• Title/Summary/Keyword: 이수열

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Super-growth of Carbon Nanotubes by O2-assisted Microwave Plasma Chemical Vapor Deposition

  • Park, Sang-Eun;Kim, Yu-Seok;Kim, Seong-Hwan;Lee, Su-Il;Jo, Ju-Mi;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.387-387
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    • 2011
  • 탄소 나노튜브(Carbon nanotubes, CNTs)는 육각형 모양의 구조로서 오직 탄소만으로 이루어진 소재이다. CNT는 열전도율이 다이아몬드보다 약 2배 우수하고, 전기 전도는 구리에 비해 1,000배 높으며, 강도는 강철보다 100배나 뛰어나다. CNT의 이러한 특성을 이용한 트랜지스터, 태양전지, 가스 검출을 위한 고감도 센서, 나노 섬유, 고분자-탄소나노튜브 고기능 복합체 등 많은 분야에서 연구가 활발히 진행되고 있다. 또한 수직으로 성장된 탄소 나노튜브는 일반적인 재료에서는 보기 드물게 힘들게 직경이 나노 크기인 반면 길이는 수 mm까지 합성 되기 때문에 앞서 언급한 분야로의 활용이 더욱 유리하며, 그 중에서도 나노 섬유, 나노 복합체로서의 활용에 극히 유용하다. 이러한 이유로 수직 배열된 CNT 합성에 많은 연구가 집중 되고 있다. 여러 합성 방법 중 성장 변수를 비교적 용이하게 조절 가능한 열 화학 기상 증착법(Thermal chemical vapor deposition, TCVD)을 이용하여 수직 배열된 수 mm의 CNT를 합성한 연구 결과들이 보고된 바 있다. 그러나 앞선 연구결과들은 CNT의 성장속도가 느릴 뿐만 아니라 합성 시간이 길어질수록 성장 속도가 감소하는 경향을 보였다. 반면, 마이크로웨이브 플라즈마 화학 기상 증착법(Microwave plasma CVD, MPCVD)은 기존의 다른 TCVD에 비해 낮은 온도에서 CNT를 합성할 수 있는 장점을 가지며, 고출력(~600 W 이상)의 플라즈마를 사용하기 때문에 성장률이 높고 고밀도의 CNT 합성이 가능하다. 본 연구에서는 철을 촉매금속으로 사용하고 MPCVD을 이용하여 얇은 다중벽 CNT를 합성하였다. 철은 직류 마그네트론 스퍼터(D.C magnetron sputter)를 사용하여 증착하였다. 합성시 가스는 탄소 공급원인 메탄($CH_4$)과 함께 플라즈마 공급원인 수소($H_2$)를 사용하였다. 또한 산소($O_2$)의 주입 여부에 따른 CNT의 성장 속도와 성장 길이를 비교하였다. 산소를 주입하였을 때, CNT의 성장 속도와 길이 모두 크게 향상됨을 확인 할 수 있었다. 이는 촉매금속 표면의 비정질 탄소의 흡착으로 인해 활성화된 촉매금속의 반응시간을 증가시키기 때문이다. 성장된 CNT는 주사전자 현미경(Scanning Electron Microscopy, SEM)과 라만 분광법(Raman spectroscopy)을 통해 표면형상과 결정성을 분석하였다.

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Phase Formation and Thermo-physical Properties of Lanthanum/Gadolinium Zirconate with Reduced Rare-earth Contents for Thermal Barrier Coatings (열차폐코팅을 위한 희토류가 저감된 란타눔/가돌리늄 지르코네이트의 상형성 및 열물성)

  • Lee, Sujin;Kwon, Chang-Sup;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Nahm, Sahn;Kim, Seongwon
    • Journal of Powder Materials
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    • v.22 no.6
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    • pp.420-425
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    • 2015
  • Rare-earth zirconates, such as lanthanum zirconates and gadolinium zirconates, have been intensively investigated due to their excellent properties of low thermal conductivity as well as chemical stability at high temperature, which can make these materials ones of the most promising candidates for next-generation thermal barrier coating applications. In this study, three compositions, lanthanum/gadolinium zirconates with reduced rare-earth contents from stoichiometric $RE_2Zr_2O_7$ compositions, are fabricated via solid state reaction as well as sintering at $1600^{\circ}C$ for 4 hrs. The phase formation, microstructure, and thermo-physical properties of three oxide ceramics are examined. In particular, each oxide ceramics exhibits composite structures between pyrochlore and fluorite phases. The potential of lanthanum/gadolinium zirconate ceramics for TBC applications is also discussed.

