• Title/Summary/Keyword: 이화학적 성질

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Physicochemical Properties of Corn Starch Oxidized with Sodium Hypochlorite (산화에 따른 옥수수 전분의 이화학적 특성 변화)

  • 한진숙;안승요
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.31 no.2
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    • pp.189-195
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    • 2002
  • Corn starch was modified by oxidation with sodium hypochlorite (NaOCl) as an attempt to expand the application of starches in food industry. Corn starch was oxidized with 0.25, 0.5, 0.75, 1.0 and 1.5% active Cl/g starch at pH 7.0 and $25^{\circ}C$ for 10 minutes. The size, shape and amylose content of oxidized starches were similar to those of native corn starch. As the extent of oxidation increased, solubility, swelling power and the amount of soluble amylose increased, X-ray diffraction patterns changed, and relative crystallinity decreased. In Brabender amylogram, oxidation did not chance the gelatinization temperature, but oxidized starches had a lower peak in viscosity and their cooled pastes gave less setback, compared with native corn starch.

Physicochemical Properties of Sodium Hypochlorite Oxidized Potato Starch (Sodium Hypochlorite로 산화된 감자 전분의 이화학적 특성)

  • 김미라
    • Journal of the East Asian Society of Dietary Life
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    • v.7 no.3
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    • pp.315-324
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    • 1997
  • Physicochemical properties of potato starches oxidized with sodium hypochlorite containing 1.5, 3.0, 4.5, and 6.0% active Cl/g starch at pH 7.0 were examined. Carboxyl group contents of oxidized potato starches were proportional to active chlorine concentration in use and water binding capacity, alkali number, and solubility increased with increasing the degree of oxidation. Blue value and iodine binding property indicated the change of amylose structure by the oxidation. Gelatinization trends obtained from transmittance and DSC thermograms showed that gelatinization temperature was lower as starch was oxidized higher. X-ray diffraction patterns and scanning electron micrographs implied oxidation might occur on the surface amorphous regions of starch granule.

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Physicochemical and Gelatinization Properties of Glutinous Rice Flour and Starch Steeped at Different Conditions (수침한 찹쌀가루와 전분의 이화학적 및 호화 특성)

  • 최은정;김향숙
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.1
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    • pp.17-24
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    • 1997
  • The effects of steeping on the physicochemical and gelatinization characteristics of glutinous rice flour and its starch were studied. Steeping conditions were 1 day at 25"C,7 days at 2iC and 7 days at 35"C. Crude protein, lipid and ash content were decreased br steeping. It was observed with scanning electron microscopy that endosperm cell wall of glutinous rice flour was diminished by steeping. Although morphology of the glutinous rice starch granules was not affected, the size was decreased by steeping. Density and water binding capacity(WBC) of glutinous rice flour and its starch were changed by steeping. X-ray diffraction pattern of glutinous rice starch was A type and was not affected by steeping. Swelling power of glutinous rice flour and its starch was increased but solubility was decreased by steeping. In Brabender amylographic examination, peak viscosity of untreated glutinous rice flour was very low and increased enormously by steeping resulting in the similar Brabender viscosity pattern to its starch. The gelatinization temperature examined by X-ray diffractometry was lowered by steeping. And the degree of gelatinization under the conclusion temperature increased with increasing of steeping Period and temperature.mperature.

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Physicochemical Properties of Defatted High Amylose Corn Starch (탈지한 고아밀로오스 옥수수전분의 이화학적 특성)

  • Choi, Cha-Ran;Kim, Jeong-Ok;Lee, Shin-Kyung;Shin, Mal-Shick
    • Applied Biological Chemistry
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    • v.38 no.5
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    • pp.403-407
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    • 1995
  • For the use of starch gel like Mook(a Korean traditional gel food), the physicochemical properties and gelatinization patterns of defatted high amylose corn starch were investigated. The crude and total lipid contents of starch decreased by defatting from 0.07%, 0.92% to 0.03%, 0.19%, respectively. But iodine affinity increased from 51.6% to 71.3%. Water binding capacity of starches increased from 104.6% to 117.3% after defatting. Soluble carbohydrate and leached amylose of untreated and defatted starches were increased rapidly above $110^{\circ}C$. The apparent viscosity of starch dispersion using alkali solution increased above 0.3N NaOH solution but the transmittance increased above 0.4 N NaOH. The DSC thermograms of both starches showed broad and double endotherm with relatively low enthalpy, but the second peak of endotherm was larger in defatted starch than in untreated starch.

