• Title/Summary/Keyword: 이산화탄소 재활용

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A study on $CO_2$ absorption of concrete during life cycle of building (건물 생애주기 동안 콘크리트의 이산화탄소 흡수에 관한 연구)

  • Lee, Sang-Hyun;Lee, Han-Seoung;Song, Hoon
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.577-580
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    • 2008
  • Concrete absorbs $CO_2$ in the air because of carbonation. according to rising concern for lasting earth environment efforts of reducing greenhouse gas, especially co2, are occurred whole industry throughout the world. In this paper selected one building and computed amount of production and absorbtion of co2 during its lifecycle at concrete. In computing amount of absorbtion of co2 considered amount of absorbtion according to the area of concrete changing senarioes of servicelife(40,60,80 years) and deconstruct preiod(60,40,20 years). As a result, size of concrete and maintenance period of disused concrete work increasement of $CO_2$ as main factors. We came to the conclusion that maintenance period is more important than recycle of unused concrete as a method for reducing environmental load in architectural industry.

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Studies on the Recovery of Triglyceride from Used Shortening by Supercritical Fluid Extraction (초임계유체 추출에 의한 폐식용유의 재활용에 대한 기초연구)

  • Han, Byung-Seok;Yoon, Jung-Ro;Kwon, Young-An;Jung, Mun-Yhung;Kim, Kong-Hwan
    • Korean Journal of Food Science and Technology
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    • v.31 no.5
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    • pp.1300-1307
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    • 1999
  • Supercritical fluid extraction was applied to recycling triglyceride from used shortening. Used shortening and its fractions were analyzed with high performance size exclusion chromatography for their composition in triglycerides, polymer and low molecular weight compounds. Conjugated diene value and color of the fractions were also measured with a UV spectrophotometer and a colorimeter, respectively. Pressure and temperature ranges employed were $15{\sim}30$ MPa and $40{\sim}60^{\circ}C$, respectively. Concentration of fat in supercritical (SC) $CO_2$ ranged from $0.3\;X\;10^{-3}{\sim}7.4\;X10^{-3}(g\;fat/g\;CO_2)$. An exponential relation between concentration of fat in SC $CO_2$ and density was observed. Color of the extracts was light yellow which was very close to that of the fresh shortening. Low molecular weight compounds were preferentially concentrated in the initial fraction, while polymer was extracted in the final fraction. Conjugated diene value of the initial fractions was clearly lower than that of feed. It increased sharply as the polymer content in the fraction became significantly large.

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Desorption Characteristics of Grinding Oil from Swarf by using Supercritical Carbon Dioxide (초임계 이산화탄소를 이용한 스와프로부터 연마유 탈착 특성)

  • Yang, Jun Youl;Lee, Youn-Woo;Lim, Jong Sung
    • Clean Technology
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    • v.10 no.3
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    • pp.139-148
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    • 2004
  • The recovery of stainless steel fiber by removing cutting oil from grinding swarf, which is classified as specified wastes, was investigated. Swarf loaded with grinding oil was regenerated by supercritical carbon dioxide. And, the effects of temperature(313.15K-323.15K), pressure(10MPa-30MPa) on regeneration efficiency were studied. Regeneration effiency was increased as the pressure was increased. Also, at the same pressure, the experiments at higher temperature were more efficient for regeneration. The experiment results was predicted by applying a one-parameter mathematical model assuming linear desorption kinetics. The predicted value showed good agreement with experimental data.

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Economic Analysis of the Valuable Minerals Recycling in a Mobile Phone: Focusing on the Social Cost of Carbon (폐휴대전화 유용 광물 재활용의 사회‧경제적 효과 분석: 탄소를 중심으로)

