• Title/Summary/Keyword: 자기치유재료

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A Study on the Development of Self-Healing Smart Concrete Using Microbial Biomineralization (미생물의 생체광물형성작용을 이용한 자기치유 스마트 콘크리트 개발에 관한 기초연구)

  • Kim, Wha-Jung;Kim, Sung-Tae;Park, Sung-Jin;Ghim, Sa-Youl;Chun, Woo-Young
    • Journal of the Korea Concrete Institute
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    • v.21 no.4
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    • pp.501-511
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    • 2009
  • This study was conducted to develop self-healing ability of concrete so that inspection could be available even in the event of minute cracks without complex works at any time for more economic concrete structure maintenance and longevity. A completely different method has been carried out in comparison with many of similar researches on self-healing concrete. This is a basic study on the development of self-healing concrete using microbial biomineralization. Compounds were generated except for cells by precipitation reaction of CaC$O_3$ during the microbial metabolism and we examined the use as a binder that hardens the surface of sand using biomineralization that Sporosarcina pasteurii precipitates CaC$O_3$. In result, the formation of new mineral and hardening of sand surface could be verified partly, and it was available for cracks to be repaired by calcite with organic (microorganism) and inorganic (CaC$O_3$) complex structure through the basic experiment a little bit. Therefore the use of biomineralization by this sort of microbial metabolism for concrete structure helps to develop absolute repair-concrete like this concrete with microorganism. The effect of microbial application will be one of the most important research tasks having influence on not only repair for concrete structure but also development of new materials able to reduce environmental problems.

Repair methods of water leakage cracks using crack self-healing technologies for subway tunnels (균열자기치유 기술을 적용한 지하철 터널 누수공사)

  • Ahn, Tae-Ho;Bang, Sin-Young;Kim, Jeong-Mi;Shim, Kwang-Bo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.05a
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    • pp.15-16
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    • 2015
  • In this research, the application of repair methods of water leakage cracks using self-healing technologies for subway tunnels is presented. In order to apply crack self-healing water stop agents and quick setting agents in subway tunnels, laboratory and field tests were performed based on various previous researches. Especially, this study focused on development of crack repair materials and their new repair methods. Therefore, various repair materials were examined for new repair materials with self-healing capability applied to crack sealing method and to patching repair method.

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New maintenance method of concrete micro crack using repair stick with self-healing capability and manufacture of repair stick containing the self-healing ingredient (균열자기치유조성물을 함유한 균열보수스틱 제조 및 그를 이용한 새로운 콘크리트 미세균열 보수방법)

  • Ahn, Tae Ho;Kim, Hong Gi;Kim, Kyung Min;So, Kwang Ho
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.111-112
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    • 2014
  • This research focuses on the study that micro-crack of concrete is repaired to use self-healing technology. Self-healing concrete is widely studied in domestic and international construction field recently. Micro-crack(less than 0.3mm)of concrete is repaired using a crack repair stick which containing self-healing agents. Therefore, the crack on construction structure will be easily repaired by using a crack repair stick. Also experiment was proceeded because of evaluating the long term durability.

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Self-healing Performance Evaluation of Cement Mortar with Inorganic Additives Based on Clinker Binder (클링커 바인더 기반 무기계 혼합재를 활용한 시멘트 모르타르의 치유성능 평가)

  • Jung-Il, Suh;Yoon-Suk, Choi;Byung-Sun, Park;Kwang-Myong, Lee
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.561-568
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    • 2022
  • In this study, the mechanical properties and self-healing performance of cement mortar containing clinker binder, calcium sulfoaluminate(CSA), and sodium sulfate(Na2SO4) were evaluated. The mechanical properties of cement mortar were investigated by measuring compressive strength and flexural strength, and the healing performance was evaluated through hydrostatic water permeability test and gas diffusion test. In addition, the healing products precipitated in the cracks were visually observed through an optical microscope and a scanning electron microscope(SEM). As a result, the incorporation of the clinker binder-based inorganic additives improved the initial and 28-day strength by about 20 %. Depending on the healing performance evaluation method, there was a difference in the healing rate, and the healing rate showed a tendency to be underestimated. Nevertheless, CaCO3 was precipitated as the main healing product inside the 0.3 mm crack when the inorganic additives were mixed with cement mortar, improving the self-healing performance.

