• Title/Summary/Keyword: 잔류방사능

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Uptake of the Residues of the Herbicide Bentazon in Soil by Soybean and Radish (토양중(土壤中) 제초제(除草劑) Bentazon 잔류물(殘留物)의 콩과 무우에 의한 흡수(吸收))

  • Lee, Jae-Koo;Cheon, Sam-Yeong;Kyung, Kee-Sung
    • Korean Journal of Environmental Agriculture
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    • v.7 no.1
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    • pp.1-7
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    • 1988
  • In order to clarify how much of the residues of Bentazon could be taken up by crops, soybean and radish were grown for 28 days in soils containing freshly treated $^{14}C-Bentazon$ and non-extractable soil-hound residues of $^{14}C-Bentazon.$ The results obtained are summarized as follows. 1. $^{14}CO_2$ evolution from $^{14}C$-Bentazon during the 6-month pre-incubation in soil was 14.79% relative to the applied radioactivity. 2. Mineralization of ^$^{14}C$-Bentazon in soil to $^{14}CO_2$ during 28 days of crop growing was much higher in the freshly treated soil than in the bound soil, and much higher in radish than in soybean. 3. The amounts of $^{14}C-Bentazon$ and its metabolites absorbed by soybean and radish were 45.41 and 21.48%, respectively, in freshly treated soil, whereas those were 3.92 and 1.23% in bound soil, respectively. The translocation ratios of radioactivity .from the root to the shoot were much higher in radish than in soybean, remarkably. 4. The uptake ratios of the freshly treated $^{14}C-Bentazon$ to the bound $^{14}C-Bentazon$ by soybean and radish were 12 : 1 and 17 : 1, respectively. 5. It was well verified that the presence of crops enhanced the mineralization to $^{14}CO_2$ and the transformation to polar metabolites of Bentazon.

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Recoil Effects of Neutron-irradiated Metal Salts

  • Lee, Byung-Hun;Lee, Jong-Du
    • Nuclear Engineering and Technology
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    • v.12 no.2
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    • pp.99-105
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    • 1980
  • The distribution of $^{55}$ Mn and $^{38}$ Cl recoil species following radiative neutron capture in permanganates, chlorates and perchlorates has been investigated by using ion-exchange chromatography method. The whole of the $^{55}$ Mn radioactivity in permanganates appeared in two valence states, the $^{38}$ Cl radioactivity in chlorates in two valence states and also the $^{38}$ Cl radioactivity in perchlorates in three valence states. Recoil energy was calculated. The internal conversion of $^{38}$ Cl isomer transition affects the retention value. The greater the radii of the cation, the higher is the probability of the recoil atom breaking through the secondary cage. In ammonium salt, the ammonium ion behaves as a reducing agent. Crystal structures with their greater free space have shown low retention.

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Compositional Qualification of Radiation Protection in Neutron Radiotherapy Room with KCCH Cyclotron (원자력병원(原子力病院) 싸이클로트론 중성자선(中性子線) 치료실(治療室)의 방사선(放射線) 방어(防禦)에 관한 총합적(總合的) 평가(評價))

  • Yoo, Seong-Yul;Cho, Chul-Koo;Koh, Kyoung-Hwan
    • Journal of Radiation Protection and Research
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    • v.14 no.2
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    • pp.45-50
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    • 1989
  • Radiation exposure of the personnel in the neutron therapy facility of KCCH cyclotron neutron system is discussed. In neutron therapy room, medical personnel is exposed to photons of the remanent induced radioactivity from the isocentric gantry in which targets and collimators are mounted. The radiation level of the neutron therapy room of KCCH cyclotron was acceptable and it decreased immediately after beam off. Personal exposure measured by individual monitor was far less than permissible level.

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Uptake of the Fresh and Aged Residues of Carbofuran by Rice Plants from Soil (침투성(浸透性) 살충제(殺蟲劑) Carbofuran 토양(土壤) 잔류물(殘留物)의 벼에 의(依)한 흡수(吸收))

