• Journal of the Korean Chemical Society
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• v.40 no.10
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• pp.649-655
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• 1996

The chemical behaviour of Pt(Ⅱ) and Pd(Ⅱ) complexes with the organic ligand tetramethylenesulfoxide(TMSO) has been investigated by UV/vis-spectrophotometric, magnetic, and electrochemical methods. Two energy absorption bands are observed in the spectra of these complexes. The crystal field splitting energy, spin pairing energy, and bond strength were obtained from the spectra of the complexes. The electronic properties of the complexes are found to be delocalized, and low-spin state. The correlation between ligand and metals were strong bonding strength. These complexes are diamagnetics. The redox reaction processes of the complexes were investigated by cyclic voltammetry in an aprotic solvent. The redox processes of complexes turned out to be respect to one-electrton one step. These complexes were considerably diffusion and reaction controlled.

• Proceedings of the Computational Structural Engineering Institute Conference
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• 2009.04a
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• pp.323-326
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• 2009

콘크리트의 보강재로 높은 인장 강도와 비부식성, 비자기성, 비전기성 등의 장점을 갖는 FRP의 사용에 대한 연구가 활발히 진행되고 있다. 하지만 FRP가 갖는 낮은 탄성계수와 취성적 성질로 인해 기존 설계방법을 적용하기에는 문제가 있다. 본 연구에서는 보강비 변화에 따른 AFRP 보강 콘크리트 보의 구조 실험을 수행하여 FRP 보강근을 사용한 콘크리트 부재의 휨 성능 연구에 대한 기초적 자료를 제공하고자 하였다. 각 실험체의 결과 데이터를 비교 분석한 결과 균형보강비를 기준으로 저보강 실험체는 FRP의 파단에 의해 급격한 파괴양상을 보인 반면에, 과보강 실험체는 콘크리트가 압괴하는 파괴 징후를 보이며 파괴에 도달하였다. FRP 보강근을 사용한 보 부재의 설계에 균형보강 이상의 설계가 요구되며, 과보강의 경우 고강도 콘크리트의 사용이 요구되는 것으로 분석되었다.

• Korean Journal of Materials Research
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• v.13 no.2
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• pp.81-87
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• 2003

Microstructures and mechanical properties of variously heat treated 0.85% carbon steel(eutectoid steel) were evaluated by magnetic property measurements. Microstructural analysis (pearlite interstellar spacing), measurement of mechanical properties(Rockwell hardness, yield stress, fracture stress) and magnetic properties(coercivity, remanence, hysteresis loss, saturation magnetization) were performed to clarify mutual relationships among these parameters. Water quenched specimens with martensite structure showed much higher coercivity and remanence than air cooled or furnace cooled specimens with pearlite structure. The linear dependence of coercivity and remanence on pearlite interlamellar spacing as well as on Rockwell hardness, yield stress and fracture stress was observed in the pearlitic steel. Hysteresis loss and saturation magnetization showed no distinct trend with pearlite interlamellar spacing.

• Journal of the Korean Ceramic Society
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• v.17 no.2
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• pp.89-95
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• 1980

The effect of non-stoichimetry and sintering temperature on the magnetic properties of materials in the system $Ni_{0.39}Zn_{0.61}Fe_{2.0+x}O_4$ have been investigated. The value of x used in initial weighing of oxides were varied from -0.04 to -0.12. The value of x, however, appears to be from +0.04 to -0.04 after ferrite powder preparation due to iron pick up during ball mill mixing and grinding. The densities of specimens which were deficientinrion were higher than those with excess ion. Specimens with near stoichiometric composition showed maximum initial permeability an dminimum coercivity whereas high values of quality factor (Q) were observed in iron deficient specimens. The quality factor decreased monotonically with increasing sintering temperature, but the permeability showed maxima with increasing sintering temperature. Thus highest value of figure of merit $\mu$Q was obtained in composition $Ni_{0.39}Zn_{0.61}Fe_{1.98O4}$ sintered at 100$0^{\circ}C$ for 3 hrs. in an air atmosphere.

• Journal of Astronomy and Space Sciences
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• v.11 no.1
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• pp.93-106
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• 1994

A three-dimensional box model has been developed to study the MHD wave coupling in the magnetosphere. In this model, the effects of the ring current are included by assuming the pressure gradients in the MHD equations. It is found that the axisymmetric ring current may play an important role in producing spectral noises in compressional waves, while field line resonances have no such disturbances. These results may explain the current observational characteristics that compressional cavity modes hardly appear in the satellite experiment, while field line resonances often occur. Our numerical resluts also suggest that any discrete spectral peaks such as the global cavity modes can hardly occur where the pressure distribution of the ring current becomes important. The continuous band of transverse waves is found to be unperturbed until the ring current becomes significantly asymmetric with respect to the dipole axis. In addition, our results in the absence of the pressure gradient are found to be consistent with the previous results from the box-like and dipole models.

