang-Ho;Park, Young-Ho;Lee, Jin-Gul
    • Journal of the Korean Geotechnical Society
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    • v.22 no.12
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    • pp.33-43
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    • 2006
  • Driving tests using model plastic piles with different hammer cushion materials were performed in order to evaluate the efficiency of energy transfer ratio from the hammer, degree of vibration of the surrounding ground and noise due to impacting. A small pile driving analyzer (PDA) was composed using straingages and Hopkinson bar which is measuring force signal and pile-head velocity. The hammer cushion (cap block) materials used for the model driving tests were commercial Micarta, plywood, polyurethane, rubber (SBR) and silicone rubber. The highest energy transfer ratio was obtained from Micarta in the same soil and driving conditions. Micarta was followed by polyurethane, plywood, rubber and silicone in descending order. The more efficient energy transfdr ratio of the hammer cushion materials became, the bigger average noisy (sound) level was found. In addition, Micarta and polyurethane provided bigger bearing capacities than other materials compared in the same soil and driving conditions in which the static loading tests were performed at the end of driving.

Rheology Control of Cement Paste for Applying ECC Produced with Slag Particles to Self-Consolidating and Shotcreting Process (고로슬래그 미분말이 혼입된 자기충전 및 숏크리트용 ECC의 개발을 위한 시멘트풀 레올로지 제어)

  • Park, Seung-Bum;Kim, Jeong-Su;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.20 no.1
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    • pp.67-75
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    • 2008
  • An engineered cementitious composite produced with slag particles (Slag-ECC) had been developed based on micromechanical principle. Base grain ingredients were properly selected, and then the mixture proportion was optimized to be capable of achieving robust tensile ductility in the hardened state. The rheological design is performed in the present study by optimizing the amount of admixtures suitable for self-consolidating casting and shotcreting process in the fresh state. A special focus is placed on the rheological control which is directly applicable to the construction in field, using prepackaged product with all pulverized ingredients. To control the rheological properties of the composite, which possesses different fluid properties to facilitate two types of processing (i.e., self-consolidating and shotcreting processing), the viscosity change of the cement paste suspensions over time was initially investigated, and then the proper dosage of the admixtures in the cement paste was selected. The two types of mixture proportion were then optimized by self-consolidating & shotcreting tests. A series of self-consolidating and shotcreting tests demonstrated excellent self-consolidation property and sprayability of the Slag-ECC. The rheological properties altered through this approach were revealed to be effective in obtaining Slag-ECC hardened properties, represented by pseudo strain-hardening behavior in uniaxial tension, allowing the readily achievement of the desired function of the fresh Slag-ECC. These ductile composites with self-consolidating and shotcreting processing can be broadly utilized for a variety of applications, e.g., in strengthening seismic resistant structures with congested reinforcements, or in repairing deteriorated infrastructures by shotcreting process.

Bleeding characteristics of coupling materials for installation of acoustic emission (AE) sensor (AE 센서 설치를 위한 커플링 재료의 블리딩 특성)

  • Lee, Jong-Won;Kim, Hyunwoo;Kim, Min-Koan;Oh, Tae-Min
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.4
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    • pp.635-650
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    • 2017
  • Acoustic emission (AE) sensors have broadly used to monitor the damage of underground structures and tunnels. The reliability of measured signal is determined by the coupling condition of the AE sensors which are embedded in the target underground structure. To secure the reliability of health monitoring results, it is important to understand the characteristics of the coupling materials. In this study, laboratory tests were performed using portland cement, micro cement, and gypsum as coupling materials in order to verify the bleeding characteristics. The effective parameters for bleeding were determined to be water-cement ratio, material type, curing time, and injected volume of coupling materials. As a results of the experimental study, the bleeding rate increases with an increase in a water-cement ratio and an injected volume; for portland cement, water-cement ratio and injected volume effects are larger than the micro cement. However, curing time is not much effective for occurrence of the bleeding phenomenon. It is anticipated that this study may be useful for the selection of suitable coupling materials for installation of acoustic emission sensors.

A Study on the Performance Evaluation of Water(wash out) Resistance of 5-Type Repair Materials in Water Leakage of Underground Concrete Structures (지하 콘크리트 구조물 누수부위에 시공되는 5계열 보수재료의 유실 저항 성능 평가 연구)

  • Kim, Soo-Yeon;Yoo, Jae-Yong;Oh, Sang-Keun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.61-68
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    • 2020
  • In this study, the international standard ISO TS 16774 Part 3 Test Method for Water (wash out) Resistance and KS F 4935 「Sealant Injection type for water leakage maintenance of adhesive flexible rubber asphalt series」, which are standardized as a quality control method of injection type repair materials used for water leakage cracks in underground concrete structures, are currently used in Korea. As a result, considering the performance criteria of "mass change rate -0.1%" stipulated in KS F 4935, the remaining 13 types repair materials, excluding RG-2 of synthetic rubber and UG-1 of urethane, need to be reviewed for stabilization of the loss resistance due to the flow of ground water. The results of this study are determined to be available as a basic indicator for the selection of repair materials used for cracks in concrete structures. In addition, it is expected that the results of this study can be utilized as reference data that can be reflected in the improvement of the quality of repair materials that will be researched and developed later.