  • Lee, Jae-Koo;Kyung, Kee-Sung;Wheeler, W.B.
    • Korean Journal of Environmental Agriculture
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    • v.8 no.2
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    • pp.103-118
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    • 1989
  • In order to investigate the uptake of the systemic insecticide, carbofuran, 2,3-dihydro-2,2-dimethyl-7-benzofuranyl-N-methyl(arbamate) residues, fresh and aged, by rice plants, they were grown for 42 days in soils containing freshly treated (T-1), 3-month-aged (T-2), and 6-month-aged residues (T-3). The amounts of $^{14}CO_2$ evolved from $^{14}C-carbofuran$ during the 3-and 6-month aging in soil (temp. $22{\pm}1^{\circ}C$ ; moisture, 50% of the maximum water-holding capacity) were 8.9 and 26.7% of the original radioactivity applied, respectively. Mineralization of $^{14}C-carbofuran$ in soil to $^{14}CO_2$ during 42 days of rice growing was 4.4% (T-1), 11.0% (T-2), and 15.7 (T-3). The methanol extract of the 3-and 6-month-aged soils revealed that 3-keto carbofuran phenol (2,3-dihydro-2,2-dimethyl-3-oxo-7-benzofuranol) was the major metabolite, where as 3-hydroxy carbofuran (2,3-dihydro-2,2-dimethyl-3-hydroxy-7-benzofuranyl-N-methylcarbamate) turned out to be the major metabolite in the shoots by the enzymatic cleavage of the possible conjugate present in the methanol extract. Volatilization of $^{14}C-carbofuran$ in soil during 3-and 6-month-aging, and 42 days of rice growing was 0.026, 0.05, and 0.012-0.018% of the applied radioactivity, respectively. The $^{14}C-radioactivity$ which was absorbed from the soils by rice plants during 42 days of the growing period and persisted in rice plant tissues was 26.8, 21.4, and 10.3% in T-1, T-2, and T-3, respectively. The non-extractable bound residues were 8.3, 37.9, and 54.6% of the originally applied carbofuran in T-1. T-2, and T-3, respectively. The small translocation of $^{14}C-radioactivity$ in T-3 upwards suggests that major metabolite 3-keto carbofuran phenol is conjugated in roots and the low recovery in T-1 indicates the loss of carbofuran from the shoots.

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Leaching of the herbicide quinclorac in soil columns (제초제 quinclorac의 토양컬럼 중 용탈)

  • Ahn, Ki-Chang;Kyung, Kee-Sung;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.4 no.4
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    • pp.19-25
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    • 2000
  • The leaching behaviour of quinclorac was elucidated using soil columns. On top of each glass column packed with a rice paddy soil up to the 30 cm height were applied three different treatments of [$^{14}C$]quinclorac: quincloiac only (T-1), quinclorac adsorbed onto active carbon (T-2), and quinclorac adsorbed onto a mixture of active carbon and $Ca(OH)_{2}$ (T-3). Half of the columns were planted with rice plants for 17 weeks and half of them unplanted for comparison. Average amounts of $^{14}C$-activity percolated from tile soil columns without rice plants in T-1, T-2, and T-3 were 81.1%, 27.8% and 48.0%, respectively, of tile originally applied $^{14}C$, whereas those with rice plants grown were 36.8%, 9.6% and 11.0%, respectively, indicating that the leaching of [$^{14}C$]quinclorac was significantly affected by vegetation and by treatment with the adsorbents. The bioavailability of the herbicide to rice plants in T-1, T-2, and T-3 were 13.6%, 11.0% and 13.9%, respectively. The residue levels of quinclorac in the edible part of rice grains would be far less than the maximum residue limit (MRL, 0.5 ppm). After the leaching, the amounts of $^{14}C$ remaining in soil in with rice planting T-1, T-2, and T-3 were 36.3%, 73.7%, and 61.8%, whereas those without rice planting were 19.7%, 71.1%, and 52.3%, respectively. The balance sheets indicate that [$^{14}C$]quinclorac translocated to rice shoots would be lost by volatilization and/or in other ways in T-1 and T-3. The $^{14}C$-activity partitioned into the aqueous phase of the leachates collected from all treatments was less than 7% of the total, but it increased gradually with time in the case of rice growing, suggesting tile formation of some polar degradation products.

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Leaching behavior of the herbicide bentazon in soil column (Soil column중 제초제 bentazon의 용탈 행적)

  • Kyung, Kee-Sung;Oh, Kyeong-Seok;Ahn, Ki-Chang;Kwon, Jeong-Wook;Lee, Jae-Koo
    • The Korean Journal of Pesticide Science
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    • v.2 no.1
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    • pp.59-64
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    • 1998
  • In order to elucidate the leaching behaviour of the herbicide bentazon in soil, soil columns(5cm ID ${\times}$ 34 cm L) were packed with three different soils up to 30 cm height, followed by the treatment of [$^{14}C$]bentazon, and rice plants(Oryza sativa L.) were grown for 9 weeks on these columns, with the columns without growing rice plants as the control for comparison. The amounts of $^{14}C$ activities percolated were about 92% of the originally applied $^{14}C$ irrespective of the physicochemical properties of the soils in the absence of rice plants, whereas $21{\sim}50%$ of the originally applied $^{14}C$ was percolated in the presence of rice plants, suggesting that the amounts of $^{14}C$ leached decreased remarkably in rice-cultivating soils. Bentazon leached faster in soil with higher pH and with lower organic matter content in the presence of growing rice plants. The amounts of $^{14}CO_{2}$ evolved from the soil columns were less than 0.2% of the originally applied $^{14}C$. Smaller amounts of $^{14}C$ were translocated into shoots via roots in soils with higher organic matter content. $^{14}C$ activities distributed into the aqueous phase of the leachate collected from the soil columns increased with leaching period and by rice cultivation, whereas the physico-chemical properties of soils did not exhibit any effect. The amounts of soil-bound residues increased remarkably by cultivating rice plants.

