• Journal of Adhesion and Interface
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• v.9 no.2
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• pp.24-31
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• 2008

In this work, calcium hydroxide and magnesium carbonate as metal ionic crosslinking agents were used to introduce ionic crosslinking points to the ethylene vinylacetate (EVA) emulsions for the enhancement of water resistance and mechanical properties of emulsion films. The properties of EVA emulsion film were investigated in crosslinking density, thermal features, surface energy, and mechanical properties, such as tensile strength, elongation at break and tear strength. With the increasing content of metal ionic crosslinking agent, the crosslinking density of the EVA emulsion film increases, resulting into the improvement of water resistance. The surface energy and mechanical properties of the EVA emulsion film, however, showed somewhat different behaviors. The highest surface energy, tensile strength, and tear strength were observed when 0.4% for calcium hydroxide and 0.5% for magnesium carbonate was added respectively, because the EVA emulsion containing carboxylic acid forms strong carboxylate-metal bond of ionically-crosslinked system. Therefore, it can be concluded that metal ionic crosslinking agents, such as magnesium carbonate and calcium hydroxide are considered to improve water resistance and mechanical properties of the EVA emulsion.

• Restorative Dentistry and Endodontics
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• v.33 no.2
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• pp.148-161
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• 2008

The purpose of this study was to evaluate the effect of chlorhexidine (CHX) on microtensile bond strength (${\mu}TBS$) of dentin bonding systems. Dentin collagenolytic and gelatinolytic activities can be suppressed by protease inhibitors, indicating that MMPs (Matrix metalloproteinases) inhibition could be beneficial in the preservation of hybrid layers. Chlorhexidine (CHX) is known as an inhibitor of MMPs activity in vitro. The experiment was proceeded as follows: At first, flat occlusal surfaces were prepared on mid-coronal dentin of extracted third molars. GI (Glass Ionomer) group was treated with dentin conditioner, and then, applied with 2 % CHX. Both SM (Scotchbond Multipurpose) and SB (Single Bond) group were applied with CHX after acid-etched with 37% phosphoric acid. TS (Clearfil Tri-S) group was applied with CHX, and then, with adhesives. Hybrid composite Z-250 and resin-modified glass ionomer Fuji-II LC was built up on experimental dentin surfaces. Half of them were subjected to 10,000 thermocycle, while the others were tested immediately. With the resulting data, statistically two-way ANOVA was performed to assess the ${\mu}TBS$ before and after thermo cycling and the effect of CHX. All statistical tests were carried out at the 95 % level of confidence. The failure mode of the testing samples was observed under a scanning electron microscopy (SEM). Within limited results, the results of this study were as follows; 1. In all experimental groups applied with 2 % chlorhexidine, the microtensile bond strength increased, and thermo cycling decreased the micro tensile bond strength (P > 0.05). 2. Compared to the thermocycling groups without chlorhexidine, those with both thermocycling and chlorhexidine showed higher microtensile bond strength, and there was significant difference especially in GI and TS groups. 3. SEM analysis of failure mode distribution revealed the adhesive failure at hybrid layer in most of the specimen. and the shift of the failure site from bottom to top of the hybrid layer with chlorhexidine groups. 2 % chlorhexidine application after acid-etching proved to preserve the durability of the hybrid layer and microtensile bond strength of dentin bonding systems.

• Journal of Adhesion and Interface
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• v.7 no.2
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• pp.26-31
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• 2006

In order to effectively improve interfacial adhesion strength between polypropylene (PP) and jute fiber, we particularly incorporated maleic anhydride grafted PP (MAPP) into the matrix through the environment-friendly process without an additional method of process and had better mechanical performances by providing the alignment into the natural fiber than those of the conventional fabrication technology such as an extrusion or injection molding. We also proposed hot pressing method which applied relatively low shear to the composites and confirmed the chemical bonds among the functional groups of MAPP and jute using FT-IR approach. The concentration of MAPP for maximum tensile strength and modulus was optimized at 3 wt%. Flexural properties had no noticeable tendency to increase with MAPP contents compared to tensile strength, which could probably be explained by the degree in wetting of PP/MAPP matrix.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.05a
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• pp.56.2-56.2
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• 2011

