• Title/Summary/Keyword: 자기적성질

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A Research on the Recycling of Ceramic Wastes as an Aggregate for Concrete (窯業廢棄物을 콘크리트용 骨材로 再活用하기 위한 硏究)

  • 문한영;김기형;신화철
    • Resources Recycling
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    • v.10 no.2
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    • pp.41-49
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    • 2001
  • In this study, the properties of cement mortar and concrete using ceramic wastes as fine aggregates and coarse aggregates are considered experimentally. Flow value of mortar using ceramic waste as fine aggregates is increased more or less, and the com- pressive strength of mortar using ceramic wastes as fine aggregates is increased with elapsed age. The slump value of concrete using ceramic wastes fine aggregates and coarse aggregates is somewhat decreased. The compressive strength of concrete using ceramic wastes as fine aggregates and coarse aggregates is lower than that of OPC concrete in early age, but has gradually increased in long ages.

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A study on the magnetic properties of high Tc superconductor $Y_{1-x}Yb_xBa_2Cu_3FyOy$ (고온 초전도체 $Y_{1-x}Yb_xBa_2Cu_3FyOy$의 자기적 성질에 관한 연구)

  • 김재욱;김채옥
    • Electrical & Electronic Materials
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    • v.9 no.6
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    • pp.578-583
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    • 1996
  • The magnetic properties have been investigated for the system of $Y_{1-x}$Yb$_{x}$Ba$_{2}$Cu$_{3}$F$_{y}$O$_{y}$ with x=0.0, 0.1, 0.2, 0.3, 0.4 and 0.5. In the magnetic hysteresis measurements, the values of the magnetic critical current densities are in the range of 10$^{4}$-10$^{5}$ A/cm$^{2}$ at the maximum external field 1.4 T. The upper critical field is over 100 T. The critical current density is estimated by the magnetization width .DELTA.M through the Bean critical state model. As the field strength is increased, the .DELTA.M diminishes slowly. The .DELTA.M for the fluorinated sample also decreases slowly with increasing field. It is considered that the large J, value results from this type is due to enhanced pinning center in grain boundary.y.ary.y.

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Evaluation for dispersive refractive indices in IR regions of amorphous and crystalline $Ge_2Sb_2Te_5$ thin films (비정질 $Ge_2Sb_2Te_5$ 박막의 IR 영역에서의 복소굴절률 평가)

  • Kim, Jin-Hee;Lee, Hyun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.334-345
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    • 2008
  • 컴퓨터의 발달과 더불어 현대사회는 기록하고 보존해야할 정보의 양이 점점 방대해 지고 있다. 그로 인해 자기기록매체처럼 정보를 사용자의 편의에 따라 반복적으로 기록하고 재생할 수 있는 광기록매체에 대한 관심이 증가되고 있다. $Ge_2Sb_2Te_5$(GST)는 기존의 CD-RW나 Floppy Disk(FD)를 대체할 차세대 기록매체로 주목받고 있다. 따라서 본 연구에서는 비정질상과 결정상으로 변하는 성질을 가지고 있는 GST롤 상변화 기록매체로서 이용하기 위해 굴절률을 평가하였다. 시료는 5N의 순도를 갖는 Ge, Sb, Te 물질을 준비하고 조성비에 맞추어서 석영관에 진공 봉입한 후 용융-냉각법으로 벌크를 제작하였고 열증착 방법으로 Si 및 유리 기판위에 1000nm 두께로 박막을 제작하였다. UV-Vis-IR spectrophotometer를 사용하여 반사도와 투과도를 측정하였고 측정한 스펙트럼을 이용하여 Swanepoel method로 굴절률을 계산하였다. 본 연구진이 자체 개발한 계산툴에 실험값을 대입하였고 실험에 의해 얻은 투과도와 계산툴에 의해 얻은 투과도 스펙트럼을 비교하였다.