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Monitoring of the Radioactive Contaminants in Dairy Products Imported from the East European Countries (동유럽 국가산 수입 유가공품의 방사능 잔류조사)

  • Lee, Myoung-heon;Cho, Mi-ran;Kim, Yeon-hee;Son, Seong-wan;Kim, Sang-keun
    • Korean Journal of Veterinary Research
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    • v.43 no.3
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    • pp.399-403
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    • 2003
  • The present studies were conducted to monitor radioactive contamination in dairy products imported from 16 countries located in the East Europe which were affected by the Chernobyl nuclear accident. The 556 samples such as butter, cheese, ice cream, whey protein and hydrolysed milk protein products were collected randomly and determined from 1999 to 2002. All sample were below the Koeran and CODEX maximum tolerance level of radioactivity for $^{131}I$, $^{134}Cs$ and $^{137}Cs$.

황산을 이용한 동전기적방법에 의한 방사능오염토양 복원 연구

  • 오원진;김계남
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.2
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    • pp.145-153
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    • 2004
  • H$_2$SO$_4$ and citric acid were used as additives for the electrokinetic remediation experiment to increase removal efficiency of $^{137}$ Cs and $^{60}$ Co from the radioactive soil waste stored for more than 10 years. The average effluent velocity discharged from the elctrokinectic remediation experimental column was 2.0${\times}$10$^{-2}$ cm/min and the discharged soil wastewater volume for 10 days is 3.6 pore volume of the column. 97% of $^{60}$ Co in the column was decontaminated for 10 days of operation, while only 54% of $^{137}$ Cs was decontaminated. These results are considered that the absorption equilibrium coefficient of $^{137}$ Cs is higher than that of $^{60}$ Co. The predicted values of the residual concentration by the proposed mathematical model were well coincided with the experimental results within the experimental error range

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Establishment Aerobic Soil Metabolism System Using [14C]Butachlor ([14C]Butachlor를 이용한 호기성 토양대사 시험법 확립)

  • Kim, Ju-Hye;Kim, Jong-Hwan;Kim, Dae-Wook;Lee, Bong-Jae;Kim, Chan Sub;Ihm, Yangbin;Seo, Jong-Su
    • The Korean Journal of Pesticide Science
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    • v.18 no.4
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    • pp.258-268
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    • 2014
  • The test method of aerobic transformation in soil has established based on international test guideline (OECD TG 307). And then, the case study was conducted with [$^{14}C$]butachlor. Butachlor is commonly used herbicide in Korea. [$^{14}C$]Butachlor was treatrd $6.83mgKg^{-1}$ in loamy soil. The treated soil was incubated in flow-through system for 60 days. The mass balance of applied radioactivity (AR) ranged from 91.1 to 95.5% and from 93.0% to 97.7% for non-sterile and sterile soils, respectively. In non-sterile soil, the concentration of [$^{14}C$]butachlor was declined from 94.4% AR at 0 day to 8.4% AR at 60 days after treatment. 2-Chloro-2',6'-diethylacetanilide was the major degradation product detected in soil extract. The calculated $DT_{50}$ and $DT_{90}$ of butachlor were 10.4 days and 34.6 days, respectively. $^{14}CO_2$ and non-extractable soil residue were increased up to 3.5% and 43.5% AR at 60 DAT. There is no significant decrease of the [$^{14}C$]butachlor through the incubation period in sterile soil.

Pesticides, heavy metals, radioactive substances, and ash of Poria cocos distributed in Korea (국내 유통 복령(Poria cocos)의 농약, 중금속, 방사선물질 및 회분 함량 조사 연구)

  • Jang, Eun-Kyoung;Jang, Hye-Mi;Wi, Chang-Heun;Ban, Seung-Eon
    • Journal of Mushroom
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    • v.19 no.4
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    • pp.294-299
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    • 2021
  • The purpose of this study is to provide basic data on the safety of Poria cocos, a major Korean herbal medicine, and to establish tolerance levels for hazardous substances. Residual pesticides (321 types), heavy metals (7 types), radioactivity (3 types), and ash content were analyzed in 10 Poria cocos products distributed in Korea (5 domestic and 5 in China). Of the residual pesticides, cypermethrin was detected at 0.03 mg/kg in one domestic sample and was below the standard value. Of the heavy metals, the levels of Zn, Pb, Ni, Cu, Hg, and Cr were below the standard values in all samples. Hg was not detected in any sample. Cd was detected at 0.011 mg/kg in one Chinese sample. The radioactivity concentration was also below the MDA value in all P. cocos samples. The ash content was less than the standard value of 1.0% in all P. cocos samples. The findings indicate that P. cocos distributed in Korea is safe. However, because P. cocos is always exposed to harmful substances because of the nature of its cultivation in the soil, it seems necessary to establish systematic management standards for the entire production stage, such as cultivation, storage, and distribution.