• Title/Summary/Keyword: 잔류오염

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Adsorption and Leaching Characteristics of the Insecticide Imidacloprid in Paddy Soils (살충제 Imidacloprid의 논토양 중 흡착 및 용탈 특성)

  • Ihm, Yang-Bin;Kyung, Kee-Sung;Kim, Chan-Sub;Lee, Hee-Dong;Ryu, Gab-Hee;Lee, Jae-Koo
    • Korean Journal of Environmental Agriculture
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    • v.25 no.1
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    • pp.58-63
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    • 2006
  • In order to elucidate the adsorption and leaching characteristics of the insecticide imidacloprid in two types of paddy soils near Suwon, this experiment was carried out with $[^{14}C]$imidacloprid as a radiotracer. In an adsorption study conducted using $[^{14}C]$imidacloprid in 2 test soils, the adsorption coefficient was higher in soil A $(K_f\;2.6)$ than that in soil B $(K_f\;1.7)$. As calculated from Freundlich constant, distribution coefficients and half lives in soils, GUS indices showed low leachabilities of imidacloprid treated on the paddy soils into the groundwater. The amount of imidacloprid leached from the soil columns during the 4 weeks of leaching was less than 2% of the originally treated $^{14}C$. In the leaching test the amounts of $^{14}C$ activities distributed in the soil layer of 0-10 cm were more than 80% of the originally tented $^{14}C$ and those in rice plants were less than 3% of the originally treated $^{14}C$, suggesting that imidacloprid has very low teachability and bioavailability.

Monitoring Program on Food Contaminants (식품중의 오염물질에 관한 조사연구)

  • 백덕우
    • Journal of Food Hygiene and Safety
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    • v.2 no.3
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    • pp.121-136
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    • 1987
  • As a part of continuing monitoring program since 1983, a study on pesticide residues on Korean agricultural products has been conducted to offer the tolerance of pesticide residues suiting Korean reality. The samples used in this experiment were collected from four areas in five provinces of Korea. The residue, levels of organochlorine pesticide (two kinds), organophosphoric pesticide (eight kinds) and carbamate pesticide (three kinds) on lettuce, garland chrysanthemum, radish Korean, potato, egg plant, green onion, persimmon and sweet potato, and the residue levels of captan and captafol on tomato, green pepper fresh, apple, peach, soybean, cucumber and cabbage Korean were determined by GC-NPD and ECD.

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Removal of Malathion Residues from Fruits and Vegetables by Washing Processes (과일채소중 말라티온 잔류분(殘溜分)의 세척효과)

  • Shim, Aei-Ryun;Choi, Eon-Ho;Lee, Su-Rae
    • Korean Journal of Food Science and Technology
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    • v.16 no.4
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    • pp.418-422
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    • 1984
  • In order to determine the removal efficiency of pesticide residues in fruits and vegetables by washing processes, samples of lettuce, young Chinese radish, Chinese cabbage, green red pepper, strawberry and grape were artificially contaminated with malathion and washed according to the household practices. After three times washings with water, the remaining ratios of malathion residues in grape, green red pepper, strawberry, young Chinese radish, lettuce and Chinese cabbage were 9.7%, 25.2%, 28.0%, 29.7%, 38.9% and 57.5%, respectively. After washing with detergent solution followed by two times rinsing with water, the remaining ratios of malathion residues in the same food samples were 1.6%, 8.3%, 15.8%, 24.8%, 27.2% and 45.9%, respectively. The removal efficiency of malathion by detergent washing was significantly higher than the water washings only. The removal ratio of malathion residues was the highest in the first washing and the ratio fell greatly in the following washings. The removal efficiency was not quite different in the temperature range of $5-35^{\circ}C$ of the washing solution, but the efficiency at $100^{\circ}C$ was 2-3 times higher than other temperature ranges.

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Plant uptake potential of endosulfan from soil by carrot and spinach (다소비 채소작물인 시금치와 당근의 토양 중 엔도설판 흡수이행능)

  • Choi, Geun-Hyoung;Jeong, Dong-Kyu;Lim, Sung-Jin;Ro, Jin-Ho;Ryu, Song-Hee;Park, Byung-Jun;Moon, Byung-Cheol;Kim, Jin Hyo
    • Journal of Applied Biological Chemistry
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    • v.60 no.4
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    • pp.339-342
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    • 2017
  • Residual endosulfan in an agricultural environment has been reported, although endosulfan was listed to persistent organic pollutants and banned. To produce the safe crop from endosulfan residue risk, the plant uptake potential of endosulfan from soil to crop should be studied. In here, the plant uptake potentials of endosulfan in various crops were surveyed and ranged from 0.002-4.460. And the bioconcentration factors (BCF) of total endosulfan in carrot and spinach were calculated from the pot experiment. The BCFs in carrot and spinach were 0.285 and 0.040-0.047 respectively. Endosulfan sulfate was contributed to over 42.8% of the crop residue as a major contributor among the three endosulfan congeners in both of carrot and spinach.