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Effect of Water Activity on the Physicochemical Properties of Sweet Potato Starch during Storage (저장 중 수분활성이 고구마 전분의 이화학적 특성에 미치는 영향)

  • Baek, Man-Hee;Shin, Mal-Shick
    • Korean Journal of Food Science and Technology
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    • v.27 no.4
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    • pp.532-536
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    • 1995
  • Effect of water activity $(0.32{\sim}0.89)$ on the physicochemical properties of sweet potato starch during the storage for 5, 15 and 30 days at $40^{\circ}C$ was investigated. Shapes and sizes of starch granules were not changed. X-ray diffraction patterns of the starches appeared equally Ca-crystal structure. Sorption isotherm with storage day was sigmoidal. A slight loss of iodine affinity, increase in water binding capacity, and decrease in swelling power at $80^{\circ}C$ occurred as water activities increased. Viscosity pattern under Brabender Amylogram was not significantly changed with water activity, but initial pasting temperature decreased as water activity increased. The viscosity at $50^{\circ}C$, consistency and setback were increased with increasing storage day and water activity.

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Establishment of Bioassay System for Developing New Insecticides I. Effects of Organic Solvents on the Toxicity against Insects, Phytotoxicity and Solubility of Compounds (살충제 개발을 위한 생물검정법의 확립 I. 각종 유기 용매가 곤충의 독성과 약해 및 화합물의 용해성에 미치는 영향)

  • 안용준;조광연
    • Korean journal of applied entomology
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    • v.31 no.2
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    • pp.182-189
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    • 1992
  • The influnces of 9 kinds of solvents on the toxicities against several insect species, phytotoxicity and solubility of compounds were evaluated by means of leaf dipping and spray methods. In case of the spray application, density and vapor pressure seemed to be a contributing factor to lethal toxicity against brown planthopper and diamond-back moth, respectively; the bigger the property of density and the smaller the vapor pressure gave the stronger toxicity. It appeared that the toxicity of solvents was not correlated with anyone of physical properties such as boiling point, dipole moment, dielectric constant, surface tension and viscosity. Spray treatment gave more toxicity to insects than leaf dipping treatment. Although dielectric constant and dipole moment seemed to be contributing factors to phytotoxic damage to rice seedling and bean plants, respectively, no general correlation between phytoxicity and the other physical properties was found. Leaf dipping application caused stronger phytotoxicity than spray application. It is concluded that 5% acetone solution may be most suitable to test chemicals because of its favorable solubility of compounds, lower toxicity to insects, and lower phytotoxicity.

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Ultrafiltration for Quality Improvement of Wine (한외여과공정을 이용한 포도주의 품질개선)

  • Chung, Jae-Ho;Mok, Chul-Kyoon;Lim, Sang-Bin;Park, Young-Seo
    • Korean Journal of Food Science and Technology
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    • v.35 no.3
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    • pp.386-392
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    • 2003
  • Physicochemical and microbiological changes of grape wine fermented and aged at 25 and $15^{\circ}C$ for 2 and 14 weeks, respectively, were investigated. Viable bacterial cell number, $3.3{\times}10^2\;CFU/mL$ at the beginning of fermentation, increased to $2.3{\times}10^6\;CFU/mL$ after 2 weeks, then decreased to $1.9{\times}10^3\;CFU/mL$ after 14 weeks. Viable yeast cell number increased from $2.8{\times}10^2\;to\;2.2{\times}10^7\;CFU/mL$ during fermentation, then decreased to $1.6{\times}10^4\;CFU/mL$ after aging. Turbidity, pH, total sugar content, reducing sugar content, and solid content of grape wine decreased during fermentation, whereas acidity and alcohol content increased to 0.64 and 8.4%, respectively. Most physicochemical properties did not change significantly during aging. When grape wine was filtered through $0.45-{\mu}m$ nitrocellulose membrane, followed by various ultrafiltration membranes with different molecular weight cut-off values, Biomax 100K membrane with $100\;L/m^2/hr$ (LMH) of initial flux was chosen for ultrafiltration process. These membrane filtration treatments resulted in complete removal of microorganisms and decreases in turbidity, reducing sugar, and solid content. Physicochemical properties of wine did not change, and no microorganisms were found during storage at $30^{\circ}C$ for 12 weeks.