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Nanohybridization of Polyoxometalate and Nanomaterials for Electrochemical Application (전기 화학 응용을 위한 폴리옥소메탈레이트와 나노물질의 나노하이브리드화)

  • Yang, MinHo;Choi, Bong Gill
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.363-368
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    • 2018
  • Polyoxometalates (POMs) have outstanding properties and a great deal of potential for electrochemical applications. As POMs are highly soluble, the implementation of POMs in various functional materials is required to fully use their potential in electrochemical devices. Here, we will review the recently developed immobilization methods to incorporate POMs into conductive nanomaterials, such as nanocarbons and conducting polymers. Various immobilization strategies involve POMs entrapped in conducting polymer matrix and integration of POMs into nanocarbons using a Langmuir-Blodgett technique, a layer-by-layer self-assembly, and an electrochemical in-situ polymerization. In addition, we will review a variety of electrochemical applications including electrocatalysts for water oxidation, lithium-ion batteries, supercapacitors, and electrochemical biosensors.

Effect of the grain boundary on the magnetic properties of the multi-seeded melt growth processed YBCO superconductors (다중종자결정성장법으로 제조한 YBCO 초전도체의 결정입계에 따른 자기적 성질의 영향)

  • Kim, Chan-Joong;Joo, Jin-Ho;Han, Young-Hee;Han, Sang-Chul;Sung, Tae-Hyun;Hong, Gye-Won;Kim, Ho-Jin
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.293-297
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    • 2000
  • Multiseeding with (100)/(100) grain junctions of top-seeded melt growth (TSMG) processed YBCO superconductors was studied. The effect of the number of seeds and the distance between two seeds on the levitation forces and the trapped magnetic fields of the TSMG-processed YBCO samples was investigated. Multiple seeding shortened the processing time for the fabrication of TSMC-processed YBCO superconductors. The large magnetic field was trapped at the grain junction when two seeds was placed without spacing, while the amount of the magnetic field decreased when the seed distance increased. This is attributed to the increased amount of the residual melt phases around the grain junctions.

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Magnetic properties of $MgB_2$ and FeTi composites (Mg$B_2$와 FeTi 합성체의 자기적 성질)

  • 이헌봉;이준호;김영철;정대영
    • Progress in Superconductivity
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    • v.5 no.2
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    • pp.109-113
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    • 2004
  • MgB$_2$ and FeTi composites was prepared to study the effect of FeTi particles on superconductivity of MgB$_2$. The sample, which had contained magnesium, boron and FeTi particles, was synthesized by the Commercial Stainless Steel Tube Enveloping Technique(COSSET) at 92$0^{\circ}C$ for 2 hours. The structure and properties of the sample was investigated by XRD, SEM, and SQUID magnetometer. It was found that there was a little change of T$_{c}$ compared with pure MgB$_2$ superconductor in spite of high percentage of FeTi particles, and there was no proof of structure change of MgB$_2$ superconductor due to FeTi particles. But the high porosity which was appeared in the pure MgB$_2$ was disappeared in the composites. We conclude that FeTi particles do not influence the superconductivity of MgB$_2$ and it is expected that fe-Ti material system will be a good material for a tube of the PIT process and for a substrate of the film.m.

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The Crystallographic Structure and Magnetic Properties of Mg1-xZnxFeAlO4 (Mg1-xZnxFeAlO4의 결정학적 구조 및 자기적 성질)

  • Ko Jeong-Dae;Hong Sung-Rak
    • Korean Journal of Materials Research
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    • v.15 no.6
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    • pp.393-398
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    • 2005
  • The crystal structure and magnetic properties of the $Mg_{1-x}Zn_xFeAlO_4\;(0{\leq}x\leq1.0)$ have been investigated by means of x-ray diffractometry and $M\ddot{o}ssbauer$ spectroscopy. The samples$(0{\leq}x\leq1.0)$ have been prepared by the ceramic sintering method. The x-ray diffraction pattern shows that the crystal structure of the samples is a cubic spinel type. The lattice constant has been found by extrapolation using the Nelson-Riley function and it increases slightly from $8.3496\AA\;to\;8.4128\AA$ with Zn concentration. The $M\ddot{o}ssbauer$ spectra for x<0.4 show a superposition of two sextets ana a paramagnetic doublet at room temperature. The superparamagnetic doublet for x<0.4 seems to be due to Al ion in tetrahedral site by the superparamagnetic clustering effect.

