• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.15 no.8
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• pp.652-660
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• 2003

T-history method, measuring heat-of-fusion of phase change material (PCM) in sealed tubes, has the advantages of a simple experimental device and no requirements in sampling process. However, a degree of supercooling used in selecting the range of latent heat release and neglecting sensible heat during the phase change process can cause significant errors in determining the heat of fusion in the original method, which has been improved in order to predict better results by us. In the present study, the modified method was applied to a variety of PCM such as paraffin and lauric acid having very small or no supercooling with a satisfactory precision. Also the selection of inflection point and temperature measurement position was fumed out not to affect the accuracy of heat-of-fusion significantly. As a result, the method can provide an appropriate means to assess a new developed PCM by cycle test even if a very accurate value cannot be obtained.

• Solar Energy
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• v.15 no.3
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• pp.15-27
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• 1995

This study presents experimental and numerical results of the temperature characteristics, the heat transfer phenomema, and the heat storage quantity during the heat storage process with sodium phyrophosphate decahydrate($Na_4P_2O_7{\cdot}10H_2O$)-Phase Change Material(PCM) in a latent heat storage tank(cubic type). It was proved that heat transfer by conduction was dominant because PCM($Na_4P_2O_7{\cdot}10H_2O$) during heating processes was gel phase, not liquid phase The gap ratio(rate of air content) of PCM became smaller, the thermal capacity of PCM became larger, therefore the temperature distribution of PCM slowly increased than that of large gap ratio. There was maximum 15% difference between measured temperatures and calculated temperatures.

• Journal of the Korean Applied Science and Technology
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• v.32 no.2
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• pp.215-225
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• 2015

Recently, the importance of energy saving and alternative energy is significantly increasing due to energy depletion and the phase change material (PCM) research for saving energy is also actively investigating. In this research, the membrane emulsification using SPG membrane was used to make various microencapsulated phase change material (MPCM) particles which were comprised of $Rubitherms^{(R)}$ (RT-21 and RT-24) core and silica coating. We investigated the pressure of the dispersion phase, the concentration of surfactant, and the ratio of $Rubitherm^{(R)}$ and silica to prepare various MPCM particles. The DSC and TGA were used to examine the heat stability and latent heat properties. Also, PSA, SEM, and optical microscopy were used to confirm the size of $Rubitherm^{(R)}$ particles and the thickness of silica shell. The average of particle size was $7-8{\mu}m$. And, FT-IR was also used to enforce the qualitative analysis. Finally, the MPCM particles obtained from membrane emulsification showed monodispersed size distribution and the heat stability and latent heat were kept up to 80% compared to pure $Rubitherm^{(R)}$. So, it can be effectively used for wallpaper, buildings and interior products for energy saving as PCMs.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.522-526
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• 2010

Heat storage application techniques can be categorized into the sensible heat storage and the latent heat storage according to the method of heat storage. Heat storage is the way of saving remaining heat when heating and cooling loads are light, and then using it when the heating and cooling loads are heavy. Latent heat storage is defined as the method of saving heat by using substances which have high potential heat when phase change is in the range of a certain temperature and when heat storage space is small, compared to those of sensible heat storage and it is possible that absorption and emission of heat at a certain temperature. This study is conducted to save energy when either air-conditioning or heating is operated in a building. We have tried to find out the essential properties of matter and the optimum mixing rate about cement and gypsum for building materials, which have been widely used for proper phase change materials (PCM), when thermal environment property is applied. So we obtained the result of the cooling delay effect about 19% with heat storage mortar containing 3 wt% of PCM.