A Study on Perceptions toward Food Safety of High School Students in Chuncheon Area (춘천지역 고등학생의 식품안전성에 대한 인식도 조사)

  • Kim, Bok-Ran
    • Journal of Korean Home Economics Education Association
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    • v.19 no.3
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    • pp.119-131
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    • 2007
  • This study was to investigate the recognition level of food safety from high school students(264 male, 276 female) in Chuncheon area using questionnaires. The results of the survey are summarized as follows : Regarding the general consciousness of the conditions of food safety, the proportion of the students who worry about it is higher, while 40.0% respond they are not concerned with it. The information pertinent to food safety was usually acquired from the mass media. As a fundamental reason responsible for the food safety accidents, they pointed out deficient sense of responsibility of the personnels who produce, distribute, and sell food products. As the most problematic materials threatening food safety, they pointed out heavy metals(24.8%), and subsequent responses were environmental hormones(24.4%), food additives(17.0%). The foods, for which they are most concerned about residual pesticides, were vegetables and fruits. High proportion of the students perceived that agricultural products are not safe from residual pesticides, and most of the students(92.4%) thought that residual pesticides are bad for their health. The examination on the food safety influenced by heavy metals reveals that 87.4% of the students thought the materials do influence food safety. As the food kind that is likely to be most polluted by heavy metals, they pointed out fishery products. The highest concern about processed food stuffs was the food additives. Most of the students thought that the containers of processed foods may be toxical. 25% of the students are more seriously considering food safety when they buy foods. High proportion of the students who responded they confirm safety-related matters at the time of food purchase thought much of food safety, while high proportion of those who didn't confirm those matters lay a great importance on the taste.

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Vertical Distribution of Persistent Organic Pollutant in Core Sediments from Upo Wetland (자연습지 우포늪 퇴적물의 연도별 잔류성 유기오염물질 축적도)

  • Boo, Min Ho;Lee, Chan Won;Lee, Sang Chun;Kim, Jong Guk;Jeon, Hong Pyo;Kim, Ki Ho;Choi, Kyung Hee;Yun, Jun Hun;Jeong, Mi Jung
    • Journal of Wetlands Research
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    • v.10 no.2
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    • pp.23-37
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    • 2008
  • The vertical distribution of dioxins and hexachlorobenzene(HCB) in a sediment core was investigated to elucidate historical trends of dioxins and HCB deposited into Upo wetland. The total concentration of dioxin ranged from 8.7 to 66.27 pg/g-dw in Upo sediments deposited, and from 17.64 to 97.03 pg/g-dw in Mokpo. Dioxin fluxes increased from the first-1990s and then reached a maximum in the mid-1990s. The major source of dioxin by comparing the congeners pattern was pentachlorophenol(PCP) used of agrochemicals. The HCB concentration in most of samples was detected below the MDL(Method Detection Limit of 0.5ng/g), except a few samples.

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Effect of alkali chemical compound on paper properties for acidic papers preservation (산성지 보존을 위한 알카리 토금속 화합물이 종이물성에 미치는 영향)

  • 최찬호;신종순;마주희
    • Proceedings of the Korean Printing Society Conference
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    • 2001.06a
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    • pp.45-45
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    • 2001
  • 자료의 보존에 있어서 종이의 열화로 인해 자료의 분석, 열화메커니즘의 해석, 종이의 보존이란 측면 하에서의 관심이 서서히 집중되고 있는 실정이며, 그 중요성도 크게 대두되고 있는 실정이다. 산성지를 중성화하는 화학적시스템, 즉, 탈산성화처리는 알카리계금속(Ca, Mg, Zn, Na)과 유기용매, 수용성용매를 이용하여 이들 약품을 종이내에 침투시켜 중성화(pH 6-8) 함으로써 종이의 주성분인 cellulose를 보다 안정화시키는 방법으로 산을 중화하여 보존성을 향상시킬 수 있는 것이다. 즉, 탈산처리란 화학적으로 종이속에 생기는 산 또는 산을 발생하는 물질을 알칼리물질로 중화하는 것이다. 또한 중화후 알칼리 물질이 종이에 잔류하면 장래에 내부적으로 발생하는 산이나 외부(대기중의 오염물질 등) 로부터 침입하는 산도 중화하여 보존성을 향상시킬 수가 있다. 따라서, 본 연구는 산성초지법에 의해 제조된 용지들의 열화특성과 알카리 토금속을 처리한 후에 알카리도를 상승시킨 용지의 열화특성을 물리·화학적 변화를 통하여 종이의 보존성을 비교 검토·규명함으로써 문(도)서의 보존체계를 마련하고자 하며, 보존과 관련된 기초자료를 얻고자 실시하였다.