최근 철강, 알루미늄, 이종재료의 접합 등 용접이 어려운 부분에 구조용 접착제의 적용이 증가하고 있는 추세이다. 이를 위해 변성 에폭시레진을 활용한 고접합 강도, 고인성의 구조용 접착제가 연구되어 지고 있다. 피착제의 표면처리는 접합부의 접합강도를 향상시키는 방법으로 알려져 있으나 최근의 구조용 접착제는 표면 전처리 없이도 우수한 접착 특성을 보이는 것으로 기대되고 있다. 본 연구에서는 변성레진에 대해서 각종 표면처리가 접합부 특성에 미치는 영향을 조사하였다. 피착제로는 자동차용 냉연강판인 SPRC440을 사용하였고, 전처리로는 무처리 상태, SiC연마지를 이용한 연마, 아르곤 및 산소가스를 이용한 마이크로웨이브 플라즈마 표면처리, 산세 등의 표면처리를 실시하였다. 에폭시 접착제는 변성 에폭시 레진과 경화제 및 촉매제를 이용하여 직접 포뮬레이션하였다. 단일 겹치기 전단강도 시험과 T-Peel 시험은 각각 ASTM D 1002 규격에 따라 준비하였으며 인장 시험 후 파면은 SEM으로 관찰하였다.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.6D
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• pp.803-810
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• 2011

The public interest of global warming and energy shortage is gradually increased, and the related industries also have become interested in developing eco-friendly material and technology. Warm-mix asphalt (WMA) is a result of the developments to alleviate global warming and energy problems. This WMA is produced at lower temperatures than the temperature at which hot mix asphalt (HMA) is produced. Because most tests in Superpave are developed only for the performance and maintenance of HMA produced by hot temperatures, it is difficult for the tests to identify properly the material properties and then evaluate the performances between HMA and WMA. This study deals with the development of a new protocol to differentiate HMA and WMA performance, and especially the interfacial properties between asphalt and aggregate are targeted as the performance indicator; thus, an evaluation method and guideline are suggested. The concept and idea of the test method applied in this study were modified from the DSR moisture damage test protocol. In addition, TSR test was performed to affirm the relation between the asphalt-aggregate interface and the asphalt-aggregate mixture performances. The followings are the results of this study. Shear stress at 85% linear visco-elastic complex modulus (LVE $G^*$) can be a better parameter than LVE $G^*$, which can assess the interfacial or bonding performance between asphalt and aggregate. Moreover, measuring the bonding performance in thinner film thicknesses will be a better way to evaluate the real and field situation between asphalt and aggregate. The interfacial properties' criteria to apply the newly developed test and parameter should be developed, after the asphalt mixture criteria relating to the interfacial properties are completed.

• Journal of the Korean Society of Clothing and Textiles
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• v.30 no.12 s.159
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• pp.1683-1689
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• 2006

Precedent researches on lyocell are mostly on lyocell structure, characteristics, physical properties by finishing and dyeability, and the like; there are little cases of researches on interlining for lyocell clothes production. To serve as a base information helpful to select fusible interlining and improve the efficiency of sewing process considering the characteristics of lyocell, this study performed t-est, F-test toward to the difference in the appearance-related properties and the mechanical properties of lyocell-interlining bonded fabric in accordance with the characteristics of fusible interlining and lyocell face fabric. This study reached following conclusions. Drapability and Crease recovery of lyocell-interlining bonded fabric are influenced by the structure of fusible interlining; stiffness of lyocell-interlining bonded fabric, by the structure of fusible interlining and the yam number of lyocell face fabric. WT is influenced by the mixture rate and yam number of lyocell face fabric. RT is influenced by the yam number of lyocell face fabric; G, 2HG, 2HG5, by the structure(woven and non-woven) of fusible interlining; B, HB, by the weight, structure(woven and non-woven) of fusible interlining, and yam number of lyocell face fabric; WC, by the weight, structure of fusible interlining; RC, by the structure of fusible interlining; thickness, by the weight of fusible interlining and the yarn number of lyocell face fabric; weight, by mixture rate and yam number of lyocell face fabric.

