Nuclear Engineering and Technology

Korean Nuclear Society (한국원자력학회)
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Halogen Exchange Reactions of Cinnamyl Halides

  • Lee, Bon-Su (Dept. of Applied Chemistry, College of Engineering, Seoul National University) ;
  • Lee, Ikchoon (Dept. of Applied Chemistry, College of Engineering, Seoul National University)
  • Published : 1969.12.01
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Abstract

Halogen exchange reactions of trans-cinnnamyl chloride and bromide with radioactive chloride, bromide and iodide ions in acetone have teen studied. Relative nucleophilicity of halide ions and relative leaving ability have been discussed invoking the principle of HSAB.

Trans-cinnamyl chloride와 bromide의 방사성 Cl$^{-}$, Br$^{-}$ 및 I$^{-}$와의 교환 반응을 아세톤 용액에서 반응속도론적으로 연구하였다. 상대적인 할로겐 이온들의 친핵성과 이탈능을 HSAB 원리를 이용하여 논의하였다.

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