• Applied Biological Chemistry
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• v.26 no.2
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• pp.104-109
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• 1983

Gas chromatographic method for the analysis of phorate(0,0-diethyl S-ethyl-thiomethyl phosphorithioate) and its metabolites in soil and vegetables was studied by using a mixed phase column(10% DC-200+8% Reoplex-400+2% QF-1 on Gas Chrom Q, $1.8{\times}2mm$ i.d, borosilicate glass column). This column can separate completely phorate and its four metabolites except phoratoxon sulfoxide. Retention time of standard mixture ranged 1.8 to 16.1 minutes at column temperature programming from 130 to $200^{\circ}C$ at $5^{\circ}C/min$ and detector sensitivity was also very high(0.05 to 1.05ng). Recoveries from soil and vegetables untreated but fortified with phorate and its three major metabolites at 0.05 and 0.5ppm levels were above 90% for phorate, phorate sulfoxide and phorate sulfone while recovery of phoratoxon metabolite was about 84%.

• Korean Journal of Optics and Photonics
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• v.9 no.5
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• pp.333-341
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• 1998

The novel integrated device, 1.55 ${\mu}{\textrm}{m}$ DR-LD(distrbuted reflector laser diode) integrated EA-MOD (electro-absorption modulator) as light source, is proposed to improve the device yield and its operational performances. This device can be easily fabricated by the selective MOVPE technique and its fabrication processes are almost the same as the reported 1.55 ${\mu}{\textrm}{m}$ DFB-LD(distributed feedback laser diode) integrated EA-MOD except the asymmetric gratings. The static and dynamic properties are investigated simultaneously by solving the transfer matrix method for light propagation, the time-dependent rate equation for carrier change and schr$\"{o}$dinger equation for QCSE (Quantum-Confined Stark Effect). The performances of the proposed device such as output power, chirp, and extinction ratio are compared with those of DFB-LD integrated EA-MOD. Under 10Gb/s NRZ modulation, we obtain that DR-LD integrated EA-MOD. is 30% higher in output power on the on-state, about 50% lower in chirp, and slightly larger in extinction ratio than DFB-LD integrated EA-MOD.-MOD.

• Journal of the Korean Geotechnical Society
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• v.34 no.11
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• pp.57-70
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• 2018

In this study, verification of the nonlinear effective stress analysis is performed for introducing performance based earthquake resistance design of port and harbor structures. Seismic response of gravitational caisson quay wall in numerical analysis is compared directly with dynamic centrifuge test results in prototype scale. Inside of the rigid box, model of the gravitational quay wall is placed above the saturated sand layer which can show the increase of excess pore water pressure. The model represents caisson quay wall with a height of 10 m, width of 6 m under centrifugal acceleration of 60 g. The numerical model is made in the same dimension with the prototype scale of the test in two dimensional plane strain condition. Byrne's liquefaction model is adopted together with a nonlinear constitutive model. Interface element is used for sliding and tensional separation between quay wall and the adjacent soils. Verification results show good agreement for permanent displacement of the quay wall, horizontal acceleration at quay wall and soil layer, and excess pore water pressure increment beneath the quay wall foundation.

• Clean Technology
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• v.29 no.2
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• pp.118-125
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• 2023

Once a site is contaminated with polychlorinated biphenyls (PCBs), serious environmental and human health risks are inevitable. Therefore, innovative but economical in situ remediation technologies must be immediately applied to the contaminated site. Recently, nanoscale zero-valent iron (nano-ZVI) particles have successfully been applied for the dechlorination of various chlorinated organic compounds like TCE, PCE and DDT, and they are considered to be environmentally safe due to the high abundance of iron in the earth's crust. Nano-ZVIs are much more reactive than granular ones, but tend to agglomerate due to their high surface energy and magnetic properties. In order to prevent them from being agglomerated toward larger particles, TiO₂ was used as a support to immobilize the nano-ZVI particles as much as possible. 10wt% ZVI/TiO₂ was prepared by adding NaBH₄ slowly into an FeSO₄/TiO₂ aqueous slurry. In spite of their non-uniformity in size, the nano-ZVI particles were quite successfully dispersed onto the exterior surface of a non-porous TiO₂ powder. The ZVI/TiO₂ was then employed to degrade Aroclor 1242, a kind of PCBs standard, in spiked soil, and its reactivity towards the degradation of Aroclor 1242 was investigated. The fabricated ZVI/TiO₂ degraded Aroclor 1242 in soil quite effectively, but the creation of remaining dechlorinated compounds, possibly high molecular weight hydrocarbons, in the soil was unavoidable.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.43 no.1
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• pp.71-77
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• 2023

With the continuous industrial development, not only natural resource depletion, waste generation, but also various weather conditions are becoming more frequent. Efforts are continuing to recycle industrial by-products to overcome the climate crisis and save resources. Slag is a representative by-product generated in the steel industry, and it is characterized by improving rutting resistance and moisture sensitivity by increasing strength and reducing deformation when used as a material for asphalt concrete. On the other hand, slag has expansion properties so it is used as a relatively low-value-added material such as embankment and refilling materials. In order to expand the application of slag, an experiment was conducted to evaluate the crack resistance of slag asphalt concrete pavement. As a result of the indirect tensile strength test, it was found that the asphalt mixture using slag aggregate showed a value 1.13 times higher than that of the general HMA with the same particle size, and the toughness was 1.17 units, improving crack resistance. In addition, it was found that the failure number of the 4-point beam fatigue experiment and the slag asphalt mixture was 20,409, which was more than doubled compared to the general HMA. Furthermore, Overlay Test showed a tensile load residual rate of 4 times or more, improving crack resistance to repeated fatigue. Accordingly, the use of slag aggregate will likely have various advantages in improving the performance of asphalt concrete pavement.

