• Title/Summary/Keyword: 잔류오염

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A study on the functional coatings using silicone resin of Architectural membrane structures products (건축용 막구조 제품의 실리콘 기능성 코팅에 관한 연구)

  • Choi, Yun-Sung;Lee, Jang-Hun;Yoon, Nam-Sik;Kim, Su-Hong;Yoo, Gu-Geun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2012.03a
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    • pp.106-106
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    • 2012
  • 막구조(Membrane structure)란 건축분야에서 "fabric structure" 또는 tension structure"와 같이 사용되는 용어로 코팅된 직물(coated fabrics)을 주재료로 사용하는 구조를 말한다. 특히 구조체로서 연성의 막을 이용 이것에 초기 장력을 주어 강성을 늘림으로서 외부하중에 대하여 안정된 형태를 유지하는 장점을 갖고 있다. 초기 창안된 독일의 온화한 기후에 적용되는 반면 한국이나 일본에는 60m/sec를 넘나드는 태풍의 피해와 많은 적설량을 보이는 기후적 제약으로 발달되지 못하였다. 그러나 최근 새로운 소재의 막구조 제품 개발과 구조해석 방법 및 시공기술 등이 개발되어 보편화되어지고 있는 실정이다. 막구조용 재료로 사용되는 섬유소재는 주로 Polyester직물을 기재로 한 PVC 코팅 제품으로 일반 PVC 막재는 장력이 약하고, 광선에 의한 물성이 쉽게 변화되어 내구연한이 5~15년에 불과하다. 유리섬유나 아라미드섬유 등으로 제직한 기재에 고내열 실리콘이나 PTFE 수지를 코팅한 제품은 약품에 대한 내구성이 높고 자외선에 대해서는 매우 큰 저항성을 가지기 때문에 내구연한이 10년에서 30년 까지도 향상된다. 그러나 실리콘 코팅막은 세계적으로 가장 좋은 막재로 알려졌으나 자정능력(Self Cleaning)에 문제가 발생되어 사용량이 감소 추세라고 할 수 있다. 일반적인 코팅 가공의 경우 MEK, Toluene, DMF 등과 같은 유기용제를 다량 사용함에 따라 작업환경 및 대기오염, 화재 위험 등의 문제점이 있으며 특히 가공시 잔류되는 유기용제의 심각성이 대두되고 있는 상황이다. 이와 같이 코팅 가공제 자체를 친환경적인 물질로 대체하여 각종 환경규제에 대응하고 유해 폐기물의 발생을 줄일 수 있는 코팅 가공제 및 가공기술 개발이 절실하다. 이에 본 연구에서는 Glass-Fiber, Aramid 등의 슈퍼 섬유와 고 강력 섬유 등을 이용하여 PTFE 코팅제품과 비슷한 수준의 성능을 부여하는 무용제형 실리콘 코팅 수지를 개발하고 내구성능 향상, Self Cleaning성, 난연성, 자외선 차단, 인장강도 및 인열 강도의 향상 등 다양한 기능성을 부여하는 최적의 환경 친화적 코팅 공정 기술을 개발하여 차세대 건축용 막구조 제품을 개발하고자 한다.

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Effects of Barely Processings on the Reduction of Deoxynivalenol (보리 가공에 의한 Deoxynivalenol의 감소 효과)

  • Pei, Shi-Chun;Lee, Won-Jong;Ryu, Gi-Hyung;Chung, Duck-Hwa
    • Journal of Food Hygiene and Safety
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    • v.19 no.3
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    • pp.119-125
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    • 2004
  • This study examined the effects of pearling, simple heating, baking and extrusion in processing of barley contaminated with deoxynivalenol (DON) on the reduction or destruction of DON. The DON contamination level of barley used in the experiment was 2.08 ppm. The DON-forming strain isolated from the barley was Fusarium graminearum, and the DON formation potential of which was 6.3 ppm on the average in Czapek-Dox broth medium. The DON removal efficiency of pearling was 56.5%, simple heating 3.8-32.7%, extrusion 53-59%, and baking 10.4%. As a large quantity of DON still remains after processing, it tis necessary to develop a new method of removing DON comletely.

