• Korean Journal of Environmental Agriculture
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• v.41 no.2
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• pp.82-94
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• 2022

BACKGROUND: Spiropidion and its metabolite are tetramic acid insecticide and require the establishment of an official analysis method for the safety management because they are newly registered in Korea. Therefore, this study was to determine the analysis method of residual spiropidion and its metabolite for the five representative agricultural products. METHODS AND RESULTS: Three QuEChERS methods (original, AOAC, and EN method) were applied to optimize the extraction method, and the EN method was finally selected by comparing the recovery test and matrix effect results. Various adsorbent agents were applied to establish the clean up method. As a result, the recovery of spiropidion was reduced when using the dispersive-SPE method with MgSO₄, primary secondary amine (PSA), graphitized carbon black (GCB) and octadecyl (C₁₈) in soybean. Color interference was minimized by selecting the case including GCB and C18 in addition to MgSO₄. This method was established as the final analysis method. LC-MS/MS was used for the analysis by considering the selectivity and sensitivity of the target pesticide and the analysis was performed in MRM mode. The results of the recovery test using the established analysis method and inter laboratory validation showed a valid range of 79.4-108.4%, with relative standard deviation and coefficient of variation were less than 7.2% and 14.4%, respectively. CONCLUSION(S): Spiropidion and its metabolite could be analyzed with a modified QuEChERS method, and the established method would be widely available to ensure the safety of residual insecticides in Korea.

• Journal of Korean Society of Steel Construction
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• v.17 no.1 s.74
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• pp.13-21
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• 2005

Advanced analysis and optimal design of steel arch bridges is presented. In the design method using an advanced analysis, separate member capacity checks after analysis are not required because the stability and strength of the structural system and its component members can be rigorously treated in the analysis. The geometric nonlinearity is considered by using the stability function. The Column Research Council tangent modulus is used to account for gradual yielding due to residual stresses. A parabolic function is used to represent the transition from elastic to zero stiffness associated with a developing hinge. An optimization technique used is a modified section increment method. The member with the largest unit value evaluated by AASHTO-LRFD interaction equation is replaced one by one with an adjacent larger member selected in the database. The objective function is taken as the weight of the steel arch bridge and the constraint functions account for load-carrying capacities and deflection requirements. Member sizes determined by the proposed method are compared with those given by other approaches.

• Korean Journal of Food Science and Technology
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• v.38 no.2
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• pp.176-182
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• 2006

Sensitive and specific monoclonal antibody (MAb) was produced from hybridoma (1H11-5) obtained by fusion of myeloma cell (V653) and spleen cell isolated from mouse immunized sulfamthazine (SMZ)-HG-KLH. Direct competitive ELISA was developed for rapid detection of SMZ in milk samples using MAb against SMZ with optimized conditions between MAb and SMZ-HG-HRP conjugate, and applicable conditions for analysis of milk samples were established. Detection range of immunoassay was 0.1 to 100 ppb. Recoveries from spiked raw milk and processed milk samples averaged 82.1-120.7 and 82.1-97.1%, respectively.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.1
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• pp.42-47
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• 2006

The biological nutrient treatment is formed with repetition and rearrangement of anaerobic, anoxic and oxic tank. In this case, VFAs is generated in the anaerobic tank and the anoxic tank. The VFAs is an important factor for removal of nitrogen and phosphate and SVI. So, in this study I investigated to find a relationship among the generation rate of the VFAs according to the change of F/M ratio and the characteristic which can eliminate organic matter and nitrogen according to the change of residual concentration of the VFAs and the efficiency of the process and also SVI in wastewater treatment. $A^2/O$ process was used for wastewater treatment. F/M ratio was under the control of the change of MLSS concentration. When the F/M ratio was changed from 0.16 to 0.08 kg-BOD/kg-MLSS/day, the VFAs's production volume increased based on the reduction of F/M ratio in batch reaction. And the residual concentration of the VFAs decreased at first and then increased later. SVI and SS were high when F/M ratio was $0.16kg/kg{\cdot}d$ and showed stable status when F/M ratio decreased $0.11{\sim}0.13kg/kg{\cdot}d$. However, SVI and SS continuously increased with decrease of F/M ratio and were high at $0.08kg/kg{\cdot}d$. In the result of comparison between residual concentration of the VFAs and denitrification rate in anoxic tank, the less residual volume of the VFAs was in anoxic tank, the higher denitrification ratio became. The optimal residual-concentration of the VFAs considering SVI and removal efficiency of nitrogenwas $1.4{\sim}2.2mg/L$. At that time F/M ratio was $0.11{\sim}0.13$ kg-BOD/kg-MLSS/day.

• Aerospace Engineering and Technology
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• v.13 no.1
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• pp.20-26
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• 2014

In this paper, yield stress, tangent modulus and failure strain were varied to ascertain the influence of impact response such as impact force histories and residual energy. And the buckling behavior of FML(Fiber Metal Laminates) were analyzed using numerical method. A number of analyses on FML and aluminum panel were conducted for shear and compression loading to compare the capability of stability. And to evaluate the static performance, static analysis has performed for box beam structure. Low-velocity impact analysis has performed on FML made of aluminum 2024 sheet and glass/epoxy prepreg layers. And the buckling and static performance of FML have been compared to aluminum using the analysis results. For the comparison of structural performance, similar analyses have been carried out on monolithic aluminum 2024 sheets of equivalent weight.