A Study of Structures and Magnetic Properties of Electrodeposited Fe-45 wt%Ni-P Alloys (전착법에 의한 Fe-45 wt%Ni-P 합금의 조직과 자기적 성질에 관한 연구)

  • 구승현;이흥렬;김동환;황태진;임태홍
    • Journal of the Korean institute of surface engineering
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    • v.36 no.6
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    • pp.461-465
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    • 2003
  • The microstructures and magnetic properties of electrodeposited Fe-45 wt%Ni-P alloys have been investigated. The structures of electrodeposited Fe-45 wt%Ni alloy was FCC i.e. ${\gamma}$ phase and the size of crystallite was 10 nm. The structure of electrodeposited Fe-45 wt%Ni-1 wt%P alloy showed ${\gamma}$ phase and 7 nm sized nanocrystalline. The electrodeposited Fe-45 wt%Ni-P alloys containing 2∼3 wt% of P exhibited ${\gamma}$$\alpha$ dual phases. The electrodeposited Fe-45 wt%Ni-P alloys above 3.5 wt% showed an amorphous structure. P in the alloys acted grain refining and phase changing element. The resistivity of the electrodeposited alloys increased with P contents. Effective permeability at high frequency (above 1 MHz) increased with P contents up to 2 wt% and this was ascribed to the easier magnetization rotation owing to the reduction of eddy current. Effective permeability decreased with P contents above 3 wt% and this was ascribed to the transformation of the ferromagnetism of Fe-45 wt%Ni alloy gradually into paramagnetism with the introduction of P into the electrodeposited alloy matrix.

Studies on Magnetic Properties of Die-upset Pr-Fe-B Magnets (Die-upset법에 의한 Pr-Fe-B자석의 자기적 성질에 관한 연구)

  • 이경섭;서수정;박현순;이병규;정지연
    • Journal of the Korean Magnetics Society
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    • v.3 no.3
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    • pp.201-207
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    • 1993
  • Starting ingot of $Pr_{15}Fe_{77}B_{8}$ were prepared by vacuum induction melting under argon atmosphere. The ingot were induction melted in a quartz crucible and then ejected as a molten alloy throuth a 0.6 mrn orifice onto a rotating cop¬per wheel. An anisotropic magnet was prepared from ribbon by hot deformation techniques. A fully dense precursor magnet first made by pressing ribbons at $680^{\circ}C$ under a pressure of $21.8\;kg/mm^{2}$. A substantially oriented magnets were obtained by die-upset under various conditions. As the compression ratio increases, the $B_{r}$ value increases pronouncedly though $_{i}H_{c}$ decreases. Also, XRD analyses show increased diffraction peak from (006). From these results, it can be known that the magnetic easy axis was formed along the compression axis. As the die-upset speed increases, $_{i}H_{c}$ increases though $B_{r}$ decreases. The $B_{r}$ increases up to $750^{\circ}C$ of die-upset temperature and above this temperature decreases. The value of $4{\pi}M_{s}$ of the $Pr_{15}Fe_{77}B_{8}$ alloy prepared is found to be 11.8 KG. When the alloy was compressed by 0.8 under the die-upset speed of 0.05 m/sec at $750^{\circ}C$, $B_{r}$ was 11.0 KG indicating that the alloy has excellent magnetic anistropy. However, this alloy has some limitation because of low $_{i}H_{c}$.

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Superparamagnetic Properties of γ-Fe2O3 Nanoparticles (초미세 나노분말 γ-Fe2O3의 초상자성 특성연구)

  • Lee, Seung-Wha;Lee, Jae-Gwang;Chae, Kwang-Pyo;An, Sung-Yong
    • Journal of the Korean Magnetics Society
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    • v.20 no.5
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    • pp.196-200
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    • 2010
  • $\gamma-Fe_2O_3$ nanoparticles have been prepared by a sol-gel method. The structural and magnetic properties have been investigated by XRD, VSM and Mossbauer spectroscopy. $\gamma-Fe_2O_3$ powder annealed at $150^{\circ}C$ has a spinel structure and superparamagnetical behavior. The estimated size of superparammagnetic $\gamma-Fe_2O_3$ nanoparticle is around 7 nm. The hyperfine fields at $-261^{\circ}C$ for the A and B patterns were found to be 503 and 485 kOe, respectively. The blocking temperature ($T_B$) of superparammagnetic $\gamma-Fe_2O_3$ nanoparticle is about $-183^{\circ}C$. The magnetic anisotropy constant of $\gamma-Fe_2O_3$ nanoparticle was calculated to be $1.6{\times}10^6ergs/cm^3$. $\gamma-Fe_2O_3$ nanoparticle annealed at $150^{\circ}C$ can be a candidate for biomedicine applications as magnetic carriers.