The Laundry Habits and the Residual Soils of White Cotton Undershirts in Repeating Home Laundry (일반 가정의 세탁 습관 및 반복 세탁에 의한 백색 면 내의의 잔류 오염)

  • 치옥선;이일심
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.4
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    • pp.549-559
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    • 1994
  • The purpose of this study was to study accumlated residual soils which may be one of the causes for yellowing of worn cloths. Wear and wash tests of white cotton undershirts were repeated at 30 households sellected at random over a period of 60 days. Laundry conditions were similar to home laundry habits in a fact-finding survey, using a powdery heavy duty detergent containing no enzymes or enzymes. The subjects in this study were survey of laundry actual condition, the undershirts from prior to and after the final washing was measured residual soils, $L^*a^*b^*$ value and mellowness index of CIE system. D3ta were analysed by simple correlation analysis of wear and wash cycle, residual soils, whiteness The results obtained were summarized as follows: 1. Using pattern of washing machine, Presoaking was no singinificant differnece in general characteristics of survey respondent. Laundry frequency was significant difference in income level, occupation of housewives whether or not. Use of cold and hot water was significant difference in residence shape. 2. The analyzed consequences of recognition and actual behavior in connection with laundry were found variables each other to have independence or not. 3. Amount of residual sebum soils is using non-enzyme detergent were much more than in using enzyme detergent, increased linearly with increase of the number of wear and wash cycles. 4. Residual protein soils with increase of the number wear and wash cycles less than in laundering more easy than sebum soils. Since accumulated residual sebum soils were much more than residual protein soils. 5. Increase of residual soils was raised mellowness index and diminshed whiteness. yellowness index of residual sebum soils was higher than protein soils. If increase of whiteness will be incresed, amount of residual sebum soils will be decreased sebum soils. Because amount of residual sebum soils much more than protein soils, yellowness index of residual sebum soils was more higher than that of protein soils.

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Effect of Biofilm Formation on Soil Sorbed Naphthalene Degradation (Biofilm 생성이 토양흡착 나프탈렌 분해에 미치는 영향)

  • Li, Guang-Chun;Chung, Seon-Yong;Park, Jeong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.14 no.6
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    • pp.45-52
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    • 2009
  • Naphthalene-degrading bacteria Pseudomonas aeruginosa CZ6 isolated from contaminated soil can adhere to crystal naphthalene and produce extracellular polymeric substance. LB, YM and MSM medium were used as culture mediums to investigate the formation of biofilm. Biofilm was developed the most in LB medium by Pseudomonas aeruginosa CZ6. In the culture, strain CZ6 growth was rarely affected by naphthalene concentration. Optimal culture condition was $30^{\circ}C$ and pH 7 at 0.10% substrate and 150 rpm shaking. The effect of culture medium on naphthalene degradation in the two soil slurry system was evaluated. The initial degradation rate of naphthalene was highest in the MSM medium of soil slurry. However, the sorbed naphthalene was rapidly degraded at the LB medium when naphthalene availability in liquid was limited. The results of this study suggest that biofilm formation and extracellular polymeric substance production increased bioavailability of soil sorbed naphthalene.

Removal of Toxicity from Kraft Pulp Mill Effluents by Activated Sludge Process (활성슬러지 공정에 의한 Kraft 펄프 폐수의 독성 제거)

  • Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.3
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    • pp.9-18
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    • 1994
  • Activated sludge pilot plant testing was conducted to determine the ability of a well-designed activated sludge treatment system to remove chromic toxicity from the bleached kraft pulp mill effluent. Removals of conventional(BOD and SS) and nonconventional(resin and fatty acids, color, AOX) pollutants were estimated. The pilot plant was operated at steady state for about 10 weeks at an F/M of 0.28 and a sludge age of 8.4 days. The average MLSS concentration was 4,309mg/l, of which volatile fraction was 57%. During the operation period, the BOD removal reaction rate(k) was determined to be 8.2/day at $30^{\circ}C$. The BOD removal was 84 percent, which was 3 to 6 percent lower than expected for full-scale treatment. The chronic toxicity of the activated sludge effluent was tested by employing both Dinnel and the BML protocols. It was found that the pilot plant could achieve in excess of 90 percent reduction in chronic echinoderm toxicity. The data show slight reduction of color and AOX across the activated sludge system. The pilot system, however, demonstrated on excellent removal of resin and fatty acids.