The Comparison of Lower Limb Muscle Activities and VMO/VLO Ratio according to Direction for Using the Ramp in the Normal Adult (정상성인에서 경사로의 사용 방향이 다리근육의 활성도 및 안쪽/가쪽넓은근의 비율에 대한 연구)

  • Lee, Sangyeol;Lee, Sukyoung
    • Journal of The Korean Society of Integrative Medicine
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    • v.5 no.3
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    • pp.57-61
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    • 2017
  • Purpose : The purpose of study was to find out the environmental risk factor that can be easily occurred imbalance muscle activities according to direction for using the ramp during one legged standing. Method : The subjects were 20 normal adults with a mean age of $23.15{\pm}2.14years$ and a Body Mmass Index (BMI) of $22.74{\pm}1.07$. Participants were measured muscle activities on vastus medialis, vastus lateralis, tibialis anterior, peroneus longus during one legged stance at four conditions ramp (down ramp, up ramp, medial ramp, lateral ramp). The statistical analyses were performed using IBM SPSS(Ver. 23) and p-value less than .05 were considered statistically significant for all cases. Result : In this study, the activity of the lower extremity muscle and the ratio of the vastus medial and lateral muscles according to the direction of use of the ramp were investigated. The changes in the muscle activity of the lower limbs along the direction of the ramp were significantly different between the vastus medial muscle and the peroneus longus muscle. Conclusion : For a short time on a ramp or a pedestrian crossing, a clerk in a ramp can move or stand by placing the lower limbs in various directions, but if performed in consideration of the individual's disease characteristics or unstable foot position, It is thought that there will be an effect to prevent on the ankle and knee unstability.

An Experimental Study on the Damage of the Data Process Equipment When $CO_2$ is Discharged ($CO_2$ 소화설비 방사시 정보저장장치의 저온손상에 관한 연구)

  • 이수경;김종훈;김영진;최종운
    • Fire Science and Engineering
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    • v.13 no.3
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    • pp.19-26
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    • 1999
  • $CO_2$ extinguishing system is the most $\phi$pular among the gas extinguishing system. $CO_2$ is usually stored with liquified state. But, it gasifies at the tip of nozzle when $CO_2$ was released through the pipe and head. A ro$\alpha$n temperature is very low when $CO_2$ was released. So electrical instrument, magnetic storage equipment and memory semiconductor are electrically or physically injured by cooling effect in a few minutes. So, we intend to find out temperature profile and electrical damage in compartment area, and supply basic d data for research and making standards and code through the full scale experiment. As result of experiment on the damage due to cooling effect from $CO_2$ extinguishing system, i instantaneous discharging temperature. was $-82.5^{\circ}C$ in average. An average temp. in the compartment after discharging $CO_2$ was $-40^{\circ}C$.

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A Study on a Process for Conversion of Carbon Dioxide through Saline Water Electrolysis (염수 전기분해와 연계한 이산화탄소의 전환 공정 연구)

  • Lee, Dong Woog;Lee, Ji Hyun;Lee, Junghyun;Kwak, No-Sang;Lee, Sujin;Shim, Jae-Goo
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.86-92
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    • 2017
  • A process, which converts carbon dioxide contained in the flue gas of coal-fired power plants to sodium bicarbonate, was studied experimentally and numerically. In this process, the carbon dioxide reacts with sodium hydroxide which is produced through saline water electrolysis. A bench scale reactor system was prepared for experiments of this process and numerical process modeling was performed for the bench scale reactor system. Comparing the process modeling results with the experimental data, responsibility of the process modeling was confirmed. Using this model, commercial scale process was simulated. Mass and energy balance of this process were calculated. Temperature profile in the reactor and carbon dioxide removal rate were obtained.

A Study on the Fire Risk Assessment and Prevention in the Recycling Process of Used Refrigerators (냉장고 파쇄 공정에서의 화재 위험성 및 예방에 관한 연구)

  • Lee, Su-Kyung;Song, Dong-Woo;Bae, Jeong-Ae
    • Fire Science and Engineering
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    • v.23 no.5
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    • pp.72-77
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    • 2009
  • In the recycling procedure of the refrigerator, the fire frequently breaks out. In this study, to clarify the exact cause of the fire, the components and concentration of the materials produced in the process are analysed as well as the problems in the process system, and the protective measure to prevent the fire and the explosion fundamentally is proposed. In this procedure, the preventive measures of fire by removing the combustible materials such as polyurethane and inflammable gases, by removing the ignition sources and by reducing the oxygen concentration to the minimum are proposed along with the protective measures to reduce the damage in the fire. In the crushing procedure where the fire or explosion can break out in diverse ways, the forced ventilation or exhaust system applied to the small partial ventilation facility are installed to reduce the concentration of inflammable gas mixture to lower than the inflammable limit by injecting and exhausting the air forcibly.

Finite Element Analysis of H-Shaped Compressive Member Exposed High Temperatures (고온에 노출된 H-형강 압축재의 유한요소해석)

  • Lee, Swoo-Heon;Lee, Hee-Du;Choi, Jun-Ho;Shin, Kyung-Jae
    • Fire Science and Engineering
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    • v.30 no.5
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    • pp.54-59
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    • 2016
  • Steel is a structural material that is inherently noncombustible. On the other hand, it has high thermal conductivity and the strength and stiffness of the material are reduced significantly when exposed to fire or high temperatures. Because the yield strength and modulus of elasticity of steel are reduced by 70% at $350^{\circ}C$ and less than 50% at $600^{\circ}C$, the load-carrying capacity of steel structure at high temperature rapidly lose. To be accepted as a fire-resisting construction, the fire test should be performed at the certificate authority. On the other hand, the fire test on a full-scale structure is limited by time, space, and high-cost. The analytical method was verified by a comparison with the fire test of H-section columns under compression and thermal analysis based on a finite element method using the ABAQUS program, and the numerical analysis method reported in this study was suggested as a complement of an actual fire test.