• Korean Journal of Materials Research
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• v.2 no.3
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• pp.197-201
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• 1992

The temperature dependence of the magentic moment was determined for the system of high $T_{c}$ superconductor $Y_{1-X}Sm_{x}Ba_2Cu_3O_{7-y}$ with x=0, 0.2, 0.4, 0, 6, 0.8 and 1.0. Also the magnetic susceptibility and the magnetic critical current density were measured from the magnetic hysterisis loops obtained at 30 K. From the results of the magnetic susceptibility measurements, the high $T_{c}$ phase were ranged from 14.7 to 49.1%. The values of the magnetic critical current densities were in the range of $10^3~10^4A/cm^2$. The penetration depth was approximately ninety times larger than the coherence length.

• Korean Journal of Materials Research
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• v.5 no.8
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• pp.1040-1044
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• 1995

Magnetic garnet films of (YSmLuCa)$_3$(FeGe)$\_$5/O$\_$12/ have been grown by the liquid phase eqitaxy method on the substrate of non-magnetic garnet Gd$_3$Ga$\_$5/O$\_$12/. The variation of Sm ion concentration were varied 0.3, 0.4, 0.6, mole/formula unit respectively. The magnetic properties of the samples for the bubble magnetic materials, such as, line width ΔH of ferromagnetic resonance (FMR), magnetic saturation induction 4$\pi$Ms, wall mobility u$\_$w/ uniaxial magnetic anisotropy energy Ku, were measured and discussed the relations between these properties. The line width ΔH decreases with increasing 4$\pi$Ms, and with decreasing Sm concentration. The anisotropy energy Ku increases not only with increasing Sm ion concentration, but also increasing 4$\pi$Ms. The value of wall mobility u$\_$w/ increase with increasing 4$\pi$Ms and decreases with increasing Sm concentration. We define a physical constant Eι from the fact that the product of 4$\pi$Ms and ΔH is constant with dimension of energy density. The Eι is dependent only on Sm concentration.density. The Eι is dependent only on Sm concentration.

• Journal of the Korean Magnetics Society
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• v.25 no.4
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• pp.106-110
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• 2015

We have studied electronic and magnetic structure of 2 kinds of diiron molecules using OpenMX method based on density functional method. The calculated density of states of diiron-2 is similar with that of diiron-4 because of equal number of 6 ligand atoms. The calculated total energy with antiferromagnetic spin configuration is lower than those of ferromagnetic configurations for both of them. The exchange interaction J of diiiron-4 between $Fe^{+3}$ atoms is one order larger than that of diiron-2, and the calculated J matches well with the experimental one. That comes from the short distance of Fe-O and the high O 2p energy levels. It derives a strong super exchange interaction. The angle of diiron-4 between Fe atoms is bigger than that of diiron-2. It also derives a strong super exchange interaction because of the ${\sigma}$-bond between Fe and O atoms.

• Journal of the Korean Magnetics Society
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• v.2 no.1
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• pp.22-28
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• 1992

Barium ferrite thin films were reactively deposited with Fe and BaO composite targets by a facing tergects sputtering unit. When thermally oxidized silicon wafers were used as substrates, minimum substrate heating of $750^{\circ}C$ was necessary for the perfect c-axis alignment in barium ferrite films. To lower the critical substrate temperature for the good c-axis alignment, such seed layers as ZnO, ${\alpha}-Fe_{2}O_{3}$ and ${\gamma}-Fe_{2}O_{3}$ were tested. The excellent c-axis algnment of BaM was obtained at a substrate temperature of $600^{\circ}C$ on ZnO seed layer whose (002) plane was parallel to the substrate surface. The magnetic properties of the BaM film showed saturation magnetization of 295 emu/cc, perpendicular coercivity of 1.7 kOe and squareness of 0.75. Optimum deposition rate of $230\;{\AA}/min$ was obtained with the composite target and this was 5 to 20 times higher than those of other investigators with oxide targets.

• Journal of the Korean Magnetics Society
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• v.8 no.4
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• pp.192-197
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• 1998

The Mossbauer spectra of the $Ni_{1-x}Cd_xFeAlO_4$ system were investigated with the Cd content x at room temperature. The spectra of the samples exhibit various patterns as follows 1) superparmagnetic relaxation for 0$\leq$x$\leq$0.2, 2) ferrimagnetic sextet for 0.3$\leq$x$\leq$0.5, 3) ferromagnetic relaxation for x=0.6, 0.7, 4) paramagnetic doublet for 0.8$\leq$x$\leq$1, with the Cd content x. In the samples with x values from 0 to 0.2, the substituted $Cd^{2+}$ ions transfer the $Al^{3+}$ ions from A-site to B-site mainly. The superparamagnetic relaxation effect and the ferromagnetic relaxation effect are derived from the $Al^{3+}$, $Cd^{2+}$ respectively. The magnetic structure of the $Ni_{1-x}Cd_xFeAlO_4$ system was explained by the Yafet-Kittel model.