Changes in the Physicochemical Property, Angiotensin Converting Enzyme Inhibitory Effect and Antimutagenicity During the Fermentation of Korean Traditional Soy Paste (Doenjang) (재래식 된장의 발효과정 중 이화학적 특성과 Angiotensin 전환효소 저해능 및 항돌연변이원성의 변화)

  • Rhee, Chang-Ho;Kim, Won-Chan;Rhee, In-Koo;Lee, Oh-Seuk;Park, Heui-Dong
    • Food Science and Preservation
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    • v.13 no.5
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    • pp.603-610
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    • 2006
  • Korean traditional soy paste (Doenjang) was fermented using Meju prepared by the culture of wild microorganisms in steamed soy beans. During the fermentation, changes in the physicochemical and several functional properties were monitored. Total acidity and amino acidity increased from 0.09 to 0.96, and 2.24% to 3.28% respectively, Amylase and protease activities increased and showed the maximal level after 60 days of fermentation, which were 4.03 and 7.29 units/ml, respectively. However, both enzyme activities decreased after then. The inhibitory activities against tyrosinase and angiotensin converting enzyme increased and reached 20.57 and 38.18% respectively. Antimutagenic activities against N-methyl-N'-nitro-N-nitiosoguanidine and 4-nitro-O-phenylenediamine (NPD) increased for 90 days and roached 70.21 and 60.01% in S. enterica serovar Typhimurium TA100, respectively. Against NPD and 4-nitroquinoline-1-oxide, the antimutagenic activities also increased and reached 50.91 and 46.35% in the strain TA98, respectively.

Characterization of a Glycosyldiglyceride Purified from Panax ginseng (인삼에서 분리된 glycosyldiglyceride의 특성)

  • Wee, Jae-Joon;Park, Jong-Dae;Kim, Man-Wook;Lee, Hyong-Joo
    • Applied Biological Chemistry
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    • v.32 no.2
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    • pp.132-136
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    • 1989
  • A new glycosyldiglyceride was purified from the ethylacetate soluble fraction of Panax ginseng extract by silica gel column chromatography and chemical structure of the compound was studied with IR, MS, $^{13}C-NMR$ spectroscopy and degradation method. The carbohydrate moiety was identified as ${\beta}-D-glucose$, and palmitic acid occupied about 70% of the acyl groups. This compound was first purified from Panax ginseng.

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Chemical and Mineralogical Properties of Two Low-Humic Gley Soils of Korea (우리나라 Low-Humic Gley Soil의 이화학적(理化學的) 및 광물학적(鑛物學的) 특성(特性)에 관(關)한 연구)

  • Dewan, H.C.;Han, K.H.;Lee, Y.S.
    • Korean Journal of Soil Science and Fertilizer
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    • v.1 no.1
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    • pp.129-136
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    • 1968
  • Low-Humic Gley Soils occur very commonly in Korea and constitute important paddy soils of the country. These soils are developed either on alluvial or fluvio-marine materials. The soils in the present invest igation are derived from the latter. The interesting morphological features of these two soils are the presence of $FeCO_3$ concretions in the subsoil and the occurrence of a buried black organic horizon of variable thickness(25-100 cm). The organic horizon overlies the greenish marine material and underlies the continental material. These soils have poor drainage and are wet most of the year. The presence of $FeCO_3$ concretions in poorly drained paddy soils has previously been reported in North America(8), Japan(9) and West Europe(7). The purpose of this investigation is to study the chemical and mineralogical characteristics of these soils; and the genesis of $FeCO_3$ concretions. Profile samples of both these soils were collected from Gimjae area, in co-operation with the Soil Survey Party. These profiles were described as follows:

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