Distribution of Organochlorines and PCB Congeners in Korean Adipose Tissue, Liver and Whole Blood (한국인 지방, 간장 및 혈액 중 유기염소제류 및 PCB congeners의 분포)

  • 유영찬;이상기;김기욱;이수연;양자열;김윤신;오승민;정규혁
    • YAKHAK HOEJI
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    • v.46 no.4
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    • pp.247-257
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    • 2002
  • Persistent organochlorine pesticides and polychlorinated biphenyls (PCBs) have been used intensively in agriculture or industry for a long time. The occurrence of organochlorine pesticides and PCBs in the environment and subsequently in parts of the food chain, resulting in the intake of these compounds by man and animal. The measure of the levels of organochlorine pesticides and PCBs in tissues or blood of human populations are good markers in determining the extent of exposure and in the evaluating the hazards. So, most countriess have conducted initial monitoring programs to determine organochlorine pesticides and PCBs in human tissues. But a few report has been presented in Korea. In this study, $\alpha$-BHC, $\beta$-BHC, ${\gamma}$-BHC, $\delta$-BHC, p,p'-DDT, p,p'-DDD, p,p'-DDE, endrin, dieldein, aldrin and 7 marker PCBs (28, 52, 101, 118, 138, 153, 180) were determined in human blood, adipose tissue and liver tissues collected at autopsy of 10 men and 10 women, 13-79 year of age. Significant differences in the levels of organochlorine pesticides and PCBs between districts where they had lived were found in the following chemicals: total PCB in the blood : $\beta$-BHC, total BHC, p,p'-DDE and total DDT in the adipose tissue : p,p'-DDE, total DDT and PCB 118 in the liver. No significant difference was found in the levels of organochlorine pesticides and PCBs between sexes and ages. Though the levels of organochlorine pesticides and PCBs were relatively lower than that of other countries, we could know that organochlorine pesticides and PCBs have been widely distributed in Korean human body.

A Study on Cervical Curvature and Thermography in Some Neck Pain Patients (경항통 환자의 경추 만곡도와 체표열에 대한 연구)

  • Yang, Jae-Sun;Lee, Sang-Gyu;Lee, Chong-woo;Yeom, Seung-Ryong;Kwon, Young-Dal;Lee, Soo-Kyung;Song, Yong-Sun
    • Journal of Korean Medicine Rehabilitation
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    • v.15 no.2
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    • pp.105-105
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    • 2005
  • Objectives : The purpose of this study was to investigate the correlation between cervical spine curvature and thermography on neck pain patients. Methods : The cervical spine curvature was assessed on lateral view of plain radiograph by three measurements(Depth of cervical curve, Method of Jochumsen, Angle of cervical curve), then the neck pain patients were divided into straight curvature group(Straight group), normal curvature group(Control I), and no neck pain group(Control II) was selected by random sampling. I measured temperature of the both side Pungji(風池, G20), Kyonjong(肩井, G21), Chonjong(天宗, SI11) by thermography examination on Experimental group(Straight group) and control group(Control I, II), then analyzed the temperature statically with student's t-test, ANOVA. Results : The temperature of six point on Straigt group was lower than that of Control I, but had no significant difference(p>0.05). The temperature of six point on Straigt group was lower than that of Control II. The descent of temperature on Lt. Pungji(風池, G20), Lt. Kyonjong(肩井, G21), Rt. Chonjong(天宗, SI11) had significance(p<0.05). There is no corelation between onset period and mean temperature of six points. Conclusions : Thermography represnets the presence of neck pain, but has no correlation with straight of cervical curvature.

Image Exposure Compensation Based on Conditional Expectation (Conditional Expectation을 이용한 영상의 노출 보정)

  • Kim, Dong-Sik;Lee, Su-Yeon
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.42 no.6
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    • pp.121-132
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    • 2005
  • In the formation of images in a camera, the exposure time is appropriately adjusted to obtain a good image. Hence for a successful alignment of a sequence of images to the same scene, it is required to compensate the different exposure times. If we have no knowledge regarding the exposure time, then we should develop an algorithm that can compensate an image with respect to a reference image without using any camera formation models. In this paper, an exposure compensation is performed by designing predictors based on the conditional expectation between the reference and input images. Further, an adaptive predictor design is conducted to manage the irregular exposure or histogram problem. In order to alleviate the blocking artifact and the overfitting problems in the adaptive scheme, a smoothing technique, which uses the pixels of the adjacent blocks, is proposed. We successfully conducted the exposure compensation using real images obtained from digital cameras and the transmission electron microscopy.