• Title/Summary/Keyword: 인장경화

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Hardening State and Basic Properties Changes According to the Mixture Ratio of MMA Resin Used as a Waterproofing Coating Material in Concrete Bridges (콘크리트 교면용 도막방수재로 사용되는 MMA 수지의 배합비율에 따른 경화상태 및 기본 물성에 관한 연구)

  • An, Ki-Won;Kang, Hyo-Jin;Oh, Sang-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.224-234
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    • 2019
  • Waterproof layers are installed in civil engineering structures and bridge construction is commonly finished by applying a layer of regular or asphalt concrete above the waterproof layer. However, asphalt materials are susceptible to melting at high temperature due to its superior temperature sensitivity, and this causes the waterproofing material to melt due to the high temperature of the asphalt concrete, thereby increasing the defect occurrence rate due to the thickness reduction. In this study, tensile strength and elongation of hard and soft type of MMA(Methyl Methacrylate) applied to bridges were compared in accordance to standard performance criteria based on different mixture ratios. Results of comparative testing showed that hard MMA resin can display a satisfactory tensile strength, and soft MMA resin displays satisfactory elongation properties, but as the two resin types are separately used, neither types are able to satisfy the standard requirements outlined in KS F 4932. When the amount of the powder exceeds 56.25% of the total amount, voids are generated on the surface after curing and self leveling was impossible and a heterogeneous surface is formed. Furthermore, when the hard resin: soft resin: powder mixture ratio was set to 15g: 85g: 150g. the tensile strength was $1.5N/mm^2$ and the elongation percentage was 133% which satisfy the tensile performance of KS F 4932.

Chemo-Mechanical Analysis of Bifunctional Linear DGEBA/Linear Amine (DDM, DDS) Resin Casting Systems (DGEBA/방향족 아민(DDM, DDS) 경화제의 벤젠링 사이의 관능기 변화가 물성 변화에 미치는 영향에 대한 연구)

  • 명인호;정인재;이재락
    • Composites Research
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    • v.12 no.4
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    • pp.71-78
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    • 1999
  • To determine the effect of chemical structure of linear amine curing agents on thermal and mechanical properties, standard epoxy resin DGEBA was cured with diaminodiphenyl methane (DDM), diaminodiphenyl sulphone (DDS) in a stoichiometrically equivalent ratio. From this work, the effect of aromatic amine curing agents. In contrast, the results show that the DGEBA/DDS cure system having the sulfone structure between the benzene rings had higher values in the conversion of epoxide, density, shrinkage (%), glass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBA/DDM cure system having methylene structure between the benzene rings, whereas the DGEBA/DDM cure system presented higher values in the maximum exothermic temperature, thermal expansion coefficient, and thermal stability. These results are caused by the relative effects of sulfone group having strong electronegativity and methylene group having (+) repulsive property and stem from the effect of the conversion ratio of epoxide group. The result of fractography shows that the each grain size of the DDM/DGEBA system with feather-like structure is larger than that of the DDS/DGEBA system.

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Chemo-mechanical Analsis of Bifunctional Linear DGEBA/Linear Amine Resin Casting Systems (DGEBA/선형 아민경화제의 주쇄에 포함된 질소 및 탄소원자 개수에 따른 물성 변화 연구)

  • 명인호;정인재;이재락
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.201-210
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    • 2000
  • To determine the effect of chain length of linear amine curing agents on the thermal and mechanical properties, standard epoxy resin, diglycidyl ether of bisphenol A (DGEBA) was cured with diethylenetriamine (DETA), triethylenetetraamine (TETA) and tetraethylenepentaamine (TEPA) in a stoichiometrically equivalent ratio. From this work, the effect of linear amine curing agents on the thermal and mechanical properties was significantly influenced by chain length of curing agents. In contrast, the results showed that the DGEBA/DETA system had higher values than the DGEBA/TETA and DGEBA/TEPA system in the density, shrinkage (%), thermal expansion coefficient, tensile modulus, and flexural strength. Whereas the DGEBA/DETA cure system had lower values than the DGEBA/TETA and DGEBA/TEPA cure system in the maximum exothermic temperature, conversion (%), and T$_{g}$. These findings imply that the differences in the maximum conversion about the chain length of curing agents affect the thermal and mechanical properties.s.

