• Title/Summary/Keyword: 장기 안정성

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Preparation and characterization of the primary gas standards for isoprene (아이소프렌 일차표준가스의 제조 및 특성 평가)

  • Kim, Taesu;Kang, Chul-Ho;Kim, Yong Doo;Lee, Seungho;Kim, Dalho
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.357-363
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    • 2014
  • Isoprene is a one of the biogenic volatile organic compounds (BVOCs) and it is known as a source of the tropospheric ozone and formaldehyde. In addition, isoprene is a trace component of the exhaled breath and it is a potential biomarker for the diagnosis of diseases such as lung cancer. In these regards, isoprene gas standards are required for the accurate measurement of isoprene in air samples. To establish a standard for isoprene gas, gravimetric preparation and characterization of primary gas standards were studied. The primary gas standards were produced independently in 4 aluminum cylinders and concentrations were examined by GC-FID. As a result, the uncertainty of the gravimetric preparations including purity of the raw material was 0.01% and reproducibility of the preparation of independent 4 cylinders was 0.08%. The primary gas standards for isoprene showed 14 months of long-term stability. The relative expended uncertainty of 2.8% (95% of confidence level, k=1.96) was assigned to the certified value of 10 ${\mu}mol$/mol level of isoprene based on the quantitative evaluation of the purity, weighing, reproducibility, adsorption and long-term stability.

Preparation of Humidity Sensor Using Novel Photocurable Sulfonated Polyimide Polyelectrolyte and their Properties (광가교성 Sulfonated Polyimide 전해질 고분자를 이용한 습도센서의 제조 및 특성 분석)

  • Lim, Dong-In;Gong, Myoung-Seon
    • Polymer(Korea)
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    • v.36 no.4
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    • pp.486-493
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    • 2012
  • Photocurable sulfonated polyimide (SPI) polyelectrolyte containing chalcone group was prepared and fabricated on an alumina electrode pretreated with chalcone-containing silane-coupling agent. SPI films with bis(tetramethyl)ammonium 2,2'-benzidinedisulfonate ($Me_4N$-BDS)/4,4'-diaminochalcone (DAC)/pyromellitic dianhydride (PA)= 90/10/100 possessed very linear response(Y = -0.04528X+7.69446, $R^2=0.99675$) and showed resistance changing from 4.48 to $2.1k{\Omega}$ between 20 and 95 %RH. The response time for absorption and desorption measurements between 33 and 94 %RH% was about 79 s, which affirmed the high efficiency of crosslinked SPI film for rapid detection of humidity. A negative temperature coefficient showing $-0.49%RH/^{\circ}C$ was found and proper temperature compensation should be considered in future applications. Moreover, pretreatment of the substrates with chalcone-containing silane-coupling agent was performed to improve the water durability and the stability of the humidity sensors at a high humidity and a high temperature and long-term stability for 480 h. The crosslinked SPI films anchored to electrode substrate could be a promising material for the fabrication of efficient humidity sensors with superior characteristics compared to the commercially available sensors.

The Impact of Capital Structure for Ship Investments on Corporate Stability (선박투자자금의 조달구조가 기업의 안정성에 미치는 영향)

  • Cho, Seong-Soon;Yun, Heesung
    • Journal of Navigation and Port Research
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    • v.45 no.6
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    • pp.276-283
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    • 2021
  • The capital structure of the shipping business, which is characterized by its capital intensity and extreme market volatility, is closely related to long-term stability. Research in this area has been conducted mostly in the form of deriving the determinants of capital structure from company-wise financial ratios. This research, on the other hand, has a different approach to the topic. It identifies the relationship between actual cash profit and loss and other variables - i.e. actual vessel prices, interest rates and leverage ratio - by employing historical simulation. The result demonstrates that the P anamax cash profit shows 0 (break-even point) when the debt weight reaches 64.38% (debt ratio 180.74%) and the Cape, 73.04% (debt ratio 270.92%). Additionally, the ships of different types show a divided pattern for the pre- and post-'Super Boom'. It indicates that the business area and the market cycle should be considered when a leverage strategy is established. This research benefits shipping companies set a rational leverage strategy as well as delivers a reasonable guideline to government authorities for the development of a sound policy on shipping finance.