Effects on the Magnetic Property Changes due to the defect in the Nuclear Reactor Vessel Material Irradiated by Fast Neutron (고속 중성자 조사에 의한 원자로 용기재료내의 결함생성이 자기적 특성변화에 미치는 영향)

  • Jeong, Myeong-Mo;Kim, Gil-Su;Jang, Gi-Sang;Yu, Geun-Bae;Park, Deok-Geun;Kim, Gil-Mu;Yun, In-Seop;Hong, Chi-Yu
    • Korean Journal of Materials Research
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    • v.9 no.12
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    • pp.1240-1244
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    • 1999
  • In order to assess the effects on the magnetic properties due to the defect in the material irradiated by fast neutron ranging $10^0-10^{18}n/cm^2$, the magnetic properties such as maximum magnetic induction, coercivity, remanence, Barkhausen Noise Amplitude(BNA), Barkhausen Noise Energy(BNE) and hardness were measured. It is shown that the magnetic properties and hardness do not change by the fast neutron irradiation under $10^{17}n/cm^2$. Therefore, in this experiment, it is understood that the magnetic properties decrease by the increase of hardness. This measurement method can be used to evaluate the neutron irradiation embrittlement nondestructively since the magnetic properties and hardness do change by the neutron irradiation over $10^{17}n/cm^2$ consistently.

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Evaluation of the stability of sandblasted, large-grit, acid-etched implants with tapered straight body design (테이퍼드 직선형 SLA 임플란트의 안정성 평가)

  • Kim, Yong-Gun;Lee, Kyu-Bok
    • Journal of Dental Rehabilitation and Applied Science
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    • v.34 no.2
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    • pp.80-88
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    • 2018
  • Purpose: Implant surface modification and implant design are the principle targets for achieving successful primary stability. The aim of this study was to measure implant stability quotient (ISQ) values of sandblasted, large-grit, acid-etched (SLA) implants with tapered straight body design during the healing period, and to determine the various factors affecting implant stability. Materials and Methods: To measure implant stability, resonance frequency analysis (RFA) was performed in 26 patients (13 women and 13 men) with 44 SLA implants with tapered straight body design. Implant stability (ISQ values) was evaluated at baseline and healing abutment connection (12 weeks), and the correlations between RFA and insertion torque (IT), bone quality, and jawbone were determined. Results: The mean ISQ value of the implants was $69.4{\pm}10.2$ at the time of implant placement (baseline) and $81.4{\pm}6.9$ at the time of healing abutment connection (P < 0.05). Significant differences were found between RFA and bone quality and between RFA and jawbone (P < 0.05). No significant differences were found between RFA and IT, insertion area, fixture diameter, and implant length (P > 0.05). Conclusion: ISQ values of SLA implants with tapered straight body design were high at baseline and healing abutment connection. It was concluded that SLA implants with tapered straight body design show improved primary and secondary stability, and that immediate or early loading may be applicable.

Performance Evaluation of Chloride and Sulfate Removal using Anion Exchange Resin in Saturated Ca(OH)2 Solutions (음이온 교환수지를 이용한 포화 수산화칼슘 수용액 내 염소이온 및 황산이온 제거 특성 평가)

  • Lee, Yun-Su;Chen, Zheng-Xin;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.2
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    • pp.146-154
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    • 2017
  • Recently, self-healing concrete has been researched as maintenance and repair of concrete structures are important challenges we face. This paper focused on possibility of ion exchange resin as a novelty material directly and actively controlling harmful ions of concrete, whereas most self-healing concrete researches have been focused on methods to automatically filling and repairing internal crack of concrete. Because equilibrium properties between ion exchange resin and harmful ion is important before design of cement mixing proportion, it was conducted to remove chloride or sulfate in saturated $Ca(OH)_2$ solutions containing NaCl or $Na_2SO_4$. The removal performance was analyzed using kinetic equation and isothermal equation. Consequently, the removal properties of anion exchange resin were relatively more dependent on pseudo second reaction equation and Langmuir equation than pseudo first reaction equation and Freundlich equation. And it was concluded that each chloride and sulfate can be removed to the maximum 1068 ppm and 1314 ppm.

Study of the Nondestructive Test Method for the Embrittlement Evaluation of Nuclear Reactor Vessel Material by $M{\ddot{o}}ssbauer$ Spectroscopy ($M{\ddot{o}}ssbauer$ 분광법에 의한 원자로 용기재료의 비파괴적 중성자 조사평가에 대한 연구)

  • Jung, M.M.;Jang, K.S.;Yoo, K.B.;Kim, G.M.;Yoon, I.S;Hong, C.Y.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.3
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    • pp.183-190
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    • 2000
  • The purpose of this study is to evaluate the magnetic property change of the nuclear reactor vessel steel irradiated by fast neutrons using $M{\ddot{o}}ssbauer$ spectroscopy, and the effects of the defects produced by neutron irradiation on the changes using X-ray diffraction. The specimens, fabricated with the dimension of $23mm{\times}18mm{\times}70{\mu}m$, were irradiated by neutron fluence from $10^{12}n/cm^2\;to\;10^{18}n/cm^2$ at 343K. Throughout the experiments, it is understood that (1) the X-ray diffraction measurement shows that the change of crystal nature is started at the irradiation of $10^{16}n/cm^2$ and a crystal structure has been severely damaged at the irradiation over $10^{17}n/cm^2$, (2) the analysis of the $M{\ddot{o}}ssbauer$ spectra has shown that magnetic transition phenomena occur at the irradiation over $10^{17}n/cm^2$ and (3) both methods can be utilized as nondestructive test methods for the embrittlement evaluation of materials irradiated by fast neutrons.

