• Title/Summary/Keyword: 잔류효과

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Development of Electro-Biosensor for the Residual Pesticides using Organic Carbon and Cobalt Phthalocyanine (Cobalt Phthalocyanine 탄소유기 전극을 이용한 농약 잔류량 측정 센서개발)

  • Yu, Young-Hun;Cho, Hyung-Jun;Park, Won-Pyo;Hyun, Hae-Nam
    • Korean Journal of Environmental Agriculture
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    • v.29 no.1
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    • pp.72-76
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    • 2010
  • We have developed the bio-electrode measuring the variance of the amount of acetylcholine affected by residual pesticide. The working electrode of the biosensor was made by combination of cobalt phthalocyanine and carbon organic compounds. The biosensors were constructed by screen-printing method. The principle of working electrode is similar to thiocholine sensor. We have fabricated the biosensor using standard screen printing method. Generally, the biosensor made by printing method formed thick film biosensor. When the electrodes were made by electrochemical cells, the generation of current by the addition of enzyme substrate was inhibited by standard solutions of organo-phosphate pesticides. The detection limit of sensor is about 0.5 $\mu{g}/L$ for carbofuran. We could improve the responsibility of the sensor by controlling the cobalt phthalocyanine and thiocholine concentration ratio. Also we have tested the EPN and Chlorpyrifos pesticides and found that the biosensor is applicable to fast determination of residual pesticides.

Residues of New Fungicide, Isopyrazam on Cucumber and Oriental Melon (Pyrazolecarboxamide계 살균제 Isopyrazam의 오이 및 참외 중 잔류특성)

  • Han, Ye-Hoon;Lee, Cheol-Yong;Park, Kwee-Doo;Park, Kwang-Wook;Lee, Kyu-Seung
    • The Korean Journal of Pesticide Science
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    • v.17 no.1
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    • pp.13-19
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    • 2013
  • Isopyrazam, a new pyrazolecarboxamide fungicide developed by Syngenta, was highly active against foliar powdery mildew pathogens on cucumber, oriental melon and various vegetables. Following foliar applications on cucumber and oriental melon, crop residues were determined using high performance liquid chromatography. For all studies, limit of quantification was 0.02 mg/kg and minimum detection level was 2.0 ng and recoveries were 83.0-88.0% on cucumber, 92.4-104.5% on oriental melon. Isopyrazam was detected 0.07-0.72 mg/kg on cucumber and < 0.02-0.68 mg/kg on oriental melon, respectively. The TMDI (Theoretical Maximum Dailly Intake) of isopyrazam on cucumber and oriental melon was estimated to less than 1.765% of ADI.

중이온가속기 진공도 요구조건에 대한 고찰

  • In, Sang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.100.1-100.1
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    • 2015
  • 중이온가속기에서 잔류기체 분자와 가속 이온의 충돌이 발생하면 이온빔 전류의 손실을 야기하는 직접적인 효과 외에 잔류 기체분자 중에서 전리된 이온들이 반발력에 의해 용기 벽에 부딪힐 때 표면에 흡착되어 있던 기체분자들을 충격탈리(stimulated desorption)시킨다. 더 심각한 경우는 산란된 고속 이온이 용기 벽과 충돌하면서 핵반응을 일으켜 방사화 시키거나 벽에서 다량의 기체를 방출시키는 것이다. 최악의 경우에는 고속이온의 에너지에 의해 용기벽이나 부품들이 열적인 손상을 입을 수도 있다. 현재 설계 및 연구개발이 진행중인 기초과학원(IBS) RISP (Rare Isotope Science Project)의 RAON 중이온가속기는 입사기에서 실험영역까지 각 부분의 진공도 조건이 일반적으로 10-8~10-9 mbar 대에 있어서 이온빔 전류의 손실이나 전리 이온들에 의한 충격탈리는 무시할 수도 있지만 고속이온의 기체방출 수율이 ~104 정도로 높은 것을 감안할 때 고속이온의 충격탈리에 의한 압력 증가가 감내할 수준인지 검토할 필요가 있다. 압력증가는 추가적인 손실을 유발하고 이것은 다시 압력을 상승시키는 진공 불안정성(vacuum instability)을 야기할 수 있다는 축면에서 조심하는 것이 좋다고 판단된다. 고속 중이온과 잔류기체 분자와의 충돌에서 이온이 손실되는 반응에는 쿨롬(coulomb) 산란과 전하교환(charge exchange)이 있는데 전자는 후자에 비해 일반적으로 1/10000 가까이 낮아서 무시할 수 있고, 전자 포획(electron capture) 또는 전자 손실(electron loss, 이온의 전리에 해당)로 대별되는 전하교환 반응이 이온 손실을 주도하는 것으로 알려져 있다. 이 연구에서는 다양한 전하교환 반응 단면적을 아우르는 비례칙(scaling law)을 사용하여 대표적인 중이온인 U33+ 및 U79+의 손실 및 잔류 기체의 전리율을 계산하고 충격탈리에 의한 표면방출 및 압력상승을 일차적으로 고려하여 진공도 조건의 타당성을 입증하려고 한다.