Geosynthetic Reinforced Segmental Retaining Wall Failure Buying Heavy Rainfall - A Case Study (집중강우시 발생한 블록식 보강토 옹벽의 붕괴사례)

  • Yoo Chung-Sik;Jeon Han-Yong;Jung Hye-Young;Jung Hyuk-Sang
    • Journal of the Korean Geotechnical Society
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    • v.21 no.4
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    • pp.135-143
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    • 2005
  • This paper presents a case history of a geosynthetics-reinforced segmental retaining wall, which collapsed during a severe rainfall immediately after the completion of the wall construction. In an attempt to identify possible causes for the collapse, a comprehensive investigation was carried out including physical and strength tests on the backfill, stability analyses on the as-built design based on the current design approaches, and slope stability analyses with pore pressure consideration. The investigation revealed that the inappropriate as-built design and the bad-quality backfill were mainly responsible for the collapse. This paper describes the site condition including wall design, details of the results of investigation and finally, lessons learned. Practical significance of the findings from this study is also discussed.

Identification of Irradiated Chicken Eggs by ESR Spectroscopy (ESR spectroscopy를 이용한 방사선 조사 계란의 확인)

  • 남혜선;이선영;양재승
    • Journal of Food Hygiene and Safety
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    • v.15 no.3
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    • pp.248-251
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    • 2000
  • Electron spin resonance (ESR) spectroscopy was used to detect irradiated chicken eggs, to investigate the effect of irradiation dose on the ESR signal intensity and to identify the stability of radicals under 77 days of storage. Raw chicken eggs were irradiated with doses of 0, 0.5, 1, 2, 3 and 5 kGy at room temperature using a Co-60 irradiator. The samples were prepared by separating, drying and powdering shells from the raw eggs. The irradiated chicken egg shells presented an asymmetric absorption in shape at g$_1$=2.0023$\pm$0.00004 and g$_2$=1.9979$\pm$0.00005, different from the non-irradiated ones. The strength of the ESR signal increased linearly with the applied doses (to S kGy). The intensity of the ESR signals after irradiation were stable even after 77-day of storage at 5$^{\circ}C$ and/or room temperature.

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Malocclusion with Congenital Missing of Lower Incisors (하악 전치의 선천적 결손을 동반한 부정 교합의 치험례)

  • Kim, Kyung-Ho;Choy, Kwang-Chul;Chung, Kil-Yong;Yun, Hee-Sun
    • The korean journal of orthodontics
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    • v.28 no.6 s.71
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    • pp.981-989
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    • 1998
  • Positions, angulation and mesiodistal dimension of lower incisors are important in esthetics, occlusion and post-treatment stability of tower arch. When lower incisor is congenitally missing, problems such as increased overjet and overbite, closing in of adjacent teeth and size/space discrepancies may occur. When creating treatment plans, incisor position and angulation, lip support, anteroposterior skeletal relationship canine-molar relationship, overjet overbite, remaining growth potential, crowding and anterior tooth ratio have to be considered. For an accurate analysis of incisal size discrepancy, diagnostic model set-up may be helpful. The two patients in this presentation both had two lower incisor missing, but the degree of crowding, skeletal relationship, lip support, molar relationship are different and therefore treatment plan was different as well. Long term follow-up may be necessary for stability and retention.

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Examination of the Restructuring of Korean Economy: Simulation of the Multisector Model (한국경제(韓國經濟)의 구조변화(構造變化) 전망(展望): 다부문모형(多部門模型)의 모의실험(模擬實驗))

  • Kim, Jung-ho;Park, Jun-kyung
    • KDI Journal of Economic Policy
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    • v.14 no.2
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    • pp.155-187
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    • 1992
  • The Korean economy has sustained high growth rate for almost three decades, that have been associated with the rapid expansion of manufacturing industries. In the beginning stage of development, the high growth of the Korean economy has been based on improvements in productivity obtained by the economies of scale. In that period, the improvements in productivity could be secured by the economies of scale in the export-oriented industries which are the labor- and material-intensive industries. In the latter half of the 1980s, the Korean economy went through rapid transition. Now Korea is at another juncture in its development process, where economic restructuring is critical to sustain high growth. However, economic restructuring in the 1990s call for much more concerted effort than before, since changes in internal and external conditions have profoundly altered the environment for economic development. If Korea is to sustain high growth in the 1990s, it has to promote balanced economic and social development in coordination with the smooth facilitation of industrial restructuring. There are no inherent conflicts among the issues involved, so they can be resolved by restructuring the economy to facilitate, in a global context, the development of knowledge- and technology-intensive activities and to ensure that the benefts of growth are reflected of qualitative improvements in national living standards. In this paper, we examined a scenario of structural changes using a mid- and long-term multisector model, in order to understand the conditions needed for realizing the growth potential. This examination explains the important features of the development course and policy directions that will help sustain high growth in the 1990s.