• Solar Energy
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• v.13 no.2_3
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• pp.65-78
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• 1993

An overdose of fossil fuel for greenhouse heating causes not only the high cost and low quality of agricultural products, but also the environmental pollution of farm village. To solve these problems it is desirable to maximize the solar energy utilization for the heating of greenhouse in winter season. In this study phase change materials were selected to store solar energy concentratively for heating the greenhouse and their characteristics of thermal energy storage were analyzed. The results were summarized as follows. The organic $C_{28}H_{58}$, and the inorganic $CH_3COONa{\cdot}3H_2O\;and\;Na_2SO_4{\cdot}10H_2O$ were selected as low temperature latent heat storage materials. The equation of critical radius was derived to define the generating mechanism of the maximum latent heat of phase change materials. The melting point of $C_{28}H_{58}$ was $62^{\circ}C$, and the latent heat was $50.0{\sim}52.0kcal/kg$. The specific heat of liquid and solid phase was $0.54{\sim}0.69kcal/kg^{\circ}C$ and $0.57{\sim}0.75kcal/kg^{\circ}C$ respectively. The melting point of $CH_3COONa{\cdot}3H_2O$ was $61{\sim}62^{\circ}C$, the latent heat was $64.9{\sim}65.8$ kcal/kg and the specific heat of liquid and solid phase was respectively $0.83kcal/kg^{\circ}C$ and $0.51{\sim}0.52kcal/kg^{\circ}C$. The melting point of $Na_2SO_4{\cdot}10H_2O$ was $30{\sim}30.9^{\circ}C$, the latent heat was 53.0 kcal/kg and the specific heat of liquid and solid phase was respectively $0.78{\sim}0.89kcal/kg^{\circ}C$ and $0.50{\sim}0.7kcal/kg^{\circ}C$ When the urea of 21.85% was added to control the melting point of $Na_2SO_4{\cdot}10H_2O$ and the phase change cycles were repeated from 0 to 600, the melting point was $16.7{\sim}16.0^{\circ}C$ and the latent heat was $36.0{\sim}28.0kcal/kg^{\circ}C$.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.44 no.4
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• pp.373-379
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• 2016

The thermal control device for the periodic working component combined solid-liquid phase change material (PCM) with heat pipes is designed and numerically studied. Due to high latent heat and retaining constant temperature during melting process the component peak temperature, not withstanding small radiator size, is reduced. The warm-up heater power consumption to keep the minimum allowed temperature is also cut down since the accumulated thermal energy is released through the solidification. The thermal buffer mass (TBM) made of Al can give the similar effect but the mass and power consumption of warm-up heater should increase compared to PCM. The amount of PCM can be optimized depending on the component heat dissipation and on/off duty time.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.11a
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• pp.622-627
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• 2010

This paper is focused on the numerical analysis of two Thermal Protection Systems. Both systems have been provided two different temperature of heating at two walls. Outer wall is heated by high temperature($T_{max}$). Inner wall is heated by heat source($710W/m^2$) while the outer wall is heated. Each system has been provided one side heating(outer wall only) and both side heating respectively. The effects of the heat transfer of both sides of wall, PCM temperature variance through the operation time and Inner space average temperature are investigated. The results have shown that the duration of latent heat mainly depends on the materials, the direction of heat transfer and the heat source and these factors should be concerned in the future.

• Journal of Bio-Environment Control
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• v.6 no.3
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• pp.216-224
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• 1997

In the recent 10 years the protected cultivation area in Korea has been increased rapidly, and now it is very important issue to develop the heating and cooling system using the renewable energy, because the greenhouse heating and cooling cost is increased with the fossil fuel price rises. Actually the development of the cooling system is more difficult than that of the heating system, since the cooling load of greenhouse in the summer season is 2―3 times larger than the heating load in the winter season. In this study low temperature phase change materials (LTPCM) for the cold storage system were selected and developed. The theoretical and experimental analysis of thermal characteristics of LTPCM makes it possible to control the phase change temperature and stabilize the thermo-physical properties. LTPCM developed in this study has good advantages to be used as the cold storage not only for the house and working space in factory but also for the cold storage of agricultural and live-stock products.

• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.59-59
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• 2018

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.173-175
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• 2000

도시기상의 원인으로는 지표면 상태의 변화, 인공구조물과 인공열 방출을 들 수 있으며 그 외 오염물질 또한 하나의 원인이다. 도시의 낮은 함수률의 지표면 증가는 증발산 영역을 감소시켜 결과적으로 잠열방출을 감소시키고 현열을 증가시킨다(Tapper, et. al., 1981). 또한 도시의 배수시설은 유입된 강수의 흐름을 시골보다 짧은 기간 머무르게 하여 도시에서 낮은 절대 습도를 가지게 한다. (중략)