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Analysis of Thermal Deformation of Carbon-fiber Reinforced Polymer Matrix Composite Considering Viscoelasticity (점탄성을 고려한 탄소 섬유강화 복합재의 열 변형 유한요소 해석)

  • Jung, Sung-Rok;Kim, Wie-Dae;Kim, Jae-Hak
    • Composites Research
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    • v.27 no.4
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    • pp.174-181
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    • 2014
  • This study describes viscoelasticity analysis of carbon-fiber reinforced polymer matrix composite material. One of the most important problem during high temperature molding process is residual stress. Residual stress can cause warpage and cracks which can lead to serious defects of the final product. For the difference in thermal expansion coefficient and change of resin property during curing, it is difficult to predict the final deformed shape of carbon-fiber reinforced polymer matrix composite. The consideration of chemical shrinkage can reduce the prediction errors. For this reason, this study includes the viscoelasticity and chemical shrinkage effects in FE analysis by creating subroutines in ABAQUS. Analysis results are compared with other researches to verify the validity of the subroutine developed, and several stacking sequences are introduced to compare tested results.

Anumerical model study on tide-induced residual currents around Chejudo Island (제주도 주변의 조석 잔차류에 대한 수치 모델 연구)

  • 박용향;김성일
    • 한국해양학회지
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    • v.22 no.1
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    • pp.9-18
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    • 1987
  • A number of hydrographic studies and some recent current measurements around Chejudo Island suggest an existence of a clockwise residual flow in the west and north coasts of the island all the year round. On the eastern side of the island the Tsushinma Current flows northward and northeastward. The contribution of tide-induced residual currents to the observed residual. flow around the island was examined here through numerical solution of the two-dimensional nonlinear shallow-water equations. The calculated tide-induced residual currents show a clockwise circulation around the island. Significant residuals of 2-4cms$\^$-1/are confined over sloping bottom topography around t he island and the far-field residuals are negligibly small. The inclusion of a permanent current into the model was also attempted in order to see the effects of the Tsushima Current system on the residual circulation around the is land. It was found that combined effects of tide-induced residuals and the permanent current field associatedwith the Tsushima Current explain qualitatively not only the observed clock wise residuals in the west and north coasts but also the northward flow on the eastern side of the island.

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A Study of Residual Pesticide Removals on the Surface of Solid Phase Using Photooxidation Process (광산화(Photooxidation)에 의한 고체 상 표면 잔류농약제거에 관한 연구)

  • Lee, Tae-jin;An, Soo-jeung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.9 no.2
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    • pp.87-92
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    • 2001
  • As well as arising the concern about pesticides known as a Carcinogenic or endocrine disorder substrates, magnitude was increased of reducing pesticides in soil or water. In this work, removals of residual pesticides on surface of solid phase were attempted by the photooxidation process with hydrogen peroxide. The optimum conditions for the removals of benomyl (carbamatic pesticide) chlorothalonil (Organochoric pesticide) were 350nm UV wavelegth and 20% (v/v) hydrogen peroxide solution as oxidant. Removals are negligible when UV radiation or the supply of hydrogen peroxide are solely applied on the target compoounds. Removal rates of the pesticides are accelerated by UV radiation with hydrogen addition. After 20 min of the treatment, about $2{\mu}g/cm^2$ of benomyl and $1,88{\mu}g/cm^2$ of chlorothalonil were disappeared on the surface of the solid phase.