• Journal of the Korean Geosynthetics Society
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• v.5 no.1
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• pp.1-7
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• 2006

Despite a number of advantages of reinforced earth walls over conventional concrete retaining walls, there exit concerns over long-term residual deformation when used as part of permanent structures. In view of these concerns, time-dependant deformation characteristics of geosynthetic reinforced modular block walls under sustained loads were investigated using reduced-scale model tests. The results indicated that a sustained load can yield appreciable magnitude of residual deformation, and that the magnitude of residual deformation depends on the loading characteristic as well as reinforcement stiffness.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 1991.04a
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• pp.169-173
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• 1991

최근 자동화기술의 발달에 따라 산업용 로보트팔의 경량화, 고속화를 실행하 게 되는 경우와 우주, 원자력발전소 등과 같은 특수한 환경하에서 매니퓰레 이터(manipulator)를 제어하게 되는 경우가 많아지고 있는데, 이때 팔의 강성 이 충분하지 않으면 위치결정시 목표점에서의 과도진동이 발생하게 되어 위 치결정정도와 작업효율이 저하된다. 그러므로 이러한 경량화된 장비들의 진 동특성을 파악하고 운동시 발생하는 진동을 효율적으로 제어할 수 있는 제 어기(controller)를 설계하여 잔류진동을 감쇠시키므로써 위치결정시간을 줄 일 수 있고, 전체 작업행정시간이 단축되므로써 작업ㅎ류을 향상시키는 효과 를 가져오게 된다. 이때 원하고자 하는 제어를 하기 위해서는 제어대상 (plant)의 계규명(system identification)을 정확히 하여야 하는데 해석적으로 계를 규명하기가 까다로운 경우 제어기를 설계하는 것이 사실상 어렵게 되 므로 이러한 경우 실험적인 방법으로 주파수응답함수(frequency response function)를 구해 계의 모형(model)을 구하는 방법이 널리 사용되고 있다. 이 분야에 있어서 기존의 논문들은 팔의 변위를 측정하여 진동을 제어하나 이 러한 방법들은 간헐적으로 움직이는 산업장비(예:로보트의 팔)의 과도응답을 제어하기에는 부적합하다. 따라서 본 연구에서는 이러한 장비들의 과도응답 을 효과적으로 제어할 수 있도록 가속도계를 사용, 가속도를 측정하여 변위 를 제어하고자 한다.

• Journal of Korean Society of Steel Construction
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• v.21 no.5
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• pp.483-492
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• 2009

In this study, nonlinear analysis of steel plane frame was performed using the refined plastic hinge method of advanced analysis techniques. In deterioration of stiffness in plastic zone, influences by flexural bending, residual stress, geometrical non-linearity, and semi-rigid connection are considered. And also, further reduced tangent modulus was used for geometrical non-linearity, top and seat angle were chosen for semi-rigid connection. Furthermore, 3 parameter power model was used for moment-rotation behaviour of beam to column connection. The loading conditions are combined with axial and lateral force and the inverse triangle distribution of lateral and eight type of analytical models were used in analysis. The results of analyses were compared with semi-rigid and rigid connection on behaviour of numerical analysis models. And also, the behaviors of frame with changes of semi-rigidity were analyzed by using the results obtained from MIIDAS-GENw.

• Journal of Industrial Technology
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• v.21 no.A
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• pp.329-336
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• 2001

In this study, a series of fatigue tests are carried out in order to estimate quantitatively the characteristics of fatigue crack growth rate for high strength steels of SM570, POSTEN60, and POSTEN80 steel, that is, the influence on fatigue crack growth rate according to the welding line, the characteristics of fatigue crack growth according to the welding method and the kinds of steel, and the characteristics of fatigue crack growth for base metal, heat affected zone and weld metal. From the test results, in case that the notch if parallel to welding line, it knows that the retardations of fatigue crack growth rate in crack tip at early stage increase remarkably than in case that the notch is perpendicular to welding line due to compressive residual stress. And the characteristics of fatigue crack growth rate according to welding method are that the dispersion of fatigue crack growth rate in case of FCAW method is smaller than that of SAW method. Also, it knows that the fatigue crack growth rate converges in high stress intensity factor range.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.424-429
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• 2001

Residual stresses can be produced during manufacturing processes, eg. welding, machining and plastic working, and also in service. It can be superimposed with externally applied loads, so that unexpected deformations and failures of members will be occurred. Especially, the strength and the life of welded components are affected extensively by the residual stresses distributed around their weldments not only under static loads, but also fatigue loads. These residual stresses are not kept constant, but relaxed or redistributed during service. Under static loads the relaxation takes place when the residual stress superimposed with external stress exceeds locally the yield stress of material used. It is shown that under fatigue loads the residual stress is considerably relieved by the first or few cycle loading, and then gradually relaxed with increasing loading cycles. Although many investigations in this field have been carried out, the phenomenon and mechanism of the stress relaxation by mechanical means are still not clear, and there are few comprehensive models for predicting specific effects on the stress relaxation. In this study, the effects of applied static and fatigue loads on the residual stress relaxation were Investigated, and a model to predict quantitatively the residual stress relaxation was proposed.