• Journal of the Korean Chemical Society
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• v.28 no.6
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• pp.366-373
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• 1984

Methanolysis rates of benzylbenzenesulfonates, substituted both on the substrate (Y) and on the leaving group (Z), were determined in MeOH-MeCN mixtures. The results showed that the reaction proceeds via the dissociative $S_N2$ mechanism, in which bond breaking proceeds in greater degree compared to bond formation at the transition state(TS). Multiple Hammett correlation analysis showed that the cross term, ${\rho}_{YZ}$, is very small and hence the cross interaction of two substituents, Y and Z, at the TS is not important, supporting the dissociative $S_N2 $ type mechanism. While transition state variations predicted by the quantum mechanical model is shown to agree in general with the experimental results, those predicted by the potential energy surface model failed to account for the leaving group effect properly.

• Journal of the Korean Chemical Society
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• v.29 no.6
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• pp.565-574
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• 1985

The rates of reaction between 4-substituted-2,6-dinitrochlorobenzenes with para-substituted anilines in methanol-acetonitrile mixtures were measured by conductometry. It was observed that the rate constant increases in the order of X = 4-$NO_2 {\gg}4-CN {\gg}4- CF_3$, where X is a substituent in the substrate. The rate constant also increases in the order of Y = p-O$CH_3{\gg}p- CH_3{\gg}H {\gg}p-Cl{\gg}m- NO_2$, where Y is a substituent in the aniline ring. Kinetic studies in the methanol-acetonitrile solvent system with various nucleophiles showed that the N-C bond forming step is making a great contribution to the overall second order rate constant. The electrophilic catalysis by methanol probably consists of the hydrogen bonding between alcoholic hydrogen and leaving chloride in the transition state. The nucleophilic catalysis by methanol may be ascribed to the formation of hydrogen bonds between alcoholic oxygen and hydrogens of amines in the transition state. All these experimental facts are supporting the operation of $S_N$Ar machanism with the second step being the rate determining. This mechanism can be successfully fitted to the PES model.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1995.04b
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• pp.336-341
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• 1995

종래의 Cam 구동방식 Pirn Winder에서는 낮은 권취속도와 만권시 권취 Bobbin이 Cradle에서 이탈될 때 권취 Yarn의 대량손실, Pirn 형성시 사층의 붕괴에 따른 과다권취등 기술적 난제가 대두되었다. 이러한 문제점을 해결하기 위하여 구미선진국에서는 Micom 제어 Pirn Winder가 개발되었다. 국내에서는 이 기계를 전량 수입에 의존하고 있어 수입 대체가 시급하지만 선진국의 기술보호주의 때문에 기술도입도 어려운 실정이다. 본 논문에서는 Micom제어 Pirn Winder에서 기본적으로 사층이 무너지지않기 위한 권취량, Traverse속도, 사속(Yarn Speed), 스핀들의 각속도 등을 결정함으로써 기구 학적 제어를 할 수 있는 알고리즘을 제시하고 컴퓨터 모사실험을 통하여 타당성을 보였다.

• Journal of Korean Society of Transportation
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• v.20 no.3
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• pp.115-128
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• 2002

Dislike the tangent sections, the horizontal curve sections of roads should be designed, considering several factors : one of such factors is widening. In other words, since widening results from that when a vehicle runs on the horizontal curve sections, the rear wheels of the vehicle run not along with tracks of the front wheels but out of that, such offtracking should be exactly investigated and reflected in design of the curve sections. Especially in the case of industrial roads which semi-trailers and large trucks run frequently or arterial roads with small curve radiuses in mountainous regions. serious offtracking Phenomenons result in increasing the risk of accidents. decreasing the capacities and jeopardizing pedestrians' safety on the curve sections. For the offtracking, widening amounts of roads has been determined under the traditional presumption that vehicles run at a low speed and there is no superelevation. In fact, however, since the vehicles run at a high speed as well as at a low speed and the superelevation is installed on the horizontal curve sections in the structural aspect of roads, the existing standards for installing widening have a limitation to reflect exactly actual Phenomenons. In particular, for articulated wheel axles of a tractor and a trailer and long articulated vehicles, not only the offtracking degree is very high but also the interpretation shows different aspects from one of single axles. Comparing and reviewing the results of Korean and foreign studies related to the trailer offtracking model theory and the standards for installing widening, this study developed a realistic dynamic offtracking model which considers geometric structures of roads and speeds of vehicles, suggested how to measure widening with this model and examined applicability of the model. The findings of this study are as follows ; First. a dynamic offtracking model. which considers dynamic movements of a tractor and a trailer and the superelevation, was developed. Second, a new method to measure widening with the developed dynamic offtracking model was developed and a method to measure widening with swept path width was suggested as well. Finally, validity of the current standards for installing widening was examined by determining actual offtracking and widening amounts with the developed model and the applicability was investigated through the case studies. Compared with the existing offtracking models, the dynamic offtracking model developed in this study can reflect practically vehicle speed. dimension and geometric structural aspects of roads. In conclusion, the meaning of this study is that it reviews validity of the current standards for installing widening and provides a base to establish such standards by suggesting new methods to measure the widening with this dynamic offtracking model.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.4
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• pp.343-352
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• 2013