  • Min Ki Choi;Jinsoo Kim
    • Environmental and Resource Economics Review
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    • v.33 no.3
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    • pp.263-289
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    • 2024
  • In this paper, we quantify the socio-economic impacts of recycling from a carbon social benefit perspective based on a life cycle assessment and economic evaluation of the printed circuit board (PCB) recycling process for waste mobile phones. In particular, we compare the metal recovery process through PCB recycling of waste mobile phones with the traditional metal mining and smelting process, and analyze the change in carbon dioxide emissions under two electricity generation mixes in 2018 and 2030. The analysis shows that for both gold and copper, PCB recycling generates 6.86 times and 3.69 times more carbon dioxide than traditional mining and smelting, respectively. However, when the 2030 electricity generation mix is applied, the amount of carbon dioxide emitted in the recycling process decreases by 44.72% and 44.65% for copper and gold recovery, respectively. This is due to the nature of the recycling process, which uses electricity as the main energy source. A cost-benefit analysis that includes the social cost of carbon dioxide shows a B/C of 1.95, indicating that recycling is economically feasible. However, this result does not take into account both the problem of securing a sufficient amount of waste PCBs and the social cost of the pollutants emitted by the recycling process. Based on the results of this study, it is expected that cost-benefit analyses reflecting the social cost of carbon and carbon dioxide emissions through life cycle assessment of the recycling process will continue to be actively conducted not only for PCB waste recycling, but also for the circular economy and recycling processes that have recently attracted attention.

Estimation of Carbon Flux caused by the shell re-treatment at coastal shellfish aquaculture fields in Korea (Review) (한국 연안 양식패류 패각 재활용을 통한 탄소수지 추정 (리뷰))

  • Young Cheol Park;Jae Won Yoo;Keun-Hyung Choi;Chang-Gun Lee;Hyejeong Kim
    • Journal of Wetlands Research
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    • v.25 no.1
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    • pp.1-13
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    • 2023
  • Coastal shellfish in the shallow aquaculture waters form carbon contained shells as they grow. The existing researches showed that carbon flux can be improved, if the shells are re-treated by the carbon stored methods. In the present study, firstly, the mechanism and the quantitative flux of carbon dioxide in the shellfish individual have been analyzed. The re-treated methods of the useful by-product in the shellfish aquaculture, shells, have been reviewed. Finally, the potential effects to reduce the greenhouse gas has been suggested, if the shells can be properly re-treated.

Eco-Packaging Technology (세미나 - 생분해성 에코 패키징 국내외 기술 및 산업화 동향)

  • (사)한국포장협회
    • The monthly packaging world
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    • s.201
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    • pp.118-128
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    • 2010
  • 전 세계적으로 녹색성장, 이산화탄소 절감, 지구온난화 문제 등이 보다 중요시되면서, 기존 규제 일변도 정책, 생분해 플라스틱 중심으로 빠르게 분해가 되는 소재로 진행되고 있던 에코패키징에 대한 패러다임이 변화되고 있다. PVC, 스티로폼 등 인체 무해성 관련 소재에 대한 강력한 규제가 시행되고 있으며, 생분해성 플라스틱 감량을 우선시하고 있다. 또한 강도, 생산성, 재활용 용이성 등 포장재의 기본 기능을 중시하면서 생분해 플라스틱을 이용한 일회용품에서 바이오 플라스틱을 중심으로 자동차, 화장품, 산업용 완충재, 멀칭필름, 문구 파일류 등 다양하고 포괄적인 분야로의 상품화 적용이 빠르게 되고 있다.

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Biological conversion of CO2 to CH4 in anaerobic fixed bed reactor under continuous operation (혐기성 고정층 생물반응기의 연속운전을 통한 이산화탄소의 메탄전환)

  • Kim, Jaehyung;Koo, Hyemin;Chang, Wonseok;Pak, Daewon
    • Journal of Energy Engineering
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    • v.22 no.4
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    • pp.347-354
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    • 2013
  • This study was carried out to examine different mole ratio of $H_2/CO_2$ and EBCT using the continuous system in the lab scale throughout biological methods with accumulated hydrogenotrophic methanogen that can convert $CO_2$ to $CH_4$. The experimental-based results with various gas mixtures of mole ratio of 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$), $H_2$ was converted more than 99% conversion rate. In case of $CO_2$, 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$) were $74.45{\pm}0.33%$, $95.8{\pm}10.7%$, respectively, in addition, the study was confirmed that the amount of $H_2$ was more needed than stoichiometric equations, where approach methods are empirical versus theoretical frameworks, for converting total $CO_2$. As such, we have noticed that $H_2$ was used for energy source of hydrogenotrophic methanogen for maintaining life. Regarding the results of the ratio of treatment by retention time, limitation of treatment capacity showed that $H_2$(99.9%) and $CO_2$(96.23%) at EBCT 3.3 hrs indicated stable conversion ratio, as well as appeared that methane production rate and $CO_2$ fixation rate were investigated $1.15{\pm}0.02m^3{\cdot}m^{-3}{\cdot}day^{-1}$ and $2.01{\pm}0.04kg{\cdot}m^{-3}{\cdot}day^{-1}$, respectively.