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Projection of Long-Term care Insurance Beneficiary and Financing (노인장기요양보험 대상자 확대에 따른 재정추계 분석)

  • Choi, In-duck;Lee, Ho-yong
    • 한국노년학
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    • v.31 no.4
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    • pp.1047-1065
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    • 2011
  • The main purpose of this study is to provide the sustainability and continuous development of Long-term care Insurance in projecting changes of the Long-term care Insurance beneficiary population and Cost. We conducted a transformed cohort-component projection method that are employed for the beneficiary population projection and applied the previous experiences in Japan and German. A transformed cohort-component method means that we also projected the increasing beneficiary of long-term care insurance for using the data of geriatric disease in NHIC and estimated the cost of insurance's financial resources. First of all, beneficiary increase and strategy of extending to level 4 are categorized 2 and the expense account projection are categorized 2. If it is thought experience of Japan and German, The Level 4 extend of insuree is projected 2012 or 2013. With the results of this study, we proposed that extended level 4 insuree include the 40%~90% of geriatric disease in elderly people. The number of beneficiaries in 2011 is expected to reach to about 342,896 and in 2015 is 415,905 on scenario 1. Scenario 2(40%of geriatric disease in elderly people), the number of beneficiaries in 2011 is 342,896 and in 2015 is 483,453. Scenario 3(90%of geriatric disease in elderly people), the number of beneficiaries in 2012 is 545,068 and in 2015 is 565,565. The cost of beneficiaries insurance benefit of scenario 1 are projected from 3,000billion in 2012 to 3,500billion won in 2015. Scenario 2 are projected from 3,100billion in 2012 to 4,000billion won 2015. Finally, The cost of Level 4 extending are need minimum 300billion to maximum 1,400billion won.

Long-Term Performance Evaluation on the Recycled Asphalt Concrete Using the Steel Slag and Reclaimed Asphalt Pavement Aggregates (제강 슬래그 및 순환골재를 사용한 순환 아스팔트 혼합물의 장기 공용성 평가)

  • Park, Kyung-Won;Jang, Dong-Bok;Lee, Jong-Min;Kang, Byung-Hwa;Kim, Hyung-Bae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.633-641
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    • 2021
  • The study performed long-term performacne evaluation on the hot mix asphalt using the steel slag aggregates and Reclaimed Asphalt Pavement (RAP). The laboratory comparative evaluation was conducted between conventional Hot Mix Asphalt (HMA) which is entitled WC-2 and HMA containing steel slag and RAP which is entitled ES WC-2(R). Dynamic stability test, dynamic modulus test, and fatigue crack test were conducted during the comparative evaluation process. The dynamic stability test result showed that ES WC-2(R) was 140% higher than WC-2. It is noted that ES WC-2(R) showed no inflection point whereas WC-2 showed inflection point during the dynamic stability test which implies ES WC-2(R) has the higher moisture susceptability than WC-2. The dynamic modulus of ES WC-2(R) were 342.3%, 486.7%, and 350.0% higher than WC-2 at medium temperature of 21℃, low temperature of -10℃, and high temperature of 38℃ respectively. The test result showed that rutting resistance of ES WC-2(R) is higher than WC-2 at all temperature spectrum. The fatigue resistance of ES WC-2(R) were 31.7%, 325.3%, 899.9% higher at low stress level, medium stress level, and high stress level, respectively. The test result showed that ES WC-2(R) is higher than WC-2 at all stress levels. Based on the laboratory comparative evaluation, The in-situ scale Accelerated Pavement Test (APT) was conducted comparing WC-2 and WC-2(R). APT found that the rutting resistance of WC-2(R) was 45% higher than WC-2.

A Study on the Evaluation of the Durability of Concrete Using Copper Slag Aggregates (동슬래그 골재를 함유한 콘크리트의 내구성 평가 연구)

  • Lee, Mun-Hwan
    • Journal of the Korea Concrete Institute
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    • v.20 no.6
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    • pp.773-784
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    • 2008
  • Even if the exploitation of copper slag produced during the smelting process of copper as aggregate for construction purpose has been permitted since 2004 in Korea, the lack of sufficient data enabling to evaluate its long-term stability that is its durability has to date impeded its application. This study intends to investigate experimentally the durability characteristics of 18 and 27 MPa-class commercial concretes in which natural sand (fine aggregates) has been partially replaced by copper slag through accelerated and exposure tests so as to provide bases promoting the application of copper slag concrete. The experimental results revealed insignificant difference of the durability characteristics in most of the mix proportions in which 30% of natural sand was replaced by copper slag. In the case where crushed sand was adopted, tests verified similar characteristics for replacement ratio of 50%. Particularly, the results of the exposure test conducted during 8 years demonstrated that equivalent level of durability was secured compared to the case using natural sand. In the case of 18MPa-class lower grade concrete, exposure test verified also that the physical lifetime similar to 50 years could be secured until carbonation reaches cover depth of 20 mm.