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Preparation and Characterization of Functional Microcapsules Containing Suspensions of Conducting Materials (전도성 물질 서스펜션을 함유한 마이크로캡슐)

  • Ihm, DaeWoo;Kwon, Won Ho
    • Applied Chemistry for Engineering
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    • v.26 no.1
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    • pp.40-46
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    • 2015
  • Microcapsules containing the suspension of conducting materials such as carbon nanotube (CNT) or polyaniline (PANI) were prepared by in-situ polymerization of melamine and formaldehyde. Stable microcapsules were prepared and the mean diameter of the observed microcapsules was in the range of $10-20{\mu}m$. The surface morphology and chemical structure of microcapsules were investigated using optical microscope (OM), scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). The thermal properties of samples were investigated by thermogravimetric analysis (TGA). The conductivity of ruptured microcapsule containing the suspension of CNTs or PANIs in tetrachloroethylene and Isopar-G was measured. As the amount of CNTs and PANIs in the core of microcapsules increased, the measured current increased. Conductivity measurement results suggest that poly (melamine-formaldehyde) based core-shell microcapsules could be applied to self-healing electronic materials systems, where CNTs or PANIs bridge a broken circuit upon release.

The effect of Ca-P coated bovine bone mineral on bone regeneration around dental implant in dogs (개 모델에서의 임플란트 주위 골결손시 Ca-P 표면 처리된 이종골의 효과)

  • Cho, Su-Yeon;Jeon, Hye-Ran;Lee, Sun-Kyoung;Lee, Seoung-Ho;Lee, Jun-Young;Han, Geum-A
    • Journal of Periodontal and Implant Science
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    • v.36 no.4
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    • pp.913-923
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    • 2006
  • 목적 : 최근 발치 후 즉시 임플란트 식립은 널리 사용되는 수술 방식이다. 이 연구의 목적은 임플란트 주위 골결손시 Ca-P으로 표면 처리된 이종골을 사용하여 골재생을 평가하기 위함이다. 재료와 방법 : 두 마리의 개 모델에서 하악 소구치와 제일 대구치를 발치하였다. 발치 6주 후 trephine bur를 이용하여 7.5 mm 지름과 5 mm 깊이를 가진 결손부를 형성하였다. 이 후 이 결손부의 중앙에 3.5 mm 지름과 15mm 길이의 fixture(GS II)를 식립하였다. 결과적으로 임플란트와 주변을 둘러싸고 있는 골 사이에는 2.0 mm정도의 gap이 만들어진다. 준비된 결손부 내로 자기골 또는 $Biocera^{(R)}$를 채웠다. 각각 4주, 8주 후 조직 절편을 제작하였다. 조직학적 평가를 위해 Block biopsy를 시행하였다. 결과 : 두 집단 모두 임상적으로 골이 완전히 채워졌다. 자가골이 이식된 부위(control)의 평균 골-임플란트 접촉(BIC)은 각각 4주째 $28.2{\pm}19%$였고, 8주째 $44.9{\pm}9%$였다. $Biocera^{(R)}$가 이식된 부위(test)의 평균 BIC는 각각 4주째 $34.6{\pm}27%$였고, 8주째 $27.6{\pm}23%$였다. 자가골이 이식된 부위(control)의 평균 골밀도는 각각 4주째 $32.7{\pm}25%$, 8주째 $37.4{\pm}17%$였다. 골-임플란트 접촉(BIC)과 골밀도의 평균 비율(%)은 비슷하였다. 조직학적으로 자가골과 이종골 이식 부위 모두 주변골과 잘 조화를 이루었고 유사한 치유 양상이 관찰되었다. 자가골과 이종골 이식 부위간 유의한 차이는 없었다.(P>0.05) 결론 : 임플란트 주위 2 mm의 골 결손부위에 자가골 또는 이종골로 채운 경우 유사한 결과를 얻었다. 이 결과 임플란트 fixture 주위의 골 결손부 해소를 위해 자가골을 대체할 수 있는 재료로 $Biocera^{(R)}$를 사용할 수 있음을 보여준다.