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Identification of operating parameters in auto-discharging filter system for treatment of urban storm water (자동방류가 가능한 여과형 비점오염처리장치의 운전인자 도출)

  • Kim, Sun-Hee;Gwon, Eun-Mi;Pak, Sung-Soon;Joh, Seong-Ju;Lim, Chea-Hoan;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.4
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    • pp.377-386
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    • 2010
  • To identify operating parameters of the up-flow filtering system, which is available to discharge filtering residue after the rain, developed for treatment of urban storm runoff, lab scale test was carried out. Removal efficiency of SS was 68.7%, 62.2%, and 58.6% at the area roading rate of 2.46m/h, 4.68m/h, and 10m/h, respectively, filtering device is desirable to operate at the lower than 4.68m/h of area roading rate to get higher level of 60% SS removal efficiency. The removal efficiency of SS was 57.1% ~ 68.7% at the raw water SS of 100mg/L ~ 600mg/L, and the SS in treated water was maintained at the constant level through the elapsed time. It is indicate that filtering device can guarantee a certain level of effluent water quality at various raw water quality. The removal efficiency of SS to the depth of filter media was 68.3%, 78.6% at the filter depth of 10 cm, 20cm respectively. The final treated water quality was showed 30.2mg/L of CODMn, 1.60mg/L of TN and 0.25mg/L of TP. The average removal efficiencies by filtering device developed in this research were recorded slightly lower levels than other research. The main reason of these results were the first, the filter depth of the media used in this test was shallow, the second, the kind of filter media in discharge port of residue. More research to kind of filter media, filter packing rate, select of media for residue discharge port should be go on to produce optimum operating condition. The result of this study would be valuable for the application of filtration device to control of urban storm water.

Association of Persistent Organic Pollutants (POPs) with Age and Body Mass Index in Korean Adults (한국 성인의 혈청 잔류성 유기오염물질 농도와 연령 및 체질량지수와의 관련성)

  • Moon, Ho Jung;Lim, Jung-Eun;Jee, Sun Ha
    • Journal of Environmental Health Sciences
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    • v.40 no.6
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    • pp.442-453
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    • 2014
  • Objectives: Persistent organic pollutants (POPs) are known to be the detrimental chemicals in the body, even at low levels, and are stored in adipose tissue. Recently, POPs have been reported to be associated with chronic diseases, including cancer and cardiovascular disease, and aging and obesity are reported as common factors in chronic disease. However, there have been only a few studies on the associations of POPs with age and body mass index (BMI) in Korea. Therefore, we analyzed the associations of serum POPs levels with age and BMI in Korea. Methods: This cross-sectional study includes 444 subjects (253 men and 191 women) from the Korean Cancer Prevention Study-II (2004-2011). Serum levels of 33 polychlorinated biphenyls (PCBs) and 19 organochlorine pesticides (OCPs) were measured by a gas chromatographer (Agilent 6890) coupled to high resolution mass spectrometer (JEOL JMS-800D). Results: Concentrations of PCB 153 (men: 12.26 ng/g lipid, women: 10.50 ng/g lipid) and p,p'-DDE (men: 94.66 ng/g lipid, women: 96.66 ng/g lipid) were the highest among serum PCBs and OCPs, respectively. PCBs and OCPs were significantly positively correlated with age in both sexes. After adjustment for age, non-dioxin like PCBs were significantly negatively correlated with body mass in women. However, cis-heptachlor epoxide was significantly positively correlated with body mass index in both sexes. When analyzed by sex, stronger associations were shown between POPs and age in men and POPs and BMI in women. Conclusion: These results may provide baseline data for the study of POPs and for the health management field in Korea.

Case Analysis of the Harmful Chemical Substances' Spill (유해화학물질 유출의 사례 분석)

  • You, Jisun;Chung, Yeong-Jin
    • Fire Science and Engineering
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    • v.28 no.6
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    • pp.90-98
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    • 2014
  • Lately accidents of harmful chemical substance in korea were repeatedly replaying. We studied problems and preparation plan in 2008 years~2014 years through analysis cases of harmful chemical substance. Leakage of chemical substance's accident situation shows that leakage in the workplace is the most 10 cases, accounting for 58.6% is the largest proportion in 2009. Leakage according to explosion accounting for 50% (5 cases) in 2004, 25% (4 cases) in 2007 and 33.3% (4 cases) in 2011 has very irregular change. Therefore, A major cause of accidents is lack of safety management. Harmful chemical substance showed various aspects, high residual substance and non-visible characteristic so response and recovery was easy. And the second damage to move a distance causes environment pollution. So a mutual-assistance system and integrated system of related organization have to build and expert of chemical incident response and therapist of chemical substance response have to establish to do efficient and rapid response.