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Effects of Shrinkage Reducing Agent (SRA) Type and Content on Mechanical Properties of Strain Hardening Cement Composite (SHCC) (수축저감제의 종류 및 혼입률에 따른 변형경화형 시멘트복합체의 역학적 특성)

  • Han, Seung-Ju;Jang, Seok-Joon;Khil, Bae-Su;Choi, Mu-Jin;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.28 no.1
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    • pp.41-48
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    • 2016
  • This research investigates the effects of shrinkage reducing agent (SRA) on the mechanical behavior of strain-hardening cement composite (SHCC). SHCC material with specified compressive strength of 50 MPa was mixed and tested in this study. All SHCC mixes reinforced with volume fraction of 2.2% polyvinyl alcohol (PVA) fiber and test variables are type and dosage of shrinkage reducing agents. The shrinkage reducing materials used in this study are phase change material as the thermal stress reducing materials that have the ability to absorb or release the heat. The effect of SRA was examined based on the change in length caused by shrinkage and hardened mechanical properties, specially compressive, tensile and flexural behaviors, of SHCC material. It was noted that SRA reduces change in length caused by shrinkage at early age. SRA can also improve the tensile and flexural strengths and toughness of SHCC material used in this study.

Effect of Curing Conditions on the Mechanical Properties of Strain-Hardening Cement Composite (SHCC) (양생조건에 따른 변형경화형 시멘트 복합체의 역학적 특성)

  • Yun, Hyun-Do;Kim, Sun-Woo;Kim, Yong-Cheol;Jeon, Esther;Kim, Yun-Su;Ji, Sang-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.909-912
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    • 2008
  • Fiber is an important ingredient in strain-hardening cementitious composite (SHCC), which can control fracture of cementitious composite by bridging action. The properties of reinforcing fiber, as tensile strength, aspect ratio and elastic modulus, have great effect on the fracture behavior of SHCC. But SHCC has serious problem as drying shrinkage because silica powder is used to make SHCC in order to improve bond strength between reinforcing fibers and cement matrix. Therefore, curing method (period and temperature) is very important for SHCC to show high tensile performance. a variety of experiments have being performed to access the performance of SHCC recently. This research emphasis is on the mechanical properties of SHCC made in Polyvinyl alcohol (PVA), Polyethylene (PE) fibers and steel cord (SC), and how curing method affects the composite property, and ultimately its strain-hardening performance.

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Properties of Polyamide Modified PVC-sol Sealants (II) (폴리아미드가 함유된 PVC졸 실란트의 물성 (II))

  • Lee, Seung-Jin;Kim, Hyun-Kyo;Park, Hwan-Man;Cho, Won-Jei;Ha, Chang-Sik
    • Elastomers and Composites
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    • v.34 no.1
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    • pp.53-64
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    • 1999
  • The mechanical, electrical, and thermal properties of polyamide-modified poly (vinyl chloride) (PVC)-sol was investigated. PVC-sol was plasticized with dioctyl phthalate (DOP). In this work, the effects of the addition of polyamide on the properties of PVC-sol seal-ants were investigated. Two kinds of polyamide resins having different amine value were used. It was found that the properties of the PVC-sol sealants were significantly affected by the contents and types of the added polyamide rosins. The PVC-sol sealants modified with polyamide A (low amino value) showed higher tensile properties than those modified with polyamide B(high amino value) did, and thermal stability of the sealants showed nearly the same trends. The tensile strength of sealants were decreased with increasing the $CaCO_3$ contents. The dielectric constant were not strongly dependent on the polyamide types and contents.

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고체 충전제의 입자 분포에 따른 추진제 특성

  • 김창기;황갑성;임유진
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2000.11a
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    • pp.28-28
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    • 2000
  • HTPB/AP/AI 추진제는 none-reinforcing filler가 다량 함유되어 있어 기계적 특성은 바인더와 고체 충진제의 계면 접착력에 따라 크게 영향을 받으며 이를 향상시키기 위해 결합제의 연구가 다수 진행되었고 추진제의 인장 변형율을 증가시키기 위해 HTPB의 관능기수에 따른 가교밀도, 경화제와 경화촉매, 가소제등 최적의 바인더조성을 위해 가능한 원료 및 함량 연구에 많은 노력을 기울여 왔다. 또한 추진제의 주원료로서 AP는 추진제의 성능 및 내탄도 관점에서 입자크기에 따른 연소특성 및 고성능을 위한 충전 분율에 대해 주로 연구되었으며 특히 Oberth와 Farris는 고체추진제 분야에서 많은 업적을 이루었다.(중략)