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A Study on the Effects of High Temperature Thermal Cycling on Bond Strength at the Interface between BCB and PECVD SiO2 Layers (고온 열순환 공정이 BCB와 PECVD 산화규소막 계면의 본딩 결합력에 미치는 영향에 대한 연구)

  • Kwon, Yongchai;Seok, Jongwon;Lu, Jian-Qiang;Cale, Timothy S.;Gutmann, Ronald J.
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.389-396
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    • 2008
  • The effect of thermal cycling on bond strength and residual stress at the interface between benzocyclobutene (BCB) and plasma enhanced chemical vapor deposited (PECVD) silicon dioxide ($SiO_2$) coated silicon wafers were evaluated by four point bending and wafer curvature techniques. Wafers were bonded using a pre-established baseline process. Thermal cycling was done between room temperature and a maximum peak temperature. In thermal cycling performed with 350 and $400^{\circ}C$ peak temperature, the bond strength increased substantially during the first thermal cycle. The increase in bond strength is attributed to the relaxation in residual stress by the condensation reaction of the PECVD $SiO_2$: this relaxation leads to increases in deformation energy due to residual stress and bond strength.

Inelastic Seismic Response of Asymmetric-Plan Self-Centering Energy Dissipative Braced Frames (비정형 셀프센터링 가새골조의 비탄성 지진응답)

  • Kim, Jin-Koo;Christopoulos, C.;Choi, Hyun-Hoon
    • Journal of the Earthquake Engineering Society of Korea
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    • v.12 no.4
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    • pp.35-44
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    • 2008
  • A self-centering energy-dissipative(SCED) bracing system has recently been developed as a new seismic force resistant bracing system. The advantage of the SCED brace system is that, unlike other comparable advanced bracing systems that dissipate energy such as the buckling restrained brace(BRB) system, it has a self-centering capability that reduces or eliminates residual building deformations after major seismic events. In order to investigate the effects of torsion on the SCED brace and BRB systems, nonlinear time history analyses were used to compare the responses of 3D model structures with three different amounts of frame eccentricity. The results of the analysis showed that the interstory drifts of SCED braced frames are more uniform than those of BRB frames, without regard to irregularity. The residual drift and residual rotation responses tended to decrease as irregularity increased. For medium-rise structures, the drift concentration factors(DCFs) for SCED systems were lower than those for BRB frames. This means that SCED-braced frames deform in a more uniform manner with respect to building height. The effect of the torsional irregularity on the magnitude of the DCFs was small.

Thermal Residual Stresses and Spring back Effects on the Frequency Selective Surface Embedded Composite Laminates (주파수 선택막이 삽입된 복합재 평판의 잔류 열응력과 스프링 백 효과)

  • Park, Kyoung-Mi;Seo, Yun-Seok;Chun, Heoung-Jae;Hong, Ic-Pyo;Park, Yong-Bae;Kim, Yun-Jae
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.6
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    • pp.475-481
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    • 2013
  • The residual stresses occur in the Frequency Selective Surface(FSS) embedded hybrid composite structures after co-curing due to mismatch among the coefficient of thermal expansions and stiffness values between the FSS and composite materials. The spring backs occur due to these residual stresses. Therefore, in this paper, the spring-backs caused by residual stresses in FSS embedded composite structures were studied with considering effect of symmetric and unsymmetric stacking sequence of composite laminates.

A Study on Removal Effect of Residual Pesticide on Adsorbent (흡착제에 의한 잔류농약 제거효과에 관한 연구)

  • An, Jung-hyeok;Kim, Joon-bum;Kwon, Young-du;Jeon, Choong;Park, Kwang-ha
    • Applied Chemistry for Engineering
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    • v.18 no.6
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    • pp.537-544
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    • 2007
  • This study was carried out to investigate adsorption characteristics of residual pesticides on an adsorbent. $Bauxsol^{TM}$ and mackban-stone as adsorbent were used. Analytical method for residual pesticides was established by GC/NPD and $GC/{\mu}ECD$. Pesticides used in this study were ${\alpha}$-endosulfan, ${\beta}$-endosulfan, pendimethalin and chlorpyrifos-methyl, fenitrothion, and recovery rates were more than 97%. Adsorption rate on an adsorbent was decreased in order of endosulfan, chlorpyrifos-methyl, pendimethalin, fenitrothion. Organochlorine pesticides showed higher removal rate than the other pesticides. $Bauxsol^{TM}$ gave both chemical decomposition and physical adsorption. Mackban-stone gave only physical adsorption on the other hand. The high pH and chloric ions structure of eluted solution have greatly affected at chemical resolution. The removal rate of pesticides was increased due to the physical property of adsorbent, i.e. high porosity. The above adsorbent is to be a candidate to remove residual pesticides in water and pond of links.