UV 나노임프린트 리소그래피의 Quartz 기판상의 Resin mold 제거를 위한 Hybrid 세정공정에 관한 연구

  • Jo, Yun-Sik;Kim, Min-Su;Gang, Bong-Gyun;Kim, Jae-Gwan;Lee, Byeong-Gyu;Park, Jin-Gu
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.81.1-81.1
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    • 2012
  • 나노임프린트 리소그라피(Nano-Imprint Lithography, NIL) 기술은 기판위의 resin을 나노구조물이 각인된 스탬프로 눌러서 나노구조물을 형성하는 기술로, 경제적이고 효과적으로 나노구조물을 제작할 수 있는 기술이다. 그중에서도 UV 기반의 나노임프린트(UV-NIL) 기술은 resin을 투명한 스탬프로 누른뒤 UV로 경화시켜 나노구조물을 형성하는 기술로써 고온, 고압($140{\sim}180^{\circ}C$, 10~30bar)이 필요한 가열식 나노임프린트 기술에 비해 상온, 상압($20^{\circ}C$, 1bar)에서도 구조물 형성이 가능하여 다층구조 형성에 적합하다. 연속적인 임프린팅 공정에 의해 resin이 quarz 스탬프에 잔류하여 패터닝에 결함을 유발하게 되므로 오염물을 제거하기 위한 세정공정이 필요하다. 하지만 UV에 의해 경화된 resin은 cross-linking을 형성하여 화학적인 내성이 증가하게 되므로 제거하기가 어렵다. 현재는 resin 제거를 위한 세정공정으로 SPM($H_2SO_4/H_2O_2$) 세정이 사용되고 있는데 세정시간이 길고 세정 후에 입자 또는 황 잔유물이 남으며 많은 유해용액 사용의 문제점이 있어 효과적으로 resin을 제거할 세정공정이 필요한 상황이다. 본 연구에서는 친환경적인 UV 세정 및 오존수 세정공정을 적용하여 경화된 resin을 제거하는 연구를 진행하였다. 실험샘플은 약 100nm 두께의 resin을 증착한 $1.5cm{\times}1.5cm$ $SiO_2$ 쿠폰 wafer를 사용하였으며, UV 및 오존수의 처리시간을 달리하여 resin 제거효율을 평가하였다. ATR-FTIR 장비를 사용하여 시간에 따른 resin의 두께를 측정한 결과, UV 세정으로 100nm 높이의 resin중에 80nm의 bulk resin이 단시간에 제거가 되었고 나머지 20nm의 resin thin film은 오존수 세정으로 쉽게 제거되는 것을 확인 하였다. 또한 표면에 남은 resin residue와 particle을 제거하기 위해서 SC-1 세정을 진행하였고 contact angle과 optical microscope 장비를 사용하여 resin이 모두 제거된 것을 확인하였다.

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Development of Cleaning Agents for Solar Silicon Wafer (태양광 실리콘 웨이퍼 세정제 개발)

  • Bae, Soo-Jeong;Lee, Ho-Yeoul;Lee, Jong-Gi;Bae, Jae-Heum;Lee, Dong-Gi
    • Clean Technology
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    • v.18 no.1
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    • pp.43-50
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    • 2012
  • Cleaning procedure of solar silicon wafer, following ingot sawing process in solar cell production is studied. Types of solar silicon wafer can be divided into monocrystalline or multicrystalline, and slurry sawn wafer or diamond sawn wafer according to the ingot growing methods and the sawing methods, respectively. Wafer surface and contaminants can vary with these methods. The characterisitics of contaminants and wafer surface are investigated for each cleaning substrate, and appropriate cleaning agents are developed. Physical properties and cleaning ability of the cleaning agents are evaluated in order to verify the application in the industry. The wafers cleaned with the cleaning agents do not show any residual contaminants when analyzed by XPS and regular patterns are formed after texturization. Furthermore, the cleaning agents are applied in the production industry, which shows superior cleaning results compared to the existing cleaning agents.