• Journal of the Microelectronics and Packaging Society
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• v.27 no.3
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• pp.49-54
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• 2020

To attach a stretchable/flexible electrode to something or something to on electrode, conductive adhesives must be stretchable/flexible to suit the properties of the electrode. In particular, conductive adhesive require durability and heat resistance, and unlike conventional adhesives, they should also have conductivity. To this end, Epoxy, which has good strength and adhesion, was selected as an adhesive, and a plasticizer and a reinforcement were mixed instead of a two-liquid material consisting of a conventional theme and a hardener, and a four-liquid material was used to give stretchability/flexibility to high molecules. The conductive filler was selected as silver, a material with low resistance, and for high conductivity, three shapes of Ag particles were used to increase packing density. Conductivity was compared with these developed conductive adhesives and two epoxy-based conductive adhesives being sold in practice, and about 10 times better conductivity results were obtained than products being actually sold. In addition, conductivity, mechanical properties, adhesion and strength were evaluated according to the presence of plasticizers and reinforcement agent. There was also no problem with 60% tensile after 5 minutes of curing at 120℃, and pencil hardness was excellently measured at 6H. As a result of checking the adhesion of electrodes through 3M tape test, all of them showed excellent results regardless of the mixing ratio of binders. After attaching the Cu sheet on top of the electrode through conductive adhesive, the contact resistance was checked and showed excellent performance with 0.3 Ω.

• Journal of the Microelectronics and Packaging Society
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• v.8 no.3
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• pp.25-30
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• 2001

The stress intensity factors for edge cracks located at the bonding interface between the semiconductor chip and the adhesive layer subjected to a uniform transverse tensile strain are investigated. Such cracks might be generated due to a stress singularity in the vicinity of the free surface. The boundary element method (BEM) is employed to investigate the behavior of interface stresses. The amplitude of complex stress intensity factor depends on the crack length, but it has a constant value at large crack lengths. The rapid propagation of interface crack is expected if the transverse tensile strain reaches a critical value.

• Journal of Adhesion and Interface
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• v.11 no.1
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• pp.35-40
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• 2010

In this study, solvent based polyurethane (PU) adhesives were prepared with the hydrocarbon resin and the acrylic modified hydrocarbon resin contents. The solvent based PU adhesive were increased with increasing tackifier concentration. The surface state of films showed good compatibility with increasing the PX-95 concentration but A-1100 series didn't present homogeneous phase more than 10 phr. Mechanical strength and peel strength were maximum at 5 phr tackifier concentration especially PX-95 series in solvent based PU adhesive.

• Composites Research
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• v.27 no.6
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• pp.242-247
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• 2014

The fabrication of flexible electrodes coated on the surface of a dielectric elastomer film, which is a type of electroactive polymer (EAP), was carried out. Controlled amounts of Xylitol powder were added (10, 30, 50 and 70 wt%) to the commercial conductive polymer (PEDOT:PSS) to enhance resilience of the electrode. To check resilience of the fabricated composite electrodes, tensile tests were carried out using silicone films coated with the polymer electrodes. From the test results, it was found that 70 wt% Xylitol containing conductive polymer had excellent elongation and high failure strains. Furthermore, surface of the silicone film was uniformly polished with various abrading papers to enhance the wettability of the conductive polymers on the surface of the silicone film. It was found that the silicone film polished with #120 abrading paper had the best wettability and guaranteed excellent bonding behavior.