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Calculation Method for the Concentration of Persistent Organic Pollutants (POPs) Collected by Passive Air Samplers (수동대기채취기를 이용한 잔류성유기오염물질의 농도산정)

  • Choi, Sung-Deuk
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.2
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    • pp.217-227
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    • 2013
  • Passive air samplers (PAS) have been developed since the early 2000s and widely used for the atmospheric monitoring of persistent organic pollutants (POPs). PAS are useful especially for the investigation of source-receptor relationship of POPs because they provide higher spatial resolution data. In Korea, however, only a few research groups have conducted POPs monitoring using PAS. One of the reasons for the limited application of PAS might be due to a complicated calculation method for air concentration. In this study, therefore, we introduced the principle of polyurethane foam (PUF)-PAS, which has been most widely used in the world, and provided an example of the calculation of air concentration of polycyclic aromatic hydrocarbons (PAHs). As all data tables and equations for this calculation were provided, this method can be used for the conversion of the amount of POPs (ng) in a PUF disk to air concentration ($ng/m^3$).

인회석을 이용한 도금폐수 내 중금속 제거효율 실내실험

  • 최정찬;라원진;강두현
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.172-174
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    • 2004
  • 본 논문은 광산산성배수(AMD)에서 철 및 알루미늄 제거 효과가 입증되고 ARD(Acid Rock Drainage)에서의 비소제거 효과가 확인된 인회석을 침전제로 사용하여 철, 알루미늄 및 비소가 아닌 다른 중긍속의 제거효율을 알아보기 위해 도금폐수를 이용하여 실내실험을 실시하였다. 실험결과, 도금폐수의 수질분석결과에 의하면 '수질환경보존법 오염물질 배출허용기준' <가>지역 방출수 기준을 초과하는 것은 pH, Zn, Fe, Cu, Cr 및 P였다. 실험 결과 인회석 40번체 통과분-100번체 잔류분을 사용하는 것이 가장 적절할 것으로 생각되며 유속은 1kg의 인회석에 11의 도금폐수를 3시간 동안 반응시키면 경제적, 시간적 측면에서 가장 적절한 것으로 사료된다. 이 경우 pH는 1.98에서 5.30으로 증가하고 Cr, Fe, Cu 및 Zn은 각각 77.10%, 99.58%, 99.39% 및 40.77% 제거되는 것으로 나타났다. 용해율은 0.3619 g/min/kg으로 계산되었다. 그러나 3시간의 반응시간으로는 크롬 및 아연을 기준치 이하로 제거하지 못하므로 인회석 반응조를 다단계로 하는 실험을 수행해 그 결과를 평가해야 할 것이다.

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Characteristics of the PCDD/DFs Emissions in the Flue Gases of Full Scale Incinerators (다양한 소각시설 배출가스 중 다이옥신류의 배출특성)

  • 최진수;문영훈;김민관;오정은;김병훈;장윤석
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.11a
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    • pp.330-331
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    • 2000
  • 환경오염 유기물질 중 다이옥신류는 높은 화학적 안정성과 생화학적 잔류성으로 인해 1970년대 이후 외국에서는 가장 중요한 환경물질의 하나로 취급되면서 다양한 연구가 이루어지고 있다. 이러한 다이옥신은 여러 가지 경로를 통해 생성되는데 이 중에서도 연소과정, 특히 폐기물 소각로에서 생성되는 것이 주 배출원으로 알려져 있다. 국내에서 1997년도 1차로 실시한 전국의 소각시설 다이옥신 배출 실태조사 이후 정부에서는 신설 도시쓰레기 소각장에 대해서는 0.1 ng-TEQ/Nm$^3$의 배출기준을 설정하고 정기적인 다이옥신 측정을 의무적으로 실시할 것을 법규화한 바 있다. (중략)

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