• Title/Summary/Keyword: 자기확산

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MAGNETORESISTANCE AND Mn DIFFUSION BEHAVIORS OF CoNbZr-BASED SPIN VALVES WITH NANO OXIDE LAYERS

  • Kim, Jong-Soo;Kim, Young-Keun;Lee, Seong-Rae
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.58-59
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    • 2002
  • 고밀도 자기기록 매체의 재생 헤드로 응용되기 위해서는 높은 자기 저항비와 소자 제조 및 작동시 발생되어지는 열에 대해서 안정해야한다. 일반적으로 스핀밸브에서 나타나는 열화현상 중 가장 주된 원인은 반강자성체에 사용된 Mn이 고정층 및 비자성층으로의 확산으로 인해 반강자성체/강자성체 산이의 교환결합력의 감소와 스핀의존산란이 감소되어 자기적 특성이 열화 되는 것이다[1]. 이러한 상호확산은 거칠기, 결정성, 결정립 크기와 같은 미세구조에 크게 의존한다[2]. (중략)

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확산텐서영상에서 확산경사자장의 방향수에 따른 FA값 및 FA의 표준편차와의 상관 관계

  • 이영주;황문정;배성진;장용민;우성구;서수지
    • Proceedings of the KSMRM Conference
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    • 2003.10a
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    • pp.33-33
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    • 2003
  • 목적: 확산텐서영상 획득시 확산경사자장의 방향수와 FA값, 그리고 FA값의 표준편차와의 상관관계를 조사해 보고자 하였다. 대상 및 방법: 3T MR scanner에서 정상성인 10명(남자 5명, 여자 5명)을 대상으로 걸어주는 확산강조 경사자장의 수(N = 6, 11, 23, 35, 47)를 증가시키며 확산텐서영상을 획득하였다. 획득된 영상들로부터 FA map을 만들고 주요 뇌구조물(frontal GM, putamen, posterior limb of internal capsule, thalamus 등)에 관심영역을 설정하여 FA값을 측정하였으며 그 FA값의 표준편차(sd) 를 계산하였다. 이때 사용한 펄스열은 Stejskal-Tanner type의 확산강조 경사자장이 포함된 single-shot SE EPI를 사용하였으며 영상획득시 사용한 피라미터는 다음과 같다. TR/TE=8000ms/71ms, Thickness/spacing=5/2mm, FOV=240mm, Matrix=$128{\times}128$, NEX= 1, b value=1000s/$\textrm{mm}^2$.

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Performance Evaluation Method of Self-Healing Concrete Using Gas Diffusion Experiment (기체확산 실험을 활용한 자기치유 콘크리트의 성능평가 방법)

  • Lee, Do-Keun;Shin, Kyung-Joon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.143-151
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    • 2020
  • Recently, research on self-healing concrete has been actively conducted, and various methods have been attempted for use in the maintenance of structures. However, contrary to the technical development of self-healing concrete, the method for evaluating the performance is insufficient. Although surface observation and permeability experiments are widely used to observe the healing of cracks, microscopic observation of surface may be insufficient to assess the overall performance. Also, permeation experiments should consider the losses caused by the dissolution of self-healed product and viscosity of water. Although a gas diffusion experiment have been proposed to overcome the shortcomings of these two test methods, verification has not been made on specimens with actual healing. Therefore, in this study, gas diffusion experiments were performed on the mortar specimens that had healed, and the adequacy of self-healing evaluation by the gas diffusion experiment was verified.

Micelle Formation of Surfactant Solution(3) -Self-Diffusion and 1H Relaxation for Mixed Micelle of Nonionic and Ionic Surfactants- (계면활성제 수용액에서 미셀형성(제3보) -비이온성과 이온성계면활성제의 혼합 미셀에 있어 자기확산 및 프로톤 이완-)

  • Choi, Seung-Ok;Kwack, Kwang-Soo;Park, Heung-Jo;Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.876-880
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    • 1999
  • The surfactant self-diffusion coefficients of mixed micellar solutions of ionic and nonionic surfactants have been measured by the NMR pulsed field gradient spin echo(FT-PGSE) method. In addition, the line widths of $^1H$ NMR signal have been monitored. The system investgated are $C_{12}EO_5/SDS/D_2O$, $C_{12}EO_5/DTAC/D_2O$, and $C_{12}EO_8/SDS/D_2O$. In the sample series, the molar ratios of $D_2O$ to surfactant(ionic+nonionic) were kept constant while the surfactant mixing ratio was varied. For the $C_{12}EO_5$ system, the surfactant self-diffusion coefficient indicates minimum when the surfactant mixing ratio is about 20% ionic surfactant. The observed decrease in self-diffusion coefficients as nonionic surfactant was replaced by ionic surfactant is interpreted to mainly be due to an increased micelle-micelle repulsion. The increase in self-diffusion coefficients occurring at higher fraction of ionic surfactant is shown to be due to a decrease in micelle size. For the $C_{12}EO_8$ system, the effect of the surfactant mixing ratio is much weaker which can be understood by considering the molecular geometry and large headgroup area. The proton NMR line widths correlate well with the self-diffusion coefficients and broadening of the alkyl chain methylene signals is found when the self-diffusion coefficients is low.

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Assessment of Recovery of Chloride Penetration Resistance of Self-healing Cement Mortars Containing Layered Double Hydroxide (이중층수산화물을 혼입한 자기치유 시멘트 모르타르의 염화물 침투 저항성 회복 평가)

  • Kyung Suk, Yoo;Seung Yup, Jang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.600-608
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    • 2022
  • This study investigates the effect of layered double hydroxide (LDH) on the healing performance of self-healing concrete by assessing the chloride penetration resistance of self-healing cement mortars using electrical chloride ion migration-diffusion test. Test results show that both mortars containing healing materials only and mortars containing healing materials and Ca-Al LDH together mostly had higher migration-diffusion coefficients right after cracking, but the migration-diffusion coefficients decreased more than that of OPC with increasing healing ages, and thus, they yielded higher healing capacities than OPC. Also, mortars containing Ca-Al LDH together with healing materials showed higher reduction of their migration-diffusion coefficients, and thus, higher healing capacities than mortars containing healing materials only. This suggests that as the self-healing product increases on the crack surface, the binding of chloride ions by LDH inside the crack increases.