• Analytical Science and Technology
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• v.21 no.6
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• pp.443-458
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• 2008

Brominated flame retardants (BFRs) are chemical compounds that inhibit the combustion of organic materials by scavenging free radicals that would otherwise encourage the spread of flames. These compounds are found in a wide variety of materials including paints, plastics, textiles, furniture and electronics. Mounting evidence, however, suggests that the non-reactive BFRs can easily leach into the environment and pose significant environmental and health concerns. PBDDs/PBDFs are often formed in the process of manufacturing brominated flame retardants and from the combustion of waste products containing flame retardants BFR. Therefore, this paper describes the general characteristics, management status, residual concentration in environments and analytical method.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.11
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• pp.758-763
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• 2014

Soil microbial fuel cells (SMFC) have gained a great attention as an eco-friendly technology that can simultaneously generate electricity and treat organic pollutants from the contaminated soil. We evaluated the effect of electrode spacing and size on the performance of SMFC treating soil contaminated with organic pollutants. Maximum power density decreased with increase in electrode distance or decrease in electrode size, likely due to higher internal resistance. The maximum voltage and power density decreased from 326 mV and $19.5mW/m^2$ with 4 cm of electrode distance to 222 mV and $5.9mW/m^2$ with 9 cm of electrode distance. In case of electrode size test, the maximum voltage and power density generated was 291 mV, $0.34mW/m^3$ when both of anode and cathode area were $64cm^2$ with 4 cm of electrode distance. The maximum voltage decreased by 19~29% when the anode area decreased to $16cm^2$ while only 3~12% of voltage decreased with cathode area decrease. The maximum power density decreased by 49~68% with decreasing anode size, and by 29~47% with decreasing cathode size. These results showed that the anode area had more significant effects than the cathode area on the power generation of SMFC which has a high internal resistance due to a coexistence of soil and wastewater in the reactor.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.7
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• pp.721-728
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• 2008

DBPs(Disinfection By-Products) are most formed through the reactions between chlorine and NOM(Natural Organic Matter) in water treatment. In this study, occurrence of DBPs including THMs(Trihalomethanes) is evaluated. Also, influencing factors by the seasons and raw water quality were investigated for correlation among them and the characteristics of THMs formation by prechlorination process. This study investigated the operation condition for THMs removal depending on raw water quality. Water treatment plant from intake station to gauging well flows for about 10 hours in Y Water Supply Office. It is limited to control of THMs formation because of excessive reaction time between chlorine and THMs precursors in the intake station. Therefore, as multi-points prechlorination from intake station to gauging well, THMs formation was decreased in the water treatment, and it was willing to prevent overdosage of chlorine. The concentration of THMs was 0.021 mg/L in the summer, 0.015 mg/L in the winter, respectively. Also, THMs formation showed that 0.013 mg/L in the water of gauging well after prechlorination, 0.014 mg/L in the flocculation/sedimentation/filtration, 0.016 mg/L in the water after postchlorination, respectively. THMFP(Trihalomethane Formation Potential) removed 42.7% and 50% through the flocculation/sedimentation and filtration, respectively, and it is similar TOC removal efficiency. In this study, multi-points prechlorination from intake station to gauging well decreases in contact time and concencrations of NOM and chlorine. Also, it decreases in THMs and amount of chlorine uesd. In the result of multi-points prechlorination in the summer, the concentration of THMs was 0.013mg/L in the treated water. In view of these facts, THMs formation can be decreased approximately 50%.

• Korean Journal of Environmental Agriculture
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• v.30 no.3
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• pp.288-294
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• 2011

BACKGROUND: Methylmercury is analyzed by HPLC-ICP/MS because of the simplicity for sample preparation and interference. However, most of the pre-treatment methods for methylmercury need a further pH adjustment of the extracted solution and removal of organic matter for HPLC. The purpose of this study was to establish a rapid and accurate analytical method for determination of methylmercury in fish by using HPLC-ICP/MS. METHOD AND RESULTS: We conducted an experiment for pre-treatment and instrument conditions and analytical method verification. Pre-treatment condition was established with aqueous 1% L-cysteine HCl and heated at $60^{\circ}C$ in microwave for 20 min. Methylmercury in $50{\mu}L$ of filtered extract was separated by a C18 column and aqueous 0.1% L-cysteine HCl + 0.1% L-cysteine mobile phase at $25^{\circ}C$. The presence of cysteine in mobile phase and sample solution was essential to eliminate adsorption, peak tailing and memory effect problems. Correlation coefficient($r^2$) for the linearity was 0.9998. The limits of detection and quantitation for this method were 0.15 and $0.45{\mu}g/kg$ respectively. CONCLUSION: Result for analytical method verification, accuracy and repeatability of the analytes were in good agreement with the certified reference materials values of methylmercury at a 95% confidence level. The advantage of the established method is that the extracted solution can be directly injected into the HPLC column without additional processes and the memory effect of mercury in the ICP-MS can be eliminated.