In this study, a smooth flat surface, low fin, Turbo-B, and Thermoexcel-E surfaces are used to examine the effect of the flow velocity on the pool boiling heat transfer coefficients (HTCs) and critical heat fluxes (CHFs). HTCs and CHFs are measured on a smooth square heater of $9.53{\times}9.53mm^2$ at $60^{\circ}C$ in a pool of pure water at various fluid velocities of 0, 0.1, 0.15, and 0.2 m/s. Test results show that for all surfaces, CHFs obtained with flow are higher than those obtained without flow. CHFs of the low fin surface are higher than those of the Turbo-B and Thermoexcel-E surfaces due largely to the increase in surface area and sufficient fin spaces for the easy removal of bubbles. CHFs of the low fin surface show even 5 times higher CHFs as compared to the plain surface. On the other hand, both Turbo-B and Thermoexcel-E surfaces do not show satisfactory results because their pore sizes are too small and water bubbles easily cover them. At low heat fluxes of less than $50kW/m^2$, HTCs increase as the flow velocity increases for all surfaces. In conclusion, a low fin geometry is good for application to steam generators in nuclear power plants.

• Proceedings of the Korean Operations and Management Science Society Conference
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• 2006.11a
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• pp.383-387
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• 2006

자기유사(self-similar)과정은 인터넷 트래픽을 보다 정확하게 분석하는데 꼭 필요한 확률과정이다. 본 연구는 계산이 간편하고 다양한 시간범위의 종속성을 반영할 수 있는 M/G/${\infty}$에 모형을 기반으로 하여 자기유사과정을 생성하는 방법을 채택하고 G를 파레토 분포로 표준화하여 적용 가능성을 다양하게 실험한다. 시뮬레이션에서 이산화를 매 단위시점으로 설정하지 않고 대기열에서의 도착, 이탈시점으로 설정하여 시뮬레이션의 속도를 높이고 보다 정확한 성능측정이 이루어지도록 시도한다.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.193-195
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• 2005

광화학측정이 이루어진 기간 중 일사량이 강한 날에 관측 오존의 농도와 광화학 모델의 광화학 정류상태로 추정된 오존의 농도는 아주 밀접한 근접성을 보였다. 광정류 상태로부터의 이탈 정도에 영향을 미치는 인자로는 측정 지역 근처에서의 지역적 NO$_{2}$ 생성원의 존재, 지역적 NO 또는 오존의 소멸, 비 정류상태 조건, 또는 측정의 오차 등에 기인한 것으로 추정된다. 오존의 생성 속도에 가장 크게 영향을 주는 화학반응은 NO와 HO$_{2}$의 화학반응으로 나타났다.

• 해운
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• s.101
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• pp.9-24
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• 2013

올 하반기 세계경제는 상반기보다 다소 호전될 전망이다. 미국경제의 회복이 재개되고 유로존이 침체에서 벗어나는 등 선진국 경제의 활력이 높아질 것으로 예상된다. 다만 하반기 선진국의 출구전략이 가시화되면서 글로벌 유동성 증가세의 둔화가 불가피할 것으로 보인다. 세계적인 금리상승이 자산 가격과 성장에 부정적 영향을 미치고 금융시장의 불확실성을 확대시킬 전망이다. 그간 자본유입이 많고 경제여건이 취약한 신흥국들을 중심으로 자본이 급격히 이탈하는 금융위기 가능성도 남아 있다. 최근 금융시장의 불안정성이 부각된 중국은 금융위기나 급격한 침체 가능성은 크지 않으나 정부의 성장견인 역할 축소로 장기적인 감속이 불가피할 것으로 보인다. 세계 경제 회복속도는 빠르지 않을 것이며 연간으로 지난해와 비슷한 3% 초반 성장에 머물 것으로 전망된다.

• Nuclear Engineering and Technology
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• v.1 no.2
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• pp.87-90
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• 1969

Halogen exchange reactions of trans-cinnnamyl chloride and bromide with radioactive chloride, bromide and iodide ions in acetone have teen studied. Relative nucleophilicity of halide ions and relative leaving ability have been discussed invoking the principle of HSAB.

• Journal of the Korean Chemical Society
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• v.41 no.6
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• pp.299-303
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• 1997

The rate constants($k_{OH}$) for the alkaline hydrolysis of the 4-substituted phenyl ethyl benzylphosphonates were determined in various buffer solutions by UV(Vis spectrophotometer. The activation entropies of the title reactions show negative values and this result is not consistent with a dissociative mechanism (EA) for which a positive or slightly negative value of the entropy of activation should be expected. An associative mechanism(AE) is favorable because the negligible negative charge is generated on the leaving group in the rate determining step from a good Hammett relationship(ρ=1.89). By the results of a kinetic study, we conclude that a dissociative mechanism is not proceeded in the title reactions.