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Tensile Performance of PE Fiber-Reinforced Highly Ductile Cementitious Composite including Coarse Aggregate (골재의 입도분포 변화에 따른 PE 섬유보강 고연성 시멘트 복합체의 인장성능)

  • Lee, Bang Yeon;Kang, Su-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.95-102
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    • 2020
  • For the purpose of developing a PE fiber-reinforced highly ductile cementitious composite having high tensile strain capacity more than 2% under the condition of containing aggregates with large particle size, this study investigated the tensile behavior of composites according to the particle size and distribution of aggregates in the composite. Compared with the mixture containing silica sand of which particle size is less than 0.6 mm, mixtures containing river sand and/or gravel with the maximum particle size of 2.36 mm, 4.75 mm, 5.6 mm, 6.7 mm were considered in the experimental design. The particle size distributions of aggregates were adjusted for the optimized distribution curves obtained from modified A&A model by blending different sizes of aggregates. All the mixtures presented clear strain-hardening behavior in the direct tensile tests. The mixtures with the blended aggregates to meet the optimum curves of aggregate size distributions showed higher tensile strain capacity than the mixture with silica sand. It was also found that the tensile strain capacity was improved as the maximum size of aggregate increased which resulted in wider particle size distribution. The mixtures with the maximum size of 5.6 mm and 6.7 mm presented very high tensile strain capacities of 4.83% and 5.89%, respectively. This study demonstrated that it was possible to use coarse aggregates in manufacturing highly ductile fiber-reinforced cementitous composite by adjusting the particle size distribution.

Study on Metal Plate Connections and Plywood Gusset Plate Connections for Light-Frame Wood Truss Tension Joint (목재 트러스 접합부의 toothed metal plate 접합과 plywood gusset plate 접합에 관한 연구)

  • Cha, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.1
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    • pp.46-50
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    • 1992
  • 본 연구는 잣나무 간벌재를 이용한 plywood gusset plate 접합과 toothed metal plate 접합에 대하여 인장력을 가해 조사하였다. plywood gusset plate 접합에 있어서는 합판과 부재 사이를 상온 경화제(초산 비닐 수지)로 접착한 후 6d 못으로 접합한 형태와 단지 합판만을 사용한 형태의 plywood gusset plate 접합 사이의 기계적 특성 차이를 조사했다. toothed metal plate 접합은 plywood gusset plate 접합보다 인장력에서 좋은 behavior를 보였다. 또한 접착제를 가한 plywood gusset plate 접합은 접합제를 가하지 않은 형태보다 큰 하중 지지력을 보였다.

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The Effect of Additives on the Mechanical Properties of Rigid Polyurethane (경질 폴리 우레탄의 기계적물성에 미치는 첨가제의 영향)

  • Na, Seok-En;Choi, Hwan-Oh;Lee, Jeon-Kyu;Kim, Si-Young;Ju, Chang-Sik
    • Korean Chemical Engineering Research
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    • v.50 no.5
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    • pp.783-788
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    • 2012
  • Stern tube bearing is a shaft device playing important roles to reduce the friction of axial rotation and to support the weight of shaft. However, because there is no domestic producer of stern tube bering, imported stern tube bearings have many practical problems including prices, delivery and after services. This is why stern tube bearing should be localization. For the purpose of development of polyurethane resin for stern tube bearings, the effect of additives on the hardness, tensile strength and elongation of the polyurethane resin were systematically investigated. For the preliminary researches, depending on the type of curing agent, MOCA type and non-MOCA type polyurethanes were synthesized. Preliminary researches concluded that MOCA type polyurethane resin has more excellent mechanical properties than non-MPCA type for stern tube bearings that Tensile strength and Hardness of non-MOCA type investigated 23 D, 4.3 Mpa. Therefore, MOCA type polyurethane was adapted as base resin of this research. Silica, calcium carbonate and graphite were selected as additives for the enhancement of mechanical properties of polyurethane resin. Effect of the type and the dosage of these additives on the hardness, tensile strength, elongation of the polyurethane resin were experimentally examined. However, addition of calcium carbonate and graphite showed only minor effect on the hardness of the resin. Polyurethane resin with silica showed relatively excellent hardness, tensile strength and improved elongation.