• Journal of Surface Science and Engineering
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• v.23 no.3
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• pp.150-159
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• 1990

The magnetic properties of electrodeposited iron and cobalt films on porous aluminum oxide film were examined. There exists perpendicular magnetic anisotropy due to the shape anisotropy. The coercivity and squareness ratio of films were strongly dependent on deposited particle diameter. The effect of packing fraction on squareness ratio was also apprecible. Unlike the iron-deposited films, the magnetic properties of cobalt films were changed by preferred orientation because of it's large crystal ansotropy constant.(about 10 times of Fe) The Fe deposited films were found to be more suitable for perpendicular magenetic recording media bacause perpendicular coercivity, squareness ratio and the ratio of perpendicular coercivity to horizontal ones of iron films are greater than those of cobalt films.

• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.48-48
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• 2000

진공부품에 사용되고 있는 재료는 여러 가지 있으나 회주철품은 진동 감쇄 및 흡진성이 우수하여 소음 발생이 적고, 조직 중에 흑연이 존재하므로 주강에 비하여 자기윤활작용이 있으며, 말차계수가 적어 마찰면의 면입이 높은 경우에도 소손 등의 이상 마멸현상이 적어 진공펌프, 내연기관, 공작 기계등과 같이 강인성과 내마멸성을 요구하는 부품에 많이 이용되어 왔다, 이 회주철도 대별하면 여러 종류가 있고, 진공 펌프용 재질은 주로 회주철 중에 ASTM A형으로 도면에 명기되어 있다. 따라서 본 제품을 개발하는 과정중에 연속 주조법으로 제조된 ASTM형이 기존의 재료에 비하여 내기밀성, 내마면성, 내피로성 및 기계적 성질등이 우수함을 확인하여본 재질로 개발하였고, 시험한 연구 결과를 발표하고자 한다. 실험은 ASTM A형으로 주조하기 위하여 용해된 용탕을 사형 주형에서 GC200으로 주조하고, ASTM D형은 D사의 연속 주조기에서 직경 30mm로 주조하였다. 이와 같이 주조된 사료를 일정한 크기로 시험편을 만들어 인장 강도, 경도, 피로한도, 피로성, 절삭성, 내유압성, 소입성과 내마멸성을 시험하였다.

• Journal of Surface Science and Engineering
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• v.29 no.3
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• pp.195-202
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• 1996

The composition, the microstructure and the magnetic properties(HC and Hk) of Fe-Co-Ni alloy electrodeposits were investigated according to the electrolysis conditions using sulfate bath paddle agitated. The current efficiency of the alloys electrodeposition was considerably low in the range of 16∼50%. The Fe content(wt.%) of the alloy increased from 20% to 57% with current density, while Ni content of them decreased in the range of 70∼24% respectively, and Co content was nearly constant. As a result, Fe/Ni ratio of the alloy increased from 0.3 to 2.0 showing the anomalous codeposition. The structure of the alloy changed from fcc to the mixed one of fcc+bcc with the increase of Fe/Ni ratio. The preferred orientation of the alloy with fcc and bcc structure were (220) and (110) respectively. The alloy with Fe/Ni ratio(0.3∼l.2) had the lowest coercivity of 0.4∼0.8 Oe.

• Journal of the Korean Chemical Society
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• v.42 no.6
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• pp.599-606
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• 1998

Since the discovery of ceramic superconductor the various theoretical developments has progressed but there are no definitive description about the superconducting transition mechanism. In special, both the double transition and the various magnetic phase transition add to the complication of the understanding of HTSC. In this paper, we presented the idea of the two-step mechanism for the superconducting transition in view of the condensation model of electron fluid for superconductivity. And these concepts are successfully applied to the double transition and the magnetic phase diagram of various types of superconductivity. Therefore, both the double transition and magnetic phase transition should be the touchstone of general theory for superconductivity.

• Journal of the Korean Chemical Society
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• v.39 no.5
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• pp.356-363
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• 1995

The chemical behavior of the transition metal (Nb4+ and Mo4+) complexes with organoligand (dichloro-bis(η-cyclopentadienyl) has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemical method. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pairing energy and bond strength was obtained from the spectra of the complexes. These are found to be delocalization, low-spin state, and strong bonding strength. The magnetic dipolemoment are found to be paramagnetic and diamagnetic complexes. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic media. As a result the redox reaction proceses of Nb-C complex was couple-single reaction with diffusion and reaction current one electron process, and also Mo-C complex was couple-single reaction with reaction current of one electron process.

