• Fire Science and Engineering
• /
• v.21 no.3
• /
• pp.33-40
• /
• 2007

The values of the AITs(Autoignition temperatures) for fire and explosion protection are normally the lowest reported. This study measured the AITs of ethylbenzene+n-hexanol and ethylbenzene+n-propionic acid Systems from ignition delay time(time lag) by using ASTM E659-78 apparatus. The AITs of ethylbenzene, n-hexanol and n-propionic acid which constituted binary systems were $475^{\circ}C,\;275^{\circ}C\;and\;511^{\circ}C$, respectively. The experimental ignition delay time of ethylbenzene+n-hexanol and ethylbenzene+n-propionic acid systems were a good agreement with the calculated ignition delay time by the proposed equations with a few A.A.D.(average absolute deviation).

• Journal of the Korean Institute of Gas
• /
• v.17 no.6
• /
• pp.67-72
• /
• 2013

The flash point is the lowest temperature at which there is enough concentration of flammable vapor to form an ignitable mixture with air. The flash point is a major physical property used to analyse the fire and explosion hazards of a flammable liquid solution. The flash point data for pure components are easily available in several literature. But the flash points of the flammable binary solutions appear to be scarce in the literature. The objective of this study is to measure and estimate the flash point of acetic acid-formic acid system. Cleveland open cup tester was used to measure the flash point. The experimental data were compared with the values estimated by the Raoult's law and the optimization methods based on van Laar and Wilson equations. As a result, the estmated values by optimization methods were found to be better than those based on the Raoult's law.

• Fire Science and Engineering
• /
• v.29 no.5
• /
• pp.1-6
• /
• 2015

Flash point is one of the most important variables used to characterize fire and explosion hazard of liquids. The lower flash point data were measured for the binary systems {methanol + 1-butanol}, {ethanol + 1-butanol} and {2-propanol + 1-butanol} at 101.3 kPa. Experiments were performed according to the standard test method (ASTM D 3278) using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following activity coefficient models: Wilson, Non-Random Two Liquid (NRTL), and UNIversal QUAsiChemical (UNIQUAC). The measured FP data agreed well with the predicted values of Raoult's law, Wilson, NRTL and UNIQUAC models. The average absolute deviation between the predicted and measured lower FP was less than 1.14 K.

• Clean Technology
• /
• v.7 no.2
• /
• pp.133-140
• /
• 2001

The adsorption characteristics of binary-component Volatile Organic Compounds(VOCs) with benzene and toluene were studied in a fixed bed backed with activated carbon. The adsorption intensites of benzene and toluene resulted from equilibrium adsorption capacity led to roll up phenomenon in a fixed bed and behaved benzene as non-key component which meant the smaller affinity to the activated carbon of the two. From comparion with breakthrough curves between binary-component and single component systems at the same concentration conditions, the stoichiomertic breakthrough time of toluene in both systems had no difference, but that of benzene as non-key component had a tendency to shorten 130min than 200min of single component. In the breakthrough characteristics of binary-component adsorbates, the magnitude of roll-up of the non-key component increased with the increasing of non-key component ratio and aspect ratio(L/D) of fixed bed, while decreased with the increasing of interstitial velocity. Especially, the roll-up phenomenon was more conspicuous with the increasing of mole fraction of key component.

• Microbiology and Biotechnology Letters
• /
• v.20 no.4
• /
• pp.437-444
• /
• 1992

An innovative process for high fructose corn syrup (HFCS) production coupled with direct saccharification of raw corn starch in the agitated bead enzyme reactor (bioattitor) was investigated. The required high concentration/purity of glucose solution suitable for isomerization was produced directly in a bioattritor. without condensation of hydrolyzate, 398 g glucose/$\ell$ and 98% glucose content from 400 g/$\ell$ (w/v) of raw corn starch after 24 hours. The unsaccharified residual starch could be separated easily upon centrifugation, and resaccharified. The obtained solution also possessed other desirable requirements as substrate for isomerization, such as. low concentrations of denatured protein and calcium ions, thereby, simplified the purification step. The obtained glucose solution was isomerized in an enzyme reactor paked with immobilized glucose isomerase to evaluate the suitability as a substrate. The proposed new HFCS process seems to have many advantages over the conventional process via liquefaction-saccharification steps. The follow-up investigations of the proposed process need to be conducted to evaluate the feasibility of industrial application.

• Journal of Adhesion and Interface
• /
• v.19 no.1
• /
• pp.5-12
• /
• 2018

The purpose of this study is to evaluate the adhesive properties of polyurethane mixed aqueous dispersions by omitting the primer, dealing with the preparation of skins for synthetic leather with excellent adhesion by omitting the pre-treatment process. The two-component mixed polyurethane water dispersion was prepared by synthesizing an ester-based polyurethane resin (PU-T) and a carbonate-based polyurethane resin (PU-C) to obtain the final resin. As a result of measuring the peel strength of the adhesive specimens omitting the pre-treatment agent, it was confirmed that the state adhesive strength (ethylene vinyl acetate (middle): $4.2kg_f/cm$ and rubber (outsole): $4.4kg_f/cm$) there was. This makes it possible to omit the pre-treatment process which has been indispensably used in the shoe manufacturing process, thereby reducing the process time and reducing the amount of volatile organic compounds (VOCs) generated in the pre-treatment product, resulting in environmentally advantageous.

• Journal of the Korean Institute of Gas
• /
• v.12 no.3
• /
• pp.50-55
• /
• 2008

The flash points for the systems, ethlybenzene+n-butanol and ethlybenzene+n-hexanol, were measured by using Tag open-cup tester (ASTM D1310-86). These binary mixtures exhibited MFPB (minimum flash point behavior), which leads to the minimum on the flash point vs composition curve. The experimental data were compared with the values calculated by the Raoult's law, the UNIQUAC equation and the NRTL equation. The calculated values based on the UNIQUAC and NRTL equations were found to be better than those based on the Raoult's law. It was concluded that the UNIQUAC and NRTL equations were more effective than the Raoult' law at describing the activity coefficients for nonideal solution such as the ethlybenzene+n-butanol and ethlybenzene+n-hexanol systems. And the predictive curve of the flash point prediction model based on the NRTL equation described the experimentally-derived data more effectively than was the case when the prediction model was based upon the UNIQUAC equation.

• Fire Science and Engineering
• /
• v.25 no.1
• /
• pp.57-62
• /
• 2011

The flash point is one of the most significant combustion properties of flammable liquids in industrial processes when evaluation process safety, In this paper, Cleveland open cup tester is used to measure the flash points for the two binary systems (n-propanol + formic acid and acetic acid + propionic acid). The measured flash points were compared with the values calculated by the Raoult's law and the optimization method using van Laar and Wilson equations. The calculated values based on the optimization method were found to be better than those based on the Raoult's law.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2021.06a
• /
• pp.334-334
• /
• 2021

최근 기후변화에 따라 세계적으로 집중호우·태풍·가뭄 등과 같은 기상재해가 증가하고 있으며, 이 중에서도 주기적으로 발생하는 가뭄의 발생빈도 또한 증가하고 있다. 2014년과 2015년 금강수계에 발생한 가뭄과 2017년 낙동강수계에 발생한 가뭄은 갈수로 인한 피해를 야기한 바 있다. 금강수계의 경우 보령댐 저수량 부족으로 제한급수를 시행하였으며, 낙동강수계의 경우 형산강수계의 농업용저수지 고갈로 긴급용수를 공급하기도 하였다. 이에 대하여 낙동강홍수통제소는 2016년부터 수계 내의 갈수상황과 향후 예상되는 갈수전망을 지속적으로 모니터링하고 있다. 수계 전역을 대상으로 강수현황, 다목적댐·용수댐 및 농업용 저수지의 저수현황, 하천의 갈수현황, 향후 기상전망 및 방류계획, 향후 유출전망 등을 1개월 단위(매주) 및 3개월 단위(매월) 작성하며, 갈수예보 및 모니터링지점 선정, 예보적용성 검증 등을 수행하고 2020년부터 갈수예보를 정식으로 시행하고 있다. 본 연구에서는 낙동강수계의 효율적인 갈수예보의 시행과 확대를 위해서 현재 낙동강 본류로 한정되어 있는 갈수관리 지점을 확대하는 방안에 대하여 검토하였다. 기준갈수량이 상대적으로 적은 중권역, 상수도 보급률, 영농여건 물리농지 비율 및 유량관측 안정화 여부를 종합적으로 검토하였으며 확대 지점을 선정하였다.

• Clean Technology
• /
• v.19 no.1
• /
• pp.8-12
• /
• 2013

Phase behavior of carbon dioxide + surfactant binary system and carbon dioxide + surfactant + water ternary system was investigated at the temperatures from 318 K to 348 K by using high pressure vapor liquid equilibrium apparatus containing variable-volume view cell. Sorbitan monopalmitate was used as the surfactant. The cloud point pressures for the binary mixture of carbon dioxide + sorbitan monopalmitate increased with an increasing of system temperatures and the maximum cloud point pressure was observed at the composition of 0.226 wt% of sorbitan monopalmitate. On the other hand, as the temperatures and compositions of water increased, the cloud point pressures for ternary system containing 0.1 wt% of sorbitan monopalmitate increased significantly. For the ternary system of constant 0.2 wt% of water, the cloud point pressure curves show relatively flat according to the change of compositions of surfactant. The cloud point pressures increased when the temperatures and compositions of water increased.