Drivability and Bearing Capacity of PHC Pile Foundation (PHC 말뚝의 항타시공성 및 지지력에 관한 연구)

  • Lee, Myung Whan;Lee, In Mo;Kim, Sang Gyun
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.5
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    • pp.223-234
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    • 1993
  • The main characteristics of PHC piles is that silica material and autoclave curing technique are used when manufacturing to have higher strength than PC piles. In this paper, pile drivability and bearing capacity characteristics of the PHC piles are studied through numerical analysis based on wave propagation theory, driving records and pile load tests in situ. It is found that we can have higher bearing capacity by using the PHC piles rather than the PC on condition that the most effective driving equipment is chosen when driving the pile. In other words, since the PHC piles have higher resistance to driving energy, the heavier ram can be used in the driving process, which results in the higher bearing capacity.

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Application of HEC-RAS and K-River for River Bed Change Prediction (하상변동예측을 위한 HEC-RAS와 K-River의 적용)

  • Byun, Jisun;Noh, Junwoo;Hur, Youngtek;Kim, Yeonsu;An, Hyunuk
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.240-240
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    • 2022
  • 하천을 안전하고 효율적으로 관리하기 위해서는 하상재료, 하천형태, 하천유황 등 자연적 또는 인위적 변화에 의한 하상변동의 해석과 예측이 수행되어야 한다. 하상변동은 하천의 일정구간을 기준으로 상류단면으로부터 유입되는 유입 유사량과 하류단면을 통해 유출되는 유사량의 차이에 의해 구간 내에서 발생하는 하상의 상승 또는 저하가 발생하는 현상을 말한다. 이러한 하상변동은 하천의 이수와 치수, 환경변화에 복합적으로 영향을 미치게 된다. 이에 본 연구에서는 댐 직하류를 대상으로 K-River 모형과 HEC-RAS 모형을 이용하여 하상변동을 계산하고, 각 모형으로부터 얻어진 모의 결과를 비교 분석하였다. K-River 모형의 하상변동 모의를 위한 경계조건을 구성하기 위해 하상토의 입도분포를 입력하고, 유역의 월별 평균 강수량과 댐 유입량을 이용하여 비유량법을 이용하였으며, 산출된 유입량을 바탕으로 댐방류량을 결정하였다. 유사량 공식의 선정은 하천 및 하상토의 특성에 맞추어 적절히 활용하여야 하나, 본 연구에서는 테스트를 목적으로 Engelund-Hansen 공식, Yang 공식, Laursen 공식 등 5가지의 유사량 공식을 선정하였다. HEC-RAS 모형의 경우 최근 유사 부정류모의 기능이 개발되었으나, 테스트 결과 안정적으로 모의가 수행되지 않아 준정류 조건을 적용하여 수행하였다. HEC-RAS와 K-River의 모의 결과를 비교한 바에 따르면 정량적인 차이가 나타나지만, 하상고의 상승 및 하강 경향은 대체로 일치하는 것으로 확인되었다.

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Development of Haetsun Bibimbab and Its Nutritional Estimation (햇순나물비빔밥 개발 및 영양성 평가)

  • Kim, Min-Ha;Jang, Hye-Lim;Kim, Nam-Jo;Jang, Se-Young;Jeong, Yong-Jin;Yoon, Kyung-Young
    • Food Science and Preservation
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    • v.18 no.2
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    • pp.191-198
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    • 2011
  • This study was performed for development of Haetsun Bibimbam as local food and estimated nutritional value of Haetsun Bibimbam. Preference on Bibimbab materials of 503 subjects was surveyed to select ingredients of Haetsun Bibimbab except for Haetsun vegetables. As results of survey, soybean sprout, carrot, shiitake mushroom, and green pumpkin were selected as ingredients of Haetsun Bibimbab. Overall preference of Haetsun Bibimbab made by the ratio of 1:1 of selected ingredients : Haetsun vegetables and 1:1:1 of Acanthopanacis cortex : Kalopanax pictus : Aralia elata was the highest among the samples. As a results of nutritional estimation, total amount and calorie of Haetsun Bibimbab were 404 g and 463.7 kcal, respectively. It contained 16.48 g of protein. 13.99 g of fat, 75.93 g of carbohydrate and 3.1 g crude fiber. The mineral contents of Haetsun Bibimbab shows 91.11 mg of calcium, 133.91 mg of phosphorous, 2.66 mg of iron, 1.314.66 mg of sodium and 444.791 mg of potassium.