• Journal of the Korean Geophysical Society
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• v.2 no.2
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• pp.123-134
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• 1999

Magnetotelluric responses may be affected by strong anisotropy of the high-conductivity layers (HCL) in the upper mantle or lower crust. We have studied two-dimensional anisotropy MT modelling to examine the effect of high anisotropic media. Electrical properties of a homogeneous anisotropic body are defined by a symmetric conductivity tensor and the problem is described by coupled diffusion equation in the frequency domain. In two-dimensional anisotropic environments, diagonal elements of the impedance tensor have higher values than those in isotropic environments. In some cases, TM mode phases reach more than 90°and apparent resistivities decrease for some frequency range because of telluric distortion. GB decomposition may be used to recover regional responses, but can be affected by the regional anisotropic effect. Considering these results, BC87 dataset was interpreted with a modified anisotropic model.

• Journal of the Korean Electrochemical Society
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• v.8 no.3
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• pp.125-129
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• 2005

We have investigated the electrochemical factors affecting the magnetic properties of hard magnetic CoP nanowires and soft magnetic CoFe nanowires fabricated by ac electrodeposition into self-made AAO(anodic aluminum oxide) nano-templates. AAO template having nano scale pores of high aspect ratio has been prepared through 2-step anodizing of aluminum foil in sulfuric acid. Hard Magnetic properties of CoP nanowires were highly conditional on the applied ac potential which could be a decisive factor to make CoP nanowires made up of either pure hcp crystals or a mixture of hop crystals and fcc crystals. On the contrary to CoFe films, there was no anomalous codeposition in the electrodeposition of soft magnetic CoFe nanowires which exhibited their best saturation magnetization of 238 emu/g at the composition of $Co_{30}Fe_{70}$.

• Journal of the Korean Magnetics Society
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• v.23 no.1
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• pp.1-6
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• 2013

Spin-orbit coupling (SOC) effect is known to be the physical origin for various exotic magnetic phenomena in the low-dimensional systems. Recently, SOC also draws lots of attention in the study on magnetically doped thermoelectric alloys to determine their properties as the thermoelectric application as well as the topological insulator via the exact electronic structures determination near the Fermi level. In this research, aiming to investigate the spin-orbit coupling effect on the structural properties such as the lattice constants and the bulk modulus of the most widely investigated thermoelectric host material, $Bi_2Te_3$, we carried out the first-principles electronic structure calculation using the all-electron FLAPW (full-potential linearized augmented plane-wave) method. Employing both the local density approximation (LDA) and the generalized gradient approximation (GGA), the structural optimization is achieved by varying the in-plane lattice constant fixing the perpendicular lattice constant and vice versa, to find that the SOC effect increases the equilibrium lattices slightly in both directions while it markedly reduces the bulk modulus value implying the strong orientational dependence, which are attributed to the material's intrinsic structural anisotropy.

• Journal of the Korean Magnetics Society
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• v.8 no.6
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• pp.362-368
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• 1998

The magnetic properties, thermal stability and anti-corrosion properties of $Cr_86Al_14$ spin valves multilayers were studied. It was found that the magnetic properties of $Cr_86Al_14$ spin valves depend on the thickness of antiferromagnetic, ferromagnetic and non-ferromagnetic layers. Exchange coupled field ($H_{ex}$) and magnetoresistance ratio (%) showed the largest value of 20 Oe, 2 % in $glass/Cr_{86}Al_{14}(600 $\AA$)/Ni_{81}Fe_{19}(50$\AA$)/Cu(40 $\AA$)/Ni_{81}Fe_{19}(40 $\AA$)$ spin valves. The $H_{ex}$ MR ratios (%) of CrAl and FeMn spin valves were decreased with increasing annealing temperatures and were lost at 150 $^{\circ}C$, 250 $^{\circ}C$ respectively. Based on these result, it was elucidated that CrAl is more thermally stable than FeMn. It was also shown that there was no change of $H_{ex}$ MR ratios in CrAl, while FeMn was changed and lost 15 days later in corrosion resistance test under 35 $^{\circ}C$, 90 % humidity condition. FeMn was found to be pitted and peeled off 15 days later by SEM micrographic analysis.

• Journal of the Korean Magnetics Society
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• v.14 no.2
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• pp.71-75
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• 2004

$\alpha$-LiFe $O_2$ powders have been prepared by a sol-gel method. The crystallographic and magnetic properties were characterized with a x-ray diffractometry, Mossbauer spectroscopy, and vibrating Samples magnetometry. The ${\gamma}$-LiFe $O_2$+LiFe$_{5}$ $O_{8}$ phase is observed in the Samples annealed at $600^{\circ}C$ for 3h in air and $\alpha$-LiFe $O_2$ phase is observed in the Samples annealed at $600^{\circ}C$ for 3 h in $H_2$(5％)/Ar(Bal.) gas atmosphere. The crystal structure of $\alpha$-LiFe $O_2$ is found to be cubic with a lattice a=4.193$\pm$0.0005 $\AA$. The Neel temperature of $\alpha$-LiFe $O_2$ is found to be 130$\pm$3 K.