Propylene Carbonate Synthesis using Supercritical $CO_2$ and Ionic Liquid (초임계 이산화탄소와 이온성 액체를 이용한 Propylene Carbonate 합성)

  • Kim, Byeong-Heon;Jang, Sung-Hyeon;Min, Se-Ryeon;Kim, Hwa-Yong
    • Clean Technology
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    • v.17 no.1
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    • pp.37-40
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    • 2011
  • Some ionic liquids are suitable for catalysts and solvents which are applicable to $CO_2$ fixation reaction converting $CO_2$ to carbonate. Using the ionic liquids, the synthesis process will become greener and simpler because of easy catalyst recycling and unnecessary use of volatile and harmful organic solvents. In this work, the synthesis of propylene carbonate from propylene oxide using carbon dioxide and ionic liquids were measured at high pressures up to ~140 bar and at temperatures between $60^{\circ}C$ and $80^{\circ}C$. As a results, we found the optimum condition and obtained the maximum yield under that condition.

Working partial pressure of $CO_2$ gas in aqueous solution

  • Kim Dong-Su
    • Resources Recycling
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    • v.14 no.4 s.66
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    • pp.47-52
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    • 2005
  • Carbonate species in aqueous solution play an important role in the determination of chemical properties of water in relation with alkalinity, buffer capacity, biological productivity, and so on. These compounds also have reactive characteristics such as interphasal reactions between solid, liquid, and gas phases. In the absence of solid materials, the total amount and relative abundance of each carbonate species are directly influenced by the partial pressure of $CO_2$ gas in the atmosphere, which in turn significantly affects the properties of aquatic system. In the water/wastewater treatment process along with the wastes treatment and recycling process which occurring in aquatic environment, it is essential to figure out its characteristics for their optimization and one of its most influential features upon these processes is determined by carbonate species. To understand the fundamental aspect of the relationship between the partial pressure of $CO_2$ gas and chemical features of water, especially pH, the working partial pressure of pure $CO_2$ gas that produced by contacting the dry ice with water has been estimated based on equilibrium calculation. The equilibrium constants for the dissociation ot carbonic acid were determined using van't Hoff equation and the distribution diagram of carbonate species according to the pH has been constructed to substantiate the results of equilibrium calculation. The estimated working partial pressure of pure $CO_2$ gas was found to be a function of the concentration of carbonates in solution, which suggesting that Prior evaluation of the working partial pressure of gas is essential for a better understanding of aquatic interactions.

Applications and prospect of CDM project through recycling of inorganic waste (무기질(無機質) 폐기물(廢棄物)의 재활용(再活用)을 통한 CDM 사업(事業) 적용사례(適用事例) 및 전망(展望) - 시멘트 산업(産業)을 중심(中心)으로 -)

  • Cho, Jin-Sang;Cho, Kye-Hong;Ahn, Ji-Whan;Um, Seong-Il;Yeon, Kyu-Seok
    • Resources Recycling
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    • v.20 no.2
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    • pp.3-15
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    • 2011
  • Current, Registration fields of CDM projects are being conducted in a variety of parts such as mostly energy, chemical processing and manufacturing processes. However, there are not many CDM project registrations by recycling of inorganic waste. In this paper, analysis abroad CDM project and applications in order to review possibility of CDM project registration through the recycling of domestic inorganic waste were investigated. As a results, registered case of CDM project by inorganic waste recycling was researched to registrate in raw material alternative field of cement industry that inorganic waste can be used in large quantities. Application prospects of CDM project in Korea will be possible to analysis industrial scale, industry using inorganic raw materials, green house gas emissions and inorganic waste generated in large quantities.