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Adsorption and Leaching Characteristics of the Insecticide Imidacloprid in Paddy Soils

살충제 Imidacloprid의 논토양 중 흡착 및 용탈 특성

  • Ihm, Yang-Bin (Department of Crop Life Safety, National Institute of Agricultural Science and Technology) ;
  • Kyung, Kee-Sung (Department of Agricultural Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University) ;
  • Kim, Chan-Sub (Department of Crop Life Safety, National Institute of Agricultural Science and Technology) ;
  • Lee, Hee-Dong (Department of Crop Life Safety, National Institute of Agricultural Science and Technology) ;
  • Ryu, Gab-Hee (Department of Crop Life Safety, National Institute of Agricultural Science and Technology) ;
  • Lee, Jae-Koo (Department of Agricultural Chemistry, College of Agriculture, Life and Environmental Sciences, Chungbuk National University)
  • 임양빈 (농업과학기술원 농산물안전성부) ;
  • 경기성 (충북대학교 농화학과) ;
  • 김찬섭 (농업과학기술원 농산물안전성부) ;
  • 이희동 (농업과학기술원 농산물안전성부) ;
  • 류갑희 (농업과학기술원 농산물안전성부) ;
  • 이재구 (충북대학교 농화학과)
  • Published : 2006.03.31

Abstract

In order to elucidate the adsorption and leaching characteristics of the insecticide imidacloprid in two types of paddy soils near Suwon, this experiment was carried out with $[^{14}C]$imidacloprid as a radiotracer. In an adsorption study conducted using $[^{14}C]$imidacloprid in 2 test soils, the adsorption coefficient was higher in soil A $(K_f\;2.6)$ than that in soil B $(K_f\;1.7)$. As calculated from Freundlich constant, distribution coefficients and half lives in soils, GUS indices showed low leachabilities of imidacloprid treated on the paddy soils into the groundwater. The amount of imidacloprid leached from the soil columns during the 4 weeks of leaching was less than 2% of the originally treated $^{14}C$. In the leaching test the amounts of $^{14}C$ activities distributed in the soil layer of 0-10 cm were more than 80% of the originally tented $^{14}C$ and those in rice plants were less than 3% of the originally treated $^{14}C$, suggesting that imidacloprid has very low teachability and bioavailability.

국내에서 광범위하게 사용되고 있는 살충제 imidacloprid의 토양흡착 특성과 벼 재배 환경중 용탈 가능성을 평가하기 위하여 방사성 동위원소로 표지된 $[^{14}C]$limidacloprid를 이용하여 수원근교 논토양 2종을 대상으로 시험하였다. Freundlich 흡착 등온식으로부터 구한 imidacloprid의 흡착상슈$(K_f)$$1.7{\sim}2.6$, 기울기(1/n)는 1 미만, 토양 유기탄소기준흡착계수$(K_{oc})$$228{\sim}249$, 토양 반감기를 이용한 지하수 오염가능성(GUS index)은 $1.6{\sim}2.4$로 흡착성이 중간 정도로 평가되어 토양중 용탈 가능성은 높지 않았다. 논토양에서 용탈성은 숙성잔류물 함유 토양보다 신생잔류물 함유 토양에서 더 높았다. 논토양의 토층별 $^{14}C$의 분포는 $0{\sim}10cm$ 깊이에 80% 이상이 분포하였으며, 벼 재배구에서 처리된 $^{14}C$의 식물체로의 이동성은 신생잔류물 함유 토양이 숙성잔류물 함유 토양보다 높았으나 식물체로 흡수된 $^{14}C$은 총처리량의 약 3% 미만으로서 imidacloprid의 용탈성과 생물이용도가 매우 낮음을 